CN108863298A - A kind of the Shi ceramic tile and its production technology of high rigidity and high water absorbing capacity - Google Patents
A kind of the Shi ceramic tile and its production technology of high rigidity and high water absorbing capacity Download PDFInfo
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- CN108863298A CN108863298A CN201810781396.6A CN201810781396A CN108863298A CN 108863298 A CN108863298 A CN 108863298A CN 201810781396 A CN201810781396 A CN 201810781396A CN 108863298 A CN108863298 A CN 108863298A
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- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/04—Clay; Kaolin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/21—Ink jet for multi-colour printing
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- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
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- C04B33/00—Clay-wares
- C04B33/24—Manufacture of porcelain or white ware
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62204—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/14—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3436—Alkaline earth metal silicates, e.g. barium silicate
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
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- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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Abstract
A kind of Shi ceramic tile of high rigidity and high water absorbing capacity, the Shi ceramic tile are prepared by the composition of raw materials component below based on quality percentage：New wound sand 8-14%, name all sand 5-7%, new figure potassium sand 10-14%, Chinese potassium sand 12-14%, Samsung mountain flour 0-25%, joins prosperous mountain flour 0-10%, and potassium sodium mountain flour 0-11% converges into mud 6-8%, summer water mud 7-10%, bright heart mud 5-8%, high alumina mud 0-8% polish slag 7-9% and talcum 1-3%.The invention proposes by stringent production stage and material selection, provide that a kind of water absorption rate is high, hardness is not in crack phenomenon well and is suitable for the high-quality Shi ceramic tile of interior wall, exterior wall and ground decoration simultaneously for user.
Description
Technical field
The present invention relates to technical field of construction and decoration materials, in particular to the Shi ceramic tile of a kind of high rigidity and high water absorbing capacity and
Its production technology.
Background technique
Due to the surplus of production capacity, product homogeneity, traditional tile product market is being fallen sharply, and price is dropping, can only
Capture rural market or the engineering project of some low sides, and wall (i.e. wall on floor tile) in the Imitation Rock Porcelain Tiles of low suction rate, part can be captured
High-end market, but it is easy to appear obscissions for wall on floor tile, cause paving expense relatively high, the firing temperature of floor tile compared with
Height, the pattern for also resulting in product does not enrich, and not energy-efficient and environmental protection.
Surface fracture, Product Process technology be single caused by traditional porcelain flake products are easy to because of external force, competitiveness of product not
Foot, color be not bright-coloured and figure sense is not strong.
For this purpose, the present invention proposes the Shi ceramic tile and its production technology of a kind of high rigidity and high water absorbing capacity, it is both compatible with tradition
All advantages of wall on tile and floor tile, the shortcomings that in turn avoiding them, be the perfect product of traditional internal wall brick transition and upgrade.
Summary of the invention
The main object of the present invention is the Shi ceramic tile and its production technology for proposing a kind of high rigidity and high water absorbing capacity, by tight
The production stage and material selection of lattice provide a kind of good Shi ceramic tile for user.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of Shi ceramic tile of high rigidity and high water absorbing capacity, the Shi ceramic tile is by the composition of raw materials below based on quality percentage
What component was prepared：New wound sand 8-14%, name all sand 5-7%, new figure potassium sand 10-14%, Chinese potassium sand 12-14%, Samsung stone
Powder 0-25% joins prosperous mountain flour 0-10%, potassium sodium mountain flour 0-11%, converges into mud 6-8%, summer water mud 7-10%, bright heart mud 5-8%,
High alumina mud 0-8% polishes slag 7-9% and talcum 1-3%.
A kind of technique producing high rigidity and high water absorbing capacity Shi ceramic tile, including automatic blending-continuous ball milling-level-one mistake
Sieve-slurry homogenizing-second level, which is crossed, screens out the aging-molding compacting-biscuiting-glazing-ink-jet print of iron-spray drying-powder
Flower-glaze firing-glaze paint half is thrown or full throwing-edging-inspection, it is characterised in that：
1. automatic blending：Several feeders are controlled according to the demand of factory formula by intelligent controller, it is precisely quantitative
Control and ingredient make various raw materials carry out independent feeding and continuous discharge；
2. continuous ball milling：The good raw material ball of automatic mixing is worn into uniform slurry, the company by continuous ball mill
Continuous ball mill is connected in series by multiple ball milling compartments, and the raw material good to automatic mixing realizes stable and high-quality ball milling, ball milling
After out raw material slurry fineness be：250 mesh screen residue 1.3-1.8%, moisture content：35-37%, flow velocity：30-60 seconds, ball milling yield：
85-95 ton/hours；
3. level-one is sieved：Raw material after ball milling starches out after ball the raw material slurry clout using 50 meshes, after sieving by setting
The return of serve that preserved skin band is transmitted back to continuous ball mill entrance automatically uses；
4. slurry is homogenized：Raw material slurry after level-one is sieved is transported to large-scale high-order stock tank by plunger pump and is homogenized
Processing, the high-order stock tank are made of 2 1800 tons of stock tank；
5. second level, which is crossed, screens out iron：Raw material slurry after homogenizing again passes by 60 meshes, and removes iron using high strong electromagnetic
Device handle except iron to raw material slurry；
6. being spray-dried：Will homogenizing, sieving and except iron treated slurry, under the conveying of high-pressure plunger pump, be sent into heat
The drying tower intrinsic fog of air is melted into fine droplets, while to droplet desiccant to be made to the graininess powdery with grain composition, being made
Powder lot humidity afterwards：7.3-7.8%, grain composition：On 20 mesh≤2.0%, on 30 mesh≤25%, 120 now≤3.0%；
7. powder is aging：Powder after being made is placed in storage tank, is being not less than 48 using the aging homogenizing of preceding storage
Hour；
8. molding compacting：Powder carry after will be aging is to press, by the automatic brick machine of 3800 ton large-scales by powder pressure
Green body is made；
9. biscuiting：Green body after compression moulding is burnt into, biscuiting temperature control base after 1050-1100 DEG C, biscuiting
The modulus of rupture of body is in 10-13MPa, water absorption rate 14-16%；
