CN110122954A - A kind of antistatic knitted gloves and preparation method thereof - Google Patents
A kind of antistatic knitted gloves and preparation method thereof Download PDFInfo
- Publication number
- CN110122954A CN110122954A CN201910399672.7A CN201910399672A CN110122954A CN 110122954 A CN110122954 A CN 110122954A CN 201910399672 A CN201910399672 A CN 201910399672A CN 110122954 A CN110122954 A CN 110122954A
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- CN
- China
- Prior art keywords
- antistatic
- composite fibre
- electrically conductive
- knitting
- knitted
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Classifications
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0006—Gloves made of several layers of material
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
- A41D19/01529—Protective gloves with thermal or fire protection
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/08—Impregnating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/18—Handling of layers or the laminate
- B32B38/1808—Handling of layers or the laminate characterised by the laying up of the layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/026—Knitted fabric
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/06—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by a fibrous or filamentary layer mechanically connected, e.g. by needling to another layer, e.g. of fibres, of paper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/16—Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/18—Other fabrics or articles characterised primarily by the use of particular thread materials elastic threads
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/22—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration
- D04B1/24—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel
- D04B1/28—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel gloves
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/03—3 layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/20—All layers being fibrous or filamentary
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
- B32B2260/023—Two or more layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0261—Polyamide fibres
- B32B2262/0269—Aromatic polyamide fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0276—Polyester fibres
- B32B2262/0284—Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/06—Vegetal fibres
- B32B2262/062—Cellulose fibres, e.g. cotton
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/106—Carbon fibres, e.g. graphite fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/14—Mixture of at least two fibres made of different materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/202—Conductive
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/21—Anti-static
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/51—Elastic
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
- B32B2437/02—Gloves, shoes
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
- Gloves (AREA)
Abstract
The invention discloses a kind of antistatic knitted gloves, including glove bulk, glove bulk includes being knitted liner, the conductive shield for being set to knitting liner outer layer, the electrostatic protection outer layer being set on the outside of conductive shield;Knitting liner is that cotton-polyester blend yarn is knitted, and cotton-polyester blend yarn includes long-staple cotton fiber, PTT elasticity terylene, and conductive shield is electrically conductive composite fibre layer, and electrically conductive composite fibre includes that mass ratio is 1:(10~20) graphene, stoste aramid fiber.Antistatic knitted gloves of the invention has comfortable soft, ventilative nice and cool, the advantage that antistatic property is lasting, efficient.
Description
Technical field
The present invention relates to gloves technical field, in particular to a kind of antistatic knitted gloves and preparation method thereof.
Background technique
Gloves are that hand is warming or articles for labour protection, are also had ornamental.Gloves have become cold district heat preservation at present
The object of indispensability, or medical fungi-proofing, industrial protective products.Gloves are divided into sewing, knitting, impregnation etc. according to production method.Gloves
It is sewed with the cutting of various leathers, rubber, knitted fabric or woven fabric.The knitted gloves pure spinning of various textile fabrics or mixed yarn
Line weaves on glove knitting machine, processes through sewing, such as in clamping, rib collar, seam finger tip and fourchette, using napping or fulling milling, heat
Stabilised finish forms product.The group of knitted gloves is woven with plain, rib-loop, tuck, leno etc., and fancy has plain color and yarn-dyed jacquard
Deng.Labour protection is more thick and solid with gloves requirement, and some is handled by surface plastic coating, to improve wear-resisting, anti-skidding, waterproof performance.
Dress glove requires beauty, mostly by artistic processing such as embroidery, nail pearls.
Existing notification number is the patent of invention of CN102657395B, discloses a kind of anti-cutting knitting hand of no glass fibre
Set, which is knitted using three one threads, including the first composite yarn, by one or more high-wearing feature polyamide yarn
It is coated in composite core and is prepared, composite core is by by stainless steel yarn and one or more high abrasion or high tenacity polyamide
Yarn, which is directly knitted, to be made;Second polyamide elastane yarn and third para-aramid yams are added by bilateral knitting
Yarn mode is weaved, so that the first and second yarns are located on the first side of knitted fabric and para-aramid yams are located at
In second side of knitted fabric.
