CN110199999A - A kind of composition pesticide containing fluorine oxazole amide and Tolfenpyrad - Google Patents
A kind of composition pesticide containing fluorine oxazole amide and Tolfenpyrad Download PDFInfo
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- CN110199999A CN110199999A CN201910535468.3A CN201910535468A CN110199999A CN 110199999 A CN110199999 A CN 110199999A CN 201910535468 A CN201910535468 A CN 201910535468A CN 110199999 A CN110199999 A CN 110199999A
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- tolfenpyrad
- oxazole amide
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
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- General Health & Medical Sciences (AREA)
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Abstract
The invention discloses a kind of composition pesticide containing fluorine oxazole amide and Tolfenpyrad, belongs to pesticide compositional and applied technical field.Its effective component is fluorine oxazole amide and Tolfenpyrad, and the weight fraction ratio 10: 1~1: 5 of fluorine oxazole amide and Tolfenpyrad, remaining is auxiliary agent, and suspending agent, missible oil, microemulsion, wettable powder, water dispersible granules can be made in composition.Composition of the present invention has significant synergies, and can reduce the dosage and number of fluorine oxazole amide and Tolfenpyrad, mitigates environmental pollution and delays the generation of pest resistance to insecticide.
Description
Technical field
The invention belongs to the field of pesticides of agricultural insect pests control, and in particular to one kind is with fluorine oxazole amide and Tolfenpyrad
For the composition pesticide of effective component, it is primarily adapted for use in Lepidoptera, Homoptera, coleoptera and Thysanoptera prevention and treatment.
Background technique
Fluorine oxazole amide is the novel isoxazole class insecticide formulated by Japanese Nissan chemical company, English name:
Fluxametamide, molecular formula: C20H16Cl2F3N3O3, fluorine oxazole amide is that γ-aminobutyric acid gates chloride channel and glutamic acid door
Chloride channel antagonist is controlled, with Fipronil no interactions resistance, there is extensive insecticidal activity, be suitable for fruit tree, vegetables, soybean, cotton
The prevention and treatment of lepidoptera pest, thrips, aleyrodid, Liriomyza, beetle on the crops such as flower, tea tree and mite class.It is mentioned here
Fluorine oxazole amide is interpreted as the compound having the following structure or isomers.
Tolfenpyrad is the novel pyrazole heterocyclic insecticidal/acaricidal agent of Japanese pesticide company exploitation, English name
Tolfenpyrad, molecular formula: C21H22ClN3O2.Mechanism of action is that the electronics in mitochondrial metabolism system is hindered to convey system multiple
Fit I prevents insect from providing and storing energy so that electronics reception and registration be made to be hindered, and referred to as Mitochondrial electron is conveyed multiple
Fit Inhibitors (METI).Tolfenpyrad insecticidal spectrum is wide, to various bony wing meshes, Semiptera, beetle mesh, Hymenoptera, Diptera evil
Worm and mite class control efficiency with higher.
It the use of pesticide is to guarantee high crop yield, stable yields, high-quality important guarantee, the status of pesticide in agricultural production can not
It shakes.However as the throughout the year unreasonable use of pesticide, the resistance problem of pest is also more and more obvious, and the dosage of pesticide is also more next
It is bigger.How to delay pest resistance to insecticide and reduce Pesticide Residue to be one of problem of researcher.
It carries out control of insect using same single dose for a long time easily to develop drug resistance risk, pesticide compositional being capable of very great Cheng
The generation for delaying pest resistance to insecticide of degree improves preventive effect, while expanding insecticidal spectrum, reduces pharmaceutical use and environmental pollution.So
And most of agriculture chemical compounding is summation action, some even antagonisms, only a small number of compoundings are with synergistic effect.This hair
Bright people has carried out a large amount of screening studies, as a result, it has been found that having in certain ratio range after fluorine oxazole amide and Tolfenpyrad compounding
There is a significant synergistic effect, rather than simple summation action, while in the application of crop field, to the various pests of crops
Outstanding preventive effect is all had, while having no the document for being used to prevent and treat agricultural pests in relation to fluorine oxazole amide and Tolfenpyrad compounding agent
Report, after further research, complete the present invention.
Summary of the invention
To solve the above problems, the present invention provides a kind of efficient, less toxic compounding containing fluorine oxazole amide and Tolfenpyrad
Composition pesticide, Lepidoptera, Homoptera, coleoptera and Thysanoptera prevention and treatment on crops.