10. glazing：It further include that glaze is prepared and cleaned to the green body after biscuiting, glazing is according to product before glazing
Demand is using two methods of leaching glaze and glaze spraying, wherein leaching glaze drenches glaze using bell jar, the bell jar drenches side of the glaze by overflow
Method makes glaze slip form glaze serous coat, passes through green body under glaze film, sticks in billet surface and paint a layer of glaze, and leaching glaze generally drenches two layers
Glaze is ground coat enamel and overglaze respectively, and every 300x600 ground coat enamel drenches 105 grams, and overglaze drenches 133 grams, and another enameling method is glaze spraying, spray
Glaze handicraft is by glaze using compressed air by spray gun atomisation, and green body is adhered on green body by misty glaze, glaze slip
Density and glaze spraying amount determine the thickness of glaze layer, every 300x600 ground coat enamel sprays 133 grams, and overglaze sprays 160 grams；
It is ink-jet printed：Using the printing technique of digital ink-jet machine, pattern is mixed up color, is then input to digital ink-jet
In the controller of machine, pattern can be printed upon on brick face as printer, the color of the digital ink-jet machine ink has indigo plant
Color, brown, yellow, the red, black and white of package etc., functional ink have light ink, dumb light ink, finishing impression ink, sagging ink
Water etc.；
Glaze firing：Green body after will be ink-jet printed carries out high-temperature calcination, and the temperature of high-temperature calcination is 1150-1200 DEG C, burns
It is 40-60min at the time, the modulus of rupture of green body is in 11-15MPa, water absorption rate 15-18% after glaze firing；
Edging：Adobe after glaze firing is ground with regard to each standard requirements by edge polisher, the equipment of outfit includes
Automatic brick feeding, lower brick machine, rail mounted intelligently store up base system and dry edge machine etc.；
It examines：
According to quality control requirement, according to standard GB/T/T4100-2015 (annex K)《Ceramic Tiles annex K dry-pressing ceramics
Brick (6% < E≤10%BII b class)》, GB6566-2010《Radioactive material radionuclides limitation》With company standard Q/MSC1-
2017《Ceramic Tiles》Regulation carries out physicochemical property inspection to product；
According to company standard Q/MSC1-2017《Ceramic Tiles》Carry out surface quality hierarchical verification, the capital equipment of outfit and
Method has scan-type ceramic tile detection all-in-one machine, slide calliper rule, clearance gauge and range estimation, detection project to have size and deviation, straightness of sides, right angle
Degree, surface smoothness, surface defect and color difference etc..
Preferably, the glaze preparation side method of the glazing is as follows：
1. according to glazing glaze formula design requirement, by various glaze with raw material by intelligent controller automatic batching system into
Row precise weighing ingredient；
2. add water mill at fineness 0.25-0.4% (325 mesh) the glaze raw material prepared by 5 tons of ball mills,
1.80-1.83 grams per cubic centimeter of specific gravity, 40-60 seconds glaze slips of flow velocity；
3. by the good glaze slip of ball milling by 200 mesh vibrating screens sieving removal coarse granule.It is strong using 20000 gauss magnetic fields simultaneously
The electromagnetic deironing machine of degree carries out glaze slip except iron；
4. screen out the glaze after iron for crossing, examined qualified glaze slip be put into big glaze pond be homogenized it is spare.
Preferably, the green body after biscuiting is cleaned in the glazing, be the surface of green body after biscuiting is carried out it is clear
Clean processing.
Preferably, the Shi ceramic tile is after patterning step, and for the surface effect for increasing ceramics, it is special by a step to increase
The process of glaze decorating, the special glaze decorating process apply a kind of fine particulate crystal on glaze paint surface layer using dry granular, should
The dry granular applying method of process uses high pressure spray booth, is made of three spray guns, every square 200-300 grams of glaze slip of spray drying grain.
Preferably, the Shi ceramic tile is after being fired by glaze step, for the surface treatment for increasing glaze paint, moreover it is possible to increase a step glaze paint half
The bistrique or abrading block of the process thrown or thrown entirely, half throwing of the glaze paint or the process 200-1000 mesh thrown entirely are to the brick face after glaze firing
Carry out semipolish and the processing of full polishing effect.
Preferably, the Shi ceramic tile in production technology engineering, cross remaining after screening out iron by clout, second level after level-one sieving
After generating after underproof useless base, biscuiting underproof useless base after underproof useless base, edging after material, molding compacting and examining not
Waste product up to standard can be transmitted back to continuous ball mill return of serve by equipment and be reused.
Beneficial effects of the present invention：
The specific following advantages of Shi ceramic tile made of production technology through the invention：
In performance：Shi ceramic tile its modulus of rupture after present invention process is made is promoted to 30MPa or more, and product is not easy because outer
Power causes surface fracture, with the promotion of firing temperature, improves product sintering degree, and improve the thermal stability of product,
Prevent cracking from generating.
In technique：A variety ofization of production technology of the present invention, complication can promote product competitiveness, avoid the homogeneity of product
Change.Main technique has：3D ink-jet, male and female mold, finishing impression glaze, sheen glaze, the application of various dry granulars, dumb light ink, light ink
Application of the functions technology such as water etc., using allowing Shi ceramic tile of the invention aesthetically objective leap.
In color：Shi ceramic tile firing temperature made of present invention process can be fresher in the color of 1180 DEG C or so products
It is gorgeous, texture can it is apparent, naturally, and traditional Imitation Rock Porcelain Tiles temperature is excessively high, color is desalinated, scheme it is sympathetic will not be too strong.
On product：Shi ceramic tile made of present invention process keeps production flexible and convenient, can burst product by being burnt into twice
Personalization, fashion, even can be with customized production.It can satisfy the demand of different user.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below
There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this
Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with
The structure shown according to these attached drawings obtains other attached drawings.
Fig. 1 is process principle figure of the invention.
The embodiments will be further described with reference to the accompanying drawings for the realization, the function and the advantages of the object of the present invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiment is only a part of the embodiments of the present invention, instead of all the embodiments.Base
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts it is all its
His embodiment, shall fall within the protection scope of the present invention.
