CN110199998A - A kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii - Google Patents
A kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii Download PDFInfo
- Publication number
- CN110199998A CN110199998A CN201910565020.6A CN201910565020A CN110199998A CN 110199998 A CN110199998 A CN 110199998A CN 201910565020 A CN201910565020 A CN 201910565020A CN 110199998 A CN110199998 A CN 110199998A
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- China
- Prior art keywords
- sclerotium rolfsii
- recompounded pesticide
- brassin lactones
- peanut sclerotium
- pesticide
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
Abstract
The invention discloses a kind of Recompounded pesticides of synergy prevention peanut sclerotium rolfsii, including active constituent and brassin lactones class compound, the active constituent to be compounded by methoxy acrylic bactericide and triazole bactericidal agent.Recompounded pesticide of the present invention shows fabulous synergistic effect to prevention peanut sclerotium rolfsii in the ratio range, the effect for significantly improving prevention peanut sclerotium rolfsii compared with its single dose reduces the drug cost of peasant to reduce dosage, meanwhile reducing effect on environment degree.
Description
Technical field
The present invention relates to technical field of pesticide, the Recompounded pesticide of specifically a kind of synergy prevention peanut sclerotium rolfsii.
Background technique
Roots of Peanut, pod and basal part of stem it is aggrieved after, just brown soft rotten shape has white thin,tough silk shape mycelia at overground part rhizome
(therefore claiming southern blight), usually the soil surface near subaerial basal part of stem and its is initially formed white spun silk, and sick portion fades to
Crineous and it is glossy.Plant basal part of stem is dead by scab girdling.Under conditions of high humidity, the overground part of infected plant can be white
Color ozonium is covered, and is then expanded to neighbouring native face and is infected on other plant.Under extremely moist environment, mycelia
Cluster is unobvious, and aggrieved basal part of stem is by tool is filbert or even the spindle shape scab of the strong protuberance of red cork covers.In arid
Under the conditions of, lesion betides under ground surface on stem, and brown shuttle shape is about 0.5 centimetre.And having coleseed shape sclerotium, cauline leaf becomes
Huang, gradually withered, peanut pod rots.The germ starts to sprout under the condition of high temperature and high humidity, disseminates peanut, sand, company
Continuous continuous cropping, planting density are excessive, morbidity rainy days is heavier.
Chemical method sterilization is one of the main means for agriculturally controlling disease.In recent years, due to some fungicide kinds
Large area is used alone, and already leads to many plant diseases and develops drug resistance.Meanwhile principle when disease generation is complicated, it is single
Kind fungicide is all shown defects and limitations in one aspect using the disease that not can solve agricultural product.It is not of the same race
The advantages of class fungicide mixture, has enhancing actual effect, and delay disease drug resistance, time and labour saving.
Fluoxastrobin is methoxy acrylic bactericide, wide sterilization spectrum, and bactericidal activity is high, have protect, root out, interior suction
Activity.It is for example white to almost all of mycota (Ascomycotina, Basidiomycotina, Mastigomycotina and Deuteromycotina) disease
Powder disease, rust, glume blight, net blotch, downy mildew, rice blast etc. have good activity.Fluoxastrobin is that mitochondrial respiratory inhibits
Agent, i.e., by inhibiting the electron transmission between cytochrome b and c1 that the ATP of cell is prevented to synthesize, so that mitochondria be inhibited to exhale
It inhales.It is to the demethoxylated enzyme inhibitor of 14-, benzamides, dicarboxylic dihydrazides amine and benzimidazole without cross tolerance.Phonetic bacterium
Ester can be used for that cauline leaf is spraying, seed treatment, can also carry out soil treatment, be mainly used for cereal, rice, peanut, grape, Ma Ling
Potato, fruit tree, vegetables, coffee, lawn, garden crop etc., can effectively prevent powdery mildew, rust, glume blight, net blotch, downy mildew,
The crop diseases such as rice blast, anthracnose, banded sclerotial blight, alternaria leaf spot of apple, bitter rot or anthracnose of grape, Cruciferae flowers powdery mildew.
But the product single dose use cost is too high, not yet general large area and popularization and use.It selects and other types fungicide mixture
Cost is reduced, and control efficiency can be improved, slow down resistance development, but azoxystrobin compound product is few, wherein maximum technological difficulties
One of be exactly formulation and auxiliary agent selection on.
