CN110204982A - A kind of mosquito-proof coating of environmental protection and preparation method thereof - Google Patents

A kind of mosquito-proof coating of environmental protection and preparation method thereof Download PDF

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Publication number
CN110204982A
CN110204982A CN201910510888.6A CN201910510888A CN110204982A CN 110204982 A CN110204982 A CN 110204982A CN 201910510888 A CN201910510888 A CN 201910510888A CN 110204982 A CN110204982 A CN 110204982A
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CN
China
Prior art keywords
mosquito
environmental protection
proof coating
parts
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910510888.6A
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Chinese (zh)
Inventor
杨佃辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DONGGUAN DABAO CHEMICAL PRODUCTS Co Ltd
Original Assignee
DONGGUAN DABAO CHEMICAL PRODUCTS Co Ltd
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Priority to CN201910510888.6A priority Critical patent/CN110204982A/en
Publication of CN110204982A publication Critical patent/CN110204982A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to mosquito-proof paint fields, more particularly to a kind of mosquito-proof coating of environmental protection, the mosquito-proof coating of environmental protection includes following components in parts by weight: 20-30 parts of water, 0.1-1 parts of dispersing agent, 0.1-1 parts of defoaming agent, 1-20 parts of titanium dioxide, 1-20 parts of calcium carbonate, 0.1-1 parts of coalescing agent, 0.1-1 parts of antifreeze, 0.1-1 parts of Ph buffer, thickener 0.1-1,20-40 parts of biology base acrylic emulsion, 1-10 parts of culicifuge.The mosquito-proof coating of environmental protection of the invention has environmental protection characteristic, is free of anaphylactogen, and mosquito repelling rate is high, fills up the domestic blank for lacking mosquito-proof coating.