It is to be appreciated that if relating to directionality instruction (such as up, down, left, right, before and after ...) in the embodiment of the present invention,
Then directionality instruction be only used for explain under a certain particular pose (as shown in the picture) between each component relative positional relationship,
Motion conditions etc., if the particular pose changes, directionality instruction is also correspondingly changed correspondingly.
In addition, being somebody's turn to do " first ", " second " etc. if relating to the description of " first ", " second " etc. in the embodiment of the present invention
Description be used for description purposes only, be not understood to indicate or imply its relative importance or implicitly indicate indicated skill
The quantity of art feature." first " is defined as a result, the feature of " second " can explicitly or implicitly include at least one spy
Sign.It in addition, the technical solution between each embodiment can be combined with each other, but must be with those of ordinary skill in the art's energy
It is enough realize based on, will be understood that the knot of this technical solution when conflicting or cannot achieve when occurs in the combination of technical solution
Conjunction is not present, also not the present invention claims protection scope within.
The present invention proposes the Shi ceramic tile and its production technology of a kind of high rigidity and high water absorbing capacity, by using Shi ceramic tile percentage
Than explaining the present invention for raw material and Shi ceramic tile production process etc..
A kind of Shi ceramic tile of high rigidity and high water absorbing capacity, the Shi ceramic tile is by the composition of raw materials below based on quality percentage
What component was prepared：New wound sand 8-14%, name all sand 5-7%, new figure potassium sand 10-14%, Chinese potassium sand 12-14%, Samsung stone
Powder 0-25% joins prosperous mountain flour 0-10%, potassium sodium mountain flour 0-11%, converges into mud 6-8%, summer water mud 7-10%, bright heart mud 5-8%,
High alumina mud 0-8% polishes slag 7-9% and talcum 1-3%.
A kind of technique producing high rigidity and high water absorbing capacity Shi ceramic tile, including automatic blending-continuous ball milling-level-one mistake
Sieve-slurry homogenizing-second level sieving-spray drying-powder is aging-and molding compacting-biscuiting-glazing-is ink-jet printed-
Glaze firing-edging-inspection：
1. automatic blending：Several feeders are controlled according to the demand of factory formula by intelligent controller, it is precisely quantitative
Control and ingredient make various raw materials carry out independent feeding and continuous discharge, and easy to operate, realize to the accurate fixed of raw material
Ingredient and control are measured, to ensure that the stability of formula；
2. continuous ball milling：The good raw material ball of automatic mixing is worn into uniform slurry, the company by continuous ball mill
Continuous ball mill is connected in series by multiple ball milling compartments, and the raw material good to automatic mixing realizes stable and high-quality ball milling, ball milling
After out raw material slurry fineness be：250 mesh screen residue 1.3-1.8%, moisture content：35-37%, flow velocity：30-60 seconds, ball milling yield：
85-95 ton/hours, the step by continuous ball mill realize the automation to raw material as far as possible, discharging, make raw material starch yield
Greatly, make ball-milling technology high degree of automation, keep raw material slurry stay in grade high-quality；
3. level-one is sieved：Raw material after ball milling starches out after ball the raw material slurry clout using 50 meshes, after sieving by setting
The return of serve that preserved skin band is transmitted back to continuous ball mill entrance automatically uses；
4. slurry is homogenized：Raw material slurry after level-one is sieved is transported to large-scale high-order stock tank by plunger pump and is homogenized
Processing, the high-order stock tank are made of 2 1800 tons of stock tank, ensure that original by the raw material slurry of the equipment and stock tank homogenizing
The uniformity and stability of slurry quality；
5. second level, which is crossed, screens out iron：Raw material slurry after homogenizing again passes by 60 meshes, and removes iron using high strong electromagnetic
Device handle except iron to raw material slurry, greatly reduces because coarse granule or other products cause various defects；
6. being spray-dried：Will homogenizing, sieving and except iron treated slurry, under the conveying of high-pressure plunger pump, be sent into heat
The drying tower intrinsic fog of air is melted into fine droplets, while to droplet desiccant to be made to the graininess powdery with grain composition, being made
Powder lot humidity afterwards：7.3-7.8%, grain composition：On 20 mesh≤2.0%, on 30 mesh≤25%, 120 now≤3.0%；
7. powder is aging：Powder after being made is placed in storage tank, is being not less than 48 using the aging homogenizing of preceding storage
Hour, effectively it is homogenized powder lot humidity, so as to improve the performance of powder；
8. molding compacting：Powder carry after will be aging is to press, by the automatic brick machine of 3800 ton large-scales by powder pressure
Green body is made；
9. biscuiting：Green body after compression moulding is burnt into, biscuiting temperature control base after 1050-1100 DEG C, biscuiting
The modulus of rupture of body provides the intensity of green body in 10-13MPa, water absorption rate 14-16%, is conducive to subsequent decorations and processes；
10. glazing：It further include that glaze is prepared and cleaned to the green body after biscuiting, glazing is according to product before glazing
Demand is using two methods of leaching glaze and glaze spraying, wherein leaching glaze drenches glaze using bell jar, the bell jar drenches side of the glaze by overflow
Method makes glaze slip form glaze serous coat, passes through green body under glaze film, sticks in billet surface and paint a layer of glaze, and leaching glaze generally drenches two layers
Glaze is ground coat enamel and overglaze respectively, and every 300x600 ground coat enamel drenches 105 grams, and overglaze drenches 133 grams, and another enameling method is glaze spraying, spray
Glaze handicraft is by glaze using compressed air by spray gun atomisation, and green body is adhered on green body by misty glaze, glaze slip
Density and glaze spraying amount determine the thickness of glaze layer, every 300x600 ground coat enamel sprays 133 grams, and overglaze sprays 160 grams；
It is ink-jet printed：Using the printing technique of digital ink-jet machine, pattern is mixed up color, is then input to digital ink-jet
In the controller of machine, pattern can be printed upon on brick face as printer, the color of the digital ink-jet machine ink has indigo plant
Color, brown, yellow, the red, black and white of package etc., functional ink have light ink, dumb light ink, finishing impression ink, sagging ink
Water etc., the color ink are used to show pattern color abundant, and the functional ink can increase the light of glaze paint in conjunction with pattern
The concave-convex effect of pool variation and surface makes product become abundant and natural；
Glaze firing：Green body after will be ink-jet printed carries out high-temperature calcination, and the temperature of high-temperature calcination is 1150-1200 DEG C, burns
As 40-60min.