Although the gloves in prior art are weaved by a variety of anti-cutting fibers, thus keeping gloves to wear spirit
While active, anti-cutting effect is played, but uses gloves made of the weaving of a variety of synthetic yarns in actual use process
In, it is easy to produce electrostatic phenomenon, will affect work when serious, or even cause harm to the human body, it is therefore desirable to knitted gloves
Static electricity resistance can be carried out improvement.
Summary of the invention
The purpose of the present invention is to provide a kind of antistatic knitted gloves and preparation method thereof, manufactured gloves have softness
Comfortably, good permeability, the advantage that antistatic property is lasting, efficient.
To achieve the above object, the present invention provides the following technical scheme that a kind of antistatic knitted gloves, including gloves sheet
Body, the glove bulk include being knitted liner, the conductive shield for being set to knitting liner outer layer, being set to outside conductive shield
The electrostatic protection outer layer of side;
The knitting liner is that cotton-polyester blend yarn is knitted, and the conductive shield is electrically conductive composite fibre layer, described quiet
Electricity protection outer layer is antistatic finish tissue layer.
By using above-mentioned technical proposal, the sucting wet air permeability of cotton is good, and elasticity is good for terylene, intensity is high, and needle can be improved
Liner is knitted to the compactness of hand, knitting liner is made by cotton-polyester blend yarn, the moisture absorption that gloves patch skin layers can be improved is saturating
Gas and soft comfortable degree;Conductive shield is made using electrically conductive composite fibre, can use the electric conductivity of conductive fiber itself
Can, play the role of quickly guiding the charge on gloves, reduces charge buildup and form static discharge phenomenon;Using antistatic whole
Electrostatic protection outer layer made of reason tissue layer can reduce the phenomenon that fiber surface generation, stored charge, to improve gloves table
The antistatic property in face.
The present invention is further arranged to, and the cotton-polyester blend yarn includes long-staple cotton fiber, PTT elasticity terylene, the length
The mass ratio of suede cotton fiber and PTT elasticity terylene is 2:(1~1.5).
By using above-mentioned technical proposal, the fiber quality of long-staple cotton fiber is high, and fiber sucting wet air permeability is good, and soft easypro
Appropriateness is higher than common cotton fiber, and PTT elasticity terylene soft highly-elastic, fiber drapability are good, and it is restorative good to extend, and can be improved needle
Knit the elasticity and adaptability of liner.
The present invention is further arranged to, the electrically conductive composite fibre include mass ratio be 1:(10~20) graphene, original
Liquid aramid fiber.
By using above-mentioned technical proposal, graphene is a kind of green safe new material, with it is excellent resist it is quiet
Electrical property can significantly improve fiber and fabric antistatic property;On the other hand, graphene conductive is high, with general carbon fiber knot
It closes, the electric conductivity of fiber can be improved, and then increase the permanent antistatic performance of fiber.
Aramid fiber is a kind of novel synthetic fibers, the unique molecular structure having, without chemical treatment
Can effective anti-flaming thermal-insulation, and anti-flaming thermal-insulation consistency of performance;Aramid fiber also has superhigh intensity, high-modulus, acid-fast alkali-proof, again
The excellent performances such as amount is light, insulate, is anti-aging;Stoste aramid fiber colour fastness to rubbing can achieve 4~5 grades, can also significantly mention
The dry and wet friction color fastness of high fabric.
The present invention is further arranged to, and the stoste aramid fiber is meta-aramid.
By using above-mentioned technical proposal, the macromolecular of meta-aramid is serrated, and is a kind of flexible macromolecule, and fracture is strong
Degree is higher than ordinary polyester, cotton etc., and elongation is larger, and flexibility is good, good spinnability, meanwhile, the limit oxygen index of meta-aramid is big
In 28, there is self-gravitation, be a kind of permanent fire retardant fiber;On the other hand, meta-aramid has excellent elongation after fracture, resistance to
Fire, oxidative resistance are good, are used continuously 1000h under 200~300 DEG C of high temperature, intensity be still able to maintain former intensity 50%~
65%.Therefore, using meta-aramid as electrically conductive composite fibre basic material, the intensity, wear-resisting of gloves can preferably be improved
Property and flame retardant property.
