CN110177538A

CN110177538A - Hair styling agent composition

Info

Publication number: CN110177538A
Application number: CN201880005678.5A
Authority: CN
Inventors: 藤田范子; 桥本佳和; 森野修
Original assignee: Mandom Corp
Current assignee: Mandom Corp
Priority date: 2017-04-27
Filing date: 2018-03-15
Publication date: 2019-08-27
Anticipated expiration: 2038-03-15
Also published as: KR102256328B1; CN110177538B; WO2018198564A1; JP6784834B2; KR20190091315A; JPWO2018198564A1; CN110167520A; WO2018198563A1; KR102226577B1; JP6793820B2; KR20190091498A; JPWO2018198563A1; CN110167520B

Abstract

A kind of hair styling agent composition is provided, its operability when haircuting is excellent, it is capable of forming tiny topknot, by the characteristic (arrange power) of topknot forming, the characteristic for erecting topknot from root of hair and for a long time the excellent of hair style is kept, can inhibit the reflecting feel after haircuting.A kind of hair styling agent composition, contains A: the powder selected from one or more of the group being made of silica, talcum, titanium dioxide and mica；B: including the Crodaret of B1 (Crodaret that the average addition molal quantity of EO is 45~65) and B2 (Crodaret that the average addition molal quantity of EO is 75~125)；C: the polymer for using (methyl) acrylic acid and/or (methyl) alkyl acrylate and (methyl) acrylic acid polyoxyethylene alkyl ether to obtain；D: carboxyl vinyl polymer and/or alkyl-modified carboxyl group polyvinyl；And E: water, the content of above-mentioned A is that the content that the total content of 0.5~5.0 mass %, above-mentioned B1 and above-mentioned B2 is 3.0~25.0 mass %, above-mentioned C is 0.1~1.5 mass %, the content of above-mentioned D is 0.05~1.5 mass %, and mass ratio [B1/ (B1+B2)] is 0.1~0.9.

Description

Hair styling agent composition

Technical field

The present invention relates to the hair styling agent compositions used in the hair styling agent arranged to hair.This application claims 2017 On April 27, in submits the excellent of Japanese Patent Application No. 2017-088806 and Japanese Patent Application 2017-088807 of patent application in Japan It first weighs, its content is applied at this.

Background technique

The characteristic of haircuting that hair styling agent composition for arranging hair can be played have it is various, for example: Hair is arranged to the characteristic for getting up and being formed topknot each other；By hair forming, the characteristic for forming the flow direction of hair and moulding hair style (arranging power)；The characteristic that hair is put together；The characteristic for erecting hair；The characteristic of hair style is kept for a long time；Light is assigned to hair The characteristic in pool；Improve the mutual slickness of hair and assigns the characteristic of dry feeling；Etc..According to target haircut hair style, object hair Matter etc., hair styling agent composition are designed to that one of above-mentioned characteristic or multifrequency nature can be played.In addition, as hair styling agent group Character, the dosage form for closing object, also there is the various characters such as liquid, wax-like, gel, fat shape, the hair styling agent composition of various characters With respectively different usability, use feeling and characteristic of haircuting.

As specific hair styling agent composition, such as known use wax-like hair styling agent group of the wax as Hairsetting ingredient Close object.The hair of this wax-like hair styling agent composition erects easiness and topknot forming easiness (arranging power) is excellent.It is another Aspect, in coating with tacky tendency, washing away property is poor.

In addition, for example known use polymer and forms polymer as Hairsetting ingredient and mixed carboxy vinyl gathers Close the gelatinous hair styling agent composition (such as patent document 1 etc.) of the gelling agents such as object.This gelatinous hair styling agent composition Due to having viscosity to a certain degree, is taken out from tubular container etc. and be difficult to flow down when using to hand, treatability is excellent.It removes Other than this, expansion when being applied to hair is also good, and coating is also excellent.In addition, gelatinous hair styling agent composition passes through institute The effect of the polymer and forms polymer of mixture and form overlay film, therefore characteristic, the long-time that hair is put together on the surface of hair Keep the characteristic of hair style also excellent.On the other hand, poor in the following aspects: arrangement power is low, is difficult to form the flow direction of hair, because being formed Overlay film and can not be naturally completed.

In addition, the hair styling agent composition excellent as characteristic, the forming easiness for assigning gloss to hair, it is known that fat shape Hair styling agent composition (so-called hair rouge, water fat) (such as patent document 2 etc.).Rouge hair styling agent composition paste includes water With comparatively large number of hydrophilic non-ionic surfactant, more gelatinous hair styling agent composition is harder, with no mobility or The minimum character of mobility.Therefore, can be filled into can container etc., taken from container with finger it is appropriate etc. use, handle Property it is also excellent, when coating expansion might as well, coating is also excellent, i.e., operational excellent.

Existing technical literature

Patent document

Patent document 1: Japanese Unexamined Patent Publication 10-87448 bulletin

Patent document 2: Japanese Unexamined Patent Publication 2009-286750 bulletin

Summary of the invention

Problems to be solved by the invention

But for the hair style for being haircuted using existing rouge hair styling agent composition paste, hair is from hair Root is held down along the shape on head, the not formed topknot of hair and become planar.In addition, the reflecting feels such as gloss are strong.In this way, existing Rouge hair styling agent composition paste do not pursue the hair style being naturally done.In contrast, in recent years, need one kind with rouge The character of paste hair styling agent composition, haircuting of can also being haircuted in a manner of being naturally done while arrange power and operability Agent composition.

Therefore, the purpose of the present invention is to provide a kind of hair styling agent compositions, and the operability when haircuting is excellent, can Tiny topknot is formed, keeps the characteristic (arranging power) of topknot forming, the characteristic for erecting topknot from root of hair and for a long time sending out The excellent of type, and can inhibit the reflecting feel after haircuting.

Means for solving the problems

The present inventor has made intensive studies in order to achieve the above object, as a result, it has been found that, by the way that following hair styling agent groups are made Object is closed, can obtain being capable of forming tiny topknot, arrange power, the characteristic for erecting topknot from root of hair and keeping hair style for a long time Excellent, haircut after reflecting feel be suppressed and the excellent hair styling agent composition of operability, the hair styling agent composition contain By ingredient (A): the powder selected from one or more of the group being made of silica, talcum, titanium dioxide and mica；Ingredient (B): the Crodaret comprising following compositions (B1) and following compositions (B2) (ingredient (B1): put down by ethylene oxide Crodaret that equal addition molal quantity is 45~65, ingredient (B2): the average addition molal quantity of ethylene oxide is 75~125 Crodaret)；Ingredient (C): (methyl) acrylic acid and/or (methyl) alkyl acrylate are used The polymer obtained with (methyl) acrylic acid polyoxyethylene alkyl ether；Ingredient (D): carboxyl vinyl polymer and/or alkyl change Property carboxyl vinyl polymer；And ingredient (E): water, the content of ingredient (A), ingredient (B1) and ingredient (B2) total content, at Total content of the content of the content of point (C), the content of ingredient (D) and ingredient (B1) relative to ingredient (B1) and ingredient (B2) Mass ratio be respectively in particular range.The present invention is completed based on these technical ideas.

That is, the present invention provides a kind of hair styling agent composition, to contain following compositions (A), following compositions (B), Xia Shucheng The hair styling agent composition of point (C), following compositions (D) and following compositions (E), relative to above-mentioned 100 mass % of hair styling agent composition, The content of mentioned component (A) is 0.5~5.0 mass %, the total content of following compositions (B1) and following compositions (B2) is 3.0~ 25.0 mass %, the content of mentioned component (C) are 0.1~1.5 mass %, and the content of mentioned component (D) is 0.05~1.5 matter Measure %, mass ratio of the content of mentioned component (B1) relative to mentioned component (B1) and the total content of mentioned component (B2) [(B1)/{ (B1)+(B2) }] is 0.1~0.9.

