CN110149869A - Inhibit the preparation and method of cadmium enrichment in rice - Google Patents

Inhibit the preparation and method of cadmium enrichment in rice Download PDF

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Publication number
CN110149869A
CN110149869A CN201910452596.1A CN201910452596A CN110149869A CN 110149869 A CN110149869 A CN 110149869A CN 201910452596 A CN201910452596 A CN 201910452596A CN 110149869 A CN110149869 A CN 110149869A
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CN
China
Prior art keywords
rice
preparation
cadmium
enrichment
cadmium enrichment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910452596.1A
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Chinese (zh)
Inventor
保琼莉
黄益宗
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Environmental Protection Research And Monitoring Institute Of Ministry Of Agriculture And Rural Areas
Original Assignee
Environmental Protection Research And Monitoring Institute Of Ministry Of Agriculture And Rural Areas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Environmental Protection Research And Monitoring Institute Of Ministry Of Agriculture And Rural Areas filed Critical Environmental Protection Research And Monitoring Institute Of Ministry Of Agriculture And Rural Areas
Priority to CN201910452596.1A priority Critical patent/CN110149869A/en
Publication of CN110149869A publication Critical patent/CN110149869A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C21/00Methods of fertilising, sowing or planting
    • A01C21/005Following a specific plan, e.g. pattern
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00Other inorganic fertilisers
    • C05D9/02Other inorganic fertilisers containing trace elements
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers

Abstract

The invention discloses the preparations and method of cadmium enrichment in a kind of inhibition rice, it is intended to which solving existing preparation reduces that cadmium concentration effect is bad, technical problem at high cost.Every 1L said preparation is made of the sodium selenite and 10 ~ 30mL of 60 ~ 90mg of the product An Rongle that 882 Co., Ltd, South Africa Ni Le Cisco produces;The preparation for inhibiting cadmium enrichment in rice is sprayed in rice plant of tillering stage, heading stage and/or Early filling stage, the amount of spraying is 0.1L/m every time2, preparation method is simple, and it is easy to use, it is suitble to the needs of scale industrial production.

