CN110067037A - A kind of regenerated celulose fibre - Google Patents
A kind of regenerated celulose fibre Download PDFInfo
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- CN110067037A CN110067037A CN201910341679.3A CN201910341679A CN110067037A CN 110067037 A CN110067037 A CN 110067037A CN 201910341679 A CN201910341679 A CN 201910341679A CN 110067037 A CN110067037 A CN 110067037A
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
Abstract
A kind of regenerated celulose fibre, including following component: regenerated cellulose, component A and component B；Wherein, component A is one or more of polyvinyl chloride, Vingon and polyvinyl bromide；Component B is the mixture in the oxide of antimony or the oxide of antimony and organic phosphorus combustion agent；The mass ratio of regenerated cellulose dry weight and component A are 100:10~80；The mass ratio of component A and component B are 100:2~70.The present invention is also illustrated the preparation method of above-mentioned regenerated celulose fibre.The regenerated cellulose with anti-flammability obtained can carry out certain proportion with the synthetic fibers such as the cellulose fibres such as not fire-retardant cotton, viscose glue, animal origin or not fire-retardant terylene, acrylic fibers and nylon and mix through the invention, and other fibers can be without any flame retardant treatment, obtained mixture integrally has certain flame retardant property；The raw material sources that the regenerated celulose fibre is added are cheap extensively, can substantially reduce production cost.
Description
Technical field
The present invention relates to flame-retardant textile technical field more particularly to a kind of regenerated celulose fibres.
Background technique
Fabric will realize flame retarding function, and generally there are two types of methods:
1, chemical processing will be carried out in non-flame resistant fabric or fiber；Chemical drugs artificially are carried out to non-flame resistant fabric or fiber
Agent dipping fire-cures or in non-flame resistant web surface or fiber surface coating flame retardant chemicals layer；To non-flame resistant fabric or fiber
It is obtained cheap with flame retarding function fabric for carrying out the benefit of fire-retardant post-processing, but the anti-flammability of fabric can be with washing
The increase of number and decline；In addition, the carcinogens such as the meeting such as remaining chemical agent sustained release formaldehyde on fabric, and producing
The pernicious gas of exhaust emission environment is understood in the process.
2, using the fire-retardant mode of material, i.e. the fiber of composition flame-retardant textile or fiber combinations itself have anti-flammability, are not required to
Want fire-retardant post-processing.The anti-flammability of material flame-retardant textile is stablized, but price is high；The exploitation and processing of material flame-retardant textile are relatively tired
It is difficult.Therefore market is good at low cost, comfort and the demand of the fire resistance fibre of handling ease is very big.
Fire-retardant regenerated cellulose fiber currently on the market is mainly being based on viscose glue, Modal, bamboo fibre or lyocell
On the basis of equal regenerated celulose fibres, addition organophosphorous fire retardant, quartz (silica) fire retardant, nitrogenated flame retardant,
Silicon nitrogenated flame retardant, bromide fire retardant and carbon flame retardant are made；The pole of regenerated celulose fibre is made by above-mentioned material
Limited oxygen index be greater than or equal to 28, above-mentioned regenerated celulose fibre is mixed with other fire resistance fibres, then by spinning with
Weaving, braiding or nonwoven processes obtain material flame-retardant textile；Material flame-retardant textile made from the above method is used for individual protection
Or household flame protection etc..Due to having the presence of regenerated celulose fibre, regenerated celulose fibre tool in material flame-retardant textile
Standby preferable water absorbing capacity, can increase the comfort of material flame-retardant textile；Therefore the material flame-retardant textile use scope is more next
It is more extensive.
In addition, there are also a kind of synthetic fibers on the market, belong to modacrylic acid series fiber；The synthetic fibers can be with
The non-flame resistant fiber such as cotton, viscose glue, fiber crops and wool carries out the mixing close to 1:1, and to non-flame resistant fiber without any resistance
Combustion processing；Obtained mixture is integrally still able to maintain 28 or more limit oxygen index.
