CN110132020A - A comprehensive treatment device for electric furnace flue gas based on waste tire incineration - Google Patents
A comprehensive treatment device for electric furnace flue gas based on waste tire incineration Download PDFInfo
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- CN110132020A CN110132020A CN201910511658.1A CN201910511658A CN110132020A CN 110132020 A CN110132020 A CN 110132020A CN 201910511658 A CN201910511658 A CN 201910511658A CN 110132020 A CN110132020 A CN 110132020A
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
- F27D17/20—Arrangements for treatment or cleaning of waste gases
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
- F27D17/10—Arrangements for using waste heat
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
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Abstract
本发明属于工业窑炉烟气利用和处理领域,涉及一种基于废旧轮胎焚烧的电炉烟气综合处理装置,用于回收电炉第四孔烟气余热并处理烟气中的污染物,包括废钢预热装置、烟气旁路、余热锅炉、脱硫塔、粉剂喷射装置、布袋除尘器和引风机等;电炉烟气经电炉第四孔喷出后分为两路,一路进入废钢预热装置中加热废钢进行初步余热回收,另一路直接进入余热锅炉进行余热回收,最后进入脱硫塔,经除尘管道、粉剂喷射装置、布袋除尘器除尘后经引风机排至大气。本发明对目前加入的废旧轮胎的电炉进行综合处理,不仅可以回收烟气中的余热,而且能够对烟气中的二氧化硫和二噁英等有害物质进行联合脱除。
The invention belongs to the field of industrial kiln flue gas utilization and treatment, and relates to a comprehensive treatment device for electric furnace flue gas based on the incineration of waste tires, which is used to recover the waste heat of the flue gas in the fourth hole of the electric furnace and treat pollutants in the flue gas, including waste steel pretreatment. heating device, flue gas bypass, waste heat boiler, desulfurization tower, powder injection device, bag dust collector and induced draft fan, etc.; the electric furnace flue gas is sprayed through the fourth hole of the electric furnace and divided into two paths, and one path enters the scrap steel preheating device for heating Scrap steel undergoes preliminary waste heat recovery, and the other way directly enters the waste heat boiler for waste heat recovery, and finally enters the desulfurization tower, and is discharged to the atmosphere through the induced draft fan after dust removal through the dust removal pipeline, powder injection device, and bag filter. The present invention comprehensively treats the electric furnace of waste tires added at present, not only can recover the waste heat in the flue gas, but also can jointly remove harmful substances such as sulfur dioxide and dioxin in the flue gas.
Description
技术领域technical field
本发明属于工业窑炉烟气利用和处理领域,涉及一种基于废旧轮胎焚烧的电炉烟气综合处理装置。The invention belongs to the field of industrial kiln flue gas utilization and treatment, and relates to an electric furnace flue gas comprehensive treatment device based on waste tire incineration.
背景技术Background technique
电炉钢占据了世界钢铁总量的30%,过去20年来,电炉钢比例不断上升。电弧炉炼钢中,电能输入占总能源的60~65%,化学能占35~40%。化学能主要是吹氧产生碳氧反应的结果。电炉要可持续发展,减少煤炭消耗的方法是试用潜在的替代燃料,而橡胶轮胎和废弃的塑料制品就是煤炭的替代品,这些不仅仅是电炉炼钢优良的替代品,对这些替代品进行燃烧,也可以解决环保问题。Electric furnace steel accounts for 30% of the world's total steel, and the proportion of electric furnace steel has been increasing in the past 20 years. In electric arc furnace steelmaking, electrical energy input accounts for 60-65% of the total energy, and chemical energy accounts for 35-40%. The chemical energy is mainly the result of the reaction of oxygen blowing to produce carbon and oxygen. For the sustainable development of electric furnaces, the way to reduce coal consumption is to try potential alternative fuels, and rubber tires and discarded plastic products are substitutes for coal. These are not only good substitutes for electric furnace steelmaking, but burning these substitutes , can also solve environmental problems.