The present invention passes through indoor toxicity test and field trial, it is determined that fluorine oxazole amide and Tolfenpyrad weight ratio are 20
: it is had obvious synergistic function between 1~1: 20, there is better control efficiency compared with using single insecticide.
The technical scheme is that a kind of composition pesticide, including a effective amount of effective component fluorine oxazole amide and azoles
Insect amide.Wherein, fluorine oxazole amide and the weight fraction ratio of Tolfenpyrad are 10: 1~1: 5.Effective component fluorine oxazole amide and
The mass percent that the sum of weight of Tolfenpyrad accounts for total weight is 3%~90%.
Described composition pesticide those skilled in the art can choose suitable pesticidal preparations auxiliary according to known methods
Ingredient, can prepare at the suitable agent agriculturally used such as suspending agent, missible oil, microemulsion, wettable powder, water dispersible granules
Type.The processing technology of the various preparations of composition pesticide of the present invention is the prior art, can be varied according to different situations.
Specifically, the auxiliary element of the pesticidal preparations in the Pesticidal combination be solvent, emulsifier, wetting agent,
The mixing of one or more of stabilizer, dispersing agent, thickener, pH adjusting agent, defoaming agent, antifreezing agent, packing agent etc., and
It can be varied, be not particularly limited according to different situations.
Composition pesticide produced by the present invention is applied to the control of insect of crops.
On the way, crops include rice, corn, wheat, potato, soybean, cotton, fruit to the use of the composition pesticide
Tree, tea tree, melon dish, flower crop.
On the way, pest includes Lepidoptera, Homoptera, coleoptera and Thysanoptera to the use of the composition pesticide, specifically
Including rice leaf roller, striped rice borer, pink rice borer, planthopper, beet armyworm, oriental tobacco budworm, prodenia litura, mythimna separata, thrips, aleyrodid, aphid
Worm, pear sucker, diamondback moth, phyllotreta striolata, Liriomyza, small heart-eating peach worm and corn borer.
Composition pesticide provided by the invention have it is following the utility model has the advantages that
1, composition pesticide provided by the invention, by the different medicament of two kinds of mechanism of action of fluorine oxazole amide and Tolfenpyrad
Composition, compounding have significant synergistic effect, show apparent synergistic function to diamondback moth, phyllotreta striolata.
2, the insecticidal spectrum of composition pesticide provided by the invention and control efficiency are better than single dose effect, reduce pesticide
Dosage reduces the influence of drug cost and pesticide residue to environment.
3, composition pesticide provided by the invention, can reduce long-term single use fluorine oxazole amide and Tolfenpyrad generates
Anti- medicine risk, to extend medicament service life it is significant.
Specific embodiment
Essence in order to better understand the present invention, below with reference to embodiment, the content of the present invention will be further explained, needs
It should be understood that presented below is only the relatively good case study on implementation of the present invention, it is used only to describe the present invention, it is unintelligible
For the limitation to use scope of the present invention.
The formula of embodiment one and FORMULATION PROCESS EXAMPLES
1 20% fluorine oxazole amide Tolfenpyrad suspending agent (1: 1) of preparation
Fluorine oxazole amide raw medicine (folding hundred) 10%, Tolfenpyrad raw medicine (folding hundred) 10%, polycarboxylate 2%, phosphate
2%, block polyoxy polyethers 1%, silicone compound 0.15%, propylene glycol 3%, polyvinyl alcohol 0.3%, preservative sodium benzoate
0.5%, deionized water adds to 100%, weighs sand milling, filtering after each component in proportion, that is, can be made into 20% fluorine oxazole amide
Tolfenpyrad suspending agent.
2 30% fluorine oxazole amide Tolfenpyrad missible oil (1: 5) of preparation
Fluorine oxazole amide raw medicine (folding hundred) 5%, Tolfenpyrad raw medicine (folding hundred) 25%, 10% fatty alcohol polyoxyethylene ether,
5% alkylbenzene sulfonate, heavy aromatic solvent oil complement to 100%, in proportion by mixing stirring and processing mistake after weighing each component
I.e. can be made into 30% fluorine oxazole amide Tolfenpyrad missible oil can be added suitable dimethylbenzene according to actual needs after filter.