But the above-mentioned fire-retardant regenerated cellulose fiber referred to and synthetic fibers all have respective defect:
For above-mentioned fire-retardant regenerated cellulose fiber, fire-retardant regenerated cellulose fiber can only be mixed with fire resistance fibre
It closes；If fire-retardant regenerated cellulose fiber is mixed with non-flame resistant fiber, if the content of non-flame resistant fiber more than 10%, mixture
Entirety will lose anti-flammability.If fire-retardant regenerated cellulose fiber is mixed with other fire resistance fibres, the overall flame of mixture
Property will be lower than the anti-flammability of any single fire resistance fibre in mixture；That is the fiber can only be carried out with fire resistance fibre
Mixing, it is lower with the anti-flammability fitness of fire resistance fibre.
For above-mentioned synthetic fibers, synthetic fibers are mixed with non-flame resistant fiber, the dyeing property difference of two kinds of fibers
It is huge, and dyestuff is not also identical；Synthetic fibers must be using two bath methods when flame-retardant textile is made；Two bath process are complicated, and control
System is difficult；Efficient long vehicle dyeing assembly line cannot be used to be processed, should not be widely applied.
Summary of the invention
(1) goal of the invention
To solve technical problem present in background technique, the present invention proposes a kind of regenerated celulose fibre, system of the present invention
The regenerated cellulose with anti-flammability can be with the cellulose fibres such as not fire-retardant cotton, viscose glue, animal origin or not fire-retardant
The synthetic fibers such as terylene, acrylic fibers and nylon carry out certain proportion mixing, and other fibers can be without any fire-retardant place
Reason；Obtained mixture integrally has certain flame retardant property.
(2) technical solution
To solve the above problems, the present invention provides a kind of regenerated celulose fibre, including following component: regenerated fiber
Element, component A and component B；Wherein, component A is one or more of polyvinyl chloride, Vingon and polyvinyl bromide；
Component B is the mixture of the oxide of antimony or the oxide of antimony and organophosphorous fire retardant；
The dry weight of regenerated cellulose and the mass ratio of component A are 100:10~80；The mass ratio of component A and component B
For 100:2~70.
Preferably, the oxide of antimony includes antimony oxide, antimony pentoxide and antimony tetroxide.
Preferably, above-mentioned regenerated celulose fibre, component A are polyvinyl chloride；Component B is antimony oxide；By weight
Meter, regenerated cellulose, component A and component B are respectively 100 parts, 80 parts and 1.6 parts.
Preferably, above-mentioned regenerated celulose fibre, component A are polyvinyl chloride；Component B is antimony oxide；By weight
Meter, regenerated cellulose, component A and component B are respectively 100 parts, 10 parts and 7 parts.
Preferably, above-mentioned regenerated celulose fibre, component A are polyvinyl chloride；Component B is antimony oxide；By weight
Meter, regenerated cellulose, component A and component B are respectively 100 parts, 50 parts and 35 parts.
Preferably, above-mentioned regenerated celulose fibre, component A are Vingon；Component B is antimony pentoxide and organic phosphorus
Sulfate；By weight, regenerated cellulose, component A, antimony pentoxide and organic phosphorus sulfate be respectively 100 parts, 60 parts,
20 parts 10 parts.
Preferably, above-mentioned regenerated celulose fibre, component A are polyvinyl chloride；Component B is antimony pentoxide and three oxidations two
Antimony；By weight, regenerated cellulose, component A, antimony pentoxide and antimony oxide be respectively 100 parts, 80 parts, 36 parts and
20 parts.
Preferably, the preparation method specific steps of above-mentioned regenerated celulose fibre are as follows:
S1, it weighs to put into beating equipment after regenerated cellulose corresponding to dry weight by weight and is beaten, obtain
To cellulose pulp C；
S2, component A is weighed by weight, obtain raw material D；Component B is weighed by weight, obtains raw material E；
S3, it will be stirred in component B addition blender, and component A be at the uniform velocity added in blender and stirs to get mixing
Object F；
S4, mixture F and cellulose pulp C is put into uniform stirring in mixing tank, obtains mixture G；
S5, mixture G and dilute alkaline soln are subjected to cross jet flow high pressure mixing, obtain mixture H；And again by mixture H
Secondary progress cross jet flow high pressure mixing, obtains mixture I；
S6, the viscosity for mixture I being sent into storage tank and being added into storage tank dilute alkaline soln adjustment mixture I, obtain
To mixture J；Again de-soak twice is filtered to mixture J three times, obtains mixture K；Mixture K is added in ageing can body
And uniform stirring, obtain mixture L；
S6, mixture L and carbon disulfide are acted on, obtains mixture M；
S7, spinning is carried out to mixture M and is solidified in acid solution, obtain tow N；
S8, to tow N carry out refining removal of impurities obtain product O；Product O is successively dried, is done temperature at 135~155 DEG C
Drawing-off and secondary retraction, regain are balanced, crumple, shear and are packaged, and obtain product P.
