CN107935395A - It is a kind of for the white glaze of glass surface and the preparation process of glass Mosaic - Google Patents

It is a kind of for the white glaze of glass surface and the preparation process of glass Mosaic Download PDF

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Publication number
CN107935395A
CN107935395A CN201711002151.0A CN201711002151A CN107935395A CN 107935395 A CN107935395 A CN 107935395A CN 201711002151 A CN201711002151 A CN 201711002151A CN 107935395 A CN107935395 A CN 107935395A
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glass
glaze
mosaic
white glaze
white
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CN107935395B (en
Inventor
姚文江
刘勇
王飞
任东
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FOSHAN VIEWGRES Co Ltd
Foshan Unique Decorative Building Materials Co Ltd
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FOSHAN VIEWGRES Co Ltd
Foshan Unique Decorative Building Materials Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/20Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/3411Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2204/00Glasses, glazes or enamels with special properties
    • C03C2204/04Opaque glass, glaze or enamel
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2205/00Compositions applicable for the manufacture of vitreous enamels or glazes
    • C03C2205/02Compositions applicable for the manufacture of vitreous enamels or glazes for opaque enamels or glazes
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/20Materials for coating a single layer on glass
    • C03C2217/29Mixtures
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/72Decorative coatings
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/11Deposition methods from solutions or suspensions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/11Deposition methods from solutions or suspensions
    • C03C2218/119Deposition methods from solutions or suspensions by printing
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/30Aspects of methods for coating glass not covered above
    • C03C2218/32After-treatment

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

It is a kind of for the white glaze of glass surface and the preparation process of glass Mosaic, the white glaze is according to mass percent, including the following raw material:72~82% life glass dust, 10~20% waste glass powders, 4~6% titanium dioxide, 0~0.5% auxiliary material and surplus are water;And the fineness of the white glaze is 250~300 mesh;White glaze proposed by the present invention for glass surface, not only realize and cullet powder is effectively recycled, reduce manufacturing cost, and the glazing effect of dumb light can be formed, whiteness is high, its glaze paint is uniformly and color development more stablizes distinctness, and glaze paint is more soft and smooth, its technique more simplifies, more energy conservation and environmental protection and low production cost.

Description

It is a kind of for the white glaze of glass surface and the preparation process of glass Mosaic
Technical field
The present invention relates to glass preparation processing technique field, more particularly to a kind of white glaze and glass horse for glass surface The preparation process of match gram.
Background technology
It is existing in the preparation process for the glass Mosaic with matte effect at present, typically using mosaic base Mosaic glass base substrate is made in body raw material after dry-pressing, and uses the manufacturing procedure mode of pickling after being fired again, to make The surface of glass Mosaic reaches with matte effect, but for pickling process during often produce substantial amounts of exhaust gas and Waste water, be easy to cause the pollution of environment and influences the physical and mental health of employee, while to exhaust gas waste water caused by pickling processing Processing makes manufacturing cost increase significantly, so that the production limited for dumb light glass Mosaic is used, and after overpickling If glass surface when directly carrying out ink-jet decoration, the color on its surface is unstable, color distortion and easily glaze paint occurs and lacks The problem of falling into.
The content of the invention
It is an object of the invention to propose a kind of white glaze for glass surface, not only realize effective to cullet powder Recycling, reduce manufacturing cost, and the glazing effect of dumb light can be formed, whiteness is high, its glaze paint uniformly and color development more Stablize distinctness, glaze paint is more soft and smooth.
It is another object of the present invention to propose a kind of preparation process of glass Mosaic, its with preparation process more The characteristics of simplification, more energy conservation and environmental protection and low production cost.
For this purpose, the present invention uses following technical scheme:
A kind of white glaze for glass surface, the white glaze is according to mass percent, including the following raw material:72~82% lifes Glass dust, 10~20% waste glass powders, 4~6% titanium dioxide, 0~0.5% auxiliary material and surplus are water;And the white glaze is thin Spend for 250~300 mesh.
