CN105456052A - Skin care composition - Google Patents
Skin care composition Download PDFInfo
- Publication number
- CN105456052A CN105456052A CN201510988160.6A CN201510988160A CN105456052A CN 105456052 A CN105456052 A CN 105456052A CN 201510988160 A CN201510988160 A CN 201510988160A CN 105456052 A CN105456052 A CN 105456052A
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- skin care
- care compositions
- gellan gum
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/044—Suspensions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/33—Free of surfactant
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to a skin care composition. The skin care composition is prepared from the following raw materials in percentage by mass: 0.01 to 2 percent of gellan gum; 0.01 to 2 percent of xanthan gum; 0.001 to 15 percent of liquid grease; 0 to 20 percent of assistant; the balance of water, wherein the mass ratio of the xanthan gum to the gellan gum is 1 to (0.5 to 10), and the mass ratio of the sum of the xanthan gum and the gellan gum to the liquid grease is 1 to (0.02 to 50); the liquid grease consists of high-density liquid grease with the density of 1.0 to 1.2g/ml, and low-density liquid grease with the density being less than 1.0g/ml; the mass of the high-density liquid grease is not less than 40 percent of the total mass of the liquid grease; the skin care composition provided by the invention has no surface active agent, so that the potential irritation of a surface active agent to skin is effectively avoided, and better reliability is realized, and the skin care composition provided by the invention is more moistening and fresher, free of greasy feel and good in smearing handfeel.
Description
Technical field
The present invention relates to cosmetic field, be specifically related to a kind of skin care compositions.
Background technology
Skin-protection product is through development for many years, derive much different skin protection categories, there are pure Oil soluble materials system, pure water soluble material system, W/O emulsion-type, O/W emulsion-type, in addition multiple emulsion system, often kind of different architecture has himself feature, also brings different experiences to consumer.The product of the skin care compositions of main flow mainly W/O emulsion-type and O/W emulsion-type in the market, this series products the skin quality different according to client can add the different oils and fats of different, the salubrious degree of content and corresponding functional raw material from demand.Comparatively speaking, this type of formulation types flexibility ratio is very high, can meet the needs of most of client's skin protection.
But, no matter be W/O emulsion or O/W emulsion, emulsifying agent must be contained in product, i.e. surfactant, surfactant can not be ignored the skin irritant potential risk of client, although along with the development of science and technology, increasing gentle emulsifying agent is had to introduce to the market, this can be more and more less to skin irritant risk, but for the consumer of skin sensitivity, this risk still can not be ignored.Constantly increasing the weight of particularly along with problems such as environmental pollution, photoaging, air pollutions, the consumer of skin sensitivity can become more responsive, and requiring the mildness of skin-protection product can be more and more higher; Therefore, need badly seek a kind of not containing the skin care compositions that the gentleness of surfactant is non-stimulated.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of skin care compositions is provided, any surfactant is not added in skin care compositions provided by the invention, effectively can avoid the potential stimulus that surfactant brings to skin, and there is good stability, skin care compositions of the present invention is more moist, salubriouser, without glutinous soapy feeling, smears good hand touch.
For achieving the above object, the present invention adopts following technical scheme:
A kind of skin care compositions, described skin care compositions is made up of following raw material by mass percentage:
Gellan gum 0.01 ~ 2%;
Xanthan gum 0.01 ~ 2%;
Liquid fat 0.001 ~ 15%;
Auxiliary agent 0 ~ 20%;
Surplus is water;
Wherein, the mass ratio of described xanthan gum and gellan gum is 1:0.5 ~ 10; The mass ratio of described xanthan gum and gellan gum sum and liquid fat is 1:0.02 ~ 50; Described liquid fat is that the low density liquid oils and fats that the high density liquid oils and fats of 1.0 ~ 1.2g/ml and density are less than 1.0g/ml forms by density; The quality of described high density liquid oils and fats is not less than 40% of liquid fat gross mass.