Ingredient (A): the powder selected from one or more of the group being made of silica, talcum, titanium dioxide and mica

Ingredient (B): including the Crodaret of following compositions (B1) and following compositions (B2)

Ingredient (B1): the Crodaret that the average addition molal quantity of ethylene oxide is 45~65

Ingredient (B2): the Crodaret that the average addition molal quantity of ethylene oxide is 75~125

Ingredient (C): (methyl) acrylic acid and/or (methyl) alkyl acrylate and (methyl) acrylic acid polyoxyethylene are used The polymer that alkyl ether obtains

Ingredient (D): carboxyl vinyl polymer and/or alkyl-modified carboxyl group polyvinyl

Ingredient (E): water

Mentioned component (B) preferably comprises following compositions (B3).

Ingredient (B3): the average addition molal quantity of ethylene oxide is 5 Crodaret more than and less than 45

Mentioned component (C) is preferably (acrylic acid (ester) class/- 25 methacrylate of docosyl alcohol polyethers) copolymer.

Hair styling agent composition of the invention may include following compositions (F), relative to above-mentioned 100 matter of hair styling agent composition % is measured, the content of mentioned component (F) is 0.1~7.0 mass %.

Ingredient (F): polymer and forms polymer

Hair styling agent composition of the invention is preferably free of diglycerol, polyglycereol and dipropylene glycol, alternatively, relative to hair styling agent 100 mass % of composition, the total content of diglycerol, polyglycereol and propylene glycol is less than 5 mass %.

The effect of invention

Hair styling agent composition of the invention is capable of forming tiny topknot, is bent the direction of topknot freely and the spy that shapes Property (arrange power), the excellent that erects topknot from root of hair.Therefore, it using hair styling agent composition of the invention, is capable of forming What existing fat shape hair styling agent composition cannot achieve makes topknot from root of hair standing and fully formed hair style.And after haircuting Reflecting feel be inhibited.Therefore, using hair styling agent composition of the invention, can fully shape, and be capable of forming with The existing rouge hair styling agent composition paste hair style more natural compared to completion.In addition, the spy of hair style is kept after haircuting for a long time Property is excellent.It in addition, operability is excellent, can be filled into can container etc., not flow down and can be taken from container with finger appropriate etc. It uses, treatability is excellent, and expansion when being applied to hair is also good, and coating is excellent.

Specific embodiment

Hair styling agent composition of the invention includes at least: selected from what is be made of silica, talcum, titanium dioxide and mica The powder of one or more of group；Crodaret；Use (methyl) acrylic acid and/or (methyl) acrylic acid alkyl The polymer that ester and (methyl) acrylic acid polyoxyethylene alkyl ether obtain；Carboxyl vinyl polymer and/or alkyl-modified carboxyl group Polyvinyl；And water.In addition, above-mentioned Crodaret includes at least the average addition mole of ethylene oxide The polyoxyethylene hydrogen that number is 75~125 for 45~65 Crodaret and the average addition molal quantity of ethylene oxide Change castor oil.

It should be noted that in this specification, sometimes by above-mentioned selected from by silica, talcum, titanium dioxide and mica The powder of one or more of the group of composition is known as " ingredient (A) ".In addition, sometimes by the average addition mole of above-mentioned ethylene oxide Number is known as " ingredient (B1) " for 45~65 Crodaret, is by the average addition molal quantity of above-mentioned ethylene oxide 75~125 Crodaret is known as " ingredient (B2) ", sometimes will include mentioned component (B1) and mentioned component (B2) Crodaret is known as " ingredient (B) ".In addition, sometimes by above-mentioned use (methyl) acrylic acid and/or (first Base) the obtained polymer of alkyl acrylate and (methyl) acrylic acid polyoxyethylene alkyl ether is known as " ingredient (C) ".In addition, having When above-mentioned carboxyl vinyl polymer and/or alkyl-modified carboxyl group polyvinyl be known as " ingredient (D) ".In addition, sometimes Above-mentioned water is known as " ingredient (E) ".

That is, hair styling agent composition of the invention at least contains ingredient (A), ingredient (B), ingredient (C), ingredient (D) and ingredient (E).Hair styling agent composition of the invention also may include the ingredient other than mentioned component (A)~(E).In addition, of the invention is whole Each ingredient, such as ingredient (A), ingredient (B), ingredient (C), ingredient (D) and ingredient (A)~(E) for including in hair agent composition Each ingredient such as ingredient in addition may be used alone or in combination of two or more respectively.

[ingredient (A)]

Mentioned component (A) is selected from one or more of the group being made of silica, talcum, titanium dioxide and mica Powder.By using ingredient (A), it is able to suppress the reflecting feel after haircuting, and then is able to suppress hair and is excessively bonded each other, is passed through So that hair is moderately scattered each other and is capable of forming tiny topknot.In addition to this, it can inhibit the sticky of hair, raising washes away Property.Mentioned component (A) may be used alone or in combination of two or more.

As above-mentioned silica, known or usual silica (silicic acid anhydride) can be used.Above-mentioned silica can Think the silicic acid anhydride (hydrophilic silica) without silicic acid anhydride, or hydrophobization silicic acid anhydride.In addition, above-mentioned two Silica may be the silica being surface-treated with amino acid, ester or lecithin etc..In addition, above-mentioned silica It may be so-called easy disintegrating silica dioxide granule.Above-mentioned silica may be used alone or in combination of two or more.

Above-mentioned hydrophobization silicic acid anhydride is to have carried out the substance of silicic acid anhydride to silicic acid anhydride (such as untreated silicic acid anhydride). As inorganic agent used in silicic acid anhydride, Organosilyl compound, silicone compounds etc. can be enumerated.As above-mentioned Organosilyl compound can enumerate methyl trichlorosilane, dimethyldichlorosilane, trim,ethylchlorosilane, hexamethyl two Silazane, methyl trialkoxysilane, dimethyldialkylammonium oxysilane, trimethylalkyoxys iotalane, ethyl trichlorosilane, propyl Trichlorosilane, hexyl trichlorosilane, chain alkyl trichlorosilane, ethyltrialkoxysilanes, propyl trialkoxy silane, hexyl Trialkoxy silane, chain alkyl trialkoxy silane, methacryl silanes, fluoroalkyl silanes, perfluoroalkyl silanes etc.. As above-mentioned silicone compounds, the poly- silicon oxygen of dimethyl polysiloxane (silicone oil), methyl phenyl silicone, methyl hydrogen can be enumerated Alkane, amino modified silicone etc..As the method for above-mentioned silicic acid anhydride, well known method can be used.As above-mentioned hydrophobization The method of processing can enumerate liquid phase method, vapor phase method, autoclave method etc..

As the preference of above-mentioned hydrophobization silicic acid anhydride, dimethyl silane oxygroup SiClx acid anhydrides, trimethyl can be enumerated Siloxy SiClx acid anhydrides, octyl siloxy SiClx acid anhydrides, silicone oil processes silicic acid anhydride, methacrylic acid siloxy SiClx acid anhydrides etc..

Above-mentioned easy disintegrating silica dioxide granule is multiple silica primary particle set and the particle formed.As upper Silica primary particle is stated, is not particularly limited, for example, spherical silica particles, flakey silica Grain, amorphous silica particles etc..The average grain diameter of above-mentioned silica primary particle is not particularly limited.

In addition, above-mentioned easy disintegrating silica dioxide granule can include the ingredient other than silica.As above-mentioned dioxy Ingredient (hereinafter sometimes referred to " component content ") other than SiClx, is not particularly limited, for example, surfactant, more First alcohol, higher alcohol, sugar alcohol, silicone oil, chelating agent, antioxidant, plant extracts, dyestuff, pigment, fragrance, moisturizer, vitamin Class, amino acids, freshener etc..In these ingredients, preferred amino acid class, silicone oil, vitamins.As above-mentioned amino acid Class is not particularly limited, can enumerate two (lauramide glutamine) lysine Na (for example, Asahi Kasei Corporation manufacture, Trade name " pellicer "), trimethylglycine, glutamic acid etc..By including above-mentioned easy disintegrating silica dioxide granule State component content, when haircuting if above-mentioned easy disintegrating silica dioxide granule disintegration if release component content, can play with The corresponding effect of the type of component content.For example, can be played by above-mentioned easy disintegrating silica dioxide granule embedded amine groups acids The damage nursing function of hair out.As the manufacturing method of above-mentioned easy disintegrating silica dioxide granule, it is not particularly limited, it can be with Use well known method.