A kind of white glaze for glass surface proposed by the present invention, wherein will raw glass dust and cullet in composition of raw materials Powder compounds by a certain percentage, that is, make use of between the life glass dust of relatively low melting temperature and the waste glass powder of high melt temperature The melting temperature formed is poor, and controls the grain fineness of powder to be eventually adding a certain amount of two in the range of 250~300 mesh Titanium oxide, auxiliary material and water are ground the low-temperature glaze obtained available for glass surface, its cloth is imposed on glass surface forms Glaze layer and after low temperature is fired, the glaze layer of the glass surface can form the matte effect of even compact, not only realize Cullet powder is more effectively recycled, reduces manufacturing cost, and dumb light glazing effect is more preferable.
Wherein, due to the increase of the firing number with waste glass powder, its melting temperature can constantly rise, therefore it is in glass During the low-firing of glass mosaic, it can be in half molten state;After it is mixed in a certain ratio with raw glass, make During firing, its puddle can fully be merged with raw glass dust, Glass body surface, so as to form stable glaze layer Structure;The particle diameter for reducing powder particles is adjusted at the same time, and by adding titanium dioxide and auxiliary material, makes powder mixing more equal It is even, make the non-melt part of waste glass powder can be distributed evenly in glaze layer, matte effect is formed under light, glaze paint is more soft It is sliding.
In addition, being used as brightening agent by adding titanium dioxide, the whiteness of glaze paint, Er Qieli can be not only further improved With titanium dioxide and raw glass dust, the abundant fusion reaction of the puddle of waste glass powder, make puddle and non-melt part Between transition more relax naturally, glaze paint carry out ink-jet after, its surface color it is distincter uniformly, so as to be beneficial to glass horse The stability of gram surface color development is matched, the texture of glaze paint is more preferable, and feel is soft and smooth, good visual effect.
Further illustrate, the waste glass powder for soda-lime-silica glass, quartz glass, high osmanthus oxygen glass, lead silicate glass, Any one or more in alumina silicate glass and canopy silicate glass.It is using the waste glass powder of said components that it is constantly heavy After resintering system, after reaching 1000 DEG C of > with its melting temperature, the matte effect of even compact can be not only realized, but also can To further improve the intensity of glaze paint and wear-resisting property.
Further illustrate, the white glaze further includes colorant, the colorant account for the mass percent of raw material gross mass for 0.1~ 6%, the colorant is inorganic ceramic colorant powder, its fineness is 250 mesh.By adding certain colorant, make colorant and glass dust Material is mutually mixed to form glass dust, the decoration glaze paint of different decorative colours can be obtained after firing, wherein can be by quality Needing to determine the dosage of colorant for effect, is preferably in percentage by weight generally 0.1%~6%, fineness is 250 mesh.
Further illustrate, the mass percent that the titanium dioxide accounts for raw material gross mass is 6%.
Further illustrate, the adjuvant includes dispersant and sagging inhibitor;The dispersant includes sodium polycarboxylate, burnt phosphorus Any one in sour sodium, calgon, ammonium polyacrylate, sodium tripolyphosphate and sodium metasilicate.By add dispersant and Sagging inhibitor, makes raw mixing between glass dust and waste glass powder more uniform and stable.
Further illustrate, the melting temperature of the raw glass dust is 600~700 DEG C, the melting temperature of the waste glass powder For 1000 DEG C of >.By controlling the melting temperature between raw glass dust and waste glass powder poor, so that it is guaranteed that being burnt in certain low temperature During system, make preferably to merge between the puddle of waste glass powder and raw glass dust, and it is non-melt partially stabilized, so that Make formed matte effect more stable and uniform.