The present invention is further arranged to, and the preparation method of the electrically conductive composite fibre includes the following steps:
S1, pretreatment: being placed in vacuum drying oven for graphene and be dried, drying temperature be 70~95 DEG C, drying time be 6~
12h;
It is S2, dry-mixed: graphene, stoste aramid fiber are put into high-speed mixer, adjust 350~400rpm of revolving speed, it is stirred 8~
10min, then 800~900rpm of revolving speed is adjusted, 3~5min is continuesd to mix, the homogeneous mixture of graphene Yu stoste aramid fiber is obtained;
S3, granulation is blended: graphene with the homogeneous mixture of stoste aramid fiber investment twin-screw blender is carried out that granulation is blended, is melted
Melting blending temperature is 550~700 DEG C, and revolving speed is 90~150rpm, and the melt blending time is 25~30min, and melt blended material squeezes
It cools down out, obtains electrically conductive composite fibre master batch through pelletizing;
S4, melt spinning: using melt spinning machine to electrically conductive composite fibre master batch melt spinning, spinning temperature is 210~220
DEG C, winding speed is set as 1400~1600m/min, obtains electrically conductive composite fibre;
S5, drafting forming: carrying out drawing-off to electrically conductive composite fibre, and drawing temperature is 90~120 DEG C, and drafting multiple is 4~6 times,
Obtain electrically conductive composite fibre.
By using above-mentioned technical proposal, graphene and stoste aramid fiber are pre-mixed, to be formed more uniform
Graphene, stoste aramid fiber mixture, make graphene and the better dispersion mixing of stoste aramid fiber.Conduction is formed using melt blending
Composite fibre master batch, to make graphene and stoste aramid fiber form the homogeneous mixture of depth integration, finally by melt spinning
Form electrically conductive composite fibre, to assigning the characteristic depth of graphene to stoste aramid fiber, and then formed electric conductivity persistently,
Efficient electrically conductive composite fibre.
The present invention is further arranged to, the antistatic finish tissue layer by mass ratio be 1:1:1 electrically conductive composite fibre,
Copper ammonia fiber and cotton the yarn of blended formation be knitted.
By using above-mentioned technical proposal, the fibre section of copper ammonia fiber is rounded, and no skin-core structure, fiber can bear height
Degree stretches, and monofilament obtained is thinner, and the feel and pliability of fabric can be improved;On the other hand, the good hygroscopicity of copper ammonia fiber,
In blended addition fabric, the sucting wet air permeability of fabric can be further improved, the wear comfort of gloves can be turned up.
The present invention is further arranged to, a kind of preparation method of antistatic knitted gloves, comprising the following steps:
S1, knitting liner preparation: cotton-polyester blend yarn is weaved on knitting machine and forms gloves knitting liner;
S2, conductive shield preparation: electrically conductive composite fibre is spinned into line, then is weaved to be formed by knitting machine and be fitted with knitting liner
The conductive shield matched;
S3, electrostatic protection outer layer preparation: by electrically conductive composite fibre, copper ammonia fiber and cotton institute blended formation yarn be knitted to be formed and
The electrostatic protection outer layer of conductive shield adaptation;
S4, antistatic finish: the antistatic agent solution that configuration quality percentage concentration is 6%~13%, by the electrostatic protection of S3 step
Outer layer is impregnated in antistatic agent solution, and bath raio is (1:3)~(1:5), and dip time is 35~50min, after dipping 75~
It is dried at 85 DEG C, drying time is 30~40min, and antistatic finish tissue layer is made;
S5, set knit suture: knitting liner being sheathed on fingerprint, conductive shield is covered on the outside of knitting liner, and will be conductive
Protective layer and knitting liner suture connect, and after the same method again connect antistatic finish tissue layer and conductive shield suture
It connects, to obtain complete gloves.
By using above-mentioned technical proposal, it is knitted liner patch skin softness, good permeability, gloves can be improved in conductive shield
Electric conductivity, the antistatic property of gloves can be improved in antistatic finish tissue layer, improves whole anti-of gloves to reach
Antistatic property.
The present invention is further arranged to, and antistatic agent is organosilicon quaternary ammonium salt antistatic agent in the S4 step.
By using above-mentioned technical proposal, organosilicon quaternary ammonium salt is the good antistatic agent of a kind of comprehensive performance, and arrangement is knitted
Such antistatic agent does not need high temperature baking when object, just can produce lasting antistatic effect after general drying, knitting after arrangement
Object not only has excellent antistatic property, but also is also equipped with good moisture absorption absorption of perspiration, flexibility, resilience, static electricity resistance,
And pollution resistance.
