CN110183250A - A kind of preparation process of dry granular glazing on glass Mosaic surface - Google Patents
A kind of preparation process of dry granular glazing on glass Mosaic surface Download PDFInfo
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- CN110183250A CN110183250A CN201910424602.2A CN201910424602A CN110183250A CN 110183250 A CN110183250 A CN 110183250A CN 201910424602 A CN201910424602 A CN 201910424602A CN 110183250 A CN110183250 A CN 110183250A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of preparation processes of glass Mosaic, comprising the following steps: (1) prepares mosaic green body, print low temperature glass dry granular in billet surface by printing machine, the mosaic green body after printing is carried out pre-burning；(2) the mosaic billet surface glazing after pre-burning；(3) green body after glazing is sent into roller kilns and is sintered.Correspondingly, the invention also discloses the glass Mosaic that above-mentioned preparation process is prepared into.Mosaic made of this preparation process, surface texture is clear, and three-dimensional sense is strong, and the tender property of glaze is good, and compared to existing Mosaic product, manufactured Mosaic product surface decoration effect is more abundant, and whole preparation process is simple.It is rationally compounded, can be sintered at low temperature by the raw material of glaze, more the saving energy.
Description
Technical field
A kind of preparation work the present invention relates to mosaic technical field more particularly to dry granular glazing on glass Mosaic surface
Skill.
Background technique
Mosaic is also known as mosaic tile or leatheroid brick, rises in ancient Greek.For being combined into the piece of various decorative patterns in building
Shape small tiles.Blank is fired into mosaic tile in kiln, is mainly used for floor file or inner wall decoration, it can also be used to exterior wall through semi-dry pressing
Facing.With the continuous improvement of people's living standards, people are also changing the decoration pursuit of household internal, to decorative wall brick
It is required that being also continuously improved.
For home decoration, more and more people tend to select the more unique mosaic of moulding, and existing at present
Mosaic product surface effect is single, cannot meet the needs.Therefore a kind of work of abundant mosaic surface decoration effect is developed
Skill is extremely important.
Summary of the invention
It is an object of the invention to propose a kind of preparation process of glass Mosaic, saving energy simple with preparation process
The characteristics of source.
Another object of the present invention is to propose a kind of glass Mosaic, have the characteristics that three-dimensional sense, incrustation are abundant.
To achieve this purpose, the present invention adopts the following technical scheme:
A kind of preparation process of glass Mosaic, comprising the following steps:
(1) mosaic green body is prepared, low temperature glass dry granular is printed in billet surface by printing machine, by the Marseille after printing
Gram green body carries out pre-burning；
(2) the mosaic billet surface glazing after pre-burning；
(3) green body after glazing is sent into roller kilns and is sintered.
Further, the size of low temperature glass dry granular is 120-200 mesh in step (1).
Further, the temperature of mosaic green body pre-burning is 700-760 DEG C in step (1), time 60min.
Further, glaze includes the following raw material by weight in step (2): 70-80 parts of cryogenic glass powder, titanium dioxide 5-
10 parts, 5-10 parts of silica flour, 0-10 parts of low temperature frit, 0-5 parts of colorant.
Further, the glaze volume of green body is (0.6-1.0) kg/m in step (2)2。
Further, the sintering temperature of green body is 790-820 DEG C in step (3), time 80-90min.
Further, above-mentioned glaze glaze slip preparation process the following steps are included:
(1) low temperature glass, titanium dioxide, silica flour, low temperature frit are weighed respectively according to the proportion, 200 mesh is screened to respectively, adds
Enter 1-2 parts and hydroxymethyl cellulose 0.2-0.8 parts of stabilizer, water is added to carry out mixing and ball milling, obtains base glaze slip；
(2) the base glaze slip for obtaining step (1), adds water mixing to adjust the density of glaze, and colorant is added according to weight ratio,
It stirs evenly, glazing glaze slip is made.