A kind of technique that glass Mosaic is prepared using white glaze, is included the following steps:
(1) raw glass dust, waste glass powder, titanium dioxide and auxiliary material are weighed respectively according to proportioning, and add water to carry out mixing ball Mill, obtains fineness and is starched for the white glaze of 220~300 mesh;
(2) mosaic glass base substrate is prepared according to known mosaic blank raw material;
(3) starched in the surface charity white glaze of mosaic glass base substrate, form glaze layer;
(4) it is ink-jet printed in the mosaic glass base substrate progress with glaze layer, after burning till, obtain glass Mosaic.
A kind of technique for preparing glass Mosaic proposed by the present invention, wherein will be by raw glass dust, waste glass powder and dioxy Change the surface that the white glaze slurry cloth that the raw materials such as titanium prepare imposes on Glass body, finally by easy fired, you can to form tool There is matte effect and glaze paint is uniform, color development is stablized a glaze layer, compared to the existing work that matte effect can only be obtained by pickling The characteristics of skill, it more simplifies with preparation process, and more energy conservation and environmental protection, low production cost.It wherein make use of dioxy Change the compounding of titanium and glass powder, glaze paint whiteness is high, after glaze layer surface carries out ink-jet, effectively prevent because glaze paint color development is unstable Glazing effect that is fixed and influencing entirety, surface color and polish stablizes distinctness, and the texture of glaze paint is more preferable, and glaze paint is more soft and smooth.
Further illustrate, the mixing and ball milling time described in step (1) is 10~20min.According to certain Ball-milling Time, make Mixing between powder particles is more uniform, and fineness is more homogeneous.
Further illustrate, the slurry of charity white glaze described in step (3) is to spray white glaze slurry, pressure 0.3- under constant-pressure conditions 2.5Mpa.In order to ensure white glaze uniformly can impose on the surface of Glass body by cloth, avoid thickness from differing and cause to go out after firing Now lack glaze or raised phenomenon, therefore by a manner of the glaze spraying by pressure for 0.3-2.5Mpa, making glaze thickness more uniform, firing Brick face effect is more preferable afterwards.
Further illustrate, the thickness that charity white glaze is starched in step (3) is 0.05~0.15mm.By controlling white glaze pulp layer Certain thickness, is the feelings of the glaze thickness inequality of the semi-molten form in order to avoid because glaze layer is blocked up, causing to be formed after firing Condition and influence brick face effect, wherein white glaze slurry thickness be preferably 0.1mm.
Further illustrate, the temperature burnt till described in step (4) is 750 DEG C -800 DEG C.By controlling firing range, Make the dumb light glazing effect more even compact formed after burning till, glaze paint color development is more stablized.
Beneficial effects of the present invention:By the way that raw glass dust and waste glass powder are compounded by a certain percentage, and control powder For grain fineness in the range of 250~300 mesh, grinding obtains the low-temperature glaze available for glass surface, its cloth is imposed on glass table Face forms glaze layer and after low temperature is fired, and the glaze layer of the glass surface can form the matte effect of even compact, not only Realize and cullet powder is more effectively recycled, reduce manufacturing cost, and dumb light glazing effect is more preferable, and glaze paint is more It is soft and smooth.
In addition, being used as brightening agent by adding titanium dioxide, the whiteness of glaze paint, Er Qietong can be not only further improved Titanium dioxide and raw glass dust, the abundant fusion reaction of the puddle of waste glass powder are crossed, makes puddle and non-melt part Between transition more relax naturally, glaze paint carry out ink-jet after, its surface color it is distincter uniformly, so as to be beneficial to glass horse The stability of gram surface color development is matched, the texture of glaze paint is more preferable, and feel is soft and smooth, good visual effect.
Embodiment
Technical scheme is further illustrated below by embodiment.
A kind of preparation processes of glass Mosaic of embodiment 1-, include the following steps:
1st, white glaze is prepared:
(1) 82% life glass dust, 10% waste glass powder, 4% titanium dioxide and 0.5% auxiliary material are weighed respectively according to proportioning, And add in 3.5% water and carry out mixing and ball milling, Ball-milling Time 10min, obtains fineness and is starched for the white glaze of 250 mesh;
The melting temperature of wherein raw glass dust is 600~700 DEG C, and the melting temperature of waste glass powder is 1000 DEG C of >.