Common feature is on main chain containing hydroxyl (ketone group), substituted-phenyl and 1,2,4- in triazole bactericidal agent chemical structure
Triazole group compound.Triazole bactericidal agent has the characteristics that efficient, wide spectrum, low-residual, the lasting period is long, absorbability is strong, simultaneously
With having both protection, treat, root out and fumigation action.The mechanism of action of such medicament is to influence sterols biosynthesis, make
Somatic cells film function is destroyed.In addition to triazole bactericidal agent oomycetes in Mastigomycotina is inactive, to Ascomycotina,
The pathogen of Basidiomycotina and Deuteromycotina is active, but being widely used with triazole bactericidal agent, it has now been found that
Many phytopathogens produce resistance to triazole bactericidal agent.
Difenoconazole, absorbability sterilization, tool protection and therapeutic effect.Difenoconazole is safety in triazole bactericidal agent
Property is relatively high, is widely used in the crops such as fruit tree, vegetables, effectively prevents scab, anthrachose of grape, white rot, spot defoliation,
Powdery mildew, brown spot, rust, stripe rust, head blight etc..Wide sterilization spectrum, to Ascomycetes, Basidiomycetes and including rod method
Category, Ascochyta, Cercospora, Colletotrichum, ball Cuo Pseudomonas, Phoma, Ramularia, Septoria, Venturia exist
Interior partly knows disease, and Erysiphaceae, Uredinales and certain Seedborne pathogens have lasting protection and therapeutic effect.To grape anthrax
Disease, white rot effect are also fine.The yield and guaranteed quality of crop can be improved in foliar treatment or seed treatment.
Tebuconazole, CAS 107534-96-3, chemical name are (RS) -1- (4- chlorphenyl) -4,4- dimethyl -3- (1H-
1,2,4-triazoles -1- ylmethyl) amyl- 3- alcohol, be it is a kind of efficiently, wide spectrum, absorbability triazole bactericidal agent, have protection, treatment,
Three zones are rooted out, wide sterilization spectrum, lasting period are long.
Currently, there are no any about with methoxy acrylic bactericide (nitre Fluoxastrobin for pesticidal preparations production field
Or Fluoxastrobin) and triazole bactericidal agent (difenoconazole or Tebuconazole) be mixed and made into pesticide activity component, with brassin lactones
Class compound is used as builder, and combination prepares the report of Recompounded pesticide.
Summary of the invention
The purpose of the present invention is to overcome the deficiency in the prior art, provides a kind of compounding agriculture of synergy prevention peanut sclerotium rolfsii
Medicine.
In order to achieve the above objectives, The technical solution adopted by the invention is as follows:
A kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii, including active constituent and brassin lactones class compound, institute
Active constituent is stated to be compounded by methoxy acrylic bactericide and triazole bactericidal agent.
Above-mentioned basic technology scheme is carried out preferably, the methoxy acrylic bactericide is selected from nitre Fluoxastrobin or phonetic
One of bacterium ester；
The structural formula of the nitre Fluoxastrobin is as follows:
The preparation of nitre Fluoxastrobin shown in structure above synthesizes basic technology route, and reaction equation is as follows:
Specific lab scale synthesis route is as follows:
Weigh 1kg pyrimidine furanone, 540g sodium onitrophenol, be added 16g catalyst triethylene diamine (DABCO),
4.5L butyl acetate (BA) stirs at a temperature of 110 DEG C, detects GC-MS per hour, after reacting 2~4h, is cooled to 80 DEG C, adds
The hot water for entering 2.3L is washed 2 times, takes organic phase, and reaction kettle is cooled to -8 DEG C~10 DEG C, and discharging filters, HPLC detect filter cake and
Filtrate raw material and product assay (raw material and proportion of products≤0.5% in water phase), are added 15.4L ethyl alcohol and stir at a temperature of 75 DEG C
Dissolution is cooled to -8 DEG C~10 DEG C, and discharging filters, and detects filtrate raw material and product assay, 50 DEG C of Vacuum dry filter cakes, detection
Content, product purity >=97%.
Above-mentioned basic technology scheme is carried out preferably, the triazole bactericidal agent is in difenoconazole or Tebuconazole
It is a kind of.
To above-mentioned basic technology scheme carry out preferably, the brassin lactones class compound be selected from 28- high brassin lactones,
24- table brassin lactones, 25- methyl brassin lactones, propionylbrassinolide, the high brassin lactones of 28- table, mixed table brassin
Any one in lactone or 14- hydroxyl brassinosteroids.