3 24% fluorine oxazole amide Tolfenpyrad microemulsion (1: 3) of preparation
Fluorine oxazole amide raw medicine (folding hundred) 6%, Tolfenpyrad raw medicine (folding hundred) 18%, fatty alcohol polyoxyethylene ether 3%, 3-
Octylpyrrolidone 5%, propylene glycol 3%, silicone oil 0.2%, deionized water supply 100%, after weighing each component mixing in proportion
It can be prepared by 24% fluorine oxazole amide Tolfenpyrad microemulsion.
4 22% fluorine oxazole amide Tolfenpyrad wettable powder (10: 1) of preparation
Fluorine oxazole amide raw medicine (folding hundred) 20%, Tolfenpyrad raw medicine (folding hundred) 2%, alkyl phenol polyoxyethylene ether 3%, ten
Sodium dialkyl sulfate 4%, white carbon black 10%, add kaolin to complement to 100%, after weighing each component co-grinding in proportion
22% fluorine oxazole amide Tolfenpyrad wettable powder is made.
5 20% fluorine oxazole amide Tolfenpyrad water dispersible granules (3: 1) of preparation
Fluorine oxazole amide raw medicine (folding hundred) 15%, Tolfenpyrad raw medicine (folding hundred) 5%, polycarboxylate 5%, detergent alkylate
Sodium sulfonate 2%, white carbon black 2%, light calcium complement to 100%, weigh each component co-grinding in proportion, and then plus water is mediated and is granulated
And after drying, that is, it can be made into 20% fluorine oxazole amide Tolfenpyrad water dispersible granules.
6 18% fluorine oxazole amide Tolfenpyrad suspending agent (5: 1) of preparation
Fluorine oxazole amide raw medicine (folding hundred) 15%, Tolfenpyrad raw medicine (folding hundred) 3%, alkyl polyoxyethylene ether phosphate ester salt
4%, block polyoxy polyethers 1%, silicone compound 0.15%, ethylene glycol 3%, xanthan gum 0.3%, preservative sodium benzoate
0.5%, deionized water adds to 100%, is weighed after each component mixes in proportion and is sanded, can be made into 18% fluorine oxazole acyl after filtering
Amine Tolfenpyrad suspending agent.
7 20% fluorine oxazole amide Tolfenpyrad suspending agent (1: 3) of preparation
Fluorine oxazole amide raw medicine (folding hundred) 5%, Tolfenpyrad raw medicine (folding hundred) 15%, polycarboxylate 2%, alkyl polyoxy second
Alkene ether phosphate salt 2%, block polyoxy polyethers 1%, ethylene glycol 3%, xanthan gum 0.3%, preservative sodium benzoate 0.5% are gone
Ionized water adds to 100%, weighs in proportion and is sanded after each component mixing, filters to get to 20% fluorine oxazole amide azoles worm acyl
Amine suspending agent.
8 15.4% fluorine oxazole amide Tolfenpyrad aqueous emulsion (10: 1) of preparation
Fluorine oxazole amide raw medicine (folding hundred) 14%, Tolfenpyrad raw medicine (folding hundred) 1.4%, alkyl phosphoric acid esters 2%, EO-
PO block copolymer 1%, dimethylbenzene 20%, propylene glycol 5%, polyvinyl alcohol 0.1%, preservative sodium benzoate 0.5%, silicone disappears
Infusion 0.5%, deionized water complement to 100%, in proportion weighing alkyl phosphoric acid esters, EO-PO block copolymer, propylene glycol,
Polyvinyl alcohol, sodium benzoate are mixed to form water phase after silicone antifoams agent and with deionized water, and fluorine oxazole amide and Tolfenpyrad are former
Medicine, which is dissolved in dimethylbenzene, forms oily phase；It is mutually added to oily in water phase under high speed shear, that is, can be made into 15.4% fluorine oxazole acyl
Amine Tolfenpyrad aqueous emulsion.
9 8% fluorine oxazole amide Tolfenpyrad water dispersible granules (1: 1) of preparation
Fluorine oxazole amide raw medicine (folding hundred) 4%, Tolfenpyrad raw medicine (folding hundred) 4%, naphthalene sulfonic acid-formaldehyde condensation product 5%, ten
Dialkyl benzene sulfonic acids sodium 2%, cornstarch 15%, kaolin complement to 100%, weigh each component co-grinding in proportion, so
Afterwards plus water is mediated and is granulated and can be made into 8% fluorine oxazole amide Tolfenpyrad water dispersible granules after drying.