Further, ball milling presses material, ball, water quality ratio 1:2:(0.8-1.2 in step (1)), the mixing and ball milling time is 2-
3h。
Further, the density of glaze is 1.30 ± 0.1g/cm in step (2)3。
A kind of glass Mosaic, including mosaic green body and positioned at the dry granule layer and glaze layer of mosaic billet surface, dry granular
Layer is to be printed to be formed by above-mentioned low temperature glass dry granular；Glaze layer is to be fired to be formed by above-mentioned glaze.
The invention has the benefit that low temperature glass dry granular is printed in mosaic billet surface by screen printing, in horse
Simultaneously mosaic is made in match gram billet surface glazing after low-firing.Mosaic surface texture made of this technology is clear,
Three-dimensional sense and crystalistic sense are strong, and the glaze even compact that is fired into, tender property are good, and surface decoration effect is more abundant.Whole system
Standby simple process, for the glaze using low temperature glass as cardinal principle, formula system is simple, is free of contaminant component, passes through glaze
Raw material is rationally compounded and can be sintered at low temperature, more the saving energy.Additionally by the addition adjustable glaze being fired into of colorant
Layer color increases the diversity on manufactured mosaic surface, keeps the application range of mosaic wider.
Specific embodiment
Technical solution of the present invention is further illustrated below by specific embodiment.
A kind of preparation process of glass Mosaic, comprising the following steps:
(1) mosaic green body is prepared, low temperature glass dry granular is printed in billet surface by printing machine, by the Marseille after printing
Gram green body carries out pre-burning；
(2) the mosaic billet surface glazing after pre-burning；
(3) green body after glazing is sent into roller kilns and is sintered.
The present invention proposes a kind of glass Mosaic preparation process, prepares mosaic base using existing mosaic body recipe
Body prints low temperature glass dry granular by printing machine in mosaic billet surface, by the mosaic base after printing low temperature glass dry granular
Finally glass Mosaic is made by low-temperature sintering in body pre-burning, glazing on the green body after pre-burning.
Printing low temperature glass dry granular is by the way of screen printing, and manufactured mosaic level is abundant, three-dimensional sense is strong.It is low
The thickness of warm glass dry granular can be used to adjust the three-dimensional sense of mosaic finished surface, and the thickness of low temperature glass dry granular is big, is made
Mosaic surface three-dimensional sense it is strong.Mosaic billet surface glazing after pre-burning, the mode of glazing are the glaze that will be modulated
Material by the random spray gun of glaze cabinet is sprayed onto billet surface, the glazing by the way of glaze spraying, can achieve that glazing is high-efficient and glaze
Smooth effect.
Mosaic made of this preparation process, surface texture is clear, and three-dimensional sense is strong, and the tender property of glaze is good, compared to existing
Some Mosaic products, manufactured Mosaic product surface decoration effect is more abundant, and whole preparation process is simple.Pass through glaze
The raw material of material rationally compounds, and can be sintered at low temperature, more the saving energy.
Further, the size of low temperature glass dry granular is 120-200 mesh in step (1).
The granular size of low temperature glass dry granular is related with the mosaic finished surface grain effect of formation, low temperature glass dry granular
Less than 120 mesh, the mosaic picture on surface texture texture of formation is poor；Low temperature glass dry granular is greater than 200 mesh, the mosaic table of formation
Face pattern texture crystalistic sense is poor；For low temperature glass dry granular size in 120-200 mesh, manufactured mosaic picture on surface texture is clear
It is clear, crystalistic sense is strong.
Further, the temperature of mosaic green body pre-burning is 700-760 DEG C in step (1), time 60min.
Green body after printing low temperature glass dry granular is subjected to pre-burning, keeps the low temperature glass dry granular for printing formation on green body
Complete pattern prevents from damaging in glazing process, and lower biscuiting temperature can guarantee billet surface there are more gap,
Facilitate glazing, moreover it is possible to guarantee that billet surface sucking is uniform, so that glaze is smooth, be conducive to the firing quality for improving glaze.