Edging：Adobe after glaze firing is ground with regard to each standard requirements by edge polisher, the equipment of outfit includes
Automatic brick feeding, lower brick machine, rail mounted intelligently store up base system and dry edge machine etc.；
It examines：
According to quality control requirement, according to standard GB/T/T4100-2015 (annex K)《Ceramic Tiles annex K dry-pressing ceramics
Brick (6% < E≤10%BII b class)》, GB6566-2010《Radioactive material radionuclides limitation》With company standard Q/MSC1-
2017《Ceramic Tiles》Regulation carries out physicochemical property inspection to product；
According to company standard Q/MSC1-2017《Ceramic Tiles》Carry out surface quality hierarchical verification, the capital equipment of outfit and
Method has scan-type ceramic tile detection all-in-one machine, slide calliper rule, clearance gauge and range estimation, detection project to have size and deviation, straightness of sides, right angle
Degree, surface smoothness, surface defect and color difference etc..
The glaze preparation side method of the glazing is as follows：
1. according to glazing glaze formula design requirement, by various glaze with raw material by intelligent controller automatic batching system into
Row precise weighing ingredient；
2. add water mill at fineness 0.25-0.4% (325 mesh) the glaze raw material prepared by 5 tons of ball mills,
1.80-1.83 grams per cubic centimeter of specific gravity, 40-60 seconds glaze slips of flow velocity；
3. by the good glaze slip of ball milling by 200 mesh vibrating screens sieving removal coarse granule.It is strong using 20000 gauss magnetic fields simultaneously
Glaze slip prevent from causing glaze paint pin hole and stain occur due to containing irony in glaze, influence to produce except iron by the electromagnetic deironing machine of degree
The quality of product；
4. screen out the glaze after iron for crossing, examined qualified glaze slip be put into big glaze pond be homogenized it is spare.
The green body after biscuiting is cleaned in the glazing, is to carry out cleaning treatment to the surface of the green body after biscuiting,
It ensure that the good combination of green body and glaze.
The Shi ceramic tile, for the surface effect for increasing ceramics, will increase by the special glaze paint dress of a step after patterning step
The process of decorations, the special glaze decorating process apply a kind of fine particulate crystal on glaze paint surface layer using dry granular, can be increased
The aesthetic feeling on surface, and the protection of brick face can be played the role of, so that product is had more class, the dry granular applying method of the process uses high pressure
Spray booth is made of three spray guns, and every square 200-300 grams of glaze slip of spray drying grain.
The Shi ceramic tile is after being fired by glaze step, for the surface treatment for increasing glaze paint, moreover it is possible to increase a step glaze paint half throwing or complete
The process of throwing, the process bistrique of 200-1000 mesh or abrading block that the glaze paint half is thrown or thrown entirely carry out half to the brick face after glaze firing
Polishing and the processing of full polishing effect.
For the Shi ceramic tile in production technology engineering, clout, second level after level-one sieving cross the clout after screening out iron, molding
It is not up to standard after generating after underproof useless base, biscuiting underproof useless base after underproof useless base, edging after compacting and examining
Waste product can be reused by the return of serve that equipment belt is transmitted back to continuous ball mill entrance automatically, obtain clout, useless base and waste product
To utilization again, corporate resources is greatly saved, effectively prevents these clouts, useless base and waste product outlet and dirt is caused to environment
Dye.
Case study on implementation one
A kind of Shi ceramic tile of high rigidity and high water absorbing capacity, the Shi ceramic tile is by the composition of raw materials below based on quality percentage
What component was prepared：New wound sand 8%, name all sand 6%, new figure potassium sand 14%, Chinese potassium sand 14%, Samsung mountain flour 0% join prosperous stone
Powder 10%, potassium sodium mountain flour 11% converge into mud 6%, summer water mud 7%, bright heart mud 5%, high alumina mud 8%, polishing slag 9% and talcum
2%.
