CN104449279A - Natural sterilization anti-mite environment-friendly type aqueous coating for glass doors and preparation method of aqueous coating - Google Patents
Natural sterilization anti-mite environment-friendly type aqueous coating for glass doors and preparation method of aqueous coating Download PDFInfo
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- CN104449279A CN104449279A CN201410568642.1A CN201410568642A CN104449279A CN 104449279 A CN104449279 A CN 104449279A CN 201410568642 A CN201410568642 A CN 201410568642A CN 104449279 A CN104449279 A CN 104449279A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
- C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/918—Polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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Abstract
The invention discloses a natural sterilization anti-mite environment-friendly type aqueous coating for glass doors. The natural sterilization anti-mite environment-friendly type aqueous coating is characterized by being prepared from the following raw materials in parts by weight: 47-53 parts of modified aqueous plant oil alkyd resin, 23-28 parts of phenolic resin, 1-2 parts of sodium bicarbonate, 2-3 parts of alkoxylation nonylphenol acrylic ester, 2-3 parts of butanediol, 0.3-0.5 part of fumed silica, 0.2-0.4 part of a leveling agent BYK-310, 0.2-0.4 part of silicon oil, 0.5-1.0 part of a silane coupling agent KH792, 1-2 parts of silicon carbide fiber, 1-3 parts of propylene glycol monomethyl ether, 0.5-0.7 part of stearic acid polyethyleneglycol, 1-2 parts of pigment, 1-2 parts of aloe oil, 2-3 parts of nano binchotan, 0.6-1.2 parts of nano titanium dioxide photocatalyst, 2-3 parts of nano bamboo fiber, 1-3 parts of blumea oil and 12-16 parts of deionized water. The self-prepared modified aqueous plant oil alkyd resin added into the coating has the property of improving the adhesion property, the water resistance, the yellowing resistance, the color retention property and the like of the coating, the nano bamboo fiber, the aloe oil, the blumea oil and the like added into the coating have the function of natural sterilization and mite killing, are environment-friendly and safe, and can do no harm to health of human bodies, and the coating disclosed by the invention is low in cost, simple to operate, free of toxicity or harm, good in adhesion property and widely applied to glass for domestic decoration and the like.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of natural disinfection anti-mite environment-friendly type glass door use coating and preparation method thereof.
Background technology
Since 20 century 70s, each industrially developed country is devoted to develop pollution-free, less energy-consumption type coating, thus provides wide market for the Application and Development of water-borne coatings.Every coating using water as solvent or make dispersion medium, all can be described as water-borne coatings.Water-borne coatings, using water as dispersion medium, only adopts a small amount of hypotoxicity alcohol ether organic solvent, safety and environmental protection, economizes on resources, and eliminates the danger of presence of fire during construction, is conducive to reducing topsoil.Water-borne coatings is very good to material surface adaptability, and can construct equally at wet environment, coating adhesion is strong.Glass and glasswork, because of attractive in appearance and needs that are performance, need apply coating thereon, glass paint is developed by solvent-borne type hydrotropisms, be the inexorable trend adapting to environment protection requirement development, replace traditional solvent-borne coating gradually at present, main flow field, occuping market.
The most important coating resin of Synolac, its consumption accounts for the first place of coatings industry resin always, it is good that phthalic resin coating has paint film adhesion, the feature such as bright, plentiful, and there is good application property, but film is softer, water-fast, alkali resistance is not good enough, for the performance improving it can improve its performance with different vegetables oil, the present invention adopts semi-drying oil refined soybean oil and siccative oil tung oil to mix common modified alkyd resin, effectively can improve the water tolerance of resin, protect the features such as look gloss retention.Along with the reinforcement of people's environmental consciousness, and organic solvent expense is surging, water soluble paint is more and more paid attention to, in order to adapt to day by day fierce market competition, modified water-soluble vegetables oil Synolac prepared by the present invention, meets the developing direction of modern coatings Industrial Green, environmental protection.