In conclusion the invention has the following advantages:
1. the electrically conductive composite fibre in the present invention is made by the way that graphene, stoste aramid fiber to be blended in twin-screw blender
Grain forms electrically conductive composite fibre master batch, then electrically conductive composite fibre master batch is answered by the conduction that melt spinning forms containing graphene
Condensating fiber makes graphene obtain depth dispersion in molecular level with fiber and is combined, so that the antistatic for obtaining almost permanent property is special
Property;
2. using stoste aramid fiber as the matrix fiber of electrically conductive composite fibre in the present invention, the intensity, resistance to of gloves is on the one hand improved
Grit, to extend the service life of gloves;On the other hand, it using the flame retardant property of the distinctive high-efficient and lasting of aramid fiber, assigns
Gloves are with excellent anti-flammability;
It is high using copper ammonia fiber sucting wet air permeability, drapability is good 3. add copper ammonia fiber in the gloves in the present invention, and have compared with
The characteristics of antistatic property got well, achieve the effect that further increase gloves snugness of fit and antistatic property;
4. the gloves in the present invention carry out antistatic finish by organosilicon quaternary ammonium salt antistatic agent finishing fluid, so that antistatic agent
It adsorbs and infiltrates into the fiber of antistatic finish tissue layer, to achieve the effect that further increase gloves antistatic property.
Detailed description of the invention
Fig. 1 is a kind of overall structure diagram of antistatic knitted gloves in Examples 1 to 5;
Fig. 2 is part A partial enlargement diagram in Fig. 1.
In figure, 1, glove bulk;11, it is knitted liner;12, conductive shield;13, electrostatic protection outer layer.
Specific embodiment
Invention is further described in detail with reference to embodiments.
The preparation example 1-3 of electrically conductive composite fibre
Preparation example 1: weighing graphene, the stoste aramid fiber that mass ratio is 1:10, graphene be placed in vacuum drying oven and is dried,
Drying temperature is 70 DEG C, drying time 6h;Graphene, stoste aramid fiber are put into high-speed mixer, adjust revolving speed 3500rpm,
It is stirred 8min, then adjusts revolving speed 800rpm, continuess to mix 3min, obtains the homogeneous mixture of graphene Yu stoste aramid fiber;
Graphene is carried out granulation is blended with the homogeneous mixture of stoste aramid fiber investment twin-screw blender, melt blending temperature is 550
DEG C, revolving speed 90rpm, the melt blending time is 25min, and melt blended material squeezes out cooling, obtains electrically conductive composite fibre through pelletizing
Master batch;Using melt spinning machine to electrically conductive composite fibre master batch melt spinning, spinning temperature is 210 DEG C, and winding speed is set as
1400m/min obtains electrically conductive composite fibre;Drawing-off is carried out to electrically conductive composite fibre, drawing temperature is 90 DEG C, drafting multiple 4
Times, obtain electrically conductive composite fibre.
Preparation example 2: weighing graphene, the stoste aramid fiber that mass ratio is 1:15, and graphene is placed in vacuum drying oven and is carried out
Dry, drying temperature is 80 DEG C, drying time 8h;Graphene, stoste aramid fiber are put into high-speed mixer, adjust revolving speed
370rpm is stirred 9min, then adjusts revolving speed 850rpm, continuess to mix 4min, obtains the uniform of graphene and stoste aramid fiber
Mixture;Graphene with the homogeneous mixture of stoste aramid fiber investment twin-screw blender is carried out that granulation, melt blending temperature is blended
Degree is 600 DEG C, revolving speed 120rpm, and the melt blending time is 27min, and melt blended material squeezes out cooling, obtains conduction through pelletizing
Composite fibre master batch;Using melt spinning machine to electrically conductive composite fibre master batch melt spinning, spinning temperature is 215 DEG C, winding speed
Degree is set as 1500m/min, obtains electrically conductive composite fibre;Drawing-off is carried out to electrically conductive composite fibre, drawing temperature is 110 DEG C, is led
Stretching multiple is 5 times, obtains electrically conductive composite fibre.