Liquid fat is the main component in skin care item; it can form hydrophobic film at skin surface; prevent the intrusion of harmful environmental material; the evaporation of skin surface moisture is suppressed time cold; prevent chapped skin; supplement the fat of skin necessity as the agent of mistake fat, thus protection skin reduces the friction of skin when massaging, play protection, moistening and soft skin effect in skin-protection product.When preparing the skin care item of W/O emulsion-type or O/W emulsion-type, in order to allow liquid fat can stable dispersion in aqueous phase, common way adds surfactant, change the interfacial tension between profit, make profit become to be integrated, and keep this relatively steady statue, if do not add surfactant by thickening agent, then stable suspension be cannot form, thus outward appearance and the result of use of skin care item affected; Gellan gum is the comparatively normal suspending agent used in beverage/food industry, it can be used for the solid particle of suspension special diameter, its suspension theory is that gellan gum is in the presence of water, cation lures that gellan gum is transformed into Double helix from random coil into, then assembled by Double helix and form land thus form gel, this gel has good suspending power, particularly to the solid particle of special diameter; Therefore, inventor attempts gellan gum to be applied in skin care compositions, but inventor finds when adding gellan gum aqueous solution in liquid fat, under the condition of not adding emulsifying agent, even if oils and fats is uniformly dispersed through special stirring technique, the liquid fat in the suspension system that gellan gum still can not be stable; And separately xanthan gum is joined also cannot be stable in skin care compositions suspension system in liquid fat.
And gellan gum, xanthan gum add to after in skin care compositions by inventor, discovery is not that the gellan gum of any addition and xanthan gum can both good suspension liquid oils and fatss, after numerous trial, inventor finds the suspension effect of the mass ratio of gellan gum and xanthan gum and the ratio regular meeting appreciable impact liquid fat between both sum and liquid fat: the too low meeting of content of gellan gum cannot stably suspension liquid oils and fats, and the too high levels of gellan gum can cause whole system too thickness, lose use value; Gellan gum and the mass ratio between xanthan gum sum and liquid fat too small, liquid fat too high levels can be caused, cannot suspension liquid oils and fats completely, and liquid fat elaioleucite can condense, and causes profit layering, unstable; And if mass ratio is excessive, relative liquid fat content is less, and the skin care compositions obtained just does not have actual application value; When the mass ratio of gellan gum and xanthan gum is 1:0.5 ~ 10, and the liquid fat in the present invention can be disperseed preferably when the mass ratio of xanthan gum and gellan gum sum and liquid fat is 1:0.02 ~ 50, obtain the suspension of uniform good stability.
Usually the liquid fat selected in this area be less than 1.0g/ml, select this type of liquid fat well to disperse mixing with regard to needing to add appropriate surfactant to make liquid fat and other component; And the potential stimulus that the present invention brings in order to avoid surfactant to skin, any surfactant is not added in the present invention, if but still all select density to be less than the liquid fat of 1.0g/ml, even if select the gellan gum of above-mentioned special ratios and mass fraction and xanthan gum to be also difficult to dispersion good for liquid fat; Inventor finds after numerous trial, when adding the dispersion of appropriate high density liquid oils and fats with regard to the whole liquid fat of promotion that can be good in the liquid fat being less than 1.0g/ml to density, and the density of high density liquid oils and fats between 1.0 ~ 1.2g/ml and mass fraction be not less than 40% better effects if, the density of high density liquid oils and fats is too high or its mass fraction is excessive, all can produce sedimentation, be unfavorable for dispersion.
Preferably, the mass ratio of described xanthan gum and gellan gum is 1:1 ~ 6.
Preferably, the mass ratio of described xanthan gum and gellan gum sum and liquid fat is 1:0.04 ~ 20.
Inventor has attempted high acyl gellan gum and low-acyl gellan gum when selecting gellan gum, found that the aqueous solution denseness of the gellan gum of high acyl group is very high, opaque, the colloid feel of formation is bad, and suspension effect is poor; And low-acyl gellan gum addition is little just can play good suspension effect, the gel shear shinning ability of formation is good, good fluidity, easy to use; Therefore preferably, described gellan gum is low-acyl gellan gum.
Preferably, the molecular weight of described gellan gum is 20 ~ 1,500,000 dalton, and further preferably, the molecular weight of described gellan gum is about 500,000 dalton.