10 24% fluorine oxazole amide Tolfenpyrad suspending agent (3: 1) of preparation
Fluorine oxazole amide raw medicine (folding hundred) 18%, Tolfenpyrad raw medicine (folding hundred) 6%, polycarboxylate 2%, alkyl polyoxy second
Alkene ether phosphate salt 2%, block polyoxy polyethers 1%, ethylene glycol 3%, xanthan gum 0.3%, preservative sodium benzoate 0.5% are gone
Ionized water adds to 100%, weighs in proportion and is sanded after each component mixing, filters to get to 24% fluorine oxazole amide azoles worm acyl
Amine suspending agent.
11 24% fluorine oxazole amide Tolfenpyrad aqueous emulsion (5: 1) of preparation
Fluorine oxazole amide raw medicine (folding hundred) 20%, Tolfenpyrad raw medicine (folding hundred) 4%, alkyl phosphoric acid esters 2%, EO-PO
Block copolymer 1%, dimethylbenzene 20%, propylene glycol 5%, polyvinyl alcohol 0.1%, preservative sodium benzoate 0.5%, silicone antifoams
Agent 0.5%, deionized water complement to 100%, weigh alkyl phosphoric acid esters, EO-PO block copolymer in proportion, and propylene glycol is gathered
Vinyl alcohol, sodium benzoate are mixed to form water phase, fluorine oxazole amide and Tolfenpyrad raw medicine after silicone antifoams agent and with deionized water
It is dissolved in dimethylbenzene and forms oily phase；It is mutually added to oily in water phase under high speed shear, that is, can be made into 24% fluorine oxazole amide
Tolfenpyrad aqueous emulsion.
12 24% fluorine oxazole amide Tolfenpyrad missible oil (1: 5) of preparation
Fluorine oxazole amide raw medicine (folding hundred) 4%, Tolfenpyrad raw medicine (folding hundred) 20%, fatty alcohol polyoxyethylene ether 10%,
Alkylbenzene sulfonate 5%, heavy aromatic solvent oil complement to 100%, in proportion by mixing stirring and processing mistake after weighing each component
I.e. can be made into 24% fluorine oxazole amide Tolfenpyrad missible oil can be added suitable dimethylbenzene according to actual needs after filter.
Two indoor biological activity assay of embodiment and field efficacy verifying
Test example one: fluorine oxazole amide is with Tolfenpyrad different ratio to the indoor toxicity test of diamondback moth
Indoor joint toxicity measuring method is referring to the insecticide indoor biological activity assay test rule " People's Republic of China (PRC)
Agricultural industry criteria NY/T 1154.14-2008 ", fluorine oxazole amide and Tolfenpyrad raw medicine acetone solution, then with containing
The aqueous solution of 0.1% Tween 80 dilutes, and prepares single dose mother liquor respectively, and devise 11 groups of proportions, each single dose according to mixed purpose
And according to 5 series mass concentration of method setting of equal ratios, (it is suitable to be configured to according to preliminary result for every group of proportion mixture
Lethasl concentration) it is stand-by；Cabbage leaves avoid the disk that vein is cut into diameter about 5cm, and leaf dish is made, by the leaf dish made immerse to
It takes out and dries after 10s in the dosing solutions of survey, be then placed in bottom and be covered in the culture dish of moisturizing filter paper, access of the same size
2 age diamondback moth larvaes, each culture dish access test worm number 20,4 repetitions of each processing, not contain the coordinative solvent of medicament
Processing is used as blank control.It is 25 DEG C that the test worm of processing, which is put into temperature, relative humidity 70%, photoperiod L: D=(16: 8) h's
Weather incubator in raise, after processing 48d check test worm death condition, motionless person is touched with writing brush and is considered as death, respectively
Total borer population and dead borer population are recorded, corrected mortality is calculated.
Using the logarithm of drug concentration (mg/L) as independent variable x, the probit value with corrected mortality is y, establishes poison respectively
Power regression equation, it is for statistical analysis with DPS7.05, count the LC of each medicament50.Calculate the co-toxicity coefficient of compound drug mixture
(CTC).Co-toxicity coefficient CTC, calculation formula are as follows:
Survey toxicity index (ATI)=(standard agent LC50/ reagent agent) × 100
Percentage composition+B the medicament toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent
Co-toxicity coefficient (CTC)=ATI/TTI × 100
According to the criteria for classifying of co-toxicity coefficient (CTC), CTC < 80 is antagonism, and 80 < CTC < 120 are summation action,
CTC > 120 is synergistic effect.