Preparation example 3: weighing graphene, the stoste aramid fiber that mass ratio is 1:20, and graphene is placed in vacuum drying oven and is carried out
Dry, drying temperature is 95 DEG C, drying time 12h;Graphene, stoste aramid fiber are put into high-speed mixer, adjust revolving speed
400rpm is stirred 10min, then adjusts revolving speed 900rpm, continuess to mix 5min, obtains the uniform of graphene and stoste aramid fiber
Mixture;Graphene with the homogeneous mixture of stoste aramid fiber investment twin-screw blender is carried out that granulation, melt blending temperature is blended
Degree is 700 DEG C, revolving speed 150rpm, and the melt blending time is 30min, and melt blended material squeezes out cooling, obtains conduction through pelletizing
Composite fibre master batch;Using melt spinning machine to electrically conductive composite fibre master batch melt spinning, spinning temperature is 220 DEG C, winding speed
Degree is set as 1600m/min, obtains electrically conductive composite fibre;Drawing-off is carried out to electrically conductive composite fibre, drawing temperature is 90~120
DEG C, drafting multiple is 4~6 times, obtains electrically conductive composite fibre.
Embodiment
Embodiment 1:
A kind of preparation method of antistatic knitted gloves, comprising the following steps:
Prepared by S1, knitting liner 11: selecting cotton-polyester blend made of long-staple cotton fiber and PTT elasticity terylene of the mass ratio for 2:1
Cotton-polyester blend yarn is weaved on knitting machine and forms gloves knitting liner 11 by yarn;
Prepared by S2, conductive shield 12: electrically conductive composite fibre being spinned into line, then weaves to be formed and knitting liner by knitting machine
The conductive shield 12 of 11 adaptations;
It is prepared by S3, electrostatic protection outer layer 13: by electrically conductive composite fibre, copper ammonia fiber and cotton the yarn of blended formation be knitted and to be formed
The electrostatic protection outer layer 13 being adapted to conductive shield 12;
S4, antistatic finish: the antistatic agent solution that configuration quality percentage concentration is 6%, by the electrostatic protection outer layer 13 of S3 step
It is impregnated in antistatic agent solution, bath raio 1:3, dip time 35min, is dried at 75 DEG C after dipping, when drying
Between be 30min, be made antistatic finish tissue layer;
S5, set knit suture: knitting liner 11 be sheathed on fingerprint, by 12 sets of conductive shield in 11 outside of knitting liner, and
Conductive shield 12 and the knitting suture of liner 11 are connected, after the same method again prevent antistatic finish tissue layer with conduction
The suture connection of sheath 12, to obtain complete gloves.
Embodiment 2:
A kind of preparation method of antistatic knitted gloves, comprising the following steps:
Prepared by S1, knitting liner 11: selecting cotton made of long-staple cotton fiber and PTT elasticity terylene of the mass ratio for 2:1.1 to wash mixed
Cotton-polyester blend yarn is weaved on knitting machine and forms gloves knitting liner 11 by yarn;
Prepared by S2, conductive shield 12: electrically conductive composite fibre being spinned into line, then weaves to be formed and knitting liner by knitting machine
The conductive shield 12 of 11 adaptations;
S3, it is antistatic protection outer layer 13 prepare: by electrically conductive composite fibre, copper ammonia fiber and cotton institute blended formation yarn knitting shape
At the antistatic protection outer layer 13 being adapted to conductive shield 12;
S4, antistatic finish: the antistatic agent solution that configuration quality percentage concentration is 8%, by the antistatic protection outer layer of S3 step
13 are impregnated in antistatic agent solution, bath raio 1:3.5, dip time 37min, are dried at 77 DEG C after dipping, dry
The dry time is 32min, and antistatic finish tissue layer is made;
S5, set knit suture: knitting liner 11 be sheathed on fingerprint, by 12 sets of conductive shield in 11 outside of knitting liner, and
Conductive shield 12 and the knitting suture of liner 11 are connected, after the same method again prevent antistatic finish tissue layer with conduction
The suture connection of sheath 12, to obtain complete gloves.