The oil absorption of above-mentioned silica is preferably 100mL/100g or more, more preferably 150mL/100g or more, into one Step is preferably 200mL/100g or more.In addition, the oil absorption of above-mentioned silica be preferably 1000mL/100g or less, more preferably For 800mL/100g or less, further preferably 700mL/100g or less.It should be noted that in this specification, oil absorption root It is measured according to the method recorded in JIS K5101.

The average grain diameter (average primary particle diameter) of above-mentioned silica is preferably 0.1nm or more, more preferably 5nm or more. In addition, the average grain diameter of above-mentioned silica is preferably 10 μm or less, more preferably 5 μm or less.In this specification, ingredient (A) Average grain diameter be volume average particle size, be able to use the particle size distribution device based on laser diffractometry and be measured.Make For above-mentioned particle size distribution device, " LA-920 " etc. of Horiba Ltd's manufacture can be enumerated.

Commercially available product also can be used in above-mentioned silica.As the commercially available product of silicic acid anhydride, for example, trade name " SILICA PEARL P-4M ", (the above are RiHui catalyst synthesis Co., Ltd's systems for trade name " SILICA PEARL 20CG " Make), trade name " SILICA MICRO BEAD P-1500 " (Catalysts & Chem Ind Co's manufacture), trade name " Sylysia 320 ", trade name " Sylysia 310P ", trade name " Sylysia 250 ", trade name " Sylysia 250N ", trade name " Sylysia 350 ", trade name " Sylysia 370 ", trade name " Sylysia 380 ", trade name " Sylysia 420 ", quotient The name of an article " Sylysia 430 ", trade name " Sylysia 440 ", trade name " Sylysia 450 ", trade name " Sylysia 470 " (the above are the manufactures of Fuji Silysia Chemical Co., Ltd.), trade name " AEROSIL 50 ", trade name " AEROSIL 90G ", trade name " AEROSIL 130 ", trade name " AEROSIL 150 ", trade name " AEROSIL 200 ", trade name " AEROSIL 300 ", trade name " AEROSIL 380 ", trade name " AEROSIL 200V ", trade name " AEROSIL OX50 " (the above are the manufactures of NIPPON AEROSIL Co., Ltd.), trade name " Sunsphere H-31 ", trade name " Sunsphere H- 51 ", trade name " Sunsphere H-121 ", trade name " Sunsphere H-201 ", trade name " Sunsphere H-32 ", quotient The name of an article " Sunsphere H-52 ", trade name " Sunsphere H-122 ", trade name " Sunsphere H-33 ", trade name " Sunsphere H-53 " (the above are the manufactures of AGC Si-Tech Co., Ltd.) etc..As dimethyl silane oxygroup SiClx acid The commercially available product of acid anhydride, for example, trade name " AEROSIL R972 ", trade name " AEROSIL R974 ", trade name " AEROSIL R9200 " (the above are the manufactures of NIPPON AEROSIL Co., Ltd.) etc..As trimethylsiloxy SiClx The commercially available product of acid anhydrides, for example, trade name " AEROSIL RX200 ", trade name " AEROSIL R8200 ", trade name " AEROSIL RX300 ", trade name " AEROSIL R812S " (the above are the manufactures of NIPPON AEROSIL Co., Ltd.) etc..Make For the commercially available product of octyl siloxy SiClx acid anhydrides, for example, trade name " AEROSIL R805 " (NIPPON The manufacture of AEROSIL Co., Ltd.) etc..As the commercially available product of silicone oil processes silicic acid anhydride, for example, trade name " AEROSIL R202 ", trade name " AEROSIL RY200 ", trade name " AEROSIL RY200S ", trade name " AEROSIL RY300 " (more than For the manufacture of NIPPON AEROSIL Co., Ltd.) etc..As the commercially available product of methacrylic acid siloxy SiClx acid anhydrides, such as Trade name " AEROSIL R711 " (manufacture of NIPPON AEROSIL Co., Ltd.) etc. can be enumerated.As above-mentioned easy disintegrating two The commercially available product of silica, for example, trade name " silica beads SB-705 " (Miyoshi Kasei Inc's manufacture), quotient The name of an article " God Ball SF-16C ", trade name " God Ball AF-6C ", trade name " God Ball AF-16C " (Suzuki grease Industrial Co., Ltd's manufacture) etc..

Above-mentioned talcum is indicated with INCI " TALK ".The oil absorption of above-mentioned talcum is not particularly limited, preferably 18~ 50mL/100g.In addition, the average grain diameter of above-mentioned talcum is not particularly limited, preferably 0.5~25 μm.Above-mentioned talcum can be with Using only a kind, two or more also can be used.As the commercially available product of above-mentioned talcum, for example, trade name " CROWN TALC PP " (Ishihara Sangyo Kaisha, Ltd.'s manufacture) etc..

Above-mentioned titanium dioxide is indicated with INCI " TITANIUM DIOXIDE ".Above-mentioned titanium dioxide is not limited especially It is fixed, such as can be fine particulate titanium dioxide or pigment titanium.Above-mentioned titanium dioxide can be used only a kind, also can be used Two or more.As the commercially available product of above-mentioned titanium dioxide, for example, trade name " TTO-55 (A) ", trade name " CR-50 " (the above are Ishihara Sangyo Kaisha, Ltd.'s manufactures) etc..

Above-mentioned mica is indicated with INCI " MICA ".The oil absorption of above-mentioned mica is not particularly limited, preferably 50~ 150mL/100g.In addition, the average grain diameter of above-mentioned mica is not particularly limited, preferably 0.5~50 μm.Above-mentioned mica can be with Using only a kind, two or more also can be used.As the commercially available product of above-mentioned mica, for example, trade name " PDM-8W " (TOPY INDUSTRIES LTD. manufacture) etc..

The content of ingredient (A) in hair styling agent composition of the invention is relative to 100 matter of hair styling agent composition of the invention Amount % is 0.5~5.0 mass %, preferably 0.8~4.0 mass %.By making in above-mentioned content above range, can be abundant To effect brought by ingredient (A) is used, it is able to suppress the reflecting feel after haircuting, and form tiny topknot.Mentioned component (A) content is the total content of the whole components (A) in hair styling agent composition of the invention.

In mentioned component (A), becoming more preferable, whiting (white floating I) from feel, (powder seems to whiten on hair Status) it obtains further suppression of aspect and sets out, preferred silica.To the silica in hair styling agent composition of the invention Content be not particularly limited, preferably 0.5~5.0 mass %, more preferably 0.8~4.0 mass %.

[ingredient (B)]

Ingredient (B) is Crodaret, and comprising ingredient (B1), (the average addition molal quantity of ethylene oxide is 45 ~65 Crodaret) and ingredient (B2) (the polyoxy second that the average addition molal quantity of ethylene oxide is 75~125 Alkene rilanit special).Hair styling agent composition of the invention has by the inclusion of such ingredient (B) and adequately arranges power and make The characteristic that hair is erected from root of hair is capable of forming tiny topknot, and has the characteristic for keeping hair style for a long time.It is specific and Speech assigns hardness and adherence to a certain degree to hair styling agent composition by compounding ingredients (B1), is easy hair each other It arranges and forms topknot, and then improve the characteristic for arranging power and erecting hair from root of hair.In addition, passing through compounding ingredients (B2) and to hair styling agent composition hardness is assigned, improves the characteristic for keeping the hair style after haircuting for a long time.Additionally it is believed that be by In being interacted using hydrophobic group and improve cohesive force, but scraped from container by sharing ingredient (B) and ingredient (C) After hair styling agent composition, the hair styling agent composition surface in container is timely naturally smoothened, and scraping trace is repaired, because This aesthetics is excellent.