Liquid fat of the present invention is the oils and fats of liquid condition at normal temperatures and pressures, and described low density liquid oils and fats is one or more in mineral grease, Vegetable oil lipoprotein, silicone oil or organic synthesis oils and fats; Preferably, described high density liquid oils and fats is one or more that TMS phenyl gathers in dimethicone, aminopropyl phenyl trimethicone, trimethyl silicane alcoxyl base esters of silicon acis.The consumption of the liquid fat in the present invention is preferably 0.1 ~ 10%, and it is dispersed in system with oil droplet form.
Except the above-described component of the present invention, the present invention can also have moisturizing, brilliant white containing other, compact or the skin care ingredient of the function such as reparation, pH adjusting agent, buffer agent can also be contained, electrolyte, antiseptic, chelating agen, attached pastil, essence solubilizing agent, attached toner, thickening agent, polymeric conditioner, plants essential oil etc.
Preferably, described plants essential oil is any one or its mixture in Flos Rosae Rugosae quintessence oil, chamomile essential oil, Cananga odorata quintessence oil, jasmin quintessence oil, Juniperus rigida Sieb.et Zucc. quintessence oil, tea tree ethereal oil.
Skin care compositions provided by the invention is in an inclined state can free-pouring liquid condition at normal temperatures, so that easily pour out from packaging, is unlikely to too rare or too thick and cannot uses.Preferably, the viscosity of described skin care compositions is more than or equal to 50mpa.s at normal temperatures, is less than or equal to 100000mpa.s.
Compared with prior art, the present invention has following beneficial effect:
Any surfactant is not added in skin care compositions provided by the invention, effectively prevent the potential stimulus that surfactant brings to skin, liquid fat in skin care compositions is dispersed in system with oil droplet form, can test through aging resistance, there will not be obvious oils and fats sedimentation, have good stability, skin care compositions of the present invention uses more moist, salubriouser, without glutinous soapy feeling, smears good hand touch; Skin care compositions appearance transparent of the present invention, has larger use value and market value.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be further described.These embodiments are only describe typical case of the present invention, but the present invention is not limited thereto.Test method used in following embodiment if no special instructions, is conventional method, the raw material used, reagent etc., if no special instructions, is the raw material and reagent that can obtain from commercial sources such as conventional markets.
Table 1: the formula of the skin care compositions of embodiment 1 ~ 3 and reference examples 1 ~ 5
The preparation method of the skin care compositions of embodiment 1 ~ 3 and reference examples 1 ~ 5 is as follows:
By the xanthan gum of component each in formula and gellan gum solution in water, add glycerol, 1 afterwards, 3 butanediols, hyaluronic acid, antiseptic, simultaneously by liquid fat Cyclomethicone, TMS phenyl gathers dimethicone density, mineral oil and quintessence oil (adding emulsifing thickener 305 in comparative example 4) and is pre-mixed evenly for subsequent use, then liquid fat is added in water tank, high-speed stirred 20min, i.e. obtained skin care compositions.
Embodiment 1 ~ 3 and reference examples 1 ~ 5 gained skin care compositions are carried out ocular estimate and aging resistance stability test; And the result of use of testing each skin care compositions on volunteer's skin carries out result of use evaluation; Method of testing is as follows, and test effect sees the following form 3 and table 4.
(1) outward appearance test:
Under room temperature 25 DEG C of conditions, the outward appearance of the test sample that detects by an unaided eye.
(2) aging resistance stability test
1. 49 DEG C of heat-resistant stability tests: be by after testing sample good seal, be placed in 49 ± 1 DEG C of calorstats, respectively through 48 hours, 7 days, the test in January, after testing, was placed in room temperature after 2 hours by test sample, observed the state of sample.
2. resistance to freezing stability test: be by after testing sample good seal, be placed in-15 ± 1 DEG C of calorstat, respectively through 48 hours, 7 days, the test in January, after testing, was placed in room temperature after 2 hours by test sample, observed the state of sample.
3. cold-resistant stability test: be by after testing sample good seal, be placed in 0 ~ 5 DEG C of calorstat, respectively through 48 hours, 7 days, the test in January, after testing, is placed in room temperature after 2 hours, the state of observation sample by test sample.
(3) patch test
By the routine subject of subject enrollment Standard Selection 30, select qualified patch material, sample is put into speckle examination device (amount of samples is 0.020 ~ 0.025g), control wells is that blank declines any material.Sample and blank are all affixed on the bent side of forearm of experimenter, gently press with palm and make it to stick equably on skin, continue 24h; Interval 30min after removal patch device, observes dermoreaction after impression disappears.
