CN110204940A - High-strength environment-friendly acrylic paint and preparation method thereof - Google Patents

High-strength environment-friendly acrylic paint and preparation method thereof Download PDF

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Publication number
CN110204940A
CN110204940A CN201910508519.3A CN201910508519A CN110204940A CN 110204940 A CN110204940 A CN 110204940A CN 201910508519 A CN201910508519 A CN 201910508519A CN 110204940 A CN110204940 A CN 110204940A
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China
Prior art keywords
parts
nano
agent
titanium dioxide
strength environment
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Pending
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CN201910508519.3A
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Chinese (zh)
Inventor
钱源
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Zhejiang Qian Jin Aerosol Products Co Ltd
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Zhejiang Qian Jin Aerosol Products Co Ltd
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Priority to CN201910508519.3A priority Critical patent/CN110204940A/en
Publication of CN110204940A publication Critical patent/CN110204940A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a kind of high-strength environment-friendly acrylic paints, are made from the following raw materials in parts by weight: 35-50 parts of acrylic resin, 10-20 parts of Nano-sized Ferric Oxide Powder, 1-3 parts of graphene, 10-15 parts of diatomite, 1-5 parts of nano-titanium dioxide, 0.5-2 parts of carboxymethyl cellulose, 1-3 parts of aluminium triphosphate, 5-10 parts of maleic acid, 3-5 parts of limonene, 0.1-2 parts of powder anticaking agent, 3-10 parts of coupling agent, 5-10 parts of dispersing agent, 1-5 parts of titanium dioxide.The high-strength environment-friendly acrylic paint has preferable antiseptic property, while improving mechanical strength, and impact strength improves, and enhances the adhesive force on surface, has popularizing value.