A kind of technique producing case study on implementation Shi ceramic tile, including automatic blending-continuous ball milling-level-one sieving-slurry are equal
Change-second level sieving-spray drying-powder is aging-ink-jet printed-special glaze paint dress of molding compacting-biscuiting-glazing-
Decorations-glaze firing-half throwing of glaze paint-edging-inspection：
1. automatic blending：Several feeders are controlled according to the demand of factory formula by intelligent controller, it is precisely quantitative
Control and ingredient make various raw materials carry out independent feeding and continuous discharge, and easy to operate, realize to the accurate fixed of raw material
Ingredient and control are measured, to ensure that the stability of formula；
2. continuous ball milling：The good raw material ball of automatic mixing is worn into uniform slurry, the company by continuous ball mill
Continuous ball mill is connected in series by multiple ball milling compartments, and the raw material good to automatic mixing realizes stable and high-quality ball milling, ball milling
After out raw material slurry fineness be：250 mesh screen residues 1.6%, moisture content：35%, flow velocity：45 seconds, ball milling yield：90 ton/hours,
The step by continuous ball mill realize the automation to raw material as far as possible, discharging, make raw material slurry yield it is big, make ball-milling technology from
Dynamicization degree is high, keeps raw material slurry stay in grade high-quality；
3. level-one is sieved：Raw material after ball milling starches out after ball the raw material slurry clout using 50 meshes, after sieving by setting
The return of serve that preserved skin band is transmitted back to continuous ball mill entrance automatically uses；
4. slurry is homogenized：Raw material slurry after level-one is sieved is transported to large-scale high-order stock tank by plunger pump and is homogenized
Processing, the high-order stock tank are made of 2 1800 tons of stock tank, ensure that original by the raw material slurry of the equipment and stock tank homogenizing
The uniformity and stability of slurry quality；
5. second level, which is crossed, screens out iron：Raw material slurry after homogenizing again passes by 60 meshes, and removes iron using high strong electromagnetic
Device handle except iron to raw material slurry, greatly reduces because coarse granule or other products cause various defects；
6. being spray-dried：Will homogenizing, sieving and except iron treated slurry, under the conveying of high-pressure plunger pump, be sent into heat
The drying tower intrinsic fog of air is melted into fine droplets, while to droplet desiccant to be made to the graininess powdery with grain composition, being made
Powder lot humidity afterwards：7.6%, grain composition：On 20 mesh≤2.0%, on 30 mesh≤25%, 120 now≤3.0%；
7. powder is aging：Powder after being made is placed in storage tank, is being not less than 48 using the aging homogenizing of preceding storage
Hour, effectively it is homogenized powder lot humidity, so as to improve the performance of powder；
8. molding compacting：Powder carry after will be aging is to press, by the automatic brick machine of 3800 ton large-scales by powder pressure
Green body is made；
9. biscuiting：Green body after compression moulding is burnt into, biscuiting temperature is controlled at 1100 DEG C, and green body is disconnected after biscuiting
Modulus is split in 12MPa, and water absorption rate 14% provides the intensity of green body, is conducive to subsequent decorations and processes；
10. glazing：It further include that glaze is prepared and cleaned to the green body after biscuiting, glazing is according to product before glazing
Demand is using two methods of leaching glaze and glaze spraying, wherein leaching glaze drenches glaze using bell jar, the bell jar drenches side of the glaze by overflow
Method makes glaze slip form glaze serous coat, passes through green body under glaze film, sticks in billet surface and paint a layer of glaze, and leaching glaze generally drenches two layers
Glaze is ground coat enamel and overglaze respectively, and every 300x600 ground coat enamel drenches 105 grams, and overglaze drenches 133 grams, and another enameling method is glaze spraying, spray
Glaze handicraft is by glaze using compressed air by spray gun atomisation, and green body is adhered on green body by misty glaze, glaze slip
Density and glaze spraying amount determine the thickness of glaze layer, every 300x600 ground coat enamel sprays 133 grams, and overglaze sprays 160 grams；
It is ink-jet printed：Using the printing technique of digital ink-jet machine, pattern is mixed up color, is then input to digital ink-jet
In the controller of machine, pattern can be printed upon on brick face as printer, the color of the digital ink-jet machine ink has indigo plant
Color, brown, yellow, the red, black and white of package etc., functional ink have light ink, dumb light ink, finishing impression ink, sagging ink
Water etc., the color ink are used to show pattern color abundant, and the functional ink can increase the light of glaze paint in conjunction with pattern
The concave-convex effect of pool variation and surface makes product become abundant and natural；
Special glaze decorating：Apply a kind of fine particulate crystal on glaze paint surface layer using dry granular, the dry granular of the process is applied
Adding method uses high pressure spray booth, is made of three spray guns, every square of 220 grams of spray drying grain glaze slip.
Glaze firing：Green body after ink-jet printed and special glaze decorating is subjected to high-temperature calcination, the temperature of high-temperature calcination is
1150 DEG C, the high-temperature calcination time is 55min.
Glaze paint half is thrown：Semipolish effect process is carried out to the brick face after glaze firing with the bistrique of 500 mesh or abrading block；
Edging：Adobe after glaze firing is ground with regard to each standard requirements by edge polisher, the equipment of outfit includes
Automatic brick feeding, lower brick machine, rail mounted intelligently store up base system and dry edge machine etc.；
It examines：
According to quality control requirement, according to standard GB/T/T4100-2015 (annex K)《Ceramic Tiles annex K dry-pressing ceramics
Brick (6% < E≤10%BII b class)》, GB6566-2010《Radioactive material radionuclides limitation》With company standard Q/MSC1-
2017《Ceramic Tiles》Regulation carries out physicochemical property inspection to product；
According to company standard Q/MSC1-2017《Ceramic Tiles》Carry out surface quality hierarchical verification, the capital equipment of outfit and
Method has scan-type ceramic tile detection all-in-one machine, slide calliper rule, clearance gauge and range estimation, detection project to have size and deviation, straightness of sides, right angle
Degree, surface smoothness, surface defect and color difference etc..
A kind of glaze preparation side method of glazing described in case study on implementation one is as follows：
1. according to glazing glaze formula design requirement, by various glaze with raw material by intelligent controller automatic batching system into
Row precise weighing ingredient；
2. the glaze raw material prepared is added water mill at fineness 0.3% (325 mesh), specific gravity by the ball mill by 5 tons
1.80 grams per cubic centimeter, 50 seconds glaze slips of flow velocity；
3. by the good glaze slip of ball milling by 200 mesh vibrating screens sieving removal coarse granule.It is strong using 20000 gauss magnetic fields simultaneously
Glaze slip prevent from causing glaze paint pin hole and stain occur due to containing irony in glaze, influence to produce except iron by the electromagnetic deironing machine of degree
The quality of product；
4. screen out the glaze after iron for crossing, examined qualified glaze slip be put into big glaze pond be homogenized it is spare.
A kind of cleaning to the green body after biscuiting for glazing described in case study on implementation one, is the surface to the green body after biscuiting
Cleaning treatment is carried out, ensure that the good combination of green body and glaze.
Case study on implementation two
A kind of Shi ceramic tile of high rigidity and high water absorbing capacity, the Shi ceramic tile is by the composition of raw materials below based on quality percentage
What component was prepared：New wound sand 10%, name all sand 6%, new figure potassium sand 10%, Chinese potassium sand 12%, Samsung mountain flour 25% join prosperous
Mountain flour 0%, potassium sodium mountain flour 0% converge into mud 8%, summer water mud 10%, bright heart mud 8%, high alumina mud 0%, polishing slag 9% and talcum
2%.