Preferably, product N also carries out spinneret drawing-off, plasticity drawing-off and the processing of fiber retraction.
Preferably, the mixing speed of blender is 39~41r/min, mixing time 30min；Component A is with 5kg/min
Speed be sent into blender；Blender continues stirring 22 minutes after the completion of component A is added.
Above-mentioned technical proposal of the invention has following beneficial technical effect:
Regenerated celulose fibre provided by the invention include regenerated cellulose, component A (polyvinyl chloride, Vingon and
One of polyvinyl bromide is a variety of) and the component B (mixing in the oxide of antimony or the oxide and organophosphorous fire retardant of antimony
Object)；Obtain the high regenerated celulose fibre of anti-flammability；And the content of component A account for regenerated cellulose quality 10%~
80%, the content of component B accounts for the 2%~70% of component A dry weight；With the regeneration of anti-flammability as made from said ratio
Cellulose can be with the cellulose fibres such as not fire-retardant cotton, viscose glue, animal origin or not fire-retardant terylene, acrylic fibers and nylon etc.
Synthetic fibers carry out certain proportion mixing, and other fibers can be without any flame retardant treatment；Obtained mixture integrally has
Standby certain flame retardant property；
In addition the fire-retardant principle of regenerated celulose fibre produced by the present invention is the chlorine element or bromo element and antimony of vinyl chloride
Oxide first reacted, absorb the heat of burning；Chlorine element or bromo element are reacted with the oxide of antimony and can be released simultaneously
The heavier-than-air body of resistance to combustion gas achievees the purpose that comburant self-extinguishment is put out a fire for hindering comburant to contact with oxygen；Regenerated fiber
It itself can slow down decomposition after cellulose fiber is merged with A group ingredient and A group ingredient is promoted to be carbonized, form complementary type reaction mechanism；Simultaneously
The regenerated celulose fibre have water absorption rate is high, heat resistance is strong, can dye, good hand touch, natural degradation, to the mankind and environmental-friendly
Many advantages, such as；The raw material sources that the regenerated celulose fibre is added are cheap extensively, can substantially reduce production cost；
The present invention increases dry heat drafting and secondary retraction during the spinning process, by the process by component A by powdered embedding
Enter and be changed to be plasticized again in fiberoptic fiber element, directly participate in the link and crosslinking of cellulose, to the raising regenerated celulose fibre
Tension failure strength play the role of it is key；Due to the intervention of adding ingredient in regenerated celulose fibre, regenerated cellulose is fine
The arc resistance of dimension is also opposite to be improved；It can be used for fire-entry suit, fire retardant protective clothing and fire-retardant using the regenerated celulose fibre
The production of textile, the regenerated celulose fibre can be used market very wide.
Specific embodiment
In order to make the objectives, technical solutions and advantages of the present invention clearer, With reference to embodiment, to this
Invention is further described.It should be understood that these descriptions are merely illustrative, and it is not intended to limit the scope of the invention.This
Outside, in the following description, descriptions of well-known structures and technologies are omitted, so as not to unnecessarily obscure the concept of the present invention.
Embodiment 1
A kind of regenerated celulose fibre proposed by the present invention, including following components: regenerated cellulose, component A and component B；
Component A is one or more of polyvinyl chloride, Vingon and polyvinyl bromide；Component B is the oxygen of antimony
The mixture of the oxide and organophosphorous fire retardant of compound or antimony；The oxide of antimony include antimony oxide, antimony pentoxide with
And antimony tetroxide；
Component A is polyvinyl chloride；Component B is antimony oxide；By weight, regenerated cellulose, component A and component B points
Not are as follows: 100Kg, 80Kg and 1.6Kg.