2nd, preparation process:
(1) mosaic glass base substrate is prepared according to known mosaic blank raw material;
(2) starched in the surface charity white glaze of mosaic glass base substrate, form glaze layer, the thickness of wherein glaze layer is 0.05mm;
(3) with glaze layer mosaic glass base substrate carry out it is ink-jet printed, after burning till, firing temperature for 750 DEG C- 800 DEG C, obtain glass Mosaic 1.
A kind of preparation processes of glass Mosaic of embodiment 2-, include the following steps:
1st, white glaze is prepared:
(1) according to proportioning weigh respectively 74% life glass dust, 12% waste glass powder, 6% titanium dioxide, 0.2% auxiliary material and 5% colorant, and add in 2.8% water and carry out mixing and ball milling, Ball-milling Time 20min, obtains fineness and is starched for the white glaze of 300 mesh;
The melting temperature of wherein raw glass dust is 600~700 DEG C, and the melting temperature of waste glass powder is 1000 DEG C of >.
2nd, preparation process:
(1) mosaic glass base substrate is prepared according to known mosaic blank raw material;
(2) surface of mosaic glass base substrate is sprayed to white glaze slurry under constant-pressure conditions, pressure 0.3Mpa, forms glaze Layer, wherein the thickness of glaze layer is 0.15mm;
(3) with glaze layer mosaic glass base substrate carry out it is ink-jet printed, after burning till, firing temperature for 750 DEG C- 800 DEG C, obtain glass Mosaic 2.
A kind of preparation processes of glass Mosaic of embodiment 3-, include the following steps:
1st, white glaze is prepared:
(1) according to proportioning weigh respectively 72% life glass dust, 20% waste glass powder, 5% titanium dioxide, 0.1% auxiliary material and 0.1% colorant, and add in 2.8% water and carry out mixing and ball milling, Ball-milling Time 15min, obtains the white glaze that fineness is 280 mesh Slurry;
The melting temperature of wherein raw glass dust is 600~700 DEG C, and the melting temperature of waste glass powder is 1000 DEG C of >.
2nd, preparation process:
(1) mosaic glass base substrate is prepared according to known mosaic blank raw material;
(2) surface of mosaic glass base substrate is sprayed to white glaze slurry under constant-pressure conditions, pressure 2.5Mpa, forms glaze Layer, wherein the thickness of glaze layer is 0.1mm;
(3) with glaze layer mosaic glass base substrate carry out it is ink-jet printed, after burning till, firing temperature for 750 DEG C- 800 DEG C, obtain glass Mosaic 3.
Under the conditions of comparative example group 1- is according to preparation process identical in embodiment 3 and identical experiment parameter, change Become the proportioning of the recipe ingredient of white glaze, it is as shown in the table:
Comparative example 1-1:
Raw material Raw glass dust Waste glass powder Auxiliary material Titanium dioxide Colorant Water
Percentage 87% 5% 0.1% 5% 0.1% 2.8%
Comparative example 1-2:
Raw material Raw glass dust Waste glass powder Auxiliary material Titanium dioxide Colorant Water
Percentage 67% 25% 0.1% 5% 0.1% 2.8%
Above-mentioned white glaze composition of raw materials is prepared into white glaze slurry according to the preparation method in embodiment 3, and according in embodiment 3 Preparation process prepares glass Mosaic 4 and glass Mosaic 5.