A kind of technique producing Shi ceramic tile, including automatic blending-continuous ball milling-level-one sieving-slurry homogenizing-second level
Sieving-spray drying-powder is aging-and molding compacting-biscuiting-glazing-is ink-jet printed-glaze firing-edging-inspection：
1. automatic blending：Several feeders are controlled according to the demand of factory formula by intelligent controller, it is precisely quantitative
Control and ingredient make various raw materials carry out independent feeding and continuous discharge, and easy to operate, realize to the accurate fixed of raw material
Ingredient and control are measured, to ensure that the stability of formula；
2. continuous ball milling：The good raw material ball of automatic mixing is worn into uniform slurry, the company by continuous ball mill
Continuous ball mill is connected in series by multiple ball milling compartments, and the raw material good to automatic mixing realizes stable and high-quality ball milling, ball milling
After out raw material slurry fineness be：250 mesh screen residues 1.6%, moisture content：35%, flow velocity：55 seconds, ball milling yield：85 ton/hours,
The step by continuous ball mill realize the automation to raw material as far as possible, discharging, make raw material slurry yield it is big, make ball-milling technology from
Dynamicization degree is high, keeps raw material slurry stay in grade high-quality；
3. level-one is sieved：Raw material after ball milling starches out after ball the raw material slurry clout using 50 meshes, after sieving by setting
The return of serve that preserved skin band is transmitted back to continuous ball mill entrance automatically uses；
4. slurry is homogenized：Raw material slurry after level-one is sieved is transported to large-scale high-order stock tank by plunger pump and is homogenized
Processing, the high-order stock tank are made of 2 1800 tons of stock tank, ensure that original by the raw material slurry of the equipment and stock tank homogenizing
The uniformity and stability of slurry quality；
5. second level, which is crossed, screens out iron：Raw material slurry after homogenizing again passes by 60 meshes, and removes iron using high strong electromagnetic
Device handle except iron to raw material slurry, greatly reduces because coarse granule or other products cause various defects；
6. being spray-dried：Will homogenizing, sieving and except iron treated slurry, under the conveying of high-pressure plunger pump, be sent into heat
The drying tower intrinsic fog of air is melted into fine droplets, while to droplet desiccant to be made to the graininess powdery with grain composition, being made
Powder lot humidity afterwards：7.8%, grain composition：On 20 mesh≤2.0%, on 30 mesh≤25%, 120 now≤3.0%；
7. powder is aging：Powder after being made is placed in storage tank, is being not less than 48 using the aging homogenizing of preceding storage
Hour, effectively it is homogenized powder lot humidity, so as to improve the performance of powder；
8. molding compacting：Powder carry after will be aging is to press, by the automatic brick machine of 3800 ton large-scales by powder pressure
Green body is made；
9. biscuiting：Green body after compression moulding is burnt into, biscuiting temperature is controlled at 1090 DEG C, and green body is disconnected after biscuiting
Modulus is split in 11MPa, and water absorption rate 16% provides the intensity of green body, is conducive to subsequent decorations and processes；
10. glazing：It further include that glaze is prepared and cleaned to the green body after biscuiting, glazing is according to product before glazing
Demand is using two methods of leaching glaze and glaze spraying, wherein leaching glaze drenches glaze using bell jar, the bell jar drenches side of the glaze by overflow
Method makes glaze slip form glaze serous coat, passes through green body under glaze film, sticks in billet surface and paint a layer of glaze, and leaching glaze generally drenches two layers
Glaze is ground coat enamel and overglaze respectively, and every 300x600 ground coat enamel drenches 105 grams, and overglaze drenches 133 grams, and another enameling method is glaze spraying, spray
Glaze handicraft is by glaze using compressed air by spray gun atomisation, and green body is adhered on green body by misty glaze, glaze slip
Density and glaze spraying amount determine the thickness of glaze layer, every 300x600 ground coat enamel sprays 133 grams, and overglaze sprays 160 grams；
It is ink-jet printed：Using the printing technique of digital ink-jet machine, pattern is mixed up color, is then input to digital spray
In the controller of black machine, pattern can be printed upon on brick face as printer, the color of the digital ink-jet machine ink has
Blue, brown, yellow, the red, black and white of package etc., functional ink have light ink, dumb light ink, finishing impression ink, sink
Ink etc., the color ink are used to show pattern color abundant, and the functional ink can increase glaze paint in conjunction with pattern
The concave-convex effect of gloss variation and surface makes product become abundant and natural；
Glaze firing：Green body after will be ink-jet printed carries out high-temperature calcination, and the temperature of high-temperature calcination is 1100 DEG C, high-temperature calcination
Time is 60min.
Edging：Adobe after glaze firing is ground with regard to each standard requirements by edge polisher, the equipment of outfit includes
Automatic brick feeding, lower brick machine, rail mounted intelligently store up base system and dry edge machine etc.；
It examines：
According to quality control requirement, according to standard GB/T/T4100-2015 (annex K)《Ceramic Tiles annex K dry-pressing ceramics
Brick (6% < E≤10%BII b class)》, GB6566-2010《Radioactive material radionuclides limitation》With company standard Q/MSC1-
2017《Ceramic Tiles》Regulation carries out physicochemical property inspection to product；
According to company standard Q/MSC1-2017《Ceramic Tiles》Carry out surface quality hierarchical verification, the capital equipment of outfit and
Method has scan-type ceramic tile detection all-in-one machine, slide calliper rule, clearance gauge and range estimation, detection project to have size and deviation, straightness of sides, right angle
Degree, surface smoothness, surface defect and color difference etc..
A kind of glaze preparation side method of glazing described in case study on implementation two is as follows：
1. according to glazing glaze formula design requirement, by various glaze with raw material by intelligent controller automatic batching system into
Row precise weighing ingredient；
2. the glaze raw material prepared is added water mill at fineness 0.4% (325 mesh), specific gravity by the ball mill by 5 tons
1.81 grams per cubic centimeter, 60 seconds glaze slips of flow velocity；
3. by the good glaze slip of ball milling by 200 mesh vibrating screens sieving removal coarse granule.It is strong using 20000 gauss magnetic fields simultaneously
Glaze slip prevent from causing glaze paint pin hole and stain occur due to containing irony in glaze, influence to produce except iron by the electromagnetic deironing machine of degree
The quality of product；
4. screen out the glaze after iron for crossing, examined qualified glaze slip be put into big glaze pond be homogenized it is spare.