In an alternative embodiment, the preparation method of regenerated celulose fibre, specific steps are as follows:
S1, it weighs to put into beating equipment after the corresponding regenerated cellulose of dry weight by weight and is beaten, obtain
Cellulose pulp C；
S2, component A is weighed by weight, obtain raw material D；Component B is weighed by weight, obtains raw material E；
S3, it will be stirred in component B addition blender, and component A be at the uniform velocity added in blender and stirs to get mixing
Object F；
S4, mixture F and cellulose pulp C is put into uniform stirring in mixing tank, obtains mixture G；Further, it mixes
Batch can selects 5000kg grades of large-scale mixing tank, keeps the revolving speed stirring of 25~28r/min；
S5, mixture G and dilute alkaline soln are subjected to cross jet flow high pressure mixing, obtain mixture H；And again by mixture H
Secondary progress cross jet flow high pressure mixing, obtains mixture I；
S6, the viscosity for mixture I being sent into storage tank and being added into storage tank dilute alkaline soln adjustment mixture I, obtain
To mixture J；Again de-soak twice is filtered to mixture J three times, obtains mixture K；Mixture K is added in ageing can body
And the revolving speed uniform stirring of 10r/min is kept, obtain mixture L；
S6, mixture L and carbon disulfide are acted on, obtains mixture M；
S7, spinning is carried out to mixture M and is solidified in acid solution, obtain tow N；
S8, to tow N carry out refining removal of impurities obtain product O；Product O is successively dried, is done temperature at 135~155 DEG C
Drawing-off and secondary retraction, regain are balanced, crumple, shear and are packaged, and obtain product P.
In an alternative embodiment, product N also carries out spinneret drawing-off, plasticity drawing-off and the processing of fiber retraction.
It should be noted that wherein the control of spinneret degree of draft is at 1.05~1.35 times；Plasticity drawing-off is controlled 1.8~2.3
Times；Fiber retraction control is 15%~35%；The elongation at break control of fiber 12%~23%,；Dry temperature degree of draft control
At 1.05~1.15 times；Retraction control twice is 5%~10%；
In an alternative embodiment, the mixing speed of blender is 39~41r/min, mixing time 30min；Group
A is divided to be sent into blender with the speed of 5kg/min；Blender continues stirring 22 minutes after the completion of component A is added；Preferably, component A
Partial size with component B is no more than 0.4um.
Embodiment 2
A kind of regenerated celulose fibre proposed by the present invention, including following components: regenerated cellulose, component A and component B；
Component A is one or more of polyvinyl chloride, Vingon and polyvinyl bromide；Component B is the oxygen of antimony
The mixture of the oxide and organophosphorous fire retardant of compound or antimony；The oxide of antimony include antimony oxide, antimony pentoxide with
And antimony tetroxide；
Component A is polyvinyl chloride；Component B is antimony oxide, by weight, regenerated cellulose, component A and component B points
It Wei not 100Kg, 10Kg and 7Kg.
In an alternative embodiment, the preparation method of regenerated celulose fibre, specific steps are as follows:
S1, it weighs to put into beating equipment after the corresponding regenerated cellulose of dry weight by weight and is beaten, obtain
Cellulose pulp C；
S2, component A is weighed by weight, obtain raw material D；Component B is weighed by weight, obtains raw material E；
S3, it will be stirred in component B addition blender, and component A be at the uniform velocity added in blender and stirs to get mixing
Object F；
S4, mixture F and cellulose pulp C is put into uniform stirring in mixing tank, obtains mixture G；Further, it mixes
Batch can selects 5000kg grades of large-scale mixing tank, keeps the revolving speed stirring of 25~28r/min；
S5, mixture G and dilute alkaline soln are subjected to cross jet flow high pressure mixing, obtain mixture H；And again by mixture H
Secondary progress cross jet flow high pressure mixing, obtains mixture I；
S6, the viscosity for mixture I being sent into storage tank and being added into storage tank dilute alkaline soln adjustment mixture I, obtain
To mixture J；Again de-soak twice is filtered to mixture J three times, obtains mixture K；Mixture K is added in ageing can body
And the revolving speed uniform stirring of 10r/min is kept, obtain mixture L；
S6, mixture L and carbon disulfide are acted on, obtains mixture M；
S7, spinning is carried out to mixture M and is solidified in acid solution, obtain tow N；
S8, to tow N carry out refining removal of impurities obtain product O；Product O is successively dried, is done temperature at 135~155 DEG C
Drawing-off and secondary retraction, regain are balanced, crumple, shear and are packaged, and obtain product P.