Other than ingredient (B1) and ingredient (B2), the average addition molal quantity that ingredient (B) preferably comprises ethylene oxide is 5 Crodaret more than and less than 45.It should be noted that in this specification, sometimes by above-mentioned ethylene oxide Average addition molal quantity is that 5 Crodaret more than and less than 45 is known as " ingredient (B3) ".Of the invention haircuts When agent composition is also used as ingredient (B) comprising ingredient (B3) other than ingredient (B1) and ingredient (B2), forming easiness and thin The formative of small topknot is more excellent.It should be noted that mentioned component (B1)~ingredient (B3) can be used only a kind respectively, Also two or more can be used.

Oxidation from the hardness and adherence aspect for assigning appropriateness to hair styling agent composition, mentioned component (B1) The average addition molal quantity of ethylene is 45~65, preferably 50~60.In addition, in terms of to hair styling agent composition imparting hardness It sets out, the average addition molal quantity of the ethylene oxide in mentioned component (B2) is 75~125, preferably 80~120.On in addition, The average addition molal quantity for stating the ethylene oxide in ingredient (B3) is 5 more than and less than 45, preferably 10~40.

As the commercially available product of ingredient (B1), for example, trade name " BLAUNON RCW-50 ", trade name " BLAUNON RCW-60 " (the above are the manufactures of green wood oil rouge Industrial Co., Ltd), trade name " EMALEX HC-50 ", trade name " EMALEX HC-60 ", trade name " EMALEX RWIS-150 ", trade name " EMALEX RWIS-350 ", trade name " EMALEX RWIS-360 " (the above are the manufactures of Nihon Emulsion Co., Ltd.) etc..

As the commercially available product of ingredient (B2), for example, trade name " BLAUNON RCW-80 ", trade name " BLAUNON RCW-100 ", trade name " BLAUNON CW-100 " (the above are the manufactures of green wood oil rouge Industrial Co., Ltd), commodity Name " EMALEX HC-80 ", trade name " EMALEX HC-100 " (the above are the manufactures of Nihon Emulsion Co., Ltd.) etc..

As the commercially available product of ingredient (B3), for example, trade name " BLAUNON RCW-20 ", trade name " BLAUNON RCW-40 ", trade name " BLAUNON CW-10 ", trade name " BLAUNON CW-25 ", trade name " BLAUNON CW-40 " (the above are the manufactures of green wood oil rouge Industrial Co., Ltd), trade name " EMALEX HC-5 ", trade name " EMALEX HC- 7 ", trade name " EMALEX HC-10 ", trade name " EMALEX HC-20 ", trade name " EMALEX HC-30 ", trade name " EMALEX HC-40 ", trade name " EMALEX RWIS-105 ", trade name " EMALEX RWIS-105EX ", trade name " EMALEX RWIS-110 ", trade name " EMALEX RWIS-110EX ", trade name " EMALEX RWIS-115 ", trade name " EMALEX RWIS-115EX ", trade name " EMALEX RWIS-120 ", trade name " EMALEX RWIS-130 ", trade name " EMALEX RWIS-140 ", trade name " EMALEX RWIS-305 ", trade name " EMALEX RWIS-310 ", trade name " EMALEX RWIS-315 ", trade name " EMALEX RWIS-315EX ", trade name " EMALEX RWIS-320 ", trade name " EMALEX RWIS-320EX ", trade name " EMALEX RWIS-330 ", trade name " EMALEX RWIS-340 " (the above are The manufacture of Nihon Emulsion Co., Ltd.) etc..

In hair styling agent composition of the invention, the content of mentioned component (B1) is relative to mentioned component (B1) and mentioned component (B2) mass ratio [(B1)/{ (B1)+(B2) }] of total content is 0.1~0.9, preferably 0.2~0.8.It is above-mentioned by making Mass ratio is the formation of forming easiness (arranging power), the characteristic, tiny topknot that erect topknot from root of hair in above range Property and keep the characteristic of hair style all excellent for a long time.From further increase the characteristic for keeping hair style for a long time in terms of go out Hair, [(B1)/{ (B1)+(B2) }] is more preferably 0.25~0.5.It should be noted that in this specification, mentioned component (B1) Content is the total content of the whole components (B1) in hair styling agent composition of the invention, and the content of mentioned component (B2) is the present invention Hair styling agent composition in whole components (B2) total content.

To in ingredient (B) ingredient (B1) and the total content of ingredient (B2) be not particularly limited, relative to ingredient (B) 100 Quality %, preferably 50.0 mass % or more (such as 50.0~100 mass %), more preferably 70.0 mass % or more, into one Step is preferably 80.0 mass % or more.If above-mentioned content be 50.0 mass % or more, can sufficiently obtain using ingredient (B1) and at Effect brought by point (B2), especially can be improved the characteristic for erecting topknot from root of hair, the formative of tiny topknot and it is long when Between keep hair style characteristic.

The total content of ingredient (B1) and ingredient (B2) in hair styling agent composition of the invention is haircuted relative to of the invention 100 mass % of agent composition is 3.0~25.0 mass %, preferably 5.0~20.0 mass %, more preferably 6.0~15.0 matter Measure %.By making in above-mentioned content above range, forming easiness, the characteristic for erecting topknot from root of hair, tiny topknot Formative and keep the characteristic of hair style all excellent for a long time.

The content of ingredient (B3) in hair styling agent composition of the invention is not particularly limited, relative to of the invention whole Send out 100 mass % of agent composition, preferably 0.5~10.0 mass %, more preferably 0.8~5.0 mass %.If above-mentioned content is In above range, then arrangement power can be further increased while inhibiting the gloss and weight of hair.In addition, being able to suppress whole Hair agent composition becomes really up to the mark, can further increase operability.

The content of ingredient (B) in hair styling agent composition of the invention is not particularly limited, relative to of the invention whole Send out 100 mass % of agent composition, preferably 3.0~30.0 mass %, more preferably 5.0~25.0 mass %, more preferably 6.0 ~20.0 mass %.If above-mentioned content is in above range, the easiness, characteristic for erecting topknot from root of hair, tiny is shaped The formative of topknot and keep for a long time hair style characteristic all it is more excellent.The content of mentioned component (B) is of the invention The total content of whole components (B) in hair styling agent composition.

[ingredient (C)]

Mentioned component (C) is to use (methyl) acrylic acid and/or (methyl) alkyl acrylate and (methyl) acrylic acid poly- Ethylene oxide alkyl ether is as polymer obtained from necessary monomer component.It should be noted that in this specification, " (methyl) third Olefin(e) acid " refers to " acrylic acid " and/or " methacrylic acid ", that is, " acrylic acid " and the two or any one in " methacrylic acid " Person.Ingredient (C) has the effect of thickening hair styling agent composition.In addition, by sharing ingredient (B) and ingredient (C), hair styling agent group The elasticity for closing object improves, and viscosity reduction under shear is suppressed, therefore when scraping hair styling agent composition from container etc., Be easy scraping (finger availability is good), be easy taken from container with finger appropriate hair styling agent composition come using, treatability is excellent, The operability of hair styling agent composition is excellent.In addition, after taking out hair styling agent composition from container, the hair styling agent composition in container Surface is timely naturally smoothened, and aesthetics is excellent.In addition to this, by using ingredient (C), hair styling agent composition it is long when Between keep hair style characteristic further increase.Ingredient (C) may be used alone or in combination of two or more.

In order to obtain the polymer of ingredient (C) and the monomer component that uses include at least selected from by (methyl) acrylic acid and At least one of the group of (methyl) alkyl acrylate composition monomer component [monomer component (c1)] and (methyl) acrylic acid are poly- Ethylene oxide alkyl ether [monomer component (c2)].In addition it is also possible to include other monomer components.That is, ingredient (C) be including at least The polymer of structural unit and the structural unit from monomer component (c2) from monomer component (c1).As monomer component (c1) and monomer component (c2) it, may be used alone or in combination of two or more respectively.