但是在用废旧轮胎等高分子聚合物替代碳粉的使用,会带来烟气中的硫化物、二噁英等污染物超标,因此如何控制烟气污染物的排放,并且有效的利用烟气中的余热成为基于废旧轮胎的电炉烟气处理技术的主要问题。However, the use of high molecular polymers such as waste tires instead of carbon powder will cause pollutants such as sulfides and dioxins in the flue gas to exceed the standard. Therefore, how to control the emission of flue gas pollutants and effectively use the flue gas Waste heat in waste tires has become a major problem in electric furnace flue gas treatment technology based on waste tires.
发明内容Contents of the invention
有鉴于此,本发明的目的在于提供一种基于废旧轮胎焚烧的电炉烟气综合处理装置,用于回收电炉烟气余热并出去烟气中含硫等污染物。In view of this, the object of the present invention is to provide a comprehensive treatment device for electric furnace flue gas based on waste tire incineration, which is used to recover the waste heat of electric furnace flue gas and remove sulfur and other pollutants in the flue gas.
为达到上述目的,本发明提供如下技术方案:To achieve the above object, the present invention provides the following technical solutions:
一种基于废旧轮胎焚烧的电炉烟气综合处理装置,包括电炉本体,所述电炉本体通过废钢预热装置连接至余热锅炉,并通过脱硫反应塔连接至除尘器,经烟囱排出。An electric furnace flue gas comprehensive treatment device based on waste tire incineration, comprising an electric furnace body connected to a waste heat boiler through a scrap steel preheating device, connected to a dust collector through a desulfurization reaction tower, and discharged through a chimney.
可选地,所述废钢预热装置通过电炉第四孔与电炉本体相连。Optionally, the scrap steel preheating device is connected with the electric furnace body through the fourth hole of the electric furnace.
可选地,所述电炉第四孔还连接有与所述废钢预热装置并联的烟气旁路。Optionally, the fourth hole of the electric furnace is also connected with a flue gas bypass connected in parallel with the scrap steel preheating device.
可选地,所述烟气旁路上设置有流量调节阀。Optionally, a flow regulating valve is arranged on the flue gas bypass.
可选地,所述除尘器包括顺次设置的粉剂喷射装置以及布袋除尘器。Optionally, the dust collector includes a powder injection device and a bag dust collector arranged in sequence.
可选地,还包括振动筛分装置,所述粉剂喷射装置的进口与振动筛分装置出口相连,粉剂通过压缩空气从振动筛分装置输送至粉剂喷射装置的进口。Optionally, a vibrating screening device is also included, the inlet of the powder injection device is connected to the outlet of the vibrating screening device, and the powder is transported from the vibrating screening device to the inlet of the powder injection device by compressed air.
可选地,所述的粉剂喷射装置为逆流喷射。Optionally, the powder injection device is a countercurrent injection.
可选地,所述旋转喷嘴进口粉末为碳酸钠或者碳酸氢钠。Optionally, the inlet powder of the rotary nozzle is sodium carbonate or sodium bicarbonate.
可选地,所述除尘器与烟囱之间还设有引风机。Optionally, an induced draft fan is also provided between the dust collector and the chimney.
可选地,所述余热锅炉朝向废钢预热装置的一侧为水冷膜式壁,远离废钢预热装置的一侧为对流换热面。Optionally, the side of the waste heat boiler facing the scrap steel preheating device is a water-cooled membrane wall, and the side away from the scrap steel preheating device is a convective heat exchange surface.
可选地,所述余热锅炉底部设有灰斗。Optionally, an ash hopper is provided at the bottom of the waste heat boiler.
可选地,所述对流换热面为立式布置,悬挂在余热锅炉顶部。Optionally, the convective heat exchange surface is vertically arranged and suspended on the top of the waste heat boiler.