Embodiment 3:
A kind of preparation method of antistatic knitted gloves, comprising the following steps:
Prepared by S1, knitting liner 11: selecting cotton made of long-staple cotton fiber and PTT elasticity terylene of the mass ratio for 2:1.2 to wash mixed
Cotton-polyester blend yarn is weaved on knitting machine and forms gloves knitting liner 11 by yarn;
Prepared by S2, conductive shield 12: electrically conductive composite fibre being spinned into line, then weaves to be formed and knitting liner by knitting machine
The conductive shield 12 of 11 adaptations;
S3, it is antistatic protection outer layer 13 prepare: by electrically conductive composite fibre, copper ammonia fiber and cotton institute blended formation yarn knitting shape
At the antistatic protection outer layer 13 being adapted to conductive shield 12;
S4, antistatic finish: the antistatic agent solution that configuration quality percentage concentration is 10%, it will be outside the antistatic protection of S3 step
Layer 13 is impregnated in antistatic agent solution, bath raio 1:4, dip time 40min, is dried at 80 DEG C after dipping, is dried
The dry time is 34min, and antistatic finish tissue layer is made;
S5, set knit suture: knitting liner 11 be sheathed on fingerprint, by 12 sets of conductive shield in 11 outside of knitting liner, and
Conductive shield 12 and the knitting suture of liner 11 are connected, after the same method again prevent antistatic finish tissue layer with conduction
The suture connection of sheath 12, to obtain complete gloves.
Embodiment 4:
A kind of preparation method of antistatic knitted gloves, comprising the following steps:
Prepared by S1, knitting liner 11: selecting cotton made of long-staple cotton fiber and PTT elasticity terylene of the mass ratio for 2:1.3 to wash mixed
Cotton-polyester blend yarn is weaved on knitting machine and forms gloves knitting liner 11 by yarn;
Prepared by S2, conductive shield 12: electrically conductive composite fibre being spinned into line, then weaves to be formed and knitting liner by knitting machine
The conductive shield 12 of 11 adaptations;
It is prepared by S3, electrostatic protection outer layer 13: by electrically conductive composite fibre, copper ammonia fiber and cotton the yarn of blended formation be knitted and to be formed
The electrostatic protection outer layer 13 being adapted to conductive shield 12;
S4, antistatic finish: the antistatic agent solution that configuration quality percentage concentration is 12%, by the electrostatic protection outer layer of S3 step
13 are impregnated in antistatic agent solution, bath raio 1:4.5, dip time 45min, are dried at 83 DEG C after dipping, dry
The dry time is 36min, and antistatic finish tissue layer is made;
S5, set knit suture: knitting liner 11 be sheathed on fingerprint, by 12 sets of conductive shield in 11 outside of knitting liner, and
Conductive shield 12 and the knitting suture of liner 11 are connected, after the same method again prevent antistatic finish tissue layer with conduction
The suture connection of sheath 12, to obtain complete gloves.
Embodiment 5:
A kind of preparation method of antistatic knitted gloves, comprising the following steps:
Prepared by S1, knitting liner 11: selecting cotton made of long-staple cotton fiber and PTT elasticity terylene of the mass ratio for 2:1.5 to wash mixed
Cotton-polyester blend yarn is weaved on knitting machine and forms gloves knitting liner 11 by yarn;
Prepared by S2, conductive shield 12: electrically conductive composite fibre being spinned into line, then weaves to be formed and knitting liner by knitting machine
The conductive shield 12 of 11 adaptations;
It is prepared by S3, electrostatic protection outer layer 13: by electrically conductive composite fibre, copper ammonia fiber and cotton the yarn of blended formation be knitted and to be formed
The electrostatic protection outer layer 13 being adapted to conductive shield 12;
S4, antistatic finish: the antistatic agent solution that configuration quality percentage concentration is 13%, by the electrostatic protection outer layer of S3 step
13 are impregnated in antistatic agent solution, bath raio 1:5, dip time 50min, are dried at 85 DEG C after dipping, drying
Time is 40min, and antistatic finish tissue layer is made;
S5, set knit suture: knitting liner 11 be sheathed on fingerprint, by 12 sets of conductive shield in 11 outside of knitting liner, and
Conductive shield 12 and the knitting suture of liner 11 are connected, after the same method again prevent antistatic finish tissue layer with conduction
The suture connection of sheath 12, to obtain complete gloves.
This specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art
Member can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as at this
All by the protection of Patent Law in the scope of the claims of invention.
