CN106619159B - The method for improving water-in-oil type creams viscosity stability - Google Patents
The method for improving water-in-oil type creams viscosity stability Download PDFInfo
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- CN106619159B CN106619159B CN201710016782.1A CN201710016782A CN106619159B CN 106619159 B CN106619159 B CN 106619159B CN 201710016782 A CN201710016782 A CN 201710016782A CN 106619159 B CN106619159 B CN 106619159B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
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- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
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- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of methods for improving water-in-oil type creams viscosity stability.The method of raising water-in-oil type creams viscosity stability of the invention in the water-in-oil type creams by adding hydrophilic smectites modifying agent and lipophilic organic clay class modifying agent, wherein the dosage of the smectites modifying agent accounts for the 0.01-5% of the water-in-oil type creams gross mass, and the dosage of the organic clay class modifying agent accounts for the 0.01-5% of the water-in-oil type creams gross mass.Compared to the prior art, the method provided by the invention for improving water-in-oil type creams viscosity stability in the water-in-oil type creams by adding hydrophilic smectites modifying agent and lipophilic organic clay class modifying agent, water-in-oil type creams viscosity stability can be significantly improved, prepared creams performance is stablized, and rheological property is good.
Description
Technical field
The present invention relates to technical field of skin care, and in particular to a kind of side for improving water-in-oil type creams viscosity stability
Method.
Background technique
Water-in-oil type (W/O) system refers to grease etc. that for foreign minister or decentralized medium, hydroaropic substance is interior phase or dispersion
Phase, hydroaropic substance disperse system in the oil in the form of drop etc.；It is relatively broad in products applications such as BB frosts, but opened in formula
In hair and technique production, the problem of being frequently encountered dispensing viscosity stability, the differences in viscosity opposite sex is big, resistance between being mainly reflected in batch
Situations such as viscosity change is obvious after heat is cold-resistant, quality risk is higher.Through analyzing, it is believed that be the rheology modifier product due to oily phase
The opposite water phase rheology modifier of kind is not abundant enough, and strong without water phase rheology modifier in terms of the effect for preventing interior phase aggregation.
Summary of the invention
The purpose of the present invention is overcoming above-mentioned technical problem, a kind of side for improving water-in-oil type creams viscosity stability is provided
Method can keep the viscosity stabilization between batch, and product itself is tried through cold and hot stability in the production process of water-in-oil type creams
It is relatively stable to test rear viscosity.
Technical scheme is as follows:
A method of water-in-oil type creams viscosity stability is improved, it is hydrophilic by being added in the water-in-oil type creams
The smectites modifying agent and lipophilic organic clay class modifying agent of property, wherein the dosage of the smectites modifying agent accounts for institute
The 0.01-5% of water-in-oil type creams gross mass is stated, it is total that the dosage of the organic clay class modifying agent accounts for the water-in-oil type creams
The 0.01-5% of quality.
Preferably, the dosage of the smectites modifying agent accounts for the 0.5% of the water-in-oil type creams gross mass, described to have
The dosage of machine clay class modifying agent accounts for the 0.5% of the water-in-oil type creams gross mass.
Preferably, the smectites modifying agent include in lithium magnesium silicate, aluminium-magnesium silicate, hectorite or bentonite at least
It is a kind of.
Preferably, the organic clay class modifying agent includes -18 bentonite of distearyl dimethylammonium hectorite or quaternary ammonium salt
At least one of.
Preferably, the water-in-oil type creams further include the component of following mass percent:
A phase: lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone
0.5-2%
- 3 diisopstearate 0.5-1.5% of polyglycereol
Titanium dioxide 7-8%
77492 0.05-0.6% of CI
77491 0.02-0.2% of CI
- 6 polyricinoleate 0.1-1% of polyglycereol
Carbonic acid dioctyl ester 2-4%
Ring five dimethyl silicone polymer 10-18%
Caprylic/capric triglyceride 4-6%；
B phase: glycerol 5-10%
EDETATE SODIUM 0.01-1%
Niacinamide 0.1-3%
Sodium chloride 0.1-1.5%；
C phase: Phenoxyethanol, Chlorphenesin and glycerol 0.1-0.5%；
D phase: essence 0.01-1%；
E phase: 1,3-PD 2-4%
Deionized water surplus.