Further, glaze includes the following raw material by weight in step (2): 70-80 parts of cryogenic glass powder, titanium dioxide 5-
10 parts, 5-10 parts of silica flour, 0-10 parts of low temperature frit, 0-5 parts of colorant.
Glaze is added made of titanium dioxide, silica flour, low temperature frit and colorant, matches using low temperature glass as primary raw material
Cube system is simple, and is free of contaminant component.Wherein, cryogenic glass powder can also be substituted for simple glass powder.Titanium dioxide conduct
Brightening agent can be further improved the whiteness of glaze.The melting temperature of glaze can be improved in addition silica flour, increases glaze and base
The viscosity of body reduces thermal expansion coefficient, improves the hardness and wearability of manufactured glaze layer.The additive amount of silica flour is 5-10 parts
When, manufactured glaze glossiness is good；When the additive amount of silica flour is less than 5 parts, manufactured glaze glossiness can be reduced；Silica flour
When additive amount is greater than 10 parts, glaze layer is burnt not yet done in the temperature of setting.Low temperature frit plays fluxing effect, and low temperature frit adds
When dosage is 0-10 parts, the glaze even compact that is fired into, tender property are good；When not adding low temperature frit, the glaze light that is fired into
Damp degree is poor；When the additive amount of low temperature frit is greater than 10 parts, the glaze being fired into has pin hole, and at high cost.Increase color in the feed
Expect the color of adjustable glaze, increases the diversity for being fired into glaze.Colorant can be copper oxide, titanium dioxide, iron oxide, dioxy
Change manganese etc..
Further, the glaze volume of green body is (0.6-1.0) kg/m in step (2)2。
Glazed thickness is controlled by glaze volume in suitable range.Glaze volume is (0.6-1.0) kg/m2When, it is manufactured
Glaze dense uniform；Glaze volume is greater than 1.0kg/m2When, glaze layer is blocked up to be caused to generate faint stress in glaze layer, weaken the bullet of glaze
Property, make glaze layer shattered crack；Glaze volume is less than 0.6kg/m2When, glaze layer is excessively thin so that liquid phase is absorbed by green body when firing, and make glaze
It is withered and unglazed.
Further, the sintering temperature of green body is 790-820 DEG C in step (3), time 80-90min.
Make the more uniform densification of glazing effect of firing by controlling sintering range, glaze color development is stablized.Sintering
Temperature is lower than 790 DEG C, the glaze low in glossiness of formation, and pin hole is more；Sintering temperature is greater than 820 DEG C, and mosaic blank deformation is soft
Change, burning expansion.
Further, above-mentioned glaze glaze slip preparation process the following steps are included:
(1) low temperature glass, titanium dioxide, silica flour, low temperature frit are weighed respectively according to the proportion, 200 mesh is screened to respectively, adds
Enter 1-2 parts and hydroxymethyl cellulose 0.2-0.8 parts of stabilizer, water is added to carry out mixing and ball milling, obtains base glaze slip；
(2) the base glaze slip for obtaining step (1), adds water mixing to adjust the density of glaze, and colorant is added according to weight ratio,
It stirs evenly, glazing glaze slip is made.
Glaze slip preparation is to obtain base glaze slip by adding a small amount of water to carry out ball milling raw material.Add water to be in order to facilitate ball milling, makes
Obtained base glaze slip is more uniform, adds water and deploys base glaze slip to the density of suitable hanging, herein plus water is to adjust
The density of glaze slip.Add the glaze slip of the available more uniform exquisiteness of water twice by separating.
Stabilizer is added in the feed can be improved glaze slip stability, and stabilizer is preferably ethylene glycol, meets process conditions
And it is at low cost.Hydroxymethyl cellulose plays the role of bonding glaze slip and green body before glaze firing, and the glaze layer on green body is made to exist
It is not easy to peel off in transportational process, moreover it is possible to play suspension effect, the particle in glaze slip is made to be not easy to precipitate.