Description

A kind of mosquito-proof coating of environmental protection and preparation method thereof
Technical field
The present invention relates to mosquito-proof paint fields, and in particular to a kind of mosquito-proof coating of environmental protection and preparation method thereof.
Background technique
Mosquito is a kind of fine winged insect with sucking mouth parts.Usually the text of female is using blood as food.It sucks blood Female mosquito be the other pathogens such as dengue fever, malaria, yellow fever, filariasis, encephalitis B intermediate host.
The method of expelling mosquito mainly has mosquito-repellent incense, Mosquito killer lamp etc. at present.Contain up to 4 kinds of objects being harmful to the human body in mosquito-repellent incense Matter, while other than these types of substance, also contain a large amount of organic filler, adhesive, fuel and other additives, can just make mosquito Perfume (or spice) can be smouldered with nonflame.These substances contained in mosquito-repellent incense are not only harmful to human body, and polluted environment.Although Mosquito killer lamp is more Environmental protection, but limitation is also more, needs again to use in dark, static environment.In the more hot summer of mosquito, nearly all Can open fan or empty day, caused by air-flow variation will affect the trap effect of Mosquito killer lamp, while Mosquito killer lamp carries out continuing work Energy consumption when making is also higher.Not yet there is the mosquito-proof coating with repelling effect in country's coating industry at present, exists in the field Certain blank.
Summary of the invention
It is an object of that present invention to provide a kind of mosquito-proof coating of environmental protection, which has repelling effect, has filled up the field Blank.
The technical scheme is that a kind of mosquito-proof coating of environmental protection, the mosquito-proof coating of environmental protection include in parts by weight with Lower component:
Preferably, the dispersing agent is the dispersing agent of Dow Chemical's production, the model of the dispersing agent product are as follows: 731A。
Preferably, the defoaming agent is mineral oil defoaming agent.
Preferably, the coalescing agent is 12 coalescing agent of alcohol ester.12 coalescing agent of alcohol ester, chemistry entitled 2,2, 4- trimethyl -1,3- pentanediol mono isobutyrate, is colourless transparent liquid.
Preferably, the thickener is polyacrylate-type thickeners.
Preferably, the biology base acrylic emulsion is the lotion of Dow Chemical's production, the product type of the lotion Number are as follows: RN1000V.
Preferably, the culicifuge is Permethrin.Permethrin is selected to have no stimulation of the skin as culicifuge.
The present invention also provides a kind of preparation method of mosquito-proof coating of environmental protection, the preparation method the following steps are included:
(1) it weighs: weighing water by the parts by weight, dispersing agent, defoaming agent, titanium dioxide, calcium carbonate, coalescing agent, resists Freeze agent, Ph buffer, thickener, biological base emulsion, culicifuge;
(2) water, dispersing agent, defoaming agent of weighing are added into vessel, is mixed, mixing speed 400- 600rmp, when stirring, are 5 minutes a length of, obtain mixture A;
(3) continue the mixture A into the vessel and the thickener weighed, Ph buffer is added, titanium dioxide, carbon is then added Sour calcium, is mixed, mixing speed 1100-1300rmp, and stirring duration is about 30 minutes, and temperature maintains less than 50 degree, Until the mixture fineness in the vessel obtains mixture B less than 50 millimeters;
(4) continue the mixture B into the vessel and the coalescing agent weighed, antifreeze is added, be mixed, stirred Speed is 700-900rmp, and when stirring is 5 minutes a length of, obtains mixture C;
(5) continue the mixture C into the vessel and the biological base emulsion weighed, culicifuge is added, be mixed, stirred Mixing speed is 120-140rmp, and when stirring is 15 minutes a length of, obtains the mosquito-proof coating of environmental protection.
Compared with prior art, the present invention have it is following the utility model has the advantages that
1, the mosquito-proof coating of environmental protection of the invention has environmental protection characteristic, and formula material is free of formaldehyde, volatile organic matter, warp Test can reach the standard of advanced U.S.'s green guardian gold medal certification;
2, the biology base acrylic emulsion that the present invention uses makes the anti-line coating of environmental protection have the low release of coating, anti-formaldehyde Function, have higher Bio-based content, meet the requirement of high-performance coating, the effect of mosquito repellent is played in combination together with culicifuge Fruit, the two are mutually mixed, and biology base acrylic emulsion plays the role of firm culicifuge, and mosquito repellent time is lasting, through testing to mosquito The scattering ratio of worm is up to 95% or more;
3, the mosquito-proof coating of environmental protection of the invention is not added with the anaphylactogens such as anti-corrosion, mould proof, reduce people by skin contact or Person's respiratory tract sucks so as to cause anaphylactoid probability.
Specific embodiment
The invention will be further described in conjunction with the embodiments.
Embodiment 1:
The present invention also provides a kind of preparation method of mosquito-proof coating of environmental protection, the preparation method the following steps are included:
(1) it weighs: weighing 20 parts of water, 0.1 part of dispersing agent, 0.1 part of defoaming agent, 1 part of titanium dioxide, calcium carbonate in parts by weight 1 part, 0.1 part of coalescing agent, 0.1 part of antifreeze, 0.1 part of Ph buffer, 0.1 part of thickener, biological 20 parts of base emulsion, culicifuge 1 part;
Wherein, dispersing agent is the dispersing agent 731A of Dow Chemical's production;Defoaming agent is mineral oil defoaming agent;Film forming Auxiliary agent is 12 coalescing agent of alcohol ester;Thickener is polyacrylate-type thickeners;Biology base acrylic emulsion is DOW Chemical The lotion of company's production, the product type of the lotion are as follows: RN1000V;Culicifuge is Permethrin, and the above raw material are buying It obtains.
(2) water, dispersing agent, defoaming agent of weighing are added into vessel, is mixed, mixing speed 500rmp, A length of 5 minutes when stirring, mixture A is obtained;
(3) continue the mixture A into the vessel and the thickener weighed, Ph buffer is added, titanium dioxide, carbon is then added Sour calcium, is mixed, mixing speed 1200rmp, and stirring duration is about 30 minutes, and temperature maintains 45 degree, until the device Mixture fineness in ware obtains mixture B less than 50 millimeters;
(4) continue the mixture B into the vessel and the coalescing agent weighed, antifreeze is added, be mixed, stirred Speed is 800rmp, and when stirring is 5 minutes a length of, obtains mixture C;
(5) continue the mixture C into the vessel and the biological base emulsion weighed, culicifuge is added, be mixed, stirred Mixing speed is 130rmp, and when stirring is 15 minutes a length of, obtains the mosquito-proof coating of environmental protection.
Embodiment 2:
The present embodiment 2 the difference from embodiment 1 is that: step (1) weigh: in parts by weight weighing 25 parts of water, dispersing agent 0.5 part, 0.5 part of defoaming agent, 10 parts of titanium dioxide, 10 parts of calcium carbonate, 0.5 part of coalescing agent, 0.5 part of antifreeze, Ph buffer 0.5 Part, 0.5 part of thickener, biological 30 parts of base emulsion, 5 parts of culicifuge.Remaining step is same as Example 1.
Embodiment 3:
The present embodiment 3 the difference from embodiment 1 is that: step (1) weigh: in parts by weight weighing 30 parts of water, dispersing agent 1 Part, 1 part of defoaming agent, 20 parts of titanium dioxide, 20 parts of calcium carbonate, 1 part of coalescing agent, 1 part of antifreeze, 1 part of Ph buffer, thickener 1 Part, biological 40 parts of base emulsion, 10 parts of culicifuge.Remaining step is same as Example 1.
Using embodiment 2 as test case, following test is carried out: one piece of blank template, one piece of painting are put into enclosed environment There is the template of the mosquito-proof coating of the environmental protection of the embodiment of the present invention 2, is put into 107 mosquitoes, after 5 minutes, records and stopped on two pieces of templates The quantity of mosquito subtracts mosquito-proof coating template number using the number of blank sample, and obtained result obtains mosquito repellent divided by blank template number Rate is 96%, illustrates that the present invention has good repelling effect.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected Protect range limitation, those skilled in the art should understand that, can modify to technical solution of the present invention or Equivalent replacement, without departing from the spirit and scope of technical solution of the present invention.