To above-mentioned basic technology scheme carry out preferably, the active constituent account for Recompounded pesticide mass percent be 1~
50%, the mass percent that the brassin lactones class compound accounts for Recompounded pesticide is 0.0075~0.01%.
To above-mentioned basic technology scheme carry out preferably, the component methoxy acrylic bactericide of the active constituent and
The mass ratio (1~1.75) of triazole bactericidal agent between the two: (5~30).
Above-mentioned basic technology scheme is carried out preferably, the dosage form of the Recompounded pesticide can be selected from wettable powder, suspension
Any one in agent, water dispersible granules, aqueous emulsion, seed treatment dry powder doses or granule.
Compared with prior art, the advantages and positive effects of the present invention are as follows:
Recompounded pesticide of the present invention shows fabulous synergistic effect to prevention peanut sclerotium rolfsii in the ratio range, compared with it
The effect that single dose significantly improves prevention peanut sclerotium rolfsii reduces the drug cost of peasant, together to reduce dosage
When, reduce effect on environment degree.
Specific embodiment
For a further understanding of the present invention, elaborate below to specific embodiment provided by the invention.
Below with reference to embodiment to pesticide Herbicidal combinations provided by the invention and its application and preparation dosage form (wettable powder
Agent, suspending agent, water dispersible granules, aqueous emulsion, seed treatment dry powder doses or granule etc.) it is described in detail.
Embodiment 1
A kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii, including active constituent and 28- high brassin lactones, the work
Property ingredient is compounded by nitre Fluoxastrobin and difenoconazole；
The structural formula of the nitre Fluoxastrobin is as follows:
The mass percent that the active constituent accounts for Recompounded pesticide is 12%, and the 28- high brassin lactones account for compounding agriculture
The mass percent of medicine is 0.0085%；
The mass ratio 1.25: 8 of the component nitre Fluoxastrobin and difenoconazole of the active constituent between the two；
The wettable powder that active components mass percentage is 12% is prepared according to conventional preparation method.
Embodiment 2
A kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii, including active constituent and 24- table brassin lactones, the work
Property ingredient is compounded by Fluoxastrobin and difenoconazole；
The mass percent that the active constituent accounts for Recompounded pesticide is 5%, and the 24- table brassin lactones account for Recompounded pesticide
Mass percent be 0.0078%；
The mass ratio 1.35: 7 of the component Fluoxastrobin and difenoconazole of the active constituent between the two；
The suspending agent that mass percentage is 5% is configured to according to conventional formulation method.
Embodiment 3
A kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii, including active constituent and 25- methyl brassin lactones, it is described
Active constituent is compounded by nitre Fluoxastrobin and Tebuconazole；
The structural formula of the nitre Fluoxastrobin is as follows:
The mass percent that the active constituent accounts for Recompounded pesticide is 20%, and the 25- methyl brassin lactones account for compounding
The mass percent of pesticide is 0.0082%；
The mass ratio 1.5: 13 of the component nitre Fluoxastrobin and Tebuconazole of the active constituent between the two；
The water dispersion granule that mass percentage is 20% is configured to according to conventional formulation method.
Embodiment 4
A kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii, including active constituent and propionylbrassinolide, the work
Property ingredient is compounded by Fluoxastrobin and Tebuconazole；
The mass percent that the active constituent accounts for Recompounded pesticide is 10%, and the propionylbrassinolide accounts for Recompounded pesticide
Mass percent be 0.0095%；
The mass ratio 1.6: 21 of the component Fluoxastrobin and Tebuconazole of the active constituent between the two；
The aqueous emulsion that mass percentage is 10% is configured to according to conventional formulation method.
Embodiment 5
A kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii, including active constituent and 28- high brassin lactones, the work
Property ingredient is compounded by nitre Fluoxastrobin and Tebuconazole；
The structural formula of the nitre Fluoxastrobin is as follows:
The mass percent that the active constituent accounts for Recompounded pesticide is 30%, and the 28- high brassin lactones account for compounding agriculture
The mass percent of medicine is 0.01%；
The mass ratio 1.72: 29 of the component nitre Fluoxastrobin and Tebuconazole of the active constituent between the two；
The seed treatment dry powder doses that mass percentage is 30% are configured to according to conventional formulation method.