Description

High-strength environment-friendly acrylic paint and preparation method thereof
Technical field:
The present invention relates to aerosol preparations technical field more particularly to a kind of high-strength environment-friendly acrylic paint and its preparation sides Method.
Background technique:
Currently, one is solvent-type acrylic paint, another kind is water soluble acrylic acid there are mainly two types of acrylic paints in the market Paint, solvent-type acrylic paint and water soluble acrylic acid paint respectively have advantage and disadvantage.Solvent-type acrylic paint surface-brightening, water resistance and attachment Power is good, has preferable outdoor durable, but it contains a large amount of organic solvent, will cause harm to human body and environment;Water Although without organic solvent in property acrylic paint, the defects of it is there are slow drying speed, adhesive force is low, poor heat resistance.
Summary of the invention:
The purpose of the present invention is in view of the drawbacks of the prior art, provide a kind of high-strength environment-friendly acrylic paint and its preparation side Method improves antiseptic property, improves weather proof performance, improves integral strength, to improve construction rate, extends and uses the longevity Life.
The present invention is achieved through the following technical solutions:
A kind of high-strength environment-friendly acrylic paint, is made from the following raw materials in parts by weight: 35-50 parts of acrylic resin, nano oxygen Change iron powder 10-20 parts, 1-3 parts of graphene, 10-15 parts of diatomite, 1-5 parts of nano-titanium dioxide, carboxymethyl cellulose 0.5-2 Part, is divided 1-3 parts of aluminium triphosphate, 5-10 parts of maleic acid, 3-5 parts of limonene, 0.1-2 parts of powder anticaking agent, 3-10 parts of coupling agent 5-10 parts of powder, 1-5 parts of titanium dioxide, surplus are deionized water.
In a preferred embodiment of the present invention, the high-strength environment-friendly acrylic paint is preferably by the raw material of following parts by weight It is made: 36.7 parts of acrylic resin, 13.9 parts of Nano-sized Ferric Oxide Powder, 1.5 parts of graphene, 12.5 parts of diatomite, nanometer titanium dioxide 4.1 parts of titanium, 1.3 parts of carboxymethyl cellulose, 1.9 parts of aluminium triphosphate, 8.4 parts of maleic acid, 3.6 parts of limonene, powder anticaking agent 0.8 part, 5.2 parts of coupling agent, 5.7 parts of dispersing agent, 4.2 parts of titanium dioxide, surplus be deionized water.
Preferably, the coupling agent is silane coupling agent;The dispersing agent is chelated dispersants;The powder anticaking agent For one of magnesia, silica, magnesium silicate or a variety of combinations.
The present invention also provides a kind of preparation methods of high-strength environment-friendly acrylic paint, include the following steps:
(1) quantitative acrylic resin, graphene, diatomite, part Nano-sized Ferric Oxide Powder and part maleic acid are placed in kettle and are stirred It mixes uniformly, slowly puts into quantitative titanium dioxide, nano-titanium dioxide, dispersing agent, mixed at high speed;
(2) uniformly the rear stick pin-type sand mill that enters is milled down to fineness less than 15 μm;
(3) quantitative carboxymethyl cellulose, remaining Nano-sized Ferric Oxide Powder and residue are slowly added into good paint vehicle made above Maleic acid, aluminium triphosphate, limonene, powder anticaking agent, coupling agent, deionized water, mix at a slow speed, obtain finished product.
The beneficial effects of the present invention are: the high-strength environment-friendly acrylic paint has preferable antiseptic property, improve simultaneously Mechanical strength, impact strength improve, and enhance the adhesive force on surface, have popularizing value.
Specific embodiment:
The preferred embodiments of the present invention will be described in detail below, so that advantages and features of the invention can be easier to by this field Personnel's understanding, so as to make a clearer definition of the protection scope of the present invention.
Embodiment 1:
(1) by 36.7 parts of acrylic resin, 1.5 parts of graphene, 12.5 parts of diatomite, 9.6 parts of Nano-sized Ferric Oxide Powder and maleic acid 5.2 parts are placed in kettle and stir evenly, and slowly put into 4.2 parts of titanium dioxide, 4.1 parts of nano-titanium dioxide, 5.7 parts of chelated dispersants, Mixed at high speed;
(2) uniformly the rear stick pin-type sand mill that enters is milled down to fineness less than 15 μm;
(3) 1.3 parts of carboxymethyl cellulose, 4.3 parts of Nano-sized Ferric Oxide Powder and Malaysia are slowly added into good paint vehicle made above Sour 3.2 parts, 1.9 parts of aluminium triphosphate, 3.6 parts of limonene, 0.8 part of silica, 5.2 parts of silane coupling agent, deionized water 13.7 Part, it mixes at a slow speed, obtains finished product.
Embodiment 2:
(1) 50 parts of acrylic resin, 3 parts of graphene, 10 parts of diatomite, 12 parts of Nano-sized Ferric Oxide Powder and 6 parts of maleic acid are placed in It is stirred evenly in kettle, slowly puts into 5 parts of titanium dioxide, 1 part of nano-titanium dioxide, 5 parts of chelated dispersants, mixed at high speed;
(2) uniformly the rear stick pin-type sand mill that enters is milled down to fineness less than 15 μm;
(3) 0.5 part of carboxymethyl cellulose, 5 parts of Nano-sized Ferric Oxide Powder and maleic acid 3 are slowly added into good paint vehicle made above Part, 1 part of aluminium triphosphate, 5 parts of limonene, 2 parts of magnesia, 3 parts of silane coupling agent, 15 parts of deionized water, mix at a slow speed, obtain Finished product.
Embodiment 3:
(1) by 42.8 parts of acrylic resin, 2.4 parts of graphene, 14.8 parts of diatomite, 8.5 parts of Nano-sized Ferric Oxide Powder and maleic acid 3.9 parts are placed in kettle and stir evenly, and slowly put into 2.7 parts of titanium dioxide, 2.7 parts of nano-titanium dioxide, 6.1 parts of chelated dispersants, Mixed at high speed;
(2) uniformly the rear stick pin-type sand mill that enters is milled down to fineness less than 15 μm;
(3) 1.0 parts of carboxymethyl cellulose, 3.2 parts of Nano-sized Ferric Oxide Powder and Malaysia are slowly added into good paint vehicle made above Sour 1.5 parts, 1.3 parts of aluminium triphosphate, 3.6 parts of limonene, 1.6 parts of magnesium silicate, 3.7 parts of silane coupling agent, deionized water 11.9 Part, it mixes at a slow speed, obtains finished product.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention Range.