Description

Inhibit the preparation and method of cadmium enrichment in rice
Technical field
The invention belongs to agricultural product security fields, are related to a kind of preparation and method for inhibiting cadmium enrichment in rice.
Background technique
In recent years studies have shown that cadmium (Cadmium, Cd) is that known toxicity is most strong and the contaminated most serious in farmland One of heavy metal;Rice is the staple food source of 50% or more population of China, but rice is to absorb the strongest large cereal of cadmium ability to make Object, cadmium is enriched in rice causes in rice cadmium exceeded serious, causes the great attention of the Chinese government and researchers. Cadmium preparation drops in convenient and effect stability rice in Study On Rice production, and nutritive value and grain security to rice all have weight Want meaning.
Chinese patent 201410056774.6 discloses a kind of preparation that accumulates in crops of reduction cadmium and its use, and one Kind reduces the preparation that cadmium accumulates in crops, and said preparation includes the component of following concentration: reductive glutathione 50 ~ 80 Mg/ L, sodium selenite 15 ~ 30mg/ L, zinc sulfate 2.0 ~ 3.0 × 103Mg/ L, but such preparation is suitable only for mild or moderate cadmium Contaminated areas, and to cadmium reduced rate in rice grain less than 35%, except cadmium effect is barely satisfactory.
Thus, how to remove or reduce the cadmium in the crops of heavy Cd contamination area is current technology in the urgent need to address Problem.
Summary of the invention
The present invention is a kind of suitable for the preparation and method for inhibiting cadmium enrichment rice in heavy Cd contamination area, to solve The prior art technical problem undesirable except cadmium effect.
In order to solve the above technical problems, the present invention adopts the following technical scheme:
A kind of preparation for inhibiting cadmium enrichment in rice is designed, the main raw material for preparing of preparation described in every 1L includes the Asia 60 ~ 90mg selenium Sour sodium and 10 ~ 30mL An Rongle.
Preferably, the main material of preparation described in every 1L includes 70mg sodium selenite and 20mL An Rongle.
When preparation, the sodium selenite of corresponding number and peace is taken to melt happy mixing moisturizing to 1L, mixing.
A kind of method inhibiting cadmium enrichment in rice is provided, is sprayed on rice plant of tillering stage, heading stage and/or Early filling stage blade face Apply the preparation that cadmium is enriched in above-mentioned inhibition rice, 0.08 ~ 0.12L/m of the amount of spraying2
It rains if spraying in rear 30min, sprays again.
0.2 ~ 0.3 kg/m of lime is first spread fertilizer over the fields into rice field before rice transplanting2
Compared with prior art, the beneficial technical effect of the present invention lies in:
1. invention formulation preparation and application is easy, the equipment and cumbersome technique of no complexity pass through artificial or equipment leaf Face sprays compound formulation solution of the invention, and process for preparation is simple, operation is convenient and quick, easy to spread.
2. after application, the drop cadmium significant effect in rice;
3. non-environmental-pollution: sodium selenite and An Rongle can be absorbed rapidly by plant, noresidue, to wheat seed and soil without Pollution.
4. the present invention is suitable for the heavily contaminated area of cadmium, preparation stabilization, reasonable recipe is convenient for saving.
5. compatibility of the present invention is reasonable, specific as follows:
Selenium (Selenium, Se) can water lift rice growth rate, inhibit Lipid peroxidation metabolism and increase oxidation resistance, apply certain The selenium of concentration can enrichment of the antagonism cadmium in rice strain;An Rongle (containing lecithin, vitamin E etc.) is contacted and is wrapped up sodium selenite Molecule can reduce the surface tension of solution;It carries out being conducive to the wax coat and leaf across rice leaf surface when foliage-spray Piece stomata, and by the transdermal delivery of cell wall, transport of the rice in-vivo element between different tissues is realized, to improve sub- selenium The effect that sour sodium resistance control cadmium is accumulated in seed.
Specific embodiment
The technical solution that the present invention will be described in detail combined with specific embodiments below, but following embodiment is not in any way It limits the scope of the invention.Reagent involved in following embodiment is commercially available conventional reagent unless otherwise instructed.
Test material: test water rice varieties are Y two excellent 7, and formulated main material has: Na2SeO3(Chinese mugwort is green in Zhejiang Chemical Industry Science Co., Ltd analyzes pure, Se content >=45.7%);An Rongle (882 Co., Ltd, South Africa Ni Le Cisco, it is raw Production lot number: 20180512;Product standard number: Q/YC BHJ 0001-2018, main component are lecithin and vitamin E).
Embodiment 1
The preparation of cadmium enrichment in a kind of inhibition rice, every 1L preparation is by the sodium selenite and 20mL of 70mg by South Africa Ni Le Cisco The product An Rongle of 882 Co., Ltds production is made.
The method for inhibiting cadmium enrichment in rice, in rice plant of tillering stage, heading stage and/or Early filling stage according to 0.1L/m2's Amount of application inhibits the preparation that cadmium is enriched in rice in foliage-spray claim 1;It rains if spraying in rear 30min, again It sprays;Rice is to be planted in cadmium heavily contaminated soil.
Embodiment 2
Difference from Example 1 is:
The preparation of cadmium enrichment in a kind of inhibition rice, preparation described in every 1L is by the sodium selenite and 20mL of 80mg by South Africa Ni Lesi The product An Rongle of 882 Co., Ltd, section production is made.
Embodiment 3
Difference from Example 1 is:
The preparation of cadmium enrichment in a kind of inhibition rice, preparation described in every 1L are made of the sodium selenite and 30mL An Rongle of 90mg.
Embodiment 4
Difference from Example 1 is:
The preparation of cadmium enrichment in a kind of inhibition rice, preparation described in every 1L are made of the sodium selenite and 10mL An Rongle of 60mg.
Embodiment 5
Difference from Example 1 is:
The preparation of cadmium enrichment in a kind of inhibition rice, preparation described in every 1L are made of the sodium selenite and 20mL An Rongle of 70mg.
Effect example
Preparation and method prepared by the embodiment of the present invention 1 verify the effect for inhibiting cadmium enrichment in rice:
Test material: rice varieties are local main breed;Preparation obtained in embodiment 1;Lime is purchased from Hebei dragon and phoenix mountain furnace Expect Co., Ltd;Water-soluble organic fertilizer (Wuhan is white to reach agricultural science and technology Co., Ltd, and execution standard No. is Q/HDNY OO).
It tests the cadmium pollution rice field in by the end of May, 2018 in by the end of September, 2018 in the township liuyang hunan Jiao Xi to carry out, in soil Cadmium content is 1.97 ± 0.13 mg/kg, pH 6.06, and according to national standard BG 2762-2017, this area belongs to cadmium heavily contaminated soil Earth.
Test grouping:
Control 1: clear water is sprayed, respectively sprays 1 clear water in rice plant of tillering stage, heading stage and Early filling stage, the amount of spraying is every time 0.1L/m2
Control 2: Spraying Se-fertilizer respectively sprays 1 Asia 0.07g/L selenium in rice plant of tillering stage, heading stage and Early filling stage respectively Sour sodium, the every time amount of spraying 0.1L/m2
Control 3: 1 gained preparation of embodiment+lime spreads fertilizer over the fields 0.225 kg/m before rice transplanting2Lime, and in rice Tillering stage, heading stage and Early filling stage respectively spray 1 embodiment, 1 gained preparation, every time the amount of spraying 0.1L/m2
Control 4: spraying 1 gained preparation of embodiment+water-soluble organic fertilizer, and 0.02L is added in gained preparation in 1L embodiment 1 Water soluble organic fertilizer uniformly mixes and mixed liquor is made, respectively sprays 1 mixing in rice plant of tillering stage, heading stage and Early filling stage respectively Liquid, the every time amount of spraying 0.1L/m2
Test example 1: 1 gained preparation of embodiment is sprayed, respectively sprays reality in rice plant of tillering stage, heading stage and Early filling stage respectively 1 gained preparation of example is applied, every time the amount of spraying 0.1L/m2
Wherein the effect of water-soluble organic fertilizer: improving chlorophyll content, enhance photosynthesis, improve various enzymatic activitys, increase Nutrient accumulation.
Test process
3 repetitions are arranged in each processing, and each area that repeats is 10 m2
It is sampled after rice is mature, each repetition takes 20 plants at random, takes seed to mix well after threshing and is ground to powder End weighs and carries out acid after 0.5 g seed powder and disappear to boil, graphite furnace atomic absorption spectrometry seed cadmium content.
Influence of 1 different disposal of table to being enriched in rice
Grouping Cadmium content Except cadmium rate
Control 1 1.30 /
Control 2 0.78 40.0%
Control 3 0.69 46.9%
Control 4 0.64 50.8%
Test example 1 0.60 53.8%
As can be seen from Table 1, the preparation of test example 1 is inhibiting effect of the cadmium in rice in terms of enrichment to be substantially better than control Group 1 ~ 4.
The present invention is described in detail above in conjunction with embodiment, still, person of ordinary skill in the field can Understand, without departing from the purpose of the present invention, each design parameter in above-described embodiment can also be changed, shape At multiple specific embodiments, it is common variation range of the invention, is no longer described in detail one by one herein.