As ingredient (C), be not particularly limited, preferably with INCI (international cosmetic raw material dictionary and handbook, the 15th Version, volume 1,2014, page 72) it is expressed as " ACRYLATES/STEARETH-20METHACRYLATE COPOLYMER ((propylene Sour -20 methacrylate of (ester) class/stereth) copolymer) " compound；With INCI (international cosmetic raw material words Allusion quotation and handbook, the 15th edition, volume 1,2014, page 73) it is expressed as " ACRYLATES/STEARETH-20METHACRYLATE The compound of CROSSPOLYMER ((- 20 methacrylate of acrylic acid (ester) class/stereth) cross-linked polymer) "；With INCI (international cosmetic raw material dictionary and handbook, the 15th edition, volume 1,2014, page 62) are expressed as " ACRYLATES/ ((acrylic acid (ester) class/- 25 methacrylate of docosyl alcohol polyethers) is total by BEHENETH-25METHACRYLATE COPOLYMER Polymers) " compound etc..

Wherein, preferred (acrylic acid (ester) class/- 25 methacrylate of docosyl alcohol polyethers) copolymer.If using (acrylic acid (ester) class/- 25 methacrylate of docosyl alcohol polyethers) copolymer is as ingredient (C), then and the spinnability of hair styling agent composition subtracts Small, operability further increases.As the commercially available of (acrylic acid (ester) class/- 25 methacrylate of docosyl alcohol polyethers) copolymer Product, for example, trade name " ACULYN 28 " (manufacture of Dow Chemical company).

Ingredient (C) is not particularly limited, preferably make after neutralizing or being neutralized with alkaline matter with alkaline matter With.As above-mentioned alkaline matter, for example, the ethyl alcohol amines such as triethanolamine or monoethanolamine, ammonia, sodium hydroxide or hydrogen Basic amino acids such as the inorganic bases such as potassium oxide, arginine etc..In addition, the additive amount of above-mentioned alkaline matter is after reaching sufficiently neutralization Ingredient (C) amount or the full amount for neutralizing ingredient (C), as long as according to the kind of ingredient (C) and above-mentioned alkaline matter Class and the appropriate mixture of the dosage of ingredient (C).

The content of ingredient (C) in hair styling agent composition of the invention is relative to 100 matter of hair styling agent composition of the invention Amount % is 0.1~1.5 mass %, preferably 0.3~1.2 mass %.By making in above-mentioned content above range, protect for a long time Characteristic and the operability for holding hair style are excellent.And then washing away property improves.The content of mentioned component (C) is that hair styling agent of the invention combines The total content of whole components (C) in object.

[ingredient (D)]

Mentioned component (D) is carboxyl vinyl polymer and/or alkyl-modified carboxyl group polyvinyl, that is, carboxyl second Alkenyl polymer and the two in alkyl-modified carboxyl group polyvinyl or any one.Ingredient (D) mainly have make system The effect of thickening.Ingredient (D) has the effect of thickening hair styling agent composition.In addition, by by ingredient (D) and ingredient (C) into Row share, can inhibit hair styling agent composition elasticity become excessively high caused by from the scraping of container be deteriorated, be easy to use finger Appropriate hair styling agent composition is taken to come using treatability improves, and the operability of hair styling agent composition improves from container.In addition, logical It crosses and shares ingredient (C) and ingredient (D), it is sticky when being able to suppress coating, it is sufficiently thickened while keeping washing away property well. In addition to this, it being thickened by using ingredient (D), expansion when hair styling agent composition is coated with becomes well, and coating improves, Therefore it is preferred that.Ingredient (D) may be used alone or in combination of two or more.

Above-mentioned carboxyl vinyl polymer is mainly the polymer of acrylic acid, abovementioned alkyl modified carboxyl polyvinyl The predominantly copolymer of acrylic acid and alkyl methacrylate (for example, total carbon atom number is 10~30 (C10~C30)).Make It for above-mentioned carboxyl vinyl polymer, is not particularly limited, can enumerate with INCI (international cosmetic raw material dictionary and hands Volume, the 15th edition, volume 1,2014, page 582~583) it is expressed as the compound of " CARBOMER (carbomer) ".As above-mentioned alkane Base modified carboxyl polyvinyl, is not particularly limited, and can enumerate with INCI (international cosmetic raw material dictionary and hands Volume, the 15th edition, volume 1,2014, page 63~64) it is expressed as " ACRYLATES/C10-30ALKYL ACRYLATE The compound of CROSSPOLYMER ((acrylic acid (ester) class/alkyl acrylate (C10-30)) cross-linked polymer) ".

As the commercially available product of above-mentioned carboxyl vinyl polymer, for example, trade name " Carbopol 934 ", quotient The name of an article " Carbopol 940 ", trade name " Carbopol 941 ", trade name " Carbopol 980 ", trade name " Carbopol 981 ", trade name " Carbopol 1342 ", trade name " Carbopol 2984 ", trade name " Carbopol Ultrez 10 ", Trade name " Carbopol ETD 2050 " (the above are the manufactures of Japanese Lu Borun Co., Ltd.), trade name " AQUPEC HV- 501 ", trade name " AQUPEC HV-504 ", trade name " AQUPEC HV-505 ", trade name " hiviswako 104 ", trade name " hiviswako 105 " (the above are Wako Pure Chemical Industries, Ltd.'s manufactures) etc..As abovementioned alkyl modified carboxyl vinyl The commercially available product of polymer, for example, trade name " PEMULEN TR-1 ", trade name " PEMULEN TR-2 ", trade name " Carbopol ETD 2020 ", trade name " Carbopol ULTREZ 20 ", trade name " Carbopol ULTREZ 21 " (with It is upper to be manufactured for Lu Borun Co., Ltd., Japan) etc..

Ingredient (D) is not particularly limited, preferably make after neutralizing or being neutralized with alkaline matter with alkaline matter With.As above-mentioned alkaline matter, for example, the ethyl alcohol amines such as triethanolamine and monoethanolamine；Ammonia, sodium hydroxide and hydrogen The inorganic bases such as potassium oxide；Basic amino acids such as arginine etc..In addition, the additive amount of above-mentioned alkaline matter is after reaching sufficiently neutralization Ingredient (D) amount or the full amount for neutralizing ingredient (D), as long as according to the kind of ingredient (D) and above-mentioned alkaline matter Class and the appropriate mixture of the dosage of ingredient (D).

The content of ingredient (D) in hair styling agent composition of the invention is relative to 100 matter of hair styling agent composition of the invention Amount % is 0.05~1.5 mass %, preferably 0.2~0.8 mass %.By making in above-mentioned content above range, hair styling agent The viscoplasticity of composition is adjusted to range appropriate, and operability improves.The content of mentioned component (D) is hair styling agent of the invention The total content of whole components (D) in composition.

[ingredient (E)]

Ingredient (E) is water, is not particularly limited, preferably pure water.Ingredient (E) makes hair styling agent composition rouge of the invention The aqueous hair styling agent composition of paste etc. and form oil-free sexy and salubrious sense of touch, there is the benefit for improving expansion, improve and apply The effect of cloth.The content of ingredient (E) in hair styling agent composition of the invention is not particularly limited, relative to of the invention 100 mass % of hair styling agent composition is preferably 40.0~95.0 mass %, more preferably 50.0~85.0 mass %.

[ingredient (F)]

Hair styling agent composition of the invention can also further contain polymer and forms polymer (sometimes referred to as " ingredient (F)").Ingredient (F) is, for example, the polymer that can form overlay film on hair after being applied to hair.Containing ingredient (F) In the case of, the characteristic that erects topknot from root of hair and keep the characteristic of hair style more excellent for a long time, therefore it is preferred that.As ingredient (F), It is not particularly limited, for example, anionic property overlay film forms polymer, cationic overlay film forms polymer, both sexes are covered Film forms polymer, nonionic overlay film forms etc..It should be noted that in this specification, ingredient (F) do not include with The comparable polymer of ingredient (C) and with ingredient (D) comparable polymer.Ingredient (F) can be used only a kind, also can be used 2 kinds More than.