Wherein CI 77492 and CI 77491 is colorant.
Compared to the prior art, the method provided by the invention for improving water-in-oil type creams viscosity stability passes through described
Hydrophilic smectites modifying agent and lipophilic organic clay class modifying agent are added in water-in-oil type creams, can significantly be mentioned
High water-in-oil type creams viscosity stability, prepared creams performance are stablized, and rheological property is good.
Specific embodiment
Below with reference to embodiment, the present invention is described in further detail, and embodiments of the present invention are not limited thereto.
The method provided by the invention for improving water-in-oil type creams viscosity stability passes through in the water-in-oil type creams
Hydrophilic smectites modifying agent and lipophilic organic clay class modifying agent are added, wherein the smectites modifying agent
Dosage accounts for the 0.01-5% of the water-in-oil type creams gross mass, and the dosage of the organic clay class modifying agent accounts for the Water-In-Oil
The 0.01-5% of type creams gross mass.
Embodiment 1-3, formula are shown in Table 1.
Table 1
The smectites modifying agent is distinguished as the component of E phase, the organic clay class modifying agent as the component of A phase
It is added in the preparation process of the water-in-oil type creams, wherein the smectites modifying agent of embodiment 1 are as follows: hectorite, it is organic
Clay class modifying agent are as follows: distearyl dimethylammonium hectorite；The smectites modifying agent of embodiment 2 are as follows: lithium magnesium silicate, it is organic glutinous
Great soil group modifying agent are as follows: -18 bentonite of quaternary ammonium salt；The smectites modifying agent of embodiment 3 are as follows: bentonite, organic clay class are modified
Agent are as follows: distearyl dimethylammonium hectorite.Comparative example 1 only add organic clay class modifying agent distearyl dimethylammonium hectorite and
Smectites modifying agent is not added, and it is modified without adding organic clay class that comparative example 2 only adds smectites modifying agent hectorite
Agent.Embodiment 1-3 and comparative example 1-2's the preparation method is as follows:
Step S1, A phase each component high speed homogenization is milled 30min, is warming up to 80 DEG C, heat preservation；
Step S2, E phase is pre-mixed, and is warming up to 80 DEG C, high speed homogenization 20 minutes；
Step S3, B phase each component is put under stiring in E phase, high speed homogenization 2 minutes；
Step S4, E phase is slowly added to A phase under stiring, high speed homogenization 10 minutes；
Step S5, C phase is added, stirring is cooled to 40 DEG C, and D phase is added, is stirred until homogeneous, and detection qualification can discharge.
The test of water-in-oil type creams viscosity stability
The creams of preparation are divided into three parts and are individually positioned in 6 months progress viscosity tracking and testings at -15 DEG C, 25 DEG C, 45 DEG C.
Test method uses BROOKFIELD DV2T RVT JO type digital display viscosity apparatus, and in 04# rotor, 12rpm is carried out under the conditions of 25 DEG C
Test, specific test result are shown in Table 2.
Table 2
From table 2 it can be seen that by adding hydrophilic smectites modifying agent and lipophilic organic glutinous in creams
After great soil group modifying agent, storage viscosity change is small at each temperature, has good stability, and only adds hydrophilic smectites modifying agent
Or lipophilic organic clay class modifying agent, then viscosity stability differs greatly, and the viscosity error range of comparative example 1 has exceeded
± 30%, even there is layering equistability exception in comparative example 2, illustrates the addition parent provided by the invention in water-in-oil type creams
The method of aqueous smectites modifying agent and lipophilic organic clay class modifying agent is to the stabilization for improving water-in-oil type creams
Property has very great help.
Compared to the prior art, the method provided by the invention for improving water-in-oil type creams viscosity stability passes through described
Hydrophilic smectites modifying agent and lipophilic organic clay class modifying agent are added in water-in-oil type creams, can significantly be mentioned
High water-in-oil type creams viscosity stability, prepared creams performance are stablized, and rheological property is good.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair
Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (5)
1. a kind of method for improving water-in-oil type creams viscosity stability, which is characterized in that by the water-in-oil type creams
The hydrophilic smectites modifying agent of middle addition and lipophilic organic clay class modifying agent, wherein the smectites modifying agent
Dosage account for the 0.01-5% of the water-in-oil type creams gross mass, the dosage of the organic clay class modifying agent accounts for the oil packet
The 0.01-5% of water type creams gross mass.