Embodiment 6
A kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii, including active constituent and the high brassin lactones of 28- table, it is described
Active constituent is compounded by Fluoxastrobin and Tebuconazole；
The mass percent that the active constituent accounts for Recompounded pesticide is 30%, and the high brassin lactones of 28- table account for compounding
The mass percent of pesticide is 0.009%；
The mass ratio 1.54: 19 of the component Fluoxastrobin and Tebuconazole of the active constituent between the two；
The granule that mass percentage is 30% is configured to according to conventional formulation method.
Embodiment 7
A kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii, including active constituent and mixed table brassin lactones, the work
Property ingredient is compounded by nitre Fluoxastrobin and difenoconazole；
The structural formula of the nitre Fluoxastrobin is as follows:
The mass percent that the active constituent accounts for Recompounded pesticide is 12%, and the mixed table brassin lactones account for Recompounded pesticide
Mass percent be 0.0085%；
The mass ratio 1.25: 8 of the component nitre Fluoxastrobin and difenoconazole of the active constituent between the two；
The wettable powder that active components mass percentage is 12% is prepared according to conventional preparation method.
Embodiment 8
A kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii, including active constituent and 14- hydroxyl brassinosteroids, it is described
Active constituent is compounded by Fluoxastrobin and Tebuconazole；
The mass percent that the active constituent accounts for Recompounded pesticide is 10%, and the 14- hydroxyl brassinosteroids account for compounding
The mass percent of pesticide is 0.0095%；
The mass ratio 1.7: 22 of the component Fluoxastrobin and Tebuconazole of the active constituent between the two；
The aqueous emulsion that mass percentage is 10% is configured to according to conventional formulation method.
Test example
1, test objective
1. probing into the experiment drug effect after different brassin lactones class compounds and peanut seed seed dressing；
2. probing into methoxy acrylic bactericide and triazole bactericidal agent to compound with brassin lactones class compound, it is
It is no to there is a possibility that synergy prevents peanut sclerotium rolfsii.
2, test medicine
0.01%28- high brassin lactones missible oil, the prosperous nation's science and technology limited Company production in Jiangxi；
0.01%24- table brassin lactones aqua, the prosperous nation's science and technology limited Company production in Jiangxi；
0.01%25- methyl brassin lactones microemulsion, the prosperous nation's science and technology limited Company production in Jiangxi；
0.003% propionylbrassinolide aqua, the prosperous nation's science and technology limited Company production in Jiangxi；
The high brassin lactones missible oil of 0.01%28- table, the prosperous nation's science and technology limited Company production in Jiangxi；
0.01% mixed table brassin lactones missible oil, the prosperous nation's science and technology limited Company production in Jiangxi；
0.0075%14- hydroxyl brassinosteroids missible oil, Chengdu New Sun Crop Science Co., Ltd.'s production；
25% nitre Fluoxastrobin suspending agent (self-control), 250 grams per liter Fluoxastrobin missible oil (self-control), 40% difenoconazole suspending
Agent (self-control), 430 grams per liter tebuconazole suspension concentrates (self-control).
3, subjects
Peanut seed
4, experimental design and method
1. by the corn seed after coating, uniform dibbling to the rectangular box of 1500ml carries out nature culture, 24 flowers
Non-hibernating eggs/repeat (6 cave 4/cave *), is arranged 1 repetition, depth of planting 2cm.
2. then, covering southern blight spore on the peanut seed in every cave.
3. distinguishing the strain number of the sowing date of each processing, emergence date, emergence rate, emergence strain number, generation deadwood
It is observed, and records in real time.
4. the indexs such as the mycelia dip dyeing situation for not sending out seed to each processing are investigated.
5, test result
The drug effect of prevention peanut sclerotium rolfsii is applied alone in the different brassin lactones class compounds of table 1
From upper table 1: all brassin kinds are applied alone, and all can not effectively guard against the generation of peanut sclerotium rolfsii in advance, cause
Peanut number of emerging is few.
The drug effect of prevention peanut sclerotium rolfsii is applied alone in the different fungicide of table 2
By upper table 2 it is found that the generation that can not effectively prevent peanut sclerotium rolfsii is applied alone in different fungicide, mycelia is caused to grow
There is different degrees of sprawling.