可选地,所述脱硫塔包括设置在脱硫塔朝向余热锅炉一侧的烟气均流装置、设置在脱硫塔上的旋转喷嘴及文丘里喷嘴。Optionally, the desulfurization tower includes a flue gas equalization device disposed on the side of the desulfurization tower facing the waste heat boiler, a rotary nozzle and a Venturi nozzle disposed on the desulfurization tower.
可选地,所述文丘里喷嘴数量是8个,环形阵列布置。Optionally, the number of Venturi nozzles is 8, arranged in an annular array.
可选地,所述废钢预热装置内设有燃烧喷嘴。Optionally, a combustion nozzle is provided in the scrap steel preheating device.
本发明的有益效果在于:The beneficial effects of the present invention are:
本发明通过设置废钢预热装置和烟气旁路,可以调节废钢预热温度,结合余热锅炉可以进一步深度回收烟气余热,提高了烟气余热利用率。本发明也可以通过振动筛分装置与粉剂喷射装置的配合,进行干式脱硫,去除烟气中的二噁英等污染物,保证烟气排放符合标准。The present invention can adjust the preheating temperature of the scrap steel by setting the scrap steel preheating device and the flue gas bypass, combined with the waste heat boiler can further deeply recover the waste heat of the flue gas, and improves the utilization rate of the waste heat of the flue gas. The present invention can also carry out dry desulfurization through the cooperation of the vibrating screening device and the powder spraying device, and remove pollutants such as dioxin in the flue gas, so as to ensure that the flue gas emission meets the standard.
本发明的其他优点、目标和特征在某种程度上将在随后的说明书中进行阐述,并且在某种程度上,基于对下文的考察研究对本领域技术人员而言将是显而易见的,或者可以从本发明的实践中得到教导。本发明的目标和其他优点可以通过下面的说明书来实现和获得。Other advantages, objects and features of the present invention will be set forth in the following description to some extent, and to some extent, will be obvious to those skilled in the art based on the investigation and research below, or can be obtained from It is taught in the practice of the present invention. The objects and other advantages of the invention may be realized and attained by the following specification.
附图说明Description of drawings
为了使本发明的目的、技术方案和优点更加清楚,下面将结合附图对本发明作优选的详细描述,其中:In order to make the purpose of the present invention, technical solutions and advantages clearer, the present invention will be described in detail below in conjunction with the accompanying drawings, wherein:
图1为本发明的整体结构示意图。Figure 1 is a schematic diagram of the overall structure of the present invention.
具体实施方式Detailed ways
以下通过特定的具体实例说明本发明的实施方式,本领域技术人员可由本说明书所揭露的内容轻易地了解本发明的其他优点与功效。本发明还可以通过另外不同的具体实施方式加以实施或应用,本说明书中的各项细节也可以基于不同观点与应用,在没有背离本发明的精神下进行各种修饰或改变。需要说明的是,以下实施例中所提供的图示仅以示意方式说明本发明的基本构想,在不冲突的情况下,以下实施例及实施例中的特征可以相互组合。Embodiments of the present invention are described below through specific examples, and those skilled in the art can easily understand other advantages and effects of the present invention from the content disclosed in this specification. The present invention can also be implemented or applied through other different specific implementation modes, and various modifications or changes can be made to the details in this specification based on different viewpoints and applications without departing from the spirit of the present invention. It should be noted that the diagrams provided in the following embodiments are only schematically illustrating the basic concept of the present invention, and the following embodiments and the features in the embodiments can be combined with each other in the case of no conflict.
其中,附图仅用于示例性说明,表示的仅是示意图,而非实物图,不能理解为对本发明的限制;为了更好地说明本发明的实施例,附图某些部件会有省略、放大或缩小,并不代表实际产品的尺寸;对本领域技术人员来说,附图中某些公知结构及其说明可能省略是可以理解的。Wherein, the accompanying drawings are for illustrative purposes only, and represent only schematic diagrams, rather than physical drawings, and should not be construed as limiting the present invention; in order to better illustrate the embodiments of the present invention, some parts of the accompanying drawings may be omitted, Enlargement or reduction does not represent the size of the actual product; for those skilled in the art, it is understandable that certain known structures and their descriptions in the drawings may be omitted.