A kind of cleaning to the green body after biscuiting for glazing described in case study on implementation two, is the surface to the green body after biscuiting
Cleaning treatment is carried out, ensure that the good combination of green body and glaze.
It is examined through Shi ceramic tile made of present invention process through national ceramics and water heating bathroom product quality supervision and inspection center
It is reported as follows：
The invention proposes the Shi ceramic tiles and its production technology of a kind of high rigidity and high water absorbing capacity, are walked by stringent production
Rapid and material selection provides the high-quality Shi ceramic tile that a kind of water absorption rate is high, hardness is not in crack phenomenon well for user.
The above description is only a preferred embodiment of the present invention, is not intended to limit the scope of the invention, all at this
Under the inventive concept of invention, using equivalent structure transformation made by description of the invention and accompanying drawing content, or directly/use indirectly
It is included in other related technical areas in scope of patent protection of the invention.
Claims (7)
1. the Shi ceramic tile of a kind of high rigidity and high water absorbing capacity, which is characterized in that the Shi ceramic tile is by below based on quality percentage
Composition of raw materials component be prepared：New wound sand 8-14%, name all sand 5-7%, new figure potassium sand 10-14%, Chinese potassium sand 12-
14%, Samsung mountain flour 0-25% join prosperous mountain flour 0-10%, potassium sodium mountain flour 0-11%, converge into mud 6-8%, summer water mud 7-10%, bright
Heart mud 5-8%, high alumina mud 0-8% polish slag 7-9% and talcum 1-3%.
2. a kind of technique for producing claim 1 high rigidity and high water absorbing capacity Shi ceramic tile, including automatic blending-continuous ball milling-
Level-one sieving-slurry homogenizing-second level cross screen out iron-spray drying-powder it is aging-molding compacting-biscuiting-glazing-
Ink-jet printed-glaze firing-edging-inspection, it is characterised in that：
1. automatic blending：Several feeders are controlled according to the demand of factory formula, precisely quantitative control by intelligent controller
And ingredient, so that various raw materials is carried out independent feeding and continuous discharge；
2. continuous ball milling：The good raw material ball of automatic mixing is worn into uniform slurry, the continuous ball by continuous ball mill
Grinding machine is connected in series by multiple ball milling compartments, and the raw material good to automatic mixing realizes that stable and high-quality ball milling, ball milling come out
Afterwards raw material slurry fineness be：250 mesh screen residue 1.3-1.8%, moisture content：35-37%, flow velocity：30-60 seconds, ball milling yield：85-
95 ton/hours；
3. level-one is sieved：Raw material after ball milling starches out after ball the raw material slurry clout using 50 meshes, after sieving and passes through equipment skin
The return of serve that band is transmitted back to continuous ball mill entrance automatically uses；
4. slurry is homogenized：Raw material slurry after level-one is sieved is transported to large-scale high-order stock tank by plunger pump and is homogenized processing,
The high-order stock tank is made of 2 1800 tons of stock tank；
5. second level, which is crossed, screens out iron：Raw material slurry after homogenizing again passes by 60 meshes, and uses high-strength electric magnetic iron remover pair
Raw material slurry handle except iron；
6. being spray-dried：Will homogenizing, sieving and except iron treated slurry, under the conveying of high-pressure plunger pump, be sent into hot-air
Drying tower intrinsic fog be melted into fine droplets, while to droplet desiccant to be made to the graininess powdery with grain composition, after being made
Powder lot humidity：7.3-7.8%, grain composition：On 20 mesh≤2.0%, on 30 mesh≤25%, 120 now≤3.0%；
7. powder is aging：Powder after being made is placed in storage tank, is not less than 48 hours using the aging homogenizing of preceding storage；
8. molding compacting：Powder carry after will be aging to press, by the automatic brick machine of 3800 ton large-scales by powder pressing at
Green body；
9. biscuiting：Green body after compression moulding is burnt into, biscuiting temperature control green body after 1050-1100 DEG C, biscuiting
The modulus of rupture is in 10-13MPa, water absorption rate 14-16%；
10. glazing：Before glazing, further include glaze preparation and the green body after biscuiting is cleaned, glazing is according to the demand of product
Using two methods of leaching glaze and glaze spraying, wherein leaching glaze drenches glaze using bell jar, the bell jar leaching glaze is made by the method for overflow
Glaze slip forms glaze serous coat, passes through green body under glaze film, sticks in billet surface and paint a layer of glaze, and leaching glaze generally drenches two layers of glaze, point
It is not ground coat enamel and overglaze, every 300x600 ground coat enamel drenches 105 grams, and overglaze drenches 133 grams, and another enameling method is glaze spraying, glaze spraying technique
It is by glaze using compressed air by spray gun atomisation, green body is adhered on green body by misty glaze, the density of glaze slip
The thickness of glaze layer is determined with glaze spraying amount, every 300x600 ground coat enamel sprays 133 grams, and overglaze sprays 160 grams；
11 is ink-jet printed：Using the printing technique of digital ink-jet machine, pattern is mixed up color, is then input to digital ink-jet machine
In controller, pattern can be printed upon on brick face as printer, the color of the digital ink-jet machine ink has blue, palm fibre
Color, yellow, the red, black and white of package etc., functional ink has light ink, dumb light ink, finishing impression ink, lower collapsible ink etc.；
12 glaze firing：Green body after will be ink-jet printed carries out high-temperature calcination, and the temperature of high-temperature calcination is 1150-1200 DEG C, when firing
Between be 40-60min, the modulus of rupture of green body is in 11-15MPa, water absorption rate 15-18% after glaze firing；
13 glaze paints half are thrown or full throwing：Semipolish and full polishing are carried out to the brick face after glaze firing with the bistrique of 200-1000 mesh or abrading block
Effect process；
14 edgings：Adobe after glaze firing is ground with regard to each standard requirements by edge polisher, the equipment of outfit includes automatic
Upper brick, lower brick machine, rail mounted intelligently store up base system and dry edge machine etc.；
15 examine：
According to quality control requirement, according to standard GB/T/T4100-2015 (annex K)《Ceramic Tiles annex K dry-pressing Ceramic Tiles
(6% < E≤10%BII b class)》, GB6566-2010《Radioactive material radionuclides limitation》With company standard Q/MSC1-
2017《Ceramic Tiles》Regulation carries out physicochemical property inspection to product；
According to company standard Q/MSC1-2017《Ceramic Tiles》Carry out surface quality hierarchical verification, the capital equipment and method of outfit
There are scan-type ceramic tile detection all-in-one machine, slide calliper rule, clearance gauge and range estimation, detection project to have size and deviation, straightness of sides, squareness, table
Surface evenness, surface defect and color difference etc..