1 fluorine oxazole amide of table is with Tolfenpyrad different ratio to the indoor toxicity test of diamondback moth
Data can be seen that CTC is all larger than 80 when fluorine oxazole amide and Tolfenpyrad ratio are 20: 1~1: 20 from table 1,
Show as significantly addition or synergistic effect.Wherein 20: 1,1: 10,1: 20 is summation action, 10: 1,5: 1,3: 1,1: 1,1: 3,
Be synergistic effect at 1: 5, and when showing that fluorine oxazole amide and Tolfenpyrad ratio are 10: 1~1: 5, the two shows as synergistic work
With the CTC value that wherein fluorine oxazole amide and Tolfenpyrad ratio are 1: 3 is maximum, and compounding effect is best.
According on the basis of indoor joint toxicity measuring result we specify the synergy of fluorine oxazole amide and Tolfenpyrad
Section carries out field efficacy verifying again on this basis with the practical drug effect of each proportion of determination.
Test example two: fluorine oxazole amide and Tolfenpyrad composition are to wild cabbage plutella xylostella field control effectiveness test
It tests and carries out in Yunnan Province Yuxi Tonghai County, for wild cabbage, wild cabbage grows fine, diamondback moth for the testing site of selection
Endanger full incidence period, predominantly 2 to 3 instar larvaes.Test method is tried referring to National Standard of the People's Republic of China's pesticide field efficacy
Criterion GB/T17980.13-2000 is tested, radix investigation before being administered, 5 points of each cell samplings, count each by every 5 plants of label
Work borer population in mark point on all plant.3d, 7d, 15d check remaining borer population living and see whether same method after administration
There is phytotoxicity, calculates Revision insect recluced rate and control efficiency.Cell uses RANDOMIZED BLOCK DESIGN, and a cell is as a repetition, often
A chemicals treatment is repeated 4 times.Test medicine is preparation 1, preparation 2, preparation 3, preparation 4, preparation 5, preparation 6, and comparison medicament is
10% fluorine oxazole amide EC (autogamy), 10% Tolfenpyrad SC (autogamy), blank control is clear water.
Drug effect calculation method:
Total borer population × 100 before Revision insect recluced rate (%)=(insect population one remains borer population living before medicine)/medicine
Preventive effect (%)=(chemicals treatment district Revision insect recluced rate-blank district Revision insect recluced rate)/(100- blank district
Revision insect recluced rate) × 100
Test result:
2 fluorine oxazole amide of table and Tolfenpyrad composition for preventing and controlling wild cabbage plutella xylostella test result
The experimental result of table 2 can be seen that preparation 1, preparation 2, preparation 3, preparation 4, preparation 5, preparation 6 for preventing and treating wild cabbage
Diamondback moth has good preventive effect, has outstanding quick-acting and lasting effect, and effect is superior to single dose, illustrates that compounding agent can
To reduce dosage and promote control efficiency, investigated during test also and find no phytotoxicity.
Test example three: fluorine oxazole amide is with Tolfenpyrad composition to the field control effectiveness test of phyllotreta striolata
The test is carried out in Wuhan Caidian District, and experimental plot is for pakchoi.Investigation method is referring to state, the People's Republic of China (PRC)
Family standard pesticide field control effectiveness test criterion GB/T17980.18-2000: each cell setting protection row, each cell take five
Point sampling, 5 plants of pakchois of every label count adult radix before medicine, 1 after medicine, 3,7d investigates the residual borer population of each cell and counts
Calculate preventive effect.Each chemicals treatment is repeated 3 times.Test medicine be preparation 6, preparation 7, preparation 8, preparation 9, preparation 10, preparation 11 with
And preparation 12, comparison medicament are 10% fluorine oxazole amide EC (autogamy), 10% Tolfenpyrad SC (autogamy).