The drug effect of the Recompounded pesticide of the present invention of table 3 prevention peanut sclerotium rolfsii
By upper table 3 it is found that methoxy acrylic bactericide (nitre Fluoxastrobin or Fluoxastrobin) and triazole bactericidal agent (benzene
Ether methyl cyclic-azole or Tebuconazole) and brassin lactones class compound (28- high brassin lactones, 24- table brassin lactones, 25- methyl
Brassin lactones, propionylbrassinolide, the high brassin lactones of 28- table, mixed table brassin lactones or 14- hydroxyl brassin steroid
Alcohol) manufactured pesticide is compounded, there is fairly obvious synergistic effect to the drug effect of prevention peanut sclerotium rolfsii.
Above-described embodiment is only more excellent embodiment of the invention, is implemented according to the technical essence of the invention to above
Any simple modification, modification and the alternate variation that example is made, belong in the range of technical solution of the present invention.
Claims (7)
1. a kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii, which is characterized in that including active constituent and brassin lactones class
Compound, the active constituent are compounded by methoxy acrylic bactericide and triazole bactericidal agent.
2. a kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii according to claim 1, which is characterized in that the methoxy
Base acrylic bactericide is selected from one of nitre Fluoxastrobin or Fluoxastrobin；
The structural formula of the nitre Fluoxastrobin is as follows:
3. a kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii according to claim 1, which is characterized in that the triazole
Class fungicide is selected from one of difenoconazole or Tebuconazole.
4. a kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii according to claim 1, which is characterized in that the rape
Plain lactone compound is selected from 28- high brassin lactones, 24- table brassin lactones, 25- methyl brassin lactones, propionyl rape
Any one in plain lactone, the high brassin lactones of 28- table, mixed table brassin lactones or 14- hydroxyl brassinosteroids.
5. a kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii according to claim 1, which is characterized in that the activity
The mass percent that ingredient accounts for Recompounded pesticide is 1~50%, and the brassin lactones class compound accounts for the quality hundred of Recompounded pesticide
Divide than being 0.0075~0.01%.
6. a kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii according to claim 1, which is characterized in that the activity
The mass ratio (1~1.75) of the component methoxy acrylic bactericide and triazole bactericidal agent of ingredient between the two: (5~
30)。
7. a kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii according to claim 1, which is characterized in that the compounding
The dosage form of pesticide can be selected from wettable powder, suspending agent, water dispersible granules, aqueous emulsion, seed treatment dry powder doses or granule
In any one.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910565020.6A CN110199998A (en) | 2019-06-27 | 2019-06-27 | A kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910565020.6A CN110199998A (en) | 2019-06-27 | 2019-06-27 | A kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii |
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| CN110199998A true CN110199998A (en) | 2019-09-06 |
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| CN201910565020.6A Pending CN110199998A (en) | 2019-06-27 | 2019-06-27 | A kind of Recompounded pesticide of synergy prevention peanut sclerotium rolfsii |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1719970A (en) * | 2002-12-03 | 2006-01-11 | 孟山都技术有限公司 | Method of protecting seeds treated with a phytotoxic agent |
| CN105594720A (en) * | 2015-12-18 | 2016-05-25 | 广东中迅农科股份有限公司 | Pesticide composition containing pyraclostrobin and brassinolide |
| CN108689950A (en) * | 2018-05-15 | 2018-10-23 | 河南省科学院高新技术研究中心 | [(6- substitutions-pyrimidine-4-yl oxygen) Ben Ji ]- 3- methoxy-methyl acrylates |
| CN109362770A (en) * | 2018-11-12 | 2019-02-22 | 安徽农业大学 | A kind of insecticidal and bactericidal composition containing Diacloden, pyraclostrobin and triazole type |
-
2019
- 2019-06-27 CN CN201910565020.6A patent/CN110199998A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1719970A (en) * | 2002-12-03 | 2006-01-11 | 孟山都技术有限公司 | Method of protecting seeds treated with a phytotoxic agent |
| CN105594720A (en) * | 2015-12-18 | 2016-05-25 | 广东中迅农科股份有限公司 | Pesticide composition containing pyraclostrobin and brassinolide |
| CN108689950A (en) * | 2018-05-15 | 2018-10-23 | 河南省科学院高新技术研究中心 | [(6- substitutions-pyrimidine-4-yl oxygen) Ben Ji ]- 3- methoxy-methyl acrylates |
| CN109362770A (en) * | 2018-11-12 | 2019-02-22 | 安徽农业大学 | A kind of insecticidal and bactericidal composition containing Diacloden, pyraclostrobin and triazole type |
Non-Patent Citations (1)
| Title |
|---|
| 卢秀兵 等: "不同药剂防治水稻稻曲病药效试验研究", 《现代农业科技》 * |
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