3. a kind of technique for producing high rigidity and high water absorbing capacity Shi ceramic tile according to claim 2, which is characterized in that described
The glaze preparation side method of glazing is as follows：
1. various glaze are carried out essence by intelligent controller automatic batching system with raw material according to glazing glaze formula design requirement
Quasi- weighing and burden；
2. the glaze raw material prepared is added water mill at fineness 0.25-0.4% (325 mesh), specific gravity by the ball mill by 5 tons
1.80-1.83 grams per cubic centimeter, 40-60 seconds glaze slips of flow velocity；
3. by the good glaze slip of ball milling by 200 mesh vibrating screens sieving removal coarse granule.Simultaneously using 20000 Gauss field intensities
Electromagnetic deironing machine carries out glaze slip except iron；
4. screen out the glaze after iron for crossing, examined qualified glaze slip be put into big glaze pond be homogenized it is spare.
4. the technique of a kind of high rigidity according to claim 2 and high water absorbing capacity production Shi ceramic tile, which is characterized in that described
The green body after biscuiting is cleaned in glazing, is to carry out cleaning treatment to the surface of the green body after biscuiting.
5. a kind of technique for producing high rigidity and high water absorbing capacity Shi ceramic tile according to claim 2, which is characterized in that described
Shi ceramic tile is after patterning step, for the surface effect for increasing ceramics, moreover it is possible to increase the process of the special glaze decorating of a step, the spy
Different glaze decorating process applies a kind of fine particulate crystal on glaze paint surface layer using dry granular, and the dry granular applying method of the process uses
High pressure spray booth is made of three spray guns, and every square 200-300 grams of glaze slip of spray drying grain.
6. a kind of technique for producing high rigidity and high water absorbing capacity Shi ceramic tile according to claim 2, which is characterized in that described
Shi ceramic tile is after being fired by glaze step, for the surface treatment for increasing glaze paint, moreover it is possible to increase the process that a step glaze paint half is thrown or thrown entirely, it is described
The process bistrique of 200-1000 mesh or abrading block that glaze paint half is thrown or thrown entirely carry out semipolish and full polishing to the brick face after glaze firing
Effect process.
7. a kind of technique for producing high rigidity and high water absorbing capacity Shi ceramic tile according to claim 2, which is characterized in that described
Shi ceramic tile in production technology engineering, cross the clout after screening out iron, generate not after molding compacting by clout, second level after level-one sieving
Underproof useless base and waste product not up to standard after examining can be by setting after underproof useless base, edging after qualified useless base, biscuiting
The standby continuous ball mill return of serve that is transmitted back to reuses.
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| CN113233905A (en) * | 2021-05-24 | 2021-08-10 | 重庆唯美陶瓷有限公司 | Preparation method of ceramic tile and ceramic tile |
| CN113336538A (en) * | 2021-06-21 | 2021-09-03 | 清远市欧雅陶瓷有限公司 | High-antiskid high-hardness antique brick and preparation method thereof |
| CN114149247A (en) * | 2021-12-31 | 2022-03-08 | 新明珠集团股份有限公司 | Super-thick black coffee through-body ceramic tile and preparation method and application thereof |
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| CN111533529A (en) * | 2020-05-15 | 2020-08-14 | 河北冠亚建材有限公司 | Manufacturing process of long-life ancient brick |
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| CN111999484A (en) * | 2020-07-28 | 2020-11-27 | 广西蒙娜丽莎新材料有限公司 | Method for detecting influence degree of ceramic raw materials on pinhole pores of ceramic finished product |
| CN112127564A (en) * | 2020-09-04 | 2020-12-25 | 闫山 | Anti-permeability ceramic tile for building exterior wall and using method thereof |
| CN112127564B (en) * | 2020-09-04 | 2021-11-02 | 孙超 | Anti-permeability ceramic tile for building exterior wall and using method thereof |
| CN113233905A (en) * | 2021-05-24 | 2021-08-10 | 重庆唯美陶瓷有限公司 | Preparation method of ceramic tile and ceramic tile |
| CN113233905B (en) * | 2021-05-24 | 2022-07-26 | 重庆唯美陶瓷有限公司 | Preparation method of ceramic tile and ceramic tile |
| CN113336538A (en) * | 2021-06-21 | 2021-09-03 | 清远市欧雅陶瓷有限公司 | High-antiskid high-hardness antique brick and preparation method thereof |
| CN113336538B (en) * | 2021-06-21 | 2023-05-02 | 肇庆市金欧雅陶瓷有限公司 | High-skid-resistance high-hardness archaized brick and preparation method thereof |
| CN116253583A (en) * | 2021-12-10 | 2023-06-13 | 佛山市东鹏陶瓷有限公司 | Full-polished glazed tile with rough and fine concave textures and preparation process thereof |
| CN114149247A (en) * | 2021-12-31 | 2022-03-08 | 新明珠集团股份有限公司 | Super-thick black coffee through-body ceramic tile and preparation method and application thereof |
| CN114149247B (en) * | 2021-12-31 | 2022-11-01 | 新明珠集团股份有限公司 | Super-thick black coffee through-body ceramic tile and preparation method and application thereof |
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Application publication date: 20181123 |