Under the conditions of comparative example group 2- is according to preparation process identical in embodiment 3 and identical experiment parameter, change Become the proportioning of the recipe ingredient of white glaze, it is as shown in the table:
Comparative example 2-1:
Raw material Raw glass dust Waste glass powder Auxiliary material Colorant Water
Percentage 77% 20% 0.1% 0.1% 2.8%
Comparative example 2-2:
Raw material Raw glass dust Waste glass powder Auxiliary material Titanium dioxide Colorant Water
Percentage 74% 20% 0.1% 3% 0.1% 2.8%
Above-mentioned white glaze composition of raw materials is prepared into white glaze slurry according to the preparation method in embodiment 3, and according in embodiment 3 Preparation process prepares glass Mosaic 6 and glass Mosaic 7.
The glass Mosaic prepared in above-described embodiment 1~3 and comparative example group 1 and 2 is subjected to glazing effect Compare, its result such as table 1 below:
Table 1:The glazing effect of different glass mosaic
As can be seen from Table 1, the matte effect for the glass Mosaic being prepared into by embodiment 1~3 is good, and glazing effect is steady Fixed, intact glaze phenomenon, whiteness is high, and it is with the characteristics of glaze paint uniform in color, glaze paint is soft and smooth;And comparative example group 1-1 In, the waste glass powder and raw glass dust that employ lower content compound, its reflectance is higher, matte effect unobvious;Contrast is real Apply in example group 1-2, the waste glass powder and raw glass dust for employing high level compound, its glaze paint part occurs and lacks showing for glaze As;In comparative example group 2-1, do not add titanium dioxide to prepare in white glaze, and comparative example group 2-2, employ compared with A small amount of titanium dioxide prepares white glaze, its glaze paint whiteness is relatively low, and the phenomenon of partial color distortion occurs in both of which.Cause This, is compounded using a certain amount of raw glass dust, waste glass powder and titanium dioxide, the low temperature available for glass surface of acquisition After glaze is fired, glazing effect is more preferable, and whiteness is high, and color stable is uniform.
Above in association with the specific embodiment technical principle that the invention has been described.These descriptions are intended merely to explain the present invention's Principle, and limiting the scope of the invention cannot be construed in any way.Based on explanation herein, the technology of this area Personnel would not require any inventive effort the other embodiments that can associate the present invention, these modes are fallen within Within protection scope of the present invention.

Claims (10)

  1. A kind of 1. white glaze for glass surface, it is characterised in that:The white glaze is according to mass percent, including the following raw material: 72~82% life glass dust, 10~20% waste glass powders, 4~6% titanium dioxide, 0~0.5% auxiliary material and surplus are water;And institute The fineness for stating white glaze is 250~300 mesh.
  2. A kind of 2. white glaze for glass surface according to claim 1, it is characterised in that:The waste glass powder is sodium calcium It is any one in silica glass, quartz glass, high osmanthus oxygen glass, lead silicate glass, alumina silicate glass and canopy silicate glass Kind is a variety of.
  3. A kind of 3. white glaze for glass surface according to claim 1, it is characterised in that:The white glaze further includes color Material, the mass percent that the colorant accounts for raw material gross mass is 0.1~6%, and the colorant is inorganic ceramic colorant powder, its fineness For 250 mesh.
  4. A kind of 4. white glaze for glass surface according to claim 1, it is characterised in that:The titanium dioxide accounts for raw material The mass percent of gross mass is 6%.
  5. A kind of 5. white glaze for glass surface according to claim 1, it is characterised in that:The adjuvant includes scattered Agent and sagging inhibitor;The dispersant includes sodium polycarboxylate, sodium pyrophosphate, calgon, ammonium polyacrylate, sodium tripolyphosphate With any one in sodium metasilicate.
  6. 6. the white glaze in a kind of usage right requirement 1~5 described in any one prepares the technique of glass Mosaic, its feature exists In:Include the following steps:
    (1) raw glass dust, waste glass powder, titanium dioxide and auxiliary material are weighed respectively according to proportioning, and add water to carry out mixing and ball milling, obtain Fineness is obtained to starch for the white glaze of 220~300 mesh;
    (2) mosaic glass base substrate is prepared according to known mosaic blank raw material;
    (3) starched in the surface charity white glaze of mosaic glass base substrate, form glaze layer;
    (4) it is ink-jet printed in the mosaic glass base substrate progress with glaze layer, after burning till, obtain glass Mosaic.