Further, ball milling presses material, ball, water quality ratio 1:2:(0.8-1.2 in step (1)), the mixing and ball milling time is 2-
3h。
Material, ball, water weight ratio are 1:2:(0.8~1.2) when, more evenly, grinding rate faster, is ground the granularity of mixture
It grinds more efficient.Mixture ball milling 2-3h, when powder particles between mix more uniform, fineness is more uniform.
Further, the density of glaze is 1.30 ± 0.1g/cm in step (2)3。
The density of glaze slip is lower than 1.20g/cm3When, the glaze layer of firing has watermark, and the density of glaze slip is higher than 1.40/cm3
When, the glaze layer of firing has glaze bubble and pin hole, uses density for 1.30 ± 0.1g/cm3Glaze slip on green body charity formed
Glaze layer bubble-free, pin hole and watermark, glaze layer is high-quality.
A kind of glass Mosaic, including mosaic green body and positioned at the dry granule layer and glaze layer of mosaic billet surface, dry granular
Layer is that above-mentioned low temperature glass dry granular is printed to be formed；Glaze layer is to be fired to be formed by above-mentioned glaze.
Low temperature glass dry granular and charity glaze slip are printed on mosaic green body, and the three-dimensional sense on mosaic surface can be enhanced,
The surface decoration effect of abundant mosaic, keeps application range wider.
The present invention is further explained by the following examples.
Experimental group A is the preparation process of glaze slip, and the glaze formula of glaze is as shown in table 1 in embodiment A1-A5:
The composition of raw materials of the glaze of 1 glaze of table in parts by weight
The preparation process of experimental group A glaze slip, comprising the following steps:
(1) low temperature glass, titanium dioxide, silica flour, low temperature frit are weighed respectively according to the proportion, 200 mesh is screened to respectively, presses
Stabilizer and hydroxymethyl cellulose is added according to the raw material proportioning of 1 glaze of table, presses material, ball, water weight ratio 1:2:(0.8-1.2) to mixing
Add water for ball milling 2-3h in material, obtains base glaze slip；
(2) the base glaze slip for obtaining step (1) adds water mixing to adjust the density of glaze, according to the raw material proportioning of 1 glaze of table
Colorant is added, stirs evenly, glazing glaze slip is made.
In embodiment A1-A5, the glaze slip preparation process of glaze is as shown in table 2:
Table 2
| Project | Embodiment A1 | Embodiment A2 | Embodiment A3 | Embodiment A4 | Embodiment A5 |
| Ball milling ratio | 1:2:1.2 | 1:2:0.9 | 1:2:0.8 | 1:2:1 | 1:2:1.1 |
| Ball-milling Time h | 2 | 3 | 3 | 2.5 | 2 |
| Glaze slip density g/cm3 | 1.25 | 1.4 | 1.3 | 1.2 | 1.35 |
Embodiment group B is glass Mosaic
The glass Mosaic of embodiment B1-B5 includes mosaic green body and the glaze layer positioned at mosaic billet surface, glaze layer
It is made of being fired as the glaze slip of one of embodiment A1-A5.The preparation process of the glass Mosaic, comprising the following steps:
(1) mosaic green body is prepared, low temperature glass dry granular is printed in billet surface by printing machine, by the Marseille after printing
Gram green body pre-burning 60min at 700-760 DEG C；
(2) glaze slip made of one of mosaic billet surface application embodiment A1-A5 after pre-burning, glaze volume are
(0.6-1.0)kg/m2；
(3) green body after glazing is sent into roller kilns and is sintered, obtain glass Mosaic.
