CN110157847B - Smelting system of iron-based polymetallic mineral aggregate - Google Patents

Smelting system of iron-based polymetallic mineral aggregate Download PDF

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Publication number
CN110157847B
CN110157847B CN201910517182.2A CN201910517182A CN110157847B CN 110157847 B CN110157847 B CN 110157847B CN 201910517182 A CN201910517182 A CN 201910517182A CN 110157847 B CN110157847 B CN 110157847B
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smelting
molten pool
feeding hole
iron
flue
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CN110157847A (en
Inventor
李东波
黎敏
刘诚
尉克俭
茹洪顺
郭亚光
徐小锋
曹珂菲
李兵
陈学刚
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China ENFI Engineering Corp
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China ENFI Engineering Corp
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/0006Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/006Starting from ores containing non ferrous metallic oxides
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/14Multi-stage processes processes carried out in different vessels or furnaces
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B34/00Obtaining refractory metals
    • C22B34/20Obtaining niobium, tantalum or vanadium
    • C22B34/22Obtaining vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B4/00Electrothermal treatment of ores or metallurgical products for obtaining metals or alloys
    • C22B4/06Alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B4/00Electrothermal treatment of ores or metallurgical products for obtaining metals or alloys
    • C22B4/08Apparatus

Abstract

The invention provides a smelting system of an iron-based multi-metal mineral aggregate. The iron-based multi-metal mineral aggregate comprises iron element, titanium element and vanadium element, and the smelting system comprises: the device comprises a mixing device, a molten pool smelting device and an electrothermal reduction device, wherein the mixing device is provided with a batching inlet and a mixing outlet; the molten pool smelting device is provided with a first feeding hole, a second feeding hole and a molten liquid outlet, the first feeding hole is arranged at the top of the molten pool smelting device, the second feeding hole is arranged on the side wall of the molten pool smelting device, and the material mixing outlet is communicated with the first feeding hole and/or the second feeding hole; and the electrothermal reduction device is provided with a slag discharge port, a metal discharge port and a melt inlet, and the melt inlet is communicated with the melt outlet. The smelting system combining the mixing device, the efficient molten pool smelting device and the electrothermal reduction device can effectively improve the recovery rate of vanadium element, reduce the operation labor intensity, and simultaneously have the advantages of reducing comprehensive energy consumption, improving environmental emission indexes and the like.