Summary of the invention
The object of this invention is to provide a kind of natural disinfection anti-mite environment-friendly type glass door use coating and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of natural disinfection anti-mite environment-friendly type glass door use coating, be made up of the raw material of following weight part: modified water-soluble vegetables oil Synolac 47-53, resol 23-28, sodium bicarbonate 1-2, alkoxide nonylphenol acrylate 2-3, butyleneglycol 2-3, aerosil 0.3-0.5, flow agent BYK-3100.2-0.4, silicone oil 0.2-0.4, silane coupling agent KH7920.5-1.0, silicon carbide fiber 1-2, propylene glycol monomethyl ether 1-3, polyoxyethylene stearic acid ester 0.5-0.7, pigment 1-2, Aloe oil 1-2, nanometer binchotan 2-3, nano-titania photocatalyst 0.6-1.2, nano bamboo fiber 2-3, Oleum Folium Artemisiae Argyi 1-3, deionized water 12-16,
Described modified water-soluble vegetables oil Synolac is made up of the raw material of following weight part: refined soybean oil 6-8, nano-calcium carbonate 1-2, nm-class rutile-type TiO 2 3-5, nano diatomite 3-5, distearyl acyl-oxygen aluminum isopropoxide acid esters 1-2, tung oil 8-12, dehydrated alcohol 8-12, dimethylethanolamine 7-9, tetramethylolmethane 18-22, antioxidant 1010 0.3-0.6, lithium hydroxide 0.01-0.1,1,2-PD 18-21, maleic anhydride 10-14, propylene glycol monobutyl ether 4-6, distilled water 50-80; Nm-class rutile-type TiO 2, nano-calcium carbonate, nano diatomite and dehydrated alcohol are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add distearyl acyl-oxygen aluminum isopropoxide acid esters be heated to backflow, isothermal reaction 1-2 hour, filters and uses distilled water wash three times to dry namely to obtain nano composite material for subsequent use.By tetramethylolmethane under the protection being connected with carbon dioxide, 1, 2-propylene glycol, maleic anhydride is added in the four-hole boiling flask that electric mixer and water-and-oil separator are housed, add lithium hydroxide and the slow raised temperature of antioxidant 1010 and react 1-1.5 hour to 190-200 ° of C, add tung oil again, refined soybean oil and the rapid raised temperature of nano composite material are to 200-220 ° of C, when system acid number is 50-60mgKOH/g, stop heating, reduce temperature to 120 ° C, add propylene glycol monobutyl ether to stir, continue to reduce temperature to a 60 ° C and add dimethylethanolamine reaction 30-45 minute, add distilled water again to stir and obtain modified water-soluble vegetables oil Synolac.
A kind of natural disinfection of the present invention anti-mite environment-friendly type glass door use coating, be made up of following concrete steps:
(1) deionized water, flow agent BYK-310, polyoxyethylene stearic acid ester, silicone oil, butyleneglycol, sodium bicarbonate, Aloe oil, Oleum Folium Artemisiae Argyi mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds propylene glycol monomethyl ether stir 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds modified water-soluble vegetables oil Synolac, resol, alkoxide nonylphenol acrylate stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds silane coupling agent KH792, aerosil, pigment, silicon carbide fiber, nano bamboo fiber, nanometer binchotan, nano-titania photocatalyst uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Advantage of the present invention is: the self-control modified water-soluble vegetables oil Synolac that the present invention adds has performances such as strengthening paint adhesion, water tolerance, yellowing resistance and Bao Se, the nano bamboo fiber added, Aloe oil, tarragon wet goods have the effect that natural antibacterial kills mite, green safety, harmless to the health of human body, coating cost of the present invention is low, simple to operate, nontoxic, sticking power is good, is widely used in the glass such as family decoration.