In embodiment B1-B5, the glaze slip and preparation technology parameter of glass Mosaic are as shown in table 3:
Table 3
Comparative example 1
Under the conditions of identical preparation step in embodiment A5 and embodiment B5 and identical technological parameter, change glaze
The proportion of the recipe ingredient of material, as shown in table 4:
The composition of raw materials of 4 parts by weight meter of table
Above-mentioned glaze formula is prepared into glaze slip according to the preparation method in embodiment A5, further according to the preparation in embodiment B5
Step and process conditions prepare glass Mosaic.
Comparative example 2
Under the conditions of identical formula in embodiment A5 and embodiment B5 and identical preparation step, change low temperature glass
The size of glass dry granular, the sintering temperature of glass Mosaic and time, as shown in table 5:
| Comparative example | Low temperature glass dry granular size/mesh | Sintering temperature DEG C | Sintering time min |
| Comparative example 2-1 | 100 | 780 | 95 |
| Comparative example 2-2 | 220 | 830 | 75 |
By the low temperature glass dry granular size in embodiment B5, parameter shown in sintering temperature and time adjustment to table 5, according still further to
Preparation step in embodiment A5 and embodiment B5 prepares glass Mosaic.
The glass Mosaic prepared in above-described embodiment group A and B, comparative example group 1 and 2 is subjected to glazing effect ratio
Compared with result is as shown in table 6 below:
Table 6: the glazing effect of glass Mosaic in embodiment B1-B5 and comparative example
| Embodiment | Surface texture | Glazing effect | Glaze color |
| Embodiment B1 | Clean mark, crystalistic sense are strong | Even compact, tender property are good | Color development is stablized |
| Embodiment B2 | Clean mark, crystalistic sense are strong | Even compact, tender property are good | Color development is stablized |
| Embodiment B3 | Clean mark, crystalistic sense are strong | Even compact, tender property are good | Color development is stablized |
| Embodiment B4 | Clean mark, crystalistic sense are strong | Even compact, tender property are good | Color development is stablized |
| Embodiment B5 | Clean mark, crystalistic sense are strong | Even compact, tender property are good | Color development is stablized |
| Comparative example 1-1 | Clean mark, crystalistic sense are strong | Glaze layer is burnt not yet done | - |
| Comparative example 1-2 | Clean mark, crystalistic sense are strong | There is pin hole | Low in glossiness |
| Comparative example 2-1 | Texture texture is poor | Even compact, tender property are good | Blank deformation softening |
| Comparative example 2-2 | Texture crystalistic sense is poor | Pin hole is more | Low in glossiness |
As can be seen from Table 6, the glass Mosaic surface texture being prepared by embodiment group A and B is clear, three-dimensional sense and
Crystalistic sense is strong, and glazing effect is stablized, even compact, and color development is stablized；And in comparative example 1-1 using high level silica flour and
Low temperature frit, manufactured mosaic glaze layer do not cook under the conditions of the temperature of setting；Lower content is used in comparative example 1-2
Silica flour and low temperature frit, manufactured mosaic glaze has pin hole, and low in glossiness；Reduce low temperature glass in comparative example 2-1
The size of glass dry granular and the temperature for reducing sintering, mosaic surface texture texture obtained is poor, and glaze has pin hole, gloss
It is poor to spend；Increase the size of low temperature glass dry granular in comparative example 2-2 and increases the temperature of sintering, mosaic surface texture obtained
Crystalistic sense is poor, and glaze pin hole is more, and low in glossiness.
Therefore, mosaic billet surface is printed on by printing machine using a certain size low temperature glass dry granular, after pre-burning,
A certain amount of cryogenic glass powder of its surface applied, titanium dioxide, silica flour, low temperature frit and colorant compound manufactured glaze slip again, low
After temperature is fired, it can obtain that surface texture is clear, and three-dimensional sense and crystalistic sense are strong, glaze layer even compact, the stable mosaic of color development,
The surface decoration effect for enriching mosaic, the range for applying it are wider.