Drug effect calculation method:
Total borer population × 100 before Revision insect recluced rate (%)=(insect population-residual borer population living before medicine)/medicine
Preventive effect (%)=(treatment region Revision insect recluced rate-blank district Revision insect recluced rate)/(100- blank district insect population
Decline rate) × 100
Test result:
3 fluorine oxazole amide of table and Tolfenpyrad composition for preventing and controlling pakchoi flea beetle test result
It can be seen that preparation 7, preparation 8, preparation 9, preparation 10, preparation 11 and preparation 12 for preventing from 3 experimental data of table
Yellow River harnessing cabbage flea beetle has outstanding control efficiency, and the control efficiency of compound preparation, which is significantly better than, is used alone single dose preventive effect, body
The value now compounded.
Therefore fluorine oxazole amide can dramatically increase preventive effect after compounding with Tolfenpyrad, it is possible to reduce field dosage, it can be with
Delay the drug resistance of pest to generate, there is very big application value in actual production.
Claims (8)
1. a kind of composition pesticide containing fluorine oxazole amide and Tolfenpyrad, it is characterised in that: including it is a effective amount of effectively at
Point fluorine oxazole amide and Tolfenpyrad, surplus be allow in pesticidal preparations using auxiliary element.
2. a kind of composition pesticide containing fluorine oxazole amide and Tolfenpyrad according to claim 1, it is characterised in that:
Weight fraction ratio between the effective component fluorine oxazole amide and Tolfenpyrad is 10: 1~1: 5.
3. a kind of composition pesticide containing fluorine oxazole amide and Tolfenpyrad according to claim 1, it is characterised in that:
The weight summation of both the effective component fluorine oxazole amide and Tolfenpyrad accounts for the quality percentage of the total weight of composition pesticide
Than being 3%~90%.
4. a kind of composition pesticide containing fluorine oxazole amide and Tolfenpyrad according to claim 1, it is characterised in that:
The effective component fluorine oxazole amide and the weight fraction ratio of Tolfenpyrad are 1: 3.
5. a kind of composition pesticide containing fluorine oxazole amide and Tolfenpyrad according to claim 1, it is characterised in that:
The composition can be configured to any one including suspending agent, missible oil, microemulsion, wettable powder, water dispersible granules
Dosage form.
6. a kind of application of the composition pesticide containing fluorine oxazole amide and Tolfenpyrad, which is characterized in that such as claim 1-5
Any one described contains control of insect of the composition pesticide of fluorine oxazole amide and Tolfenpyrad applied to crops.
7. the application of composition pesticide according to claim 6, which is characterized in that the crops include rice, corn, small
Wheat, potato, soybean, cotton, fruit tree, tea tree, melon dish, flower crop.
8. the application of Pesticidal combination according to claim 6, which is characterized in that the pest include Lepidoptera, Homoptera,
It is green to specifically include rice leaf roller, striped rice borer, pink rice borer, diamondback moth, planthopper, beet armyworm, cigarette for coleoptera and Thysanoptera
Worm, prodenia litura, mythimna separata, thrips, aleyrodid, aphid, pear sucker, phyllotreta striolata, Liriomyza, small heart-eating peach worm and corn
Snout moth's larva.
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| CN201910535468.3A CN110199999A (en) | 2019-06-19 | 2019-06-19 | A kind of composition pesticide containing fluorine oxazole amide and Tolfenpyrad |
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| CN201910535468.3A CN110199999A (en) | 2019-06-19 | 2019-06-19 | A kind of composition pesticide containing fluorine oxazole amide and Tolfenpyrad |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1930136A (en) * | 2004-03-05 | 2007-03-14 | 日产化学工业株式会社 | Isoxazoline-substituted benzamide compound and noxious organism control agent |
| CN106659160A (en) * | 2014-06-30 | 2017-05-10 | 日产化学工业株式会社 | Insecticide, miticide, nematicide, molluscicide, disinfectant, or bactericide composition, and pest control method |
-
2019
- 2019-06-19 CN CN201910535468.3A patent/CN110199999A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1930136A (en) * | 2004-03-05 | 2007-03-14 | 日产化学工业株式会社 | Isoxazoline-substituted benzamide compound and noxious organism control agent |
| CN106659160A (en) * | 2014-06-30 | 2017-05-10 | 日产化学工业株式会社 | Insecticide, miticide, nematicide, molluscicide, disinfectant, or bactericide composition, and pest control method |
Non-Patent Citations (1)
| Title |
|---|
| MIHO ASAHI等: ""Fluxametamide: A novel isoxazoline insecticide that acts via distinctive"", 《PESTICIDE BIOCHEMISTRY AND PHYSIOLOGY》 * |
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Application publication date: 20190906 |