本发明实施例的附图中相同或相似的标号对应相同或相似的部件;在本发明的描述中,需要理解的是,若有术语“上”、“下”、“左”、“右”、“前”、“后”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此附图中描述位置关系的用语仅用于示例性说明,不能理解为对本发明的限制,对于本领域的普通技术人员而言,可以根据具体情况理解上述术语的具体含义。In the drawings of the embodiments of the present invention, the same or similar symbols correspond to the same or similar components; , "front", "rear" and other indicated orientations or positional relationships are based on the orientations or positional relationships shown in the drawings, which are only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying that the referred devices or elements must It has a specific orientation, is constructed and operated in a specific orientation, so the terms describing the positional relationship in the drawings are for illustrative purposes only, and should not be construed as limiting the present invention. For those of ordinary skill in the art, the understanding of the specific meaning of the above terms.
请参阅图1,附图中的元件标号分别表示:电炉本体1、电炉第四孔2、废钢预热装置3、烟气旁路4、余热锅炉5、脱硫反应塔6、粉剂喷射装置7、布袋除尘器8、引风机9、烟囱10、振动筛分装置11、流量调节阀12、燃烧喷嘴13、水冷膜式壁14、对流换热面15、烟气均流装置16、旋转喷嘴17、文丘里喷嘴18。Please refer to Figure 1, the component numbers in the accompanying drawings represent: electric furnace body 1, electric furnace fourth hole 2, scrap steel preheating device 3, flue gas bypass 4, waste heat boiler 5, desulfurization reaction tower 6, powder injection device 7, Bag filter 8, induced draft fan 9, chimney 10, vibrating screening device 11, flow regulating valve 12, combustion nozzle 13, water-cooled membrane wall 14, convective heat exchange surface 15, flue gas equalization device 16, rotating nozzle 17, Venturi nozzle 18.
本发明涉及一种基于废旧轮胎焚烧的电炉烟气综合处理装置,包括电炉本体1,所述电炉本体1通过废钢预热装置3连接至余热锅炉5,并通过脱硫反应塔6连接至除尘器,经烟囱10排出。The present invention relates to an electric furnace flue gas comprehensive treatment device based on waste tire incineration, comprising an electric furnace body 1, the electric furnace body 1 is connected to a waste heat boiler 5 through a scrap steel preheating device 3, and is connected to a dust collector through a desulfurization reaction tower 6, It is discharged through the chimney 10.
可选地,所述废钢预热装置3通过电炉第四孔2与电炉本体1相连;所述电炉第四孔2还连接有与所述废钢预热装置3并联的烟气旁路4;所述烟气旁路4上设置有流量调节阀12。Optionally, the scrap steel preheating device 3 is connected to the electric furnace body 1 through the fourth hole 2 of the electric furnace; the fourth hole 2 of the electric furnace is also connected with a flue gas bypass 4 connected in parallel with the scrap steel preheating device 3; The flue gas bypass 4 is provided with a flow regulating valve 12 .
具体地,所述除尘器包括顺次设置的粉剂喷射装置7、布袋除尘器8、以及振动筛分装置11,所述粉剂喷射装置7的进口与振动筛分装置11出口相连,粉剂通过压缩空气从振动筛分装置11输送至粉剂喷射装置7的进口;所述的粉剂喷射装置7为逆流喷射;所述旋转喷嘴17进口粉末为碳酸钠或者碳酸氢钠;所述除尘器与烟囱10之间还设有引风机9。Specifically, the dust collector includes a powder injection device 7, a bag filter 8, and a vibratory screening device 11 arranged in sequence. The inlet of the powder injection device 7 is transported from the vibratory screening device 11; the powder injection device 7 is a countercurrent injection; the powder at the inlet of the rotary nozzle 17 is sodium carbonate or sodium bicarbonate; between the dust collector and the chimney 10 Also be provided with induced draft fan 9.