Description

Smelting system of iron-based polymetallic mineral aggregate
Technical Field
The invention relates to the field of metal smelting, in particular to a smelting system of an iron-based multi-metal mineral aggregate.
Background
Vanadium titano-magnetite is a more difficult ore to smelt. The vanadium titano-magnetite smelting device which is mature in application at present mainly comprises a blast furnace smelting device and a rotary kiln-electric furnace smelting device.
The smelting process by adopting the blast furnace smelting device mainly comprises the steps of adding vanadium titano-magnetite into a blast furnace after sintering or pelletizing, and recovering iron and vanadium. The prior document CN102041331A discloses a process for smelting vanadium titano-magnetite by using a blast furnace as a smelting device in the smelting process. But the smelting device has the main advantages of high production efficiency, large production scale, high comprehensive energy consumption, long flow, difficult separation of slag and iron, and low slag sticking and desulfurization capacity. In addition, the blast furnace method has higher requirements on the content of TiO 2 in the slag, which is generally lower than 25%.
The rotary kiln-electric furnace device is characterized in that iron concentrate obtained by ore dressing can be directly used for smelting, the flow is short, the recovery rate of iron and vanadium is higher than that of a blast furnace device, but titanium slag cannot be recycled at present. The prior document CN107815537a discloses a treatment device for vanadium titano-magnetite, which comprises a rotary kiln, a coal injector, an electric furnace and a converter. Firstly, pre-reducing vanadium titano-magnetite in a rotary kiln to obtain calcine; then the calcine enters an electric furnace for reduction smelting to obtain vanadium-containing molten iron; and finally, carrying out blowing treatment on the vanadium-containing molten iron in a converter to obtain semisteel and titanium slag. Compared with a blast furnace device, the rotary kiln-electric furnace smelting device has low comprehensive energy consumption, does not need coking or sintering, and has better environmental emission index. The rotary kiln-electric furnace method has the defects that the comprehensive energy consumption is still higher, the dependence on the electric power energy source is strong, and the method is difficult to popularize in areas with lack of electric power resources or high electric power cost.
In view of the above, there is a need to provide a low energy consumption smelting system for iron-based metalliferous mineral materials.
Disclosure of Invention
The invention mainly aims to provide a smelting system of an iron-based multi-metal mineral and aims to solve the problems of high energy consumption and low raw material adaptability of the existing smelting technology for the iron-based multi-metal mineral.
In order to achieve the above object, the present invention provides a smelting system for treating an iron-based multi-metal mineral aggregate including iron element, titanium element and vanadium element, the smelting system comprising: the device comprises a mixing device, a molten pool smelting device and an electrothermal reduction device, wherein the mixing device is provided with a batching inlet and a mixing outlet; the molten pool smelting device is provided with a first feeding hole, a second feeding hole and a molten liquid outlet, the first feeding hole is arranged at the top of the molten pool smelting device, the second feeding hole is arranged on the side wall of the molten pool smelting device, and the material mixing outlet is communicated with the first feeding hole and/or the second feeding hole; and the electrothermal reduction device is provided with a slag discharge port, a metal discharge port and a melt inlet, and the melt inlet is communicated with the melt outlet.
Further, the bath smelting device is a side-blown submerged bath smelting device, and the bath smelting device comprises at least one first side-blown lance, and the nozzle of the first side-blown lance is submerged below the liquid surface of the bath in the bath smelting device through a second feed port so as to spray fuel and oxygen-enriched air into the bath.
Further, the electrothermal reduction apparatus includes: at least one electrode, at least one second side-blowing spray gun and at least one top-blowing spray gun, wherein the tail end of the electrode is positioned below the liquid-phase material in the electrothermal reduction device and is used for supplying heat to the electrothermal reduction process; the nozzles of the second side-blowing spray gun and the top-blowing spray gun are both positioned above the liquid level in the electrothermal reduction device and are used for spraying the reducing agent into the electrothermal reduction device.
Further, the molten pool smelting device is also provided with a first flue which is communicated with the molten pool of the molten pool smelting device.
Further, the electrothermal reduction device is also provided with a second flue which is communicated with the reduction cavity of the electrothermal reduction device.
Further, the smelting system further comprises a dust collection device, the dust collection device is provided with a smoke inlet, and the smoke inlet is respectively communicated with the outlet ends of the first flue and the second flue through a smoke conveying pipeline.
Further, the smelting system also comprises a waste heat recovery device, and the waste heat recovery device is arranged on the flue gas conveying pipeline.
Further, the smelting system further comprises a crushing and drying device for crushing and drying the reaction raw materials, wherein the crushing and drying device is provided with a discharge port, and the discharge port is communicated with the batching inlet.
Further, the discharge granularity of the discharge port is smaller than 50mm.