As above-mentioned anionic property overlay film forms polymer, for example, acrylic resin alkanolamine, methyl second Alkene ether/maleate copolymer, vinyl acetate/crotonic acid copolymers, vinyl acetate/butenoic acid/vinyl neodecanoate Copolymer, vinyl acetate/butenoic acid/vinyl propionate copolymer, vinyl acetate/different ice of butyl maleate/acrylic acid Piece ester copolymer, acrylic acid/alkyl acrylate/alkyl acrylamide copolymer, polyvinylpyrrolidone/acrylate/(first Base) acrylic copolymer, (styrene/acrylic Arrcostab) copolymer, (styrene/acrylamide) copolymer, alkyl acrylate Base ester/alkyl methacrylate/Diacetone Acrylamide/methacrylic acid copolymer, urethane-acrylic copolymerization Object, kayexalate etc..

As above-mentioned cationic overlay film forms polymer, for example, vinyl pyrrolidone N, N- diformazan ammonia Base ethyl methacrylate copolymer diethyl sulfide hydrochlorate, chlorination О-[2- hydroxyl -3- (trimethyl ammonium) propyl] ethoxy are fine Tie up element, vinyl imidazole terchoride/vinylpyrrolidone copolymer, hydroxyethyl cellulose/dimethyl diallyl chlorine Change ammonium, polyvinylpyrrolidone/alkyl amido acrylate/vinyl caprolactam copolymer, chloromethyl vinyl base imidazoles Vinylpyrrolidone copolymer, (vinyl pyrrolidone/dimethylamino-propyl Methacrylamide/lauryl dimethyl amine Propyl methacrylamide) copolymer etc..

As above-mentioned both sexes overlay film forms polymer, for example, N- methacryloxyethyl N, N- dimethyl Ammonium-α-N- methyl carboxybetaine methacrylate copolymer [(methacryloxyethyl carboxybetaine/ Alkyl methacrylate) copolymer], hydroxypropyl acrylate/butylaminoethyl/acrylic acid octyl amide it is total Polymers, methacrylic acid dialkylamino ethyl/methacrylate copolymer monochloro acetic acid both sexes compound, (isobutyl Alkene/diethyl amino propyl maleimide/maleic acid) copolymer etc..

As above-mentioned nonionic overlay film forms, for example, polyvinylpyrrolidone, vinyl pyrrole Alkanone/vinyl acetate copolymer [(vinyl pyrrolidone/VA) copolymer], vinyl pyrrolidone/Methacrylamide/ Nvinylimidazole copolymers, methoxy ethylene ethyl maleate copolymer, polyvinyl alcohol, Vinylcaprolactam homopolymer, diformazan Base acrylamide/hydroxy-ethyl acrylate/methoxyethyl acrylate copolymer, hydroxy-ethyl acrylate/methoxyethyl acrylate Copolymer [(hydroxy-ethyl acrylate/methoxyethyl acrylate) copolymer] etc..

Among above-mentioned, from make topknot keep from the characteristic that root of hair erects and for a long time hair style characteristic it is superior in terms of go out Hair, preferably nonionic overlay film forms.Wherein, more preferably (hydroxy-ethyl acrylate/methoxyethyl acrylate) copolymerization Object.Above-mentioned (hydroxy-ethyl acrylate/methoxyethyl acrylate) copolymer is structural unit from hydroxy-ethyl acrylate and comes It is the copolymer of necessary structural unit from the structural unit of methoxyethyl acrylate.Above-mentioned (hydroxy-ethyl acrylate/acrylic acid first Oxygroup ethyl ester) copolymer is, for example, to be expressed as INCI: HYDROXYETHYL ACRYLATE/METHOXYETHYL ACRYLATE The compound of COPOLYMER.It, can be with as the commercially available product of above-mentioned (hydroxy-ethyl acrylate/methoxyethyl acrylate) copolymer Enumerate trade name " PLUS SIZE L-2200 " (Goo Chemical Co., Ltd.'s manufacture) etc..

In the case that hair styling agent composition of the invention contains ingredient (F), to 100 matter of hair styling agent composition of the invention The content of ingredient (F) in amount % is not particularly limited, preferably 0.1~7.0 mass %, more preferably 0.2~5.0 matter Measure %.If above-mentioned content is 0.1 mass % or more, the characteristic for erecting topknot from root of hair and the characteristic for keeping hair style for a long time It is more excellent.In addition, if 7.0 mass % hereinafter, then operability, again haircuting property raising.The content of mentioned component (F) is the present invention Hair styling agent composition in whole components (F) total content.

[other compositions]

Hair styling agent composition of the invention can also include ingredient (A)~(F) in the range of lossless effect of the present invention with Outer ingredient (other compositions).Be not particularly limited as above-mentioned other compositions, for example, commonly used in cosmetics or The ingredient etc. of quasi drug.Specifically, for example, other than ingredient (B) surfactant (other than ingredient (B) it is non-from Sub- surfactant, anionic surfactant, cationic surfactant, amphoteric surfactant)；The lower alcohols such as ethyl alcohol； The oil components such as polyalcohol, higher alcohol, silicone oil, ester oil, wax, vegetable oil, chloroflo, hydrocarbon ils, grease, higher fatty acids；Ingredient (C) With the thickener (hydroxymethyl cellulose, hydroxypropyl methyl cellulose, xanthan gum etc.) other than ingredient (D)；Fragrance；Ultraviolet radiation absorption Agent；Antioxidant；Chelating agent；Powder other than ingredient (A)；Pigment；Pigment；Dyestuff；Vitamins；Amino acids；Astringent； Whitening agent；Animal and plant extracts；PH adjusting agent；Preservative；Solvent；Acid；Alkali etc..

Hair styling agent composition of the invention preferably contains substantially no diglycerol, polyglycereol and dipropylene glycol.That is, of the invention Hair styling agent composition be preferably free of diglycerol, polyglycereol and dipropylene glycol, alternatively, double in hair styling agent composition of the invention The total content of glycerol, polyglycereol and dipropylene glycol is preferably smaller than 5.0 matter relative to 100 mass % of hair styling agent composition of the invention Measure %.Diglycerol, polyglycereol in hair styling agent composition of the invention and the total content of dipropylene glycol are more preferably 1.0 mass % It below, is more preferably 0.1 mass % or less.It, can in the case where being substantially free of diglycerol, polyglycereol and dipropylene glycol Further suppress the reflecting feel after haircuting and sticky.

About hair styling agent composition of the invention, from being difficult to when getting on hand and being applied to hair from flowing down on hand, handle The excellent aspect of property is set out, and viscosity (25 DEG C) is preferably 5000mPas or more.Above-mentioned " viscosity (25 DEG C) " can be used for example Brookfield type rotational viscometer is measured at 25 DEG C.

In addition, the consistency (25 DEG C) about hair styling agent composition of the invention, is easy from when being scooped out from container with finger It scoops out, the aspect that operability is excellent is set out, preferably 50gf or less, more preferably 30gf or less.Above-mentioned " consistency (25 DEG C) " example It such as can be used and haveThe consistency meter of flat pattern connector, under conditions of 25 DEG C, speed 60mm/ minutes and stroke 20mm into Row measurement.As above-mentioned consistency meter, " the RHEO METER " etc. of the manufacture of Sun Scientific Co., Ltd. can be enumerated.

As the character of hair styling agent composition of the invention, from being difficult to when getting on hand and being applied to hair from flowing on hand Under, the excellent aspect of treatability set out, preferably gel, fat shape；From can be filled into can container etc., with finger from container In take it is appropriate etc. come using for the use of set out, particularly preferred fat shape.That is, hair styling agent composition of the invention is preferably gel Hair styling agent composition, fat shape hair styling agent composition (referred to as hair rouge, water fat, water-soluble pomade etc.), particularly preferably fat Shape hair styling agent composition.