在本实施例中,所述余热锅炉5朝向废钢预热装置3的一侧为水冷膜式壁14,远离废钢预热装置3的一侧为对流换热面15;所述余热锅炉5底部设有灰斗;所述对流换热面15为立式布置,悬挂在余热锅炉5顶部。In this embodiment, the side of the waste heat boiler 5 facing the scrap steel preheating device 3 is a water-cooled membrane wall 14, and the side away from the scrap steel preheating device 3 is a convective heat exchange surface 15; There is an ash hopper; the convective heat exchange surface 15 is vertically arranged and suspended on the top of the waste heat boiler 5 .
可选地,所述脱硫塔包括设置在脱硫塔朝向余热锅炉5一侧的烟气均流装置16、设置在脱硫塔上的旋转喷嘴17及文丘里喷嘴18;所述文丘里喷嘴18数量是8个,环形阵列布置;所述废钢预热装置3内设有燃烧喷嘴13。Optionally, the desulfurization tower includes a flue gas equalizing device 16 arranged on the side of the desulfurization tower facing the waste heat boiler 5, a rotating nozzle 17 and a Venturi nozzle 18 arranged on the desulfurization tower; the number of the Venturi nozzles 18 is 8, arranged in an annular array; the scrap steel preheating device 3 is provided with a combustion nozzle 13 .
在具体的操作过程中,电炉本体1冶炼的烟气经电炉第四孔2进入废钢预热装置3,此时烟气温度最高可以达到1800℃,通过加热废钢后温度降至1000℃;从废钢预热装置3出来的烟气,进入到余热锅炉5中,余热锅炉5前段为辐射型宽流道换热面(水冷膜式壁14),在这里将烟气中的未燃尽的CO燃尽,并沉降大颗粒的粉尘,然后进去余热锅炉5的对流换热面15进一步换热冷却至150℃。余热锅炉5底部设有灰斗,在余热锅炉5沉降和积灰的粉尘被收集在灰斗中。In the specific operation process, the flue gas smelted by the electric furnace body 1 enters the scrap steel preheating device 3 through the fourth hole 2 of the electric furnace. The flue gas from the preheating device 3 enters the waste heat boiler 5, and the front section of the waste heat boiler 5 is a radiant wide channel heat exchange surface (water-cooled membrane wall 14), where the unburned CO in the flue gas is burned and settle large particles of dust, and then enter the convective heat exchange surface 15 of the waste heat boiler 5 for further heat exchange and cooling to 150°C. There is an ash hopper at the bottom of the waste heat boiler 5, and the dust settled and accumulated in the waste heat boiler 5 is collected in the ash hopper.
需要说明的是,废钢预热装置3底部设有燃烧喷嘴13,在电炉非冶炼期间烟气温度不够时候,通过天然气补燃强化预热废钢,提高进入电炉中的废钢达到指定温度,同时控制废钢预热装置3出口烟温不低于800℃,减少低温下二噁英的生成,保证余热锅炉5稳定运行。It should be noted that a combustion nozzle 13 is provided at the bottom of the scrap steel preheating device 3. When the flue gas temperature is not enough during the non-smelting period of the electric furnace, the scrap steel is preheated through natural gas supplementary combustion to increase the scrap steel entering the electric furnace to reach the specified temperature, and at the same time control the temperature of the scrap steel The temperature of the flue gas at the outlet of the preheating device 3 is not lower than 800°C, which reduces the formation of dioxins at low temperatures and ensures the stable operation of the waste heat boiler 5 .