By applying the technical scheme of the application, the smelting system for treating the iron-based polymetallic mineral aggregate aims at the problems of high energy consumption, poor raw material adaptability and the like of the existing blast furnace or rotary kiln-electric furnace smelting device. The smelting system combining the mixing device, the efficient molten pool smelting device and the electrothermal reduction device can effectively improve the recovery rate of vanadium element, reduce the operation labor intensity, and simultaneously have the advantages of reducing comprehensive energy consumption, improving environmental emission indexes and the like.
Drawings
The accompanying drawings, which are included to provide a further understanding of the application and are incorporated in and constitute a part of this specification, illustrate embodiments of the application and together with the description serve to explain the application. In the drawings:
FIG. 1 shows a schematic diagram of a smelting system for treating iron-based metalliferous mineral in accordance with an exemplary embodiment of the present invention;
FIG. 2 shows a schematic structural view of a smelting apparatus for iron-based multi-metal ores provided in accordance with an exemplary embodiment of the present invention;
FIG. 3 shows a schematic view of the bath smelting device of FIG. 2 in the direction A-A;
Fig. 4 is a schematic view showing the structure of the electro-thermal reduction device shown in fig. 2 in the C-C direction.
Wherein the above figures include the following reference numerals:
100. A mixing device;
200. a molten pool smelting device; 210. a first side-blowing lance; 220. a first flue; 201. a first feed inlet; 202. a second feed inlet;
300. An electrothermal reduction device; 310. an electrode; 320. a second side-blowing lance; 330. a top-blowing spray gun; 340. a second flue; 301. A slag discharge port; 302. a metal discharge port;
400. A dust collection device; 500. a waste heat recovery device; 600. crushing and drying device.
Detailed Description
It should be noted that, without conflict, the embodiments of the present application and features of the embodiments may be combined with each other. The present application will be described in detail with reference to examples.
As described in the background art, the existing smelting technology for the iron-based polymetallic mineral materials has the problems of high energy consumption and poor raw material adaptability. In order to solve the technical problems, the application provides a smelting system for treating an iron-based multi-metal mineral aggregate, wherein the iron-based multi-metal mineral aggregate comprises iron element, titanium element and vanadium element, and the smelting system comprises: the device comprises a mixing device 100, a molten pool smelting device 200 and an electrothermal reduction device 300, wherein the mixing device 100 is provided with a batching inlet and a mixing outlet; the molten pool smelting device 200 is provided with a first feeding hole 201, a second feeding hole 202 and a molten liquid outlet, the first feeding hole 201 is arranged at the top of the molten pool smelting device 200, the second feeding hole 202 is arranged on the side wall of the molten pool smelting device 200, and the mixing outlet is communicated with the first feeding hole 201 and/or the second feeding hole 202; and the electrothermal reduction device 300 is provided with a slag discharge port 301, a metal discharge port 302, and a melt inlet, which communicates with a melt outlet.
In the smelting system, after the reaction raw materials are mixed by the mixing device 100, the mixture enters the molten pool smelting device 200 through the first charging port 201 and/or the second charging port 202 to undergo melting and partial reduction processes to obtain molten liquid; then, the above-mentioned molten liquid is subjected to electrothermal deep reduction and slag depletion in electrothermal reduction apparatus 300, and after the reaction is completed, the metal is discharged through metal discharge port 302, and the slag is discharged through slag discharge port 301.
The smelting system for treating the iron-based polymetallic mineral aggregate adopts a two-in-one furnace technology of a mixing device, an oxygen-enriched molten pool smelting device and an electrothermal reduction device, and adopts a short-flow process that raw materials such as iron-based polymetallic concentrate and the like are mixed by the mixing device 100 and then directly enter the molten pool smelting device 200 and the electrothermal reduction device 300, so that pretreatment procedures such as rotary kiln smelting or sintering are omitted. The smelting system combining the mixing device 100, the efficient molten pool smelting device 200 and the electrothermal reduction device 300 can effectively improve the recovery rate of vanadium element, reduce the operation labor intensity, and simultaneously have the advantages of reducing comprehensive energy consumption, improving environmental emission indexes and the like.
In a preferred embodiment, the bath smelting device 200 is a side-blown submerged bath smelting device, the bath smelting device 200 comprising at least one first side-blown lance 210, the nozzle of the first side-blown lance 210 being submerged below the level of the bath in the bath smelting device 200 via a second feed port 202 for injecting fuel and oxygen-enriched air into the bath. The injection of fuel and oxygen-enriched air into the bath smelting device 200 by the first side-blowing lance 210 can provide strong agitation to the melt therein, thereby facilitating the improvement of mass and heat transfer efficiency, and simultaneously facilitating the improvement of the recovery rate of subsequent vanadium elements and the like.
In a preferred embodiment, electrothermal reduction device 300 includes: at least one electrode 310, at least one second side-blowing lance 320 and at least one top-blowing lance 330, the tip of the electrode 310 being located below the liquid phase material in the electrothermal reduction device 300 for supplying heat to the electrothermal reduction process; the nozzles of the second side-blowing lance 320 and the top-blowing lance 330 are both positioned above the liquid level in the electrothermal reduction apparatus 300 for injecting the reducing agent into the electrothermal reduction apparatus 300. Preferably, electrode 310 is a graphite electrode.