2. the method according to claim 1 for improving water-in-oil type creams viscosity stability, which is characterized in that described cover takes off
The dosage of stone class modifying agent accounts for the 0.5% of the water-in-oil type creams gross mass, and the dosage of the organic clay class modifying agent accounts for
The 0.5% of the water-in-oil type creams gross mass.
3. the method according to claim 1 for improving water-in-oil type creams viscosity stability, which is characterized in that described cover takes off
Stone class modifying agent includes at least one of lithium magnesium silicate, aluminium-magnesium silicate, hectorite or bentonite.
4. the method according to claim 1 or 3 for improving water-in-oil type creams viscosity stability, which is characterized in that described
Organic clay class modifying agent includes at least one of -18 bentonite of distearyl dimethylammonium hectorite or quaternary ammonium salt.
5. the method according to claim 1 for improving water-in-oil type creams viscosity stability, which is characterized in that the oil packet
Water type creams further include the component of following mass percent:
A phase: lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone 0.5-2%
Polyglyceryl-3 diisostearate 0.5-1.5%
Titanium dioxide 7-8%
77492 0.05-0.6% of CI
77491 0.02-0.2% of CI
- 6 polyricinoleate 0.1-1% of polyglycereol
Carbonic acid dioctyl ester 2-4%
Ring five dimethyl silicone polymer 10-18%
Caprylic/capric triglyceride 4-6%；
B phase: glycerol 5-10%
EDETATE SODIUM 0.01-1%
Niacinamide 0.1-3%
Sodium chloride 0.1-1.5%；
C phase: Phenoxyethanol, Chlorphenesin and glycerol 0.1-0.5%；
D phase: essence 0.01-1%；
E phase: 1,3-PD 2-4%
Deionized water surplus.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107308012A (en) * | 2017-06-30 | 2017-11-03 | 广州澳希亚实业有限公司 | Water-in-oil sunscreen emulsion with low viscosity and good suspension capacity and preparation method thereof |
| CN108550767A (en) * | 2018-04-28 | 2018-09-18 | 丹阳克帕斯特能源科技有限公司 | A kind of zinc load battery diagram modification method |
| CN110227040B (en) * | 2018-06-14 | 2022-09-06 | 广州雅纯化妆品制造有限公司 | Wax-based stick-shaped cosmetic capable of discharging water and preparation method thereof |
| CN111467274A (en) * | 2020-04-30 | 2020-07-31 | 深圳市垂纶远翔科技有限责任公司 | Eye cream for quickly removing wrinkles and bags under eyes |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US5165915A (en) * | 1986-07-24 | 1992-11-24 | Shiseido Company Ltd. | Spherical clay mineral powder, process for production thereof and composition containing the same |
| JPS6343665A (en) * | 1986-08-11 | 1988-02-24 | 株式会社資生堂 | Deodorant |
| CN1238676A (en) * | 1996-11-27 | 1999-12-15 | 普罗克特和甘保尔公司 | Mascara compositions having improved wear and beauty benefits |
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Address after: Room 3007, 888 Yuncheng West Road, Baiyun District, Guangzhou, Guangdong 510420 Patentee after: Guangzhou Anxin Cosmetics Co.,Ltd. Address before: Room 3007, 888 Yuncheng West Road, Baiyun District, Guangzhou, Guangdong 510420 Patentee before: HANHOO COSMETICS CO.,LTD. |
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Effective date of registration: 20220617 Address after: Room 189, first floor, No. 2429, Xingang East Road, Haizhu District, Guangzhou, Guangdong 510000 Patentee after: Guangzhou Zhongzhuang Meiye Cosmetics Co.,Ltd. Address before: Room 3007, 888 Yuncheng West Road, Baiyun District, Guangzhou, Guangdong 510420 Patentee before: Guangzhou Anxin Cosmetics Co.,Ltd. |