Claims (8)

1. a kind of mosquito-proof coating of environmental protection, which is characterized in that the mosquito-proof coating of environmental protection includes following components in parts by weight:
2. the mosquito-proof coating of environmental protection as described in claim 1, it is characterised in that:
The dispersing agent is the dispersing agent of Dow Chemical's production, the product type of the dispersing agent are as follows: 731A.
3. the mosquito-proof coating of environmental protection as described in claim 1, it is characterised in that:
The defoaming agent is mineral oil defoaming agent.
4. the mosquito-proof coating of environmental protection as described in claim 1, it is characterised in that:
The coalescing agent is 12 coalescing agent of alcohol ester.
5. the mosquito-proof coating of environmental protection as described in claim 1, it is characterised in that:
The thickener is polyacrylate-type thickeners.
6. the mosquito-proof coating of environmental protection as described in claim 1, it is characterised in that:
The biology base acrylic emulsion is the lotion of Dow Chemical's production, the product type of the lotion are as follows: RN1000V。
7. the mosquito-proof coating of environmental protection as described in claim 1, it is characterised in that:
The culicifuge is Permethrin.
8. a kind of preparation method of such as described in any item mosquito-proof coating of environmental protection of claim 1-7, which is characterized in that including following Step:
(1) weigh: by the parts by weight weigh water, dispersing agent, defoaming agent, titanium dioxide, calcium carbonate, coalescing agent, antifreeze, Ph buffer, thickener, biological base emulsion, culicifuge;
(2) water, dispersing agent, defoaming agent of weighing are added into vessel, is mixed, mixing speed 400-600rmp, A length of 5 minutes when stirring, mixture A is obtained;
(3) continue the mixture A into the vessel and the thickener weighed, Ph buffer is added, titanium dioxide, carbonic acid is then added Calcium is mixed, mixing speed 1100-1300rmp, and stirring duration is about 30 minutes, and temperature maintains less than 50 degree, directly Mixture fineness in the vessel obtains mixture B less than 50 millimeters;
(4) continue the mixture B into the vessel and the coalescing agent weighed, antifreeze is added, be mixed, mixing speed For 700-900rmp, when stirring, is 5 minutes a length of, obtains mixture C;
(5) continue the mixture C into the vessel and the biological base emulsion weighed, culicifuge is added, be mixed, stirring speed Degree is 120-140rmp, and when stirring is 15 minutes a length of, obtains the mosquito-proof coating of environmental protection.
CN201910510888.6A 2019-06-13 2019-06-13 A kind of mosquito-proof coating of environmental protection and preparation method thereof Pending CN110204982A (en)

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CN201910510888.6A CN110204982A (en) 2019-06-13 2019-06-13 A kind of mosquito-proof coating of environmental protection and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110746825A (en) * 2019-09-17 2020-02-04 鳄鱼制漆(上海)有限公司 Inorganic nano silicon dioxide hybrid bio-based acrylic emulsion finish paint and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102675990A (en) * 2012-04-20 2012-09-19 北京展辰化工有限公司 Biodegradable odorless emulsion paint and preparation method thereof
CN104650661A (en) * 2013-11-18 2015-05-27 上海三银制漆有限公司 Mosquito-repelling aqueous interior wall paint and preparation method thereof
CN109666349A (en) * 2017-10-14 2019-04-23 梁秋云 A kind of mosquito-proof self-cleaning exterior wall emulsion paint coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102675990A (en) * 2012-04-20 2012-09-19 北京展辰化工有限公司 Biodegradable odorless emulsion paint and preparation method thereof
CN104650661A (en) * 2013-11-18 2015-05-27 上海三银制漆有限公司 Mosquito-repelling aqueous interior wall paint and preparation method thereof
CN109666349A (en) * 2017-10-14 2019-04-23 梁秋云 A kind of mosquito-proof self-cleaning exterior wall emulsion paint coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110746825A (en) * 2019-09-17 2020-02-04 鳄鱼制漆(上海)有限公司 Inorganic nano silicon dioxide hybrid bio-based acrylic emulsion finish paint and preparation method and application thereof

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Application publication date: 20190906