Hair styling agent composition of the invention is not particularly limited, can be manufactured by known or customary way. For example, can be by above-mentioned each ingredient is stirred and is homogenized using dispersing mixer, blade mixer etc. method etc. To manufacture.

Hair styling agent composition of the invention is not particularly limited, for example, can be used in the mode being filled into container. As said vesse, bottle container, can container, tubular container etc. can be enumerated.Although being not particularly limited, in terms of treatability It sets out, in the case where hair styling agent composition of the invention is gelatinous situation, preferably bottle container, tubular container or can container, at this In the case that the hair styling agent composition of invention is fat shape, preferred can container.

Hair styling agent composition of the invention is the aqueous hair styling agent composition comprising ingredient (E), and coating is excellent.And And as main ingredient of haircuting, ingredient (B1) and ingredient (B2) used as ingredient (B).Pass through compounding ingredients (B1), energy It is enough fully to shape, and there is the characteristic for erecting topknot from root of hair；And then by compounding ingredients (B2), has and protect for a long time Hold the characteristic of the hair style after haircuting.In addition, hair styling agent composition of the invention as thickening agent combination used ingredient (C) and at Divide (D).It is thought that ingredient (C) generates the interaction with ingredient (B) while thickening hair styling agent composition, it can The elasticity of hair styling agent composition is improved, the viscosity under shearing is inhibited to reduce.But, if it is desired to it is filled merely with ingredient (C) The thickening effect divided, then the elasticity of sticky increase, washing away property variation or hair styling agent composition becomes excessively high, thus can generate The problem of operability such as finger availability reduction from container reduce.Therefore, in the present invention, by further sharing as increasing The ingredient (D) of thick ingredient can inhibit and elastic caused by ingredient (C) be excessively increased and can make hair styling agent composition moderately Thickening.It is easy to take suitable hair styling agent composition come using in addition, the painting of hair styling agent composition from container with finger as a result, Coating when cloth is excellent, operational excellent.In addition, sticky be inhibited, washing away property is improved.In addition, passing through further mixture Ingredient (A) makes the mutual bonding of hair moderately scatter, from there through with adherence and there is hardness to a certain degree The multiplier effect of ingredient (B1) can moderately form tiny topknot, and inhibit reflecting feel.In addition to this, it can inhibit Mainly by the sticky of ingredient (C) bring hair, washing away property is also improved.

In addition, its trace can remain on hair styling agent composition table when usually taking out hair styling agent composition from container with finger Face, but hair styling agent composition of the invention is due to above-mentioned composition, after trace can through when disappear, the hair styling agent group in container Conjunction object surface is naturally smoothened, and aesthetics is excellent.

Embodiment

Hereinafter, based on embodiment, the present invention will be described in more detail, but the present invention is not limited to these implementations Example.It should be noted that the blend amount recorded in table is the blend amount of each ingredient (that is, the mixture of the effective component in each raw material Amount), it is indicated as long as not special declaration with " quality % ".In addition, the "-" in blend amount in table indicates the not mixed ingredient.

Embodiment 1~19, comparative example 1~7

Using each ingredient (ingredient (A)~(F) and other compositions) recorded in table, hair styling agent group is prepared according to conventional methods Object is closed, following evaluations are carried out to each sample of embodiment and comparative example.Result is shown in table.

(evaluation)

Each hair styling agent composition obtained in embodiment and comparative example is evaluated as follows.

[test example 1: the evaluation of treatability (the acquisition easiness of hair styling agent composition)]

Hair styling agent composition 50g obtained in each embodiment and each comparative example is fitted into can container (capacity 50mL), it is right Acquisition easiness when scraping hair styling agent composition with finger is evaluated, and is commented according to following evaluation criteria " treatability " Valence.By evaluation result note in table.

Zero (good): the hair styling agent composition of sufficient amount can easily be scraped.

× (bad): the unattached enough amounts of finger.

[using haircuting for hair styling agent composition]

Then, it takes hair styling agent composition obtained in each embodiment of about 2g and each comparative example to palm, is unfolded on palm Afterwards, it is applied in wig (Co., Ltd. beaulax manufacture, trade name " スタッ Off スカットウィッグ ").To the left and right of wig It is any one to be partly coated.Later, it is haircuted with hand comb, according to making the hair of wig gently flow to head along the shape of wig The mode of rear direction is haircuted.It should be noted that in coating, hair styling agent obtained in each embodiment and each comparative example Composition is unfolded that good, coating is excellent.

[test example 2: arranging the evaluation of power (power for shaping hair)]

The state of haircuting for just having carried out the wig after above-mentioned haircut visually is observed, " arranging power " is evaluated. As a result, using other than comparative example 4 each embodiment and each comparative example obtained in the feelings haircuted of hair styling agent composition Under condition, hair, which is haircuted into, flows to back of head direction (arranging power: good).On the other hand, using whole obtained in comparative example 4 In the case that hair agent composition is haircuted, can not hair be shaped to back of head direction and (arrange power: bad).

[test example 3: the evaluation for the characteristic for erecting topknot from root of hair]

The procephalic state of haircuting for just having carried out the wig after above-mentioned haircut visually is observed, according to following evaluations Benchmark evaluates " characteristic for erecting topknot from root of hair ".By evaluation result note in table.

Zero (good): topknot is sufficiently erected from root of hair, and the weight sense of hair entirety is excellent.

Δ (can actually use): topknot is erected from root of hair, but standing is small, and the weight sense of hair entirety is slightly poor.

× (bad): the root of hair of topknot does not float, and topknot does not erect completely.Weight sense without hair entirety.

[test example 4: the evaluation of the formation easiness of tiny topknot]

The state of haircuting for just having carried out the wig after above-mentioned haircut visually is observed, according to following evaluation criteria pair " the formation easiness of topknot " is evaluated.By evaluation result note in table.

Zero (good): the mutual bonding pine of hair forms the topknot that density is low, loose.

Δ (can actually use): hair is bonded to each other, and forms close and tiny topknot.

× (bad): topknot sticks together each other and forms planar.

[test example 5: the evaluation of reflecting feel (natural gloss invariably)]

The state of haircuting for just having carried out the wig after above-mentioned haircut visually is observed, according to following evaluation criteria pair " reflecting feel (natural gloss invariably) " is evaluated.By evaluation result note in table.

Zero (good): natural gloss invariably, for haircut before the close gloss of hair.

Δ (can actually use): slightly feeling gloss, but be not unnatural gloss.

× (bad): for gloss unnatural as wet hair.

[test example 6: keeping the evaluation of the characteristic of hair style for a long time]

The state of haircuting of wig after above-mentioned haircut after 6 hours is visually observed, according to following evaluation criteria " keeping the characteristic of hair style for a long time " is evaluated.By evaluation result note in table.

Zero (good): arranged hair style is also maintained after 6 hours.

Δ (can actually use): hair style is slightly destroyed after 6 hours, but generally maintains hair style.

× (bad): hair style is destroyed completely after 6 hours, does not maintain hair style.

It should be noted that not evaluated about no arrangement power, the comparative example 4 that hair can not be shaped.

[test example 7: sticky evaluation]

The wig after just having carried out above-mentioned haircut is touched with hand, is evaluated the presence or absence of sticky.As a result, using implementing The wig that hair styling agent composition obtained in example is haircuted does not feel sticky.

[test example 8: the evaluation of washing away property]

The hair styling agent composition of attachment to hand is rinsed with flowing water at once after above-mentioned haircut, to the journey of washing away property at this time The degree of washing away property after degree and rinsing is haircuted when wig after 6 hours is evaluated.As a result, in embodiment To hair styling agent composition washing away property it is excellent.

[test example 9: the evaluation of appearance]

In test example 1, with finger after scraping hair styling agent composition in can container, to the can container after 30 minutes It is observed on interior hair styling agent composition surface.As a result, the surface of the hair styling agent composition obtained in embodiment, finger Scraping trace substantially or entirely disappears, and becomes smooth surface.