The technical principle of the invention is described above in combination with a specific embodiment.These descriptions are intended merely to explain of the invention
Principle, and shall not be construed in any way as a limitation of the scope of protection of the invention.Based on the explanation herein, the technology of this field
Personnel can associate with other specific embodiments of the invention without creative labor, these modes are fallen within
Within protection scope of the present invention.
Claims (10)
1. a kind of preparation process of glass Mosaic, which comprises the following steps:
(1) mosaic green body is prepared, low temperature glass dry granular is printed in billet surface by printing machine, by the mosaic base after printing
Body carries out pre-burning；
(2) the mosaic billet surface glazing after pre-burning；
(3) green body after glazing is sent into roller kilns and is sintered.
2. the preparation process of glass Mosaic according to claim 1, which is characterized in that low temperature glass described in step (1)
The size of glass dry granular is 120-200 mesh.
3. the preparation process of glass Mosaic according to claim 1, which is characterized in that mosaic described in step (1)
The temperature of green body pre-burning is 700-760 DEG C, time 60min.
4. the preparation process of glass Mosaic according to claim 1, which is characterized in that glaze described in step (2) is pressed
Parts by weight include the following raw material: 70-80 parts of cryogenic glass powder, 5-10 parts of titanium dioxide, 5-10 parts of silica flour, low temperature frit 0-10
Part, 0-5 parts of colorant.
5. the preparation process of glass Mosaic according to claim 1, which is characterized in that green body described in step (2)
Glaze volume is (0.6-1.0) kg/m2。
6. the preparation process of glass Mosaic according to claim 1, which is characterized in that green body described in step (3)
Sintering temperature is 790-820 DEG C, time 80-90min.
7. the preparation process of glass Mosaic according to claim 4, which is characterized in that the glaze slip of the glaze prepares work
Skill the following steps are included:
(1) low temperature glass, titanium dioxide, silica flour, low temperature frit are weighed respectively according to the proportion, is screened to 200 mesh respectively, is added steady
Determine 1-2 parts and hydroxymethyl cellulose 0.2-0.8 parts of agent, water is added to carry out mixing and ball milling, obtains base glaze slip；
(2) the base glaze slip for obtaining step (1) adds water mixing to adjust the density of glaze, and colorant, stirring is added according to weight ratio
Uniformly, glazing glaze slip is made.
8. glaze slip preparation process according to claim 7, which is characterized in that ball milling described in step (1) presses material, ball, water
Mass ratio 1:2:(0.8-1.2), the mixing and ball milling time is 2-3h.
9. glaze slip preparation process according to claim 7, which is characterized in that the density of glaze described in step (2) is
1.30±0.1g/cm3。
10. a kind of glass Mosaic, which is characterized in that including mosaic green body and positioned at mosaic billet surface dry granule layer and
Glaze layer, the dry granule layer are to be printed to be formed by low temperature glass dry granular described in claim 1；The glaze layer is by claim
Glaze described in 1, which is fired, to be formed.
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Cited By (3)
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| CN111018543A (en) * | 2020-01-02 | 2020-04-17 | 杭州诺贝尔陶瓷有限公司 | Once-fired ultra-large specification thin porcelain plate and production method thereof |
| CN112456816A (en) * | 2020-12-03 | 2021-03-09 | 于发坚 | Ultra-white glass surface matte mosaic process |
| CN115677383A (en) * | 2022-11-08 | 2023-02-03 | 广西欧神诺陶瓷有限公司 | Glazed tile prepared from polishing waste residues and preparation method thereof |
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| CN112456816A (en) * | 2020-12-03 | 2021-03-09 | 于发坚 | Ultra-white glass surface matte mosaic process |
| CN115677383A (en) * | 2022-11-08 | 2023-02-03 | 广西欧神诺陶瓷有限公司 | Glazed tile prepared from polishing waste residues and preparation method thereof |
| CN115677383B (en) * | 2022-11-08 | 2023-10-20 | 广西欧神诺陶瓷有限公司 | Glazed tile prepared from polished waste residues and preparation method thereof |
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