Claims (6)

1. it is a kind of inhibit rice in cadmium enrichment preparation, which is characterized in that preparation described in every 1L prepare in raw material include 60 ~ 90mg sodium selenite and 10 ~ 30mL An Rongle.
2. the preparation according to claim 1 for inhibiting cadmium enrichment in rice, which is characterized in that the preparation of preparation described in every 1L It include the sodium selenite and 20mL An Rongle of 70mg in raw material.
3. the preparation according to claim 1 for inhibiting cadmium enrichment in rice, which is characterized in that preparation method are as follows: first take The sodium selenite and An Rongle of corresponding number, then moisturizing is to 1L,.
4. a kind of method for inhibiting cadmium enrichment in rice, which is characterized in that in rice plant of tillering stage, heading stage and/or Early filling stage The preparation of cadmium enrichment, 0.08 ~ 0.12L/m of the amount of spraying in inhibition rice described in foliage-spray claim 12
5. inhibiting the method for cadmium enrichment in rice according to claim 4, which is characterized in that it rains if spraying in rear 30min, Then spray again.
6. inhibiting the method for cadmium enrichment in rice according to claim 4, which is characterized in that spread before rice transplanting in rice field Apply 0.2 ~ 0.3 kg/m2Lime.
CN201910452596.1A 2019-05-28 2019-05-28 Inhibit the preparation and method of cadmium enrichment in rice Pending CN110149869A (en)

Priority Applications (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111842478A (en) * 2020-07-28 2020-10-30 浙江大学 Method for repairing cadmium-polluted farmland on production side

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS526326A (en) * 1975-07-05 1977-01-18 Res Inst Electric Magnetic Alloys Vibration damping alloy and its production process
CN101884280A (en) * 2010-06-23 2010-11-17 濮阳市中原农村实用技术研究所 Method for planting selenium-enriched food for preventing diseases and resisting cancer
CN102320879A (en) * 2011-09-06 2012-01-18 李子先 High nutrient compound selenium fertilizer and preparation method thereof
CN102964177A (en) * 2012-11-13 2013-03-13 农业部环境保护科研监测所 Heavy-metal-resistant plant growth detoxification accelerant and method for using same
CN103980030A (en) * 2014-02-19 2014-08-13 浙江大学 Preparation for reducing accumulation of cadmium in crops and application method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS526326A (en) * 1975-07-05 1977-01-18 Res Inst Electric Magnetic Alloys Vibration damping alloy and its production process
CN101884280A (en) * 2010-06-23 2010-11-17 濮阳市中原农村实用技术研究所 Method for planting selenium-enriched food for preventing diseases and resisting cancer
CN102320879A (en) * 2011-09-06 2012-01-18 李子先 High nutrient compound selenium fertilizer and preparation method thereof
CN102964177A (en) * 2012-11-13 2013-03-13 农业部环境保护科研监测所 Heavy-metal-resistant plant growth detoxification accelerant and method for using same
CN103980030A (en) * 2014-02-19 2014-08-13 浙江大学 Preparation for reducing accumulation of cadmium in crops and application method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
王亮亮 等: ""生物表面活性剂对水溶肥料润湿性能的影响"", 《浙江农业科学》 *
王玉宏 等: "《山区特色种植业》", 30 September 2017, 河北科学技术出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111842478A (en) * 2020-07-28 2020-10-30 浙江大学 Method for repairing cadmium-polluted farmland on production side

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