Claims (8)
1. a kind of antistatic knitted gloves, it is characterised in that: including glove bulk (1), the glove bulk (1) includes in knitting
Gallbladder (11), the conductive shield (12) for being set to knitting liner (11) outer layer, the electrostatic being set on the outside of conductive shield (12)
It protects outer layer (13);
The knitting liner (11) is that cotton-polyester blend yarn is knitted, and the conductive shield (12) is electrically conductive composite fibre
Layer, the electrostatic protection outer layer (13) are antistatic finish tissue layer.
2. a kind of antistatic knitted gloves according to claim 1, it is characterised in that: the cotton-polyester blend yarn includes length
The mass ratio of suede cotton fiber, PTT elasticity terylene, the long-staple cotton fiber and PTT elasticity terylene is 2:(1~1.5).
3. a kind of antistatic knitted gloves according to claim 1, it is characterised in that: the electrically conductive composite fibre includes matter
Amount than be 1:(10~20) graphene, stoste aramid fiber.
4. a kind of antistatic knitted gloves according to claim 3, it is characterised in that: the stoste aramid fiber is meta position virtue
Synthetic fibre.
5. a kind of antistatic knitted gloves according to claim 3, it is characterised in that: the preparation of the electrically conductive composite fibre
Method includes the following steps:
S1, pretreatment: being placed in vacuum drying oven for graphene and be dried, drying temperature be 70~95 DEG C, drying time be 6~
12h;
It is S2, dry-mixed: graphene, stoste aramid fiber are put into high-speed mixer, adjust 350~400rpm of revolving speed, it is stirred 8~
10min, then 800~900rpm of revolving speed is adjusted, 3~5min is continuesd to mix, the homogeneous mixture of graphene Yu stoste aramid fiber is obtained;
S3, granulation is blended: graphene with the homogeneous mixture of stoste aramid fiber investment twin-screw blender is carried out that granulation is blended, is melted
Melting blending temperature is 550~700 DEG C, and revolving speed is 90~150rpm, and the melt blending time is 25~30min, and melt blended material squeezes
It cools down out, obtains electrically conductive composite fibre master batch through pelletizing;
S4, melt spinning: using melt spinning machine to electrically conductive composite fibre master batch melt spinning, spinning temperature is 210~220
DEG C, winding speed is set as 1400~1600m/min, obtains electrically conductive composite fibre;
S5, drafting forming: carrying out drawing-off to electrically conductive composite fibre, and drawing temperature is 90~120 DEG C, and drafting multiple is 4~6 times,
Obtain electrically conductive composite fibre.
6. a kind of antistatic knitted gloves according to claim 1, it is characterised in that: the antistatic finish tissue layer by
The yarn that electrically conductive composite fibre, copper ammonia fiber and the cotton blend that mass ratio is 1:1:1 are formed is knitted.
7. the preparation method of described in any item antistatic knitted gloves according to claim 1~6, which is characterized in that including with
Lower step:
S1, knitting liner (11) preparation: cotton-polyester blend yarn is weaved on knitting machine and forms gloves knitting liner (11);
S2, conductive shield (12) preparation: electrically conductive composite fibre is spinned into line, then weave by knitting machine to be formed be knitted in
The conductive shield (12) of gallbladder (11) adaptation;
S3, electrostatic protection outer layer (13) preparation: by electrically conductive composite fibre, copper ammonia fiber and cotton institute blended formation yarn knitting shape
At the electrostatic protection outer layer (13) being adapted to conductive shield (12);
S4, antistatic finish: the antistatic agent solution that configuration quality percentage concentration is 6%~13%, by the electrostatic protection of S3 step
Outer layer (13) is impregnated in antistatic agent solution, and bath raio is (1:3)~(1:5), and dip time is 35~50min, after dipping
It is dried at 75~85 DEG C, drying time is 30~40min, and antistatic finish tissue layer is made;
S5, set knit suture: knitting liner (11) being sheathed on fingerprint, conductive shield (12) is covered and is being knitted liner (11) outside
Side, and conductive shield (12) and knitting liner (11) suture are connected, after the same method again by antistatic finish fabric
Layer is connected with conductive shield (12) suture, to obtain complete gloves.
8. a kind of preparation method of antistatic knitted gloves according to claim 7, it is characterised in that: in the S4 step
Antistatic agent is organosilicon quaternary ammonium salt antistatic agent.
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