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of natural disinfection anti-mite environment-friendly type glass door use coating, be made up of the raw material of following weight part (kilogram): modified water-soluble vegetables oil Synolac 52, resol 25, sodium bicarbonate 1, alkoxide nonylphenol acrylate 2, butyleneglycol 3, aerosil 0.4, flow agent BYK-3100.4, silicone oil 0.3, silane coupling agent KH7921.0, silicon carbide fiber 1, propylene glycol monomethyl ether 3, polyoxyethylene stearic acid ester 0.7, pigment 1, Aloe oil 2, nanometer binchotan 2, nano-titania photocatalyst 0.9, nano bamboo fiber 2, Oleum Folium Artemisiae Argyi 3, deionized water 16,
Described modified water-soluble vegetables oil Synolac is made up of the raw material of following weight part (kilogram): refined soybean oil 7, nano-calcium carbonate 2, nm-class rutile-type TiO 24, nano diatomite 3, distearyl acyl-oxygen aluminum isopropoxide acid esters 1, tung oil 11, dehydrated alcohol 12, dimethylethanolamine 8, tetramethylolmethane 20, antioxidant 1010 0.3, lithium hydroxide 0.07,1,2-PD 20, maleic anhydride 13, propylene glycol monobutyl ether 5, distilled water 70; Nm-class rutile-type TiO 2, nano-calcium carbonate, nano diatomite and dehydrated alcohol are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add distearyl acyl-oxygen aluminum isopropoxide acid esters be heated to backflow, isothermal reaction 1-2 hour, filters and uses distilled water wash three times to dry namely to obtain nano composite material for subsequent use.By tetramethylolmethane under the protection being connected with carbon dioxide, 1, 2-propylene glycol, maleic anhydride is added in the four-hole boiling flask that electric mixer and water-and-oil separator are housed, add lithium hydroxide and the slow raised temperature of antioxidant 1010 and react 1-1.5 hour to 190-200 ° of C, add tung oil again, refined soybean oil and the rapid raised temperature of nano composite material are to 200-220 ° of C, when system acid number is 50-60mgKOH/g, stop heating, reduce temperature to 120 ° C, add propylene glycol monobutyl ether to stir, continue to reduce temperature to a 60 ° C and add dimethylethanolamine reaction 30-45 minute, add distilled water again to stir and obtain modified water-soluble vegetables oil Synolac.
A kind of natural disinfection of the present invention anti-mite environment-friendly type glass door use coating, be made up of following concrete steps:
(1) deionized water, flow agent BYK-310, polyoxyethylene stearic acid ester, silicone oil, butyleneglycol, sodium bicarbonate, Aloe oil, Oleum Folium Artemisiae Argyi mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds propylene glycol monomethyl ether stir 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds modified water-soluble vegetables oil Synolac, resol, alkoxide nonylphenol acrylate stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds silane coupling agent KH792, aerosil, pigment, silicon carbide fiber, nano bamboo fiber, nanometer binchotan, nano-titania photocatalyst uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
After paint solidification of the present invention, hardness of paint film is 3H, and sticking power experiment is 1 grade, wear resistance experiment (0.5g/r)/mg:5.3, shock resistance is tested: 50cm, water tolerance experiment (480h): without exception, resistance to boiling water experiment (12h): unchanged, solvent resistant experiment (12h): unchanged, alcohol resistance experiment (dehydrated alcohol 24h): unchanged, artificial ageing resistance is tested: 1000h is non-foaming, does not peel off, flawless, chalk rating 0 grade, variable color grade 1 grade.