Injecting the reducing agent into the second side-blowing lance 320 and/or the top-blowing lance 330 may increase the contact area of the melt with the reducing agent so that the two react sufficiently. Meanwhile, the reducing agent is sprayed above the liquid level of the electrothermal reduction device 300, so that stirring of the liquid level of the electrothermal reduction device 300 caused by the addition of raw materials is restrained, and the influence of the stirring on the separation efficiency of vanadium-containing molten iron and titanium slag in the slag depletion process is reduced.
In order to facilitate the discharge of the flue gas, the molten pool smelting device 200 is preferably further provided with a first flue 220, and the first flue 220 is communicated with the molten pool of the molten pool smelting device 200; preferably, the electrothermal reduction device 300 is further provided with a second flue 340, and the second flue 340 is communicated with the reduction chamber of the electrothermal reduction device 300.
In order to improve the environmental protection of the whole process, in a preferred embodiment, the smelting system further comprises a dust collecting device 400, wherein the dust collecting device 400 is provided with a flue gas inlet, and the flue gas inlet is respectively communicated with the outlet ends of the first flue 220 and the second flue 340 through a flue gas conveying pipeline.
A certain amount of flue gas is generated during smelting, and usually the flue gas contains high heat. In order to increase the energy utilization, in a preferred embodiment, the smelting system further comprises a waste heat recovery device 500, the waste heat recovery device 500 being arranged on the flue gas transport line. The crushing and drying device 600 is used for crushing and drying the reaction raw materials, and the crushing and drying device 600 is provided with a discharge port which is communicated with the batching inlet; preferably, the discharge opening has a discharge particle size of less than 50mm. The crushing and drying device is arranged, so that the granularity and the water content of the iron-based multi-metal mineral aggregate are limited in the above range, and the melting efficiency of the iron-based multi-metal raw material is improved.
The application is described in further detail below in connection with specific examples which are not to be construed as limiting the scope of the application as claimed.
The compositions of the iron-based polymetallic mineral in examples 1 to 5 are 45 to 62wt% of Fe, 0.1 to 1.2wt% of TiO 2 7~20wt%、V2O5 and the balance of impurities, and the process flow is shown in figure 1.
Example 1
As shown in fig. 1 to 4, the bath smelting device comprises a bath smelting device 200 and an electrothermal reduction device 300 which are communicated, the bath smelting device 200 is provided with a first charging port 201 and a second charging port 202, the first charging port 201 is arranged at the top of the bath smelting device 200, the second charging port 202 is arranged on the side wall of the bath smelting device 200, and the electrothermal reduction device 300 is provided with a slag discharging port 301 and a metal discharging port 302. The nozzle of the first side-blown lance 210 is submerged below the level of the molten bath in the bath smelting device 200 via the second feed port 202 to inject fuel and oxygen-enriched air into the molten bath.
The electrothermal reduction device 300 is provided with 3 electrodes 310 (self-baking electrodes) and is supplied with ac power. A second side-blowing lance 320 and a top-blowing lance 330 are provided. The end of each electrode 310 is positioned below the liquid phase material of the electroheat reduction device 300 for supplying heat to the electroheat reduction process; the nozzle of the second side-blowing lance 320 is positioned above the liquid level of the electro-thermal reduction device 300 for injecting the reducing agent into the electro-thermal reduction device 300. The reduction smelting temperature in the smelting process is 1600 ℃.
Through the smelting process, the recovery rate of vanadium element is 95wt% and the recovery rate of iron element is 87wt%.
Example 2
The differences from example 1 are:
no submerged side-blown lance is used to inject fuel into the bath smelting unit 200.
Through the smelting process, the recovery rate of vanadium element is 93wt%, the recovery rate of iron element is 88wt%, and the comprehensive energy consumption is 7% higher than that of example 1.
Example 3
The differences from example 1 are: the number of electrodes 310 is 2.
Through the smelting process, the recovery rate of the vanadium element is 94wt% and the recovery rate of the iron element is 87wt%.
Example 4
The differences from example 1 are: the electrode 310 is made of graphite electrode.
Through the smelting process, the recovery rate of the vanadium element is 92wt% and the recovery rate of the iron element is 86wt%.
Example 5
The differences from example 1 are: the reducing agent is added using a top-blowing lance 330.
Through the smelting process, the recovery rate of vanadium element is 94wt%, the recovery rate of iron element is 87wt%, and the comprehensive energy consumption is 5% higher than that of example 1.
From the above description, it can be seen that the above embodiments of the present invention achieve the following technical effects:
Compared with the existing smelting device, the smelting system combining efficient molten pool smelting and electrothermal reduction can effectively improve the recovery rate of vanadium element, and has the advantages of reducing comprehensive energy consumption, improving environmental emission indexes and the like.
The above description is only of the preferred embodiments of the present invention and is not intended to limit the present invention, but various modifications and variations can be made to the present invention by those skilled in the art. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (7)