(4) result of use evaluation
Result of use evaluation mainly refers to by 20 aspiration triers through professional training, the sample of 80ul is applied to the back of the hand, mildly circle round with another and smear 8 times, then in the mode (0 ~ 5 point of marking, mark is higher, represent the texture of this product, spreadability, flexibility, absorbability, better with rear joyful sense) evaluate successively the texture of sample, spreadability, flexibility, absorbability, with rear joyful sense, its numerical value is higher, effect is better, concrete method of testing is as follows, and criterion is as following table 2:
1. texture:
Naked eye test sample appearance, gives a mark according to fancy grade;
2. spreadability:
0.2 gram of testing sample is being spread upon inboard arm, and refer to that abdomen is smeared sample and to be looped on arm telemechanical with middle finger, experience the spreadability of sample, faster drawout, spreadability is better, has sprawled score value higher.
3. flexibility:
Sample is spread upon after on skin, give a mark by the moisture feeling degree of doigte skin;
4. absorbability:
Sample is spread upon after on skin, after 30 seconds, the absorbed degree of assess sample;
5. with rear joyful sense:
Smear test sample and experience dermal sensation after 5 minutes, perceptually fancy grade marking.
Table 2 result of use evaluation criterion
。
Table 3 skin irritation and stability test and ocular estimate
。
The evaluation of table 4 result of use
。
As shown in Table 3, from the result of stability test, the skin-protection product that each embodiment prepares all has good stability, and at room temperature, through heat-resisting cold-resistant, the resistance to senile experiment such as to freeze, stability is all good.By contrast, the stability of comparative example 1,2,3,5 is all not so good.Owing to having good stability containing traditional emulsifing thickener 305 in comparative example 4; But owing to containing emulsifing thickener 305 in comparative example 4, it is comparatively large to the zest of skin, and as seen from the above table, when the skin-protection product in comparative example 4 is carried out patch experiment test, effect is poor.
As shown in Table 4, by above result of use evaluation, various embodiments of the present invention are significantly due to each comparative example in result of use, and the result of use of sunscreen composition provided by the invention is more excellent.
Claims (10)
1. a skin care compositions, is characterized in that, described skin care compositions is made up of following raw material by mass percentage:
Gellan gum 0.01 ~ 2%;
Xanthan gum 0.01 ~ 2%;
Liquid fat 0.001 ~ 15%;
Auxiliary agent 0 ~ 20%;
Surplus is water;
Wherein, the mass ratio of described xanthan gum and gellan gum is 1:0.5 ~ 10; The mass ratio of described xanthan gum and gellan gum sum and liquid fat is 1:0.02 ~ 50; Described liquid fat is that the low density liquid oils and fats that the high density liquid oils and fats of 1.0 ~ 1.2g/ml and density are less than 1.0g/ml forms by density; The quality of described high density liquid oils and fats is not less than 40% of liquid fat gross mass.
2. skin care compositions according to claim 1, it is characterized in that, the mass ratio of described xanthan gum and gellan gum is 1:1 ~ 6.
3. skin care compositions according to claim 1, it is characterized in that, the mass ratio of described xanthan gum and gellan gum sum and liquid fat is 1:0.04 ~ 20.
4. skin care compositions according to claim 1, it is characterized in that, described gellan gum is low-acyl gellan gum.
5. skin care compositions according to claim 4, it is characterized in that, the molecular weight of described gellan gum is 20 ~ 1,500,000 dalton.
6. skin care compositions according to claim 1, it is characterized in that, the molecular weight of described gellan gum is 500,000 dalton.
7. skin care compositions according to claim 1, it is characterized in that, described low density liquid oils and fats is one or more in mineral grease, Vegetable oil lipoprotein, silicone oil or organic synthesis oils and fats.
8. skin care compositions according to claim 7, it is characterized in that, described high density liquid oils and fats is one or more that TMS phenyl gathers in dimethicone, aminopropyl phenyl trimethicone, trimethyl silicane alcoxyl base esters of silicon acis.