另一方面,在电炉第四孔2连接废钢预热装置3的管道上设有烟气旁路4,其上设有烟气流量调节阀12,通过控制烟气流量调节阀12分配废钢预热装置3中的烟气量。在冶炼期间,电炉第四孔2的烟气温度高,提高废钢预热装置3的烟气流量,提高预热效果;在非冶炼期,电炉第四孔2的烟气温度低,调小废钢预热装置3烟气流量,通过补燃天然气强化预热。On the other hand, a flue gas bypass 4 is provided on the pipe connecting the fourth hole 2 of the electric furnace to the scrap steel preheating device 3, and a flue gas flow regulating valve 12 is arranged on it, and the waste steel preheating is distributed by controlling the flue gas flow regulating valve 12. Flue gas volume in unit 3. During the smelting period, the flue gas temperature of the fourth hole 2 of the electric furnace is high, so the flue gas flow rate of the scrap steel preheating device 3 is increased to improve the preheating effect; during the non-smelting period, the flue gas temperature of the fourth hole 2 of the electric furnace is low, and the scrap steel is reduced The flue gas flow rate of the preheating device 3 is enhanced by supplementary combustion of natural gas for preheating.
冷却后的电炉烟气进入脱硫塔中,脱硫塔入口处设有烟气均流装置16,脱硫塔下部设有旋转喷嘴17,烟气与旋转喷嘴17喷出的碳酸氢钠粉末混合后,进入脱硫塔中部的文丘里喷嘴18加速形成紊流状态,在脱硫塔上部与脱硫剂充分反应,然后从脱硫塔顶部出口出来进入布袋除尘器8中。在布袋除尘器8进口管道上设有粉剂喷射装置7,从粉剂喷射装置7出来的活性炭逆向喷射到烟气中,含有活性炭的烟气进入布袋除尘器8中收集后负载在布袋覆膜滤料上,烟气中的二噁英被活性炭吸附脱除后进入烟囱10达标排放。The cooled electric furnace flue gas enters the desulfurization tower. A flue gas equalization device 16 is installed at the entrance of the desulfurization tower. A rotating nozzle 17 is installed at the lower part of the desulfurization tower. After the flue gas is mixed with the sodium bicarbonate powder ejected from the rotating nozzle 17, it enters the The Venturi nozzle 18 in the middle of the desulfurization tower accelerates to form a turbulent state, fully reacts with the desulfurization agent in the upper part of the desulfurization tower, and then exits from the top of the desulfurization tower into the bag filter 8. There is a powder injection device 7 on the inlet pipe of the bag filter 8, and the activated carbon from the powder injection device 7 is sprayed into the flue gas in reverse, and the flue gas containing activated carbon enters the bag filter 8 and is collected and loaded on the bag-coated filter material Above, the dioxins in the flue gas are adsorbed and removed by the activated carbon and then enter the chimney 10 to meet the emission standards.
在布袋除尘器8底部灰斗下设有振动筛分装置11,收集的活性炭和脱硫副产物作为循环物料送到布袋除尘器8进口的粉剂喷射装置7中,其他电炉灰等进入残余物料仓外运。There is a vibrating screening device 11 under the ash hopper at the bottom of the bag filter 8. The collected activated carbon and desulfurization by-products are sent to the powder injection device 7 at the inlet of the bag filter 8 as circulating materials, and other electric furnace ash enters the residual material bin. transport.
最后说明的是,以上实施例仅用以说明本发明的技术方案而非限制,尽管参照较佳实施例对本发明进行了详细说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本技术方案的宗旨和范围,其均应涵盖在本发明的权利要求范围当中。Finally, it is noted that the above embodiments are only used to illustrate the technical solutions of the present invention without limitation. Although the present invention has been described in detail with reference to the preferred embodiments, those of ordinary skill in the art should understand that the technical solutions of the present invention can be carried out Modifications or equivalent replacements, without departing from the spirit and scope of the technical solution, should be included in the scope of the claims of the present invention.
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