1. Use of a smelting system for treating an iron-based multi-metal mineral that includes elemental iron, elemental titanium, and elemental vanadium, the smelting system comprising:
A mixing device (100), wherein the mixing device (100) is provided with a batching inlet and a mixing outlet;
The molten pool smelting device (200), wherein the molten pool smelting device (200) is provided with a first feeding hole (201), a second feeding hole (202) and a molten liquid outlet, the first feeding hole (201) is arranged at the top of the molten pool smelting device (200), the second feeding hole (202) is arranged on the side wall of the molten pool smelting device (200), and the mixed material outlet is communicated with the first feeding hole (201) and/or the second feeding hole (202); and
An electrothermal reduction device (300), wherein the electrothermal reduction device (300) is provided with a slag discharge port (301), a metal discharge port (302) and a melt inlet, and the melt inlet is communicated with the melt outlet;
The molten pool smelting device (200) is a side-blowing submerged molten pool smelting device, the molten pool smelting device (200) comprises at least one first side-blowing spray gun (210), and a nozzle of the first side-blowing spray gun (210) is submerged below the liquid level of a molten pool in the molten pool smelting device (200) through the second feeding hole (202) so as to spray fuel and oxygen-enriched air into the molten pool;
the electrothermal reduction device (300) includes:
at least one electrode (310), the tip of the electrode (310) being located below the liquid phase material in the electrothermic reduction device (300) for supplying heat to the electrothermic reduction process;
At least one second side-blowing lance (320) and at least one top-blowing lance (330), the nozzles of the second side-blowing lance (320) and the nozzles of the top-blowing lance (330) being both located above the liquid level in the electrothermal reduction device (300) for injecting a reducing agent into the electrothermal reduction device (300).
2. The use of a smelting system according to claim 1 for treating iron-based multi-metal ores, wherein the bath smelting device (200) is further provided with a first flue (220), the first flue (220) being in communication with the bath of the bath smelting device (200).
3. The use of a smelting system according to claim 2 for treating iron-based multi-metal ores, wherein the electrothermal reduction device (300) is further provided with a second flue (340), the second flue (340) being in communication with the reduction chamber of the electrothermal reduction device (300).
4. A use of a smelting system according to claim 3 for treating iron-based multi-metal mineral aggregate, characterized in that the smelting system further comprises a dust collection device (400), the dust collection device (400) being provided with a flue gas inlet, which flue gas inlet communicates with the outlet ends of the first flue (220) and the second flue (340), respectively, via a flue gas conveying line.
5. The use of a smelting system according to claim 4 for treating iron-based multi-metal mineral aggregate, characterized in that the smelting system further comprises a waste heat recovery device (500), the waste heat recovery device (500) being arranged on the flue gas conveying line.
6. The use of a smelting system according to claim 5 for treating iron-based multi-metal mineral, characterized in that the smelting system further comprises a crushing and drying device (600) for crushing and drying the reaction raw material, the crushing and drying device (600) being provided with a discharge opening, and the discharge opening being in communication with the burden inlet.
7. The use of the smelting system according to claim 6 for treating iron-based multi-metal ore material wherein the discharge orifice has a discharge particle size of less than 50mm.
CN201910517182.2A 2019-06-14 2019-06-14 Smelting system of iron-based polymetallic mineral aggregate Active CN110157847B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101906498A (en) * 2010-08-25 2010-12-08 武钢集团昆明钢铁股份有限公司 Method for comprehensively smelting sefstromite
CN106996695A (en) * 2016-01-22 2017-08-01 中国恩菲工程技术有限公司 A kind of metallurgical furnace
CN107858502A (en) * 2017-12-07 2018-03-30 中国恩菲工程技术有限公司 Vanadium titano-magnetite processing method
CN210122577U (en) * 2019-06-14 2020-03-03 中国恩菲工程技术有限公司 Smelting system of iron-based multi-metal mineral aggregate

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101906498A (en) * 2010-08-25 2010-12-08 武钢集团昆明钢铁股份有限公司 Method for comprehensively smelting sefstromite
CN106996695A (en) * 2016-01-22 2017-08-01 中国恩菲工程技术有限公司 A kind of metallurgical furnace
CN107858502A (en) * 2017-12-07 2018-03-30 中国恩菲工程技术有限公司 Vanadium titano-magnetite processing method
CN210122577U (en) * 2019-06-14 2020-03-03 中国恩菲工程技术有限公司 Smelting system of iron-based multi-metal mineral aggregate

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