9. skin care compositions according to claim 1, it is characterized in that, described auxiliary agent is one or more in wetting agent, brilliant white agent, renovation agent, pH adjusting agent, antiseptic, chelating agen, attached pastil, essence solubilizing agent, attached toner, thickening agent, polymeric conditioner or plants essential oil.
10. skin care compositions according to claim 1, it is characterized in that, the viscosity of skin care compositions at 25 DEG C is more than or equal to 50mpa.s, is less than or equal to 100000mpa.s.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510988160.6A CN105456052A (en) | 2015-12-25 | 2015-12-25 | Skin care composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510988160.6A CN105456052A (en) | 2015-12-25 | 2015-12-25 | Skin care composition |
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| CN105456052A true CN105456052A (en) | 2016-04-06 |
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| CN201510988160.6A Pending CN105456052A (en) | 2015-12-25 | 2015-12-25 | Skin care composition |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106109391A (en) * | 2016-06-22 | 2016-11-16 | 广州科玛生物科技股份有限公司 | A kind of potent moisture retention water and preparation method thereof |
| CN106176325A (en) * | 2016-09-07 | 2016-12-07 | 高宝化妆品（中国）有限公司 | A kind of moisturizing crystallite dew and preparation method thereof |
| CN106955246A (en) * | 2017-03-06 | 2017-07-18 | 广州奥蓓斯化妆品有限公司 | A kind of active crystallite dew of suspension oil droplet and preparation method thereof |
| CN107519024A (en) * | 2017-09-18 | 2017-12-29 | 上海家化联合股份有限公司 | A kind of alcohol-free mosquito repellent/anti-pruritic compositions and preparation method thereof |
| FR3142354A1 (en) * | 2022-11-29 | 2024-05-31 | L'oreal | COMPOSITION FOR THE CARE OF KERATIN MATERIALS |
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| CN103263371A (en) * | 2013-05-23 | 2013-08-28 | 江苏隆力奇生物科技股份有限公司 | Skin care product comprising nano tamanu oil emulsion |
| CN103284909A (en) * | 2013-05-29 | 2013-09-11 | 薛羽佳 | Emulsifying agent-free protective cream |
| CN103622901A (en) * | 2013-11-21 | 2014-03-12 | 广州立白企业集团有限公司 | Skin cleaner composition capable of regulating microecological balance of skin and preparation method thereof |
| CN104382758A (en) * | 2014-11-25 | 2015-03-04 | 广州神采化妆品有限公司 | Zero-added emulsion and preparation method thereof |
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2015
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| CN103263371A (en) * | 2013-05-23 | 2013-08-28 | 江苏隆力奇生物科技股份有限公司 | Skin care product comprising nano tamanu oil emulsion |
| CN103284909A (en) * | 2013-05-29 | 2013-09-11 | 薛羽佳 | Emulsifying agent-free protective cream |
| CN103622901A (en) * | 2013-11-21 | 2014-03-12 | 广州立白企业集团有限公司 | Skin cleaner composition capable of regulating microecological balance of skin and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106109391A (en) * | 2016-06-22 | 2016-11-16 | 广州科玛生物科技股份有限公司 | A kind of potent moisture retention water and preparation method thereof |
| CN106109391B (en) * | 2016-06-22 | 2018-09-11 | 广州科玛生物科技股份有限公司 | A kind of potent moisture retention water and preparation method thereof |
| CN106176325A (en) * | 2016-09-07 | 2016-12-07 | 高宝化妆品（中国）有限公司 | A kind of moisturizing crystallite dew and preparation method thereof |
| CN106955246A (en) * | 2017-03-06 | 2017-07-18 | 广州奥蓓斯化妆品有限公司 | A kind of active crystallite dew of suspension oil droplet and preparation method thereof |
| CN107519024A (en) * | 2017-09-18 | 2017-12-29 | 上海家化联合股份有限公司 | A kind of alcohol-free mosquito repellent/anti-pruritic compositions and preparation method thereof |
| CN107519024B (en) * | 2017-09-18 | 2020-04-28 | 上海家化联合股份有限公司 | Alcohol-free mosquito-repelling/itching-relieving composition and preparation method thereof |
| FR3142354A1 (en) * | 2022-11-29 | 2024-05-31 | L'oreal | COMPOSITION FOR THE CARE OF KERATIN MATERIALS |
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Application publication date: 20160406 |
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