  7. A kind of 7. preparation process of glass Mosaic according to claim 6, it is characterised in that:Mixed described in step (1) Conjunction Ball-milling Time is 10~20min.
  8. A kind of 8. preparation process of glass Mosaic according to claim 6, it is characterised in that:Cloth described in step (3) It is to spray white glaze slurry, pressure 0.3-2.5Mpa under constant-pressure conditions to apply white glaze slurry.
  9. A kind of 9. preparation process of glass Mosaic according to claim 6, it is characterised in that:Charity is white in step (3) The thickness of glaze slip is 0.05~0.15mm.
  10. A kind of 10. preparation process of glass Mosaic according to claim 5, it is characterised in that:Step is burnt described in (4) Into temperature be 750 DEG C -800 DEG C.
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110183250A (en) * 2019-05-21 2019-08-30 佛山市唯格装饰建材有限公司 A kind of preparation process of dry granular glazing on glass Mosaic surface
US20200139750A1 (en) * 2018-07-18 2020-05-07 Foshan Pamase Building Material Co., Ltd. Full-body marble-patterned glass mosaic and preparation method thereof
CN112456816A (en) * 2020-12-03 2021-03-09 于发坚 Ultra-white glass surface matte mosaic process
CN116395964A (en) * 2023-04-11 2023-07-07 福建省德化新圣美陶瓷有限公司 White porcelain glaze and method for preparing ceramic product by using same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101386472A (en) * 2008-10-07 2009-03-18 姚文江 Crystal glass mosaic and manufacturing method thereof
CN102491791A (en) * 2011-11-25 2012-06-13 广东道氏技术股份有限公司 Antique matte glaze with delicate texture and using method thereof
CN104446657A (en) * 2014-10-31 2015-03-25 佛山市高明区海帝陶瓷原料有限公司 Dry granular additive for full polishing of ceramic tiles and preparation method of dry granular additive
CN105130193A (en) * 2015-07-14 2015-12-09 湖南华联瓷业股份有限公司 Low-temperature matte reaction glaze and production method thereof
CN106746656A (en) * 2016-12-09 2017-05-31 石家庄学院 A kind of low temperature fast firing matt glaze and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101386472A (en) * 2008-10-07 2009-03-18 姚文江 Crystal glass mosaic and manufacturing method thereof
CN102491791A (en) * 2011-11-25 2012-06-13 广东道氏技术股份有限公司 Antique matte glaze with delicate texture and using method thereof
CN104446657A (en) * 2014-10-31 2015-03-25 佛山市高明区海帝陶瓷原料有限公司 Dry granular additive for full polishing of ceramic tiles and preparation method of dry granular additive
CN105130193A (en) * 2015-07-14 2015-12-09 湖南华联瓷业股份有限公司 Low-temperature matte reaction glaze and production method thereof
CN106746656A (en) * 2016-12-09 2017-05-31 石家庄学院 A kind of low temperature fast firing matt glaze and preparation method thereof

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US20200139750A1 (en) * 2018-07-18 2020-05-07 Foshan Pamase Building Material Co., Ltd. Full-body marble-patterned glass mosaic and preparation method thereof
US11766889B2 (en) * 2018-07-18 2023-09-26 Foshan Pamase Building Material Co., Ltd. Full-body marble-patterned glass mosaic and preparation method thereof
CN110183250A (en) * 2019-05-21 2019-08-30 佛山市唯格装饰建材有限公司 A kind of preparation process of dry granular glazing on glass Mosaic surface
CN112456816A (en) * 2020-12-03 2021-03-09 于发坚 Ultra-white glass surface matte mosaic process
CN116395964A (en) * 2023-04-11 2023-07-07 福建省德化新圣美陶瓷有限公司 White porcelain glaze and method for preparing ceramic product by using same

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