CN1100721C - 制备氨合成气的蒸汽重整方法 - Google Patents
制备氨合成气的蒸汽重整方法 Download PDFInfo
- Publication number
- CN1100721C CN1100721C CN97120064A CN97120064A CN1100721C CN 1100721 C CN1100721 C CN 1100721C CN 97120064 A CN97120064 A CN 97120064A CN 97120064 A CN97120064 A CN 97120064A CN 1100721 C CN1100721 C CN 1100721C
- Authority
- CN
- China
- Prior art keywords
- reactor
- gas
- air
- pair
- stack gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000629 steam reforming Methods 0.000 title description 15
- 239000007789 gas Substances 0.000 claims abstract description 68
- 238000002485 combustion reaction Methods 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 12
- 239000000446 fuel Substances 0.000 claims abstract description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000001301 oxygen Substances 0.000 claims abstract description 10
- 230000008569 process Effects 0.000 claims abstract description 9
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 7
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 6
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 6
- 238000002407 reforming Methods 0.000 claims abstract description 3
- 239000002994 raw material Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 5
- 238000006477 desulfuration reaction Methods 0.000 claims description 3
- 230000023556 desulfurization Effects 0.000 claims description 3
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- 241000707825 Argyrosomus regius Species 0.000 claims description 2
- 230000005540 biological transmission Effects 0.000 claims description 2
- 238000002156 mixing Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 235000011089 carbon dioxide Nutrition 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000010339 dilation Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/025—Preparation or purification of gas mixtures for ammonia synthesis
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2763996P | 1996-10-04 | 1996-10-04 | |
| US027,639 | 1996-10-04 | ||
| US027639 | 1996-10-04 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1183376A CN1183376A (zh) | 1998-06-03 |
| CN1100721C true CN1100721C (zh) | 2003-02-05 |
Family
ID=21838908
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97120064A Expired - Fee Related CN1100721C (zh) | 1996-10-04 | 1997-10-05 | 制备氨合成气的蒸汽重整方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5925328A (de) |
| EP (1) | EP0834465B1 (de) |
| JP (1) | JP4105786B2 (de) |
| CN (1) | CN1100721C (de) |
| AT (1) | ATE194816T1 (de) |
| DE (1) | DE69702581T2 (de) |
| RU (1) | RU2211798C2 (de) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NO308398B1 (no) * | 1997-06-06 | 2000-09-11 | Norsk Hydro As | Fremgangsmate for utforelse av katalytiske eller ikke-katalytiske prosesser hvori oksygen er ±n av reaktantene |
| DK173496B1 (da) * | 1998-07-16 | 2001-01-02 | Topsoe Haldor As | Fremgangsmåde til fremstilling af syntesegas ved vanddampreformering under anvendelse af en katalyseret metaloverflade |
| EP1106570B1 (de) * | 1999-12-02 | 2013-08-28 | Haldor Topsoe A/S | Verfahren zum Ausführen von nicht-adiabatischen katalytischen Reaktionen |
| US20040161381A1 (en) * | 1999-12-02 | 2004-08-19 | Thomsen Soren Gyde | Process and reactor for carrying out non-adiabatic catalytic reactions |
| US6962492B2 (en) | 2001-10-05 | 2005-11-08 | Mold-Masters Limited | Gap seal between nozzle components |
| US7967878B2 (en) * | 2002-01-04 | 2011-06-28 | Meggitt (Uk) Limited | Reformer apparatus and method |
| US7138001B2 (en) * | 2003-03-16 | 2006-11-21 | Kellogg Brown & Root Llc | Partial oxidation reformer-reforming exchanger arrangement for hydrogen production |
| US7220505B2 (en) * | 2003-03-18 | 2007-05-22 | Kellogg Brown & Root Llc | Autothermal reformer-reforming exchanger arrangement for hydrogen production |
| US7320778B2 (en) * | 2004-07-21 | 2008-01-22 | Catacel Corp. | High-performance catalyst support |