Claims (2)
1. a natural disinfection anti-mite environment-friendly type glass door use coating, it is characterized in that, be made up of the raw material of following weight part: modified water-soluble vegetables oil Synolac 47-53, resol 23-28, sodium bicarbonate 1-2, alkoxide nonylphenol acrylate 2-3, butyleneglycol 2-3, aerosil 0.3-0.5, flow agent BYK-3100.2-0.4, silicone oil 0.2-0.4, silane coupling agent KH7920.5-1.0, silicon carbide fiber 1-2, propylene glycol monomethyl ether 1-3, polyoxyethylene stearic acid ester 0.5-0.7, pigment 1-2, Aloe oil 1-2, nanometer binchotan 2-3, nano-titania photocatalyst 0.6-1.2, nano bamboo fiber 2-3, Oleum Folium Artemisiae Argyi 1-3, deionized water 12-16,
Described modified water-soluble vegetables oil Synolac is made up of the raw material of following weight part: refined soybean oil 6-8, nano-calcium carbonate 1-2, nm-class rutile-type TiO 2 3-5, nano diatomite 3-5, distearyl acyl-oxygen aluminum isopropoxide acid esters 1-2, tung oil 8-12, dehydrated alcohol 8-12, dimethylethanolamine 7-9, tetramethylolmethane 18-22, antioxidant 1010 0.3-0.6, lithium hydroxide 0.01-0.1,1,2-PD 18-21, maleic anhydride 10-14, propylene glycol monobutyl ether 4-6, distilled water 50-80, nm-class rutile-type TiO 2, nano-calcium carbonate, nano diatomite and dehydrated alcohol are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add distearyl acyl-oxygen aluminum isopropoxide acid esters be heated to backflow, isothermal reaction 1-2 hour, filters and uses distilled water wash three times to dry namely to obtain nano composite material for subsequent use, by tetramethylolmethane under the protection being connected with carbon dioxide, 1, 2-propylene glycol, maleic anhydride is added in the four-hole boiling flask that electric mixer and water-and-oil separator are housed, add lithium hydroxide and the slow raised temperature of antioxidant 1010 and react 1-1.5 hour to 190-200 ° of C, add tung oil again, refined soybean oil and the rapid raised temperature of nano composite material are to 200-220 ° of C, when system acid number is 50-60mgKOH/g, stop heating, reduce temperature to 120 ° C, add propylene glycol monobutyl ether to stir, continue to reduce temperature to a 60 ° C and add dimethylethanolamine reaction 30-45 minute, add distilled water again to stir and obtain modified water-soluble vegetables oil Synolac.
2. a kind of natural disinfection anti-mite environment-friendly type glass door use coating according to claim 1, is characterized in that, be made up of following concrete steps:
(1) deionized water, flow agent BYK-310, polyoxyethylene stearic acid ester, silicone oil, butyleneglycol, sodium bicarbonate, Aloe oil, Oleum Folium Artemisiae Argyi mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds propylene glycol monomethyl ether stir 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds modified water-soluble vegetables oil Synolac, resol, alkoxide nonylphenol acrylate stirring 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds silane coupling agent KH792, aerosil, pigment, silicon carbide fiber, nano bamboo fiber, nanometer binchotan, nano-titania photocatalyst uniform stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
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| CN201410568642.1A CN104449279A (en) | 2014-10-23 | 2014-10-23 | Natural sterilization anti-mite environment-friendly type aqueous coating for glass doors and preparation method of aqueous coating |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105985689A (en) * | 2016-02-25 | 2016-10-05 | 和县明生环保材料有限责任公司 | High-solid-content round-grain mortar composite external wall paint and preparation method thereof |
| CN111560205A (en) * | 2020-07-08 | 2020-08-21 | 百草春天大生物科技(青岛)有限公司 | Artemisia argyi antioxidant water-based paint and preparation method thereof |
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| CN101831061A (en) * | 2010-05-11 | 2010-09-15 | 浙江工业大学 | Benzoic acid modified waterborne alkyd resin and amino plastic baking varnish prepared by same |
| CN103224748A (en) * | 2013-05-21 | 2013-07-31 | 苏州吉人漆业有限公司 | Water-diluted alkyd paint and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105985689A (en) * | 2016-02-25 | 2016-10-05 | 和县明生环保材料有限责任公司 | High-solid-content round-grain mortar composite external wall paint and preparation method thereof |
| CN111560205A (en) * | 2020-07-08 | 2020-08-21 | 百草春天大生物科技(青岛)有限公司 | Artemisia argyi antioxidant water-based paint and preparation method thereof |
| CN111560205B (en) * | 2020-07-08 | 2021-11-09 | 百草边大生物科技(青岛)有限公司 | Artemisia argyi antioxidant water-based paint and preparation method thereof |
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