Claims (6)

1. a kind of high-strength environment-friendly acrylic paint, which is characterized in that be made from the following raw materials in parts by weight: acrylic resin 35-50 parts, 10-20 parts of Nano-sized Ferric Oxide Powder, 1-3 parts of graphene, 10-15 parts of diatomite, 1-5 parts of nano-titanium dioxide, carboxylic first 0.5-2 parts of base cellulose, 1-3 parts of aluminium triphosphate, 5-10 parts of maleic acid, 3-5 parts of limonene, 0.1-2 parts of powder anticaking agent, idol Agent 3-10 parts of connection, 5-10 parts of dispersing agent, 1-5 parts of titanium dioxide, surplus are deionized water.
2. high-strength environment-friendly acrylic paint according to claim 1, which is characterized in that the high-strength environment-friendly acrylic acid Paint is made from the following raw materials in parts by weight: 36.7 parts of acrylic resin, 13.9 parts of Nano-sized Ferric Oxide Powder, 1.5 parts of graphene, silicon 12.5 parts of diatomaceous earth, 4.1 parts of nano-titanium dioxide, 1.3 parts of carboxymethyl cellulose, 1.9 parts of aluminium triphosphate, 8.4 parts of maleic acid, lemon 3.6 parts of lemon alkene, 0.8 part of powder anticaking agent, 5.2 parts of coupling agent, 5.7 parts of dispersing agent, 4.2 parts of titanium dioxide, surplus are deionized water.
3. high-strength environment-friendly acrylic paint according to claim 1, which is characterized in that the coupling agent is silane coupled Agent.
4. high-strength environment-friendly acrylic paint according to claim 1, which is characterized in that the dispersing agent is chelating dispersion Agent.
5. high-strength environment-friendly acrylic paint according to claim 1, which is characterized in that the powder anticaking agent is oxidation One of magnesium, silica, magnesium silicate or a variety of combinations.
6. a kind of preparation method of high-strength environment-friendly acrylic paint as described in any one in claim 1-5, which is characterized in that Include the following steps:
(1) quantitative acrylic resin, graphene, diatomite, part Nano-sized Ferric Oxide Powder and part maleic acid are placed in kettle and are stirred It mixes uniformly, slowly puts into quantitative titanium dioxide, nano-titanium dioxide, dispersing agent, mixed at high speed;
(2) uniformly the rear stick pin-type sand mill that enters is milled down to fineness less than 15 μm;
(3) quantitative carboxymethyl cellulose, remaining Nano-sized Ferric Oxide Powder and residue are slowly added into good paint vehicle made above Maleic acid, aluminium triphosphate, limonene, powder anticaking agent, coupling agent, deionized water, mix at a slow speed, obtain finished product.
CN201910508519.3A 2019-06-13 2019-06-13 High-strength environment-friendly acrylic paint and preparation method thereof Pending CN110204940A (en)

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Application Number Priority Date Filing Date Title
CN201910508519.3A CN110204940A (en) 2019-06-13 2019-06-13 High-strength environment-friendly acrylic paint and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201910508519.3A CN110204940A (en) 2019-06-13 2019-06-13 High-strength environment-friendly acrylic paint and preparation method thereof

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CN110204940A true CN110204940A (en) 2019-09-06

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101089063A (en) * 2006-06-15 2007-12-19 郎需东 Thermoplastic acrylic paint
CN103756376A (en) * 2013-12-26 2014-04-30 三棵树涂料股份有限公司 Environment-friendly coating with visible light catalysis function, and preparation method thereof
CN105505160A (en) * 2014-10-17 2016-04-20 南京长江涂料有限公司 Acrylic acid paint
CN109749543A (en) * 2017-11-07 2019-05-14 丹阳市博元安全生产服务有限公司 A kind of environmental protection acrylic paint
CN109749551A (en) * 2017-11-08 2019-05-14 丹阳市博元安全生产服务有限公司 A kind of corrosion-resistant acrylic paint

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101089063A (en) * 2006-06-15 2007-12-19 郎需东 Thermoplastic acrylic paint
CN103756376A (en) * 2013-12-26 2014-04-30 三棵树涂料股份有限公司 Environment-friendly coating with visible light catalysis function, and preparation method thereof
CN105505160A (en) * 2014-10-17 2016-04-20 南京长江涂料有限公司 Acrylic acid paint
CN109749543A (en) * 2017-11-07 2019-05-14 丹阳市博元安全生产服务有限公司 A kind of environmental protection acrylic paint
CN109749551A (en) * 2017-11-08 2019-05-14 丹阳市博元安全生产服务有限公司 A kind of corrosion-resistant acrylic paint

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Application publication date: 20190906

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