| BRPI0515031A (pt) * | 2004-09-09 | 2008-07-01 | Haldor Topsoe As | processo para produção de gás rico em hidrogênio e/ou monóxido de carbono e processo para a preparação de metanol a partir de matéria-prima de hidrocarboneto gasoso ou lìquido |
| US20060230613A1 (en) * | 2005-04-14 | 2006-10-19 | Catacel Corporation | Catalytic reactor cartridge |
| US7472936B2 (en) * | 2005-04-14 | 2009-01-06 | Catacel Corp. | Tool for insertion and removal of a catalytic reactor cartridge |
| US7565743B2 (en) * | 2005-04-14 | 2009-07-28 | Catacel Corp. | Method for insertion and removal of a catalytic reactor cartridge |
| US7682580B2 (en) * | 2005-05-19 | 2010-03-23 | Catacel Corp. | Catalytic reactor having radial leaves |
| US7504048B2 (en) * | 2005-06-14 | 2009-03-17 | Air Products And Chemicals, Inc. | Axial convective reformer |
| US7501102B2 (en) * | 2005-07-28 | 2009-03-10 | Catacel Corp. | Reactor having improved heat transfer |
| US20070237710A1 (en) * | 2006-04-05 | 2007-10-11 | Genkin Eugene S | Reforming apparatus and method for syngas generation |
| FR2914395B1 (fr) * | 2007-03-30 | 2009-11-20 | Inst Francais Du Petrole | Nouveau reacteur echangeur compact utilisant un bruleur poreux |
| US20120070347A1 (en) * | 2010-03-01 | 2012-03-22 | Plasco Energy Group, Inc. | Carbon Conversion System with Integrated Processing Zones |
| CN102319555A (zh) * | 2011-06-27 | 2012-01-18 | 吴焕松 | 一种利用空气除氧去杂制备无氧保护气体的方法及装置 |
| US8545775B2 (en) * | 2011-10-20 | 2013-10-01 | Kellogg Brown & Root Llc | Reforming exchanger system with intermediate shift conversion |
| CA2953728C (en) | 2014-07-09 | 2021-03-02 | Haldor Topsoe A/S | Process for producing hydrogen |
| FR3040167B1 (fr) * | 2015-08-18 | 2020-12-25 | Air Liquide | Procede de production de gaz de synthese au moyen de reacteurs de vaporeformage |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4079017A (en) * | 1976-11-19 | 1978-03-14 | Pullman Incorporated | Parallel steam reformers to provide low energy process |
| US4337170A (en) * | 1980-01-23 | 1982-06-29 | Union Carbide Corporation | Catalytic steam reforming of hydrocarbons |
| US4822521A (en) * | 1983-06-09 | 1989-04-18 | Uop | Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons |
| US5202057A (en) * | 1988-09-14 | 1993-04-13 | Air Products And Chemicals, Inc. | Production of ammonia synthesis gas |
| US5122299A (en) * | 1989-12-11 | 1992-06-16 | The M. W. Kellogg Company | Autothermal steam reforming process |
| US5011625A (en) * | 1989-12-11 | 1991-04-30 | The M. W. Kellogg Company | Autothermal steam reforming process |
| DK167864B1 (da) * | 1990-02-02 | 1993-12-27 | Topsoe Haldor As | Fremgangsmaade og reaktorsystem til reforming af carbonhydrider under varmeveksling |
| ATE156778T1 (de) * | 1991-07-09 | 1997-08-15 | Ici Plc | Synthesegaserzeugung |
-
1997
- 1997-09-17 DE DE69702581T patent/DE69702581T2/de not_active Expired - Lifetime
- 1997-09-17 AT AT97116134T patent/ATE194816T1/de not_active IP Right Cessation
- 1997-09-17 EP EP97116134A patent/EP0834465B1/de not_active Expired - Lifetime
- 1997-10-02 US US08/943,066 patent/US5925328A/en not_active Expired - Lifetime
- 1997-10-03 JP JP27152797A patent/JP4105786B2/ja not_active Expired - Fee Related
- 1997-10-03 RU RU97116511/12A patent/RU2211798C2/ru not_active IP Right Cessation
- 1997-10-05 CN CN97120064A patent/CN1100721C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0834465B1 (de) | 2000-07-19 |
| EP0834465A2 (de) | 1998-04-08 |
| DE69702581D1 (de) | 2000-08-24 |
| JPH10231102A (ja) | 1998-09-02 |
| RU2211798C2 (ru) | 2003-09-10 |
| JP4105786B2 (ja) | 2008-06-25 |
| EP0834465A3 (de) | 1998-04-15 |
| US5925328A (en) | 1999-07-20 |
| CN1183376A (zh) | 1998-06-03 |
| ATE194816T1 (de) | 2000-08-15 |
| DE69702581T2 (de) | 2000-11-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20030205 Termination date: 20151005 |
|
| EXPY | Termination of patent right or utility model |