[table 1]

The characteristic and keep hair style for a long time that hair styling agent composition (embodiment) of the invention erects topknot from root of hair Excellent is capable of forming tiny topknot, and the reflecting feel after haircuting is suppressed, and arrangement power is excellent, is capable of forming abundant It shapes and completes natural hair style.In addition, treatability is excellent, and then the coating on hair is also good, and operability is excellent.With This is opposite, in the case where non-compounding ingredients (A) (comparative example 1), can not form tiny topknot, and the hair after haircuting becomes face Shape.In addition, there are also unnatural reflecting feels after haircuting, keep the characteristic of hair style also poor for a long time.In addition, in non-compounding ingredients (C) in the case where (comparative example 2), the viscosity of hair styling agent composition is low, it is difficult to the hair styling agent group of sufficient amount is scraped from can container Object is closed, treatability is poor.In addition, in the case where non-compounding ingredients (D) (comparative example 3), the viscosity of hair styling agent composition is low, it is difficult to The hair styling agent composition of sufficient amount is scraped from can container, treatability is poor.In addition, (comparing in the case where non-compounding ingredients (B) Example 4), the viscosity for shearing lower hair styling agent composition reduces, therefore, it is difficult to scrape the hair styling agent composition of sufficient amount from can container, Treatability is poor.In addition, can not be fully formed by hair when haircuting, the characteristic for arranging power and erecting topknot from root of hair is poor.Separately Outside, in the case that the total content of ingredient (B1) and ingredient (B2) are less than 3.0 mass % (comparative example 5), hair haircuted into along The shape of wig is combed, and the characteristic for erecting topknot from root of hair is poor, can not form tiny topknot, and also have and haircut Reflecting feel afterwards.Also largely using in the case where ingredient (B3) other than ingredient (B1) as comparative example 5, thus it is speculated that due at It is insufficient to divide (B3) hardness, but hair does not scatter sufficiently, not formed tiny topknot, the generally heavier sense of touch of hair.In addition, In the case where non-compounding ingredients (B1) (comparative example 6), hair can not be made sufficiently to erect.In addition, in the feelings of non-compounding ingredients (B1) Under condition in the case where (comparative example 6) and non-compounding ingredients (B2) (comparative example 7), keep the characteristic of hair style poor for a long time.

The details for each ingredient recorded in table is as described below.

Silica: trade name " Silica pearl P-4M " (RiHui catalyst synthesis Co., Ltd's manufacture)

Mica: trade name " PDM-8W " (TOPY INDUSTRIES LTD. manufacture)

Talcum: trade name " CROWN TALC PP " (Ishihara Sangyo Kaisha, Ltd.'s manufacture)

Titanium dioxide: trade name " CR-50 " (Ishihara Sangyo Kaisha, Ltd.'s manufacture)

Polyoxyethylene (50E.O.) rilanit special: trade name " BLAUNON RCW-50 " (green wood oil prodution industry strain formula meeting Society manufacture), Crodaret (PEG-50 rilanit special), ethylene oxide average addition molal quantity: 50

Polyoxyethylene (60E.O.) rilanit special: trade name " BLAUNON RCW-60 " (green wood oil prodution industry strain formula meeting Society manufacture), Crodaret (PEG-60 rilanit special), ethylene oxide average addition molal quantity: 60

Polyoxyethylene (100E.O.) rilanit special: trade name " BLAUNON RCW-100 " (green wood oil prodution industry strain formula Commercial firm manufacture), Crodaret (PEG-100 rilanit special), ethylene oxide average addition molal quantity: 100

Polyoxyethylene (20E.O.) rilanit special: trade name " BLAUNON RCW-20 " (green wood oil prodution industry strain formula meeting Society manufacture), Crodaret (PEG-20 rilanit special), ethylene oxide average addition molal quantity: 20

Polyoxyethylene (40E.O.) rilanit special: trade name " BLAUNON RCW-40 " (green wood oil prodution industry strain formula meeting Society manufacture), Crodaret (Cremophor RH40), ethylene oxide average addition molal quantity: 40

(acrylic acid (ester) class/- 25 methacrylate of docosyl alcohol polyethers) copolymer: trade name " ACULYN TM28 " (manufacture of Dow Chemical company)

Carboxyl vinyl polymer: trade name " Carbopol 980 " (Japanese Lu Borun Co., Ltd. manufacture)

Alkyl-modified carboxyl group polyvinyl: trade name " Carbopol ETD 2020 " (Japanese Lu Borun Co., Ltd. Manufacture), (acrylic acid (ester) class/alkyl acrylate (C10-30)) cross-linked polymer

(hydroxy-ethyl acrylate/methoxyethyl acrylate) copolymer: trade name " PLUS SIZE L-2200 " (mutual induction Learn Industrial Co., Ltd's manufacture)

(alkyl acrylate/Diacetone Acrylamide) copolymer: trade name " PLUS SIZE L-6345U " (mutual induction Learn Industrial Co., Ltd manufacture), acrylic resin alkanolamine liquid

Diglycerol: trade name " diglycerol S " (manufacture of this pharmaceutical industries of slope Co., Ltd.)

In addition, the Formulation Example of hair styling agent composition of the invention described below.

(Formulation Example 1: hair rouge)

(Formulation Example 2: hair rouge)

(Formulation Example 3: hair rouge)

(Formulation Example 4: hair rouge)

(Formulation Example 5: hair rouge)

Industrial applicibility

The present invention relates to the hair styling agent compositions used in the hair styling agent arranged to hair.Hair styling agent of the invention Composition is preferably gel hair styling agent composition, fat shape hair styling agent composition (referred to as hair rouge, water fat, water-soluble pomade Deng), particularly preferably fat shape hair styling agent composition.

Claims

1. a kind of hair styling agent composition, to contain following compositions (A), following compositions (B), following compositions (C), following compositions (D) and the hair styling agent composition of following compositions (E), relative to the 100 mass % of hair styling agent composition, the ingredient (A) Content is 0.5~5.0 mass %, and the total content of following compositions (B1) and following compositions (B2) are 3.0~25.0 mass %, described The content of ingredient (C) is 0.1~1.5 mass %, and the content of the ingredient (D) is 0.05~1.5 mass %, the ingredient (B1) Content relative to mass ratio (B1)/{ (B1)+(B2) } of the ingredient (B1) and the total content of the ingredient (B2) be 0.1 ~0.9,

Ingredient (A): the powder selected from one or more of the group being made of silica, talcum, titanium dioxide and mica；

Ingredient (B): including the Crodaret of following compositions (B1) and following compositions (B2)；

Ingredient (B1): the Crodaret that the average addition molal quantity of ethylene oxide is 45~65；

Ingredient (B2): the Crodaret that the average addition molal quantity of ethylene oxide is 75~125；

Ingredient (C): use (methyl) acrylic acid and/or (methyl) alkyl acrylate and (methyl) acrylic acid polyxyethylated The polymer that ether obtains；

Ingredient (D): carboxyl vinyl polymer and/or alkyl-modified carboxyl group polyvinyl；

Ingredient (E): water.

2. hair styling agent composition as described in claim 1, wherein the ingredient (B) includes following compositions (B3),

Ingredient (B3): the average addition molal quantity of ethylene oxide is 5 Crodaret more than and less than 45.

3. hair styling agent composition as claimed in claim 1 or 2, wherein the ingredient (C) is (acrylic acid (ester) class/docosyl alcohol - 25 methacrylate of polyethers) copolymer.

4. hair styling agent composition according to any one of claims 1 to 3, it includes following compositions (F), relative to described whole 100 mass % of agent composition is sent out, the content of the ingredient (F) is 0.1~7.0 mass %,

Ingredient (F): polymer and forms polymer.

5. hair styling agent composition as described in any one of claims 1 to 4 is free of diglycerol, polyglycereol and dipropylene glycol, Alternatively, the total content of diglycerol, polyglycereol and propylene glycol is less than 5 matter relative to the 100 mass % of hair styling agent composition Measure %.