In an alternative embodiment, product N also carries out spinneret drawing-off, plasticity drawing-off and the processing of fiber retraction.
It should be noted that wherein the control of spinneret degree of draft is at 1.05~1.35 times；Plasticity drawing-off is controlled 1.8~2.3
Times；Fiber retraction control is 15%~35%；The elongation at break control of fiber 12%~23%,；Dry temperature degree of draft control
At 1.05~1.15 times；Retraction control twice is 5%~10%；
In an alternative embodiment, the mixing speed of blender is 39~41r/min, mixing time 30min；
Component A is sent into blender with the speed of 5kg/min；Blender continues stirring 22 minutes after the completion of component A is added；Preferably, group
Divide the partial size of A and component B no more than 0.4um.
Embodiment 3
A kind of regenerated celulose fibre proposed by the present invention, including following components: regenerated cellulose, component A and component B；
Component A is one or more of polyvinyl chloride, Vingon and polyvinyl bromide；Component B is the oxygen of antimony
The mixture of the oxide and organophosphorous fire retardant of compound or antimony；The oxide of antimony include antimony oxide, antimony pentoxide with
And antimony tetroxide；
Component A is polyvinyl chloride；Component B is antimony oxide；By weight, regenerated cellulose, component A and component B points
It Wei not 100Kg, 50Kg and 35Kg.
In an alternative embodiment, the preparation method of regenerated celulose fibre, specific steps are as follows:
S1, it weighs to put into beating equipment after the corresponding regenerated cellulose of dry weight by weight and is beaten, obtain
Cellulose pulp C；
S2, component A is weighed by weight, obtain raw material D；Component B is weighed by weight, obtains raw material E；
S3, it will be stirred in component B addition blender, and component A be at the uniform velocity added in blender and stirs to get mixing
Object F；
S4, mixture F and cellulose pulp C is put into uniform stirring in mixing tank, obtains mixture G；Further, it mixes
Batch can selects 5000kg grades of large-scale mixing tank, keeps the revolving speed stirring of 25~28r/min；
S5, mixture G and dilute alkaline soln are subjected to cross jet flow high pressure mixing, obtain mixture H；And again by mixture H
Secondary progress cross jet flow high pressure mixing, obtains mixture I；
S6, the viscosity for mixture I being sent into storage tank and being added into storage tank dilute alkaline soln adjustment mixture I, obtain
To mixture J；Again de-soak twice is filtered to mixture J three times, obtains mixture K；Mixture K is added in ageing can body
And the revolving speed uniform stirring of 10r/min is kept, obtain mixture L；
S6, mixture L and carbon disulfide are acted on, obtains mixture M；
S7, spinning is carried out to mixture M and is solidified in acid solution, obtain tow N；
S8, to tow N carry out refining removal of impurities obtain product O；Product O is successively dried, is done temperature at 135~155 DEG C
Drawing-off and secondary retraction, regain are balanced, crumple, shear and are packaged, and obtain product P.
In an alternative embodiment, product N also carries out spinneret drawing-off, plasticity drawing-off and the processing of fiber retraction.
It should be noted that wherein the control of spinneret degree of draft is at 1.05~1.35 times；Plasticity drawing-off is controlled 1.8~2.3
Times；Fiber retraction control is 15%~35%；The elongation at break control of fiber 12%~23%,；Dry temperature degree of draft control
At 1.05~1.15 times；Retraction control twice is 5%~10%；
In an alternative embodiment, the mixing speed of blender is 39~41r/min, mixing time 30min；Group
A is divided to be sent into blender with the speed of 5kg/min；Blender continues stirring 22 minutes after the completion of component A is added；Preferably, component A
Partial size with component B is no more than 0.4um.
Embodiment 4
A kind of regenerated celulose fibre proposed by the present invention, including following components: regenerated cellulose, component A and component B；
Component A is one or more of polyvinyl chloride, Vingon and polyvinyl bromide；Component B is the oxygen of antimony
The mixture of the oxide and organophosphorous fire retardant of compound or antimony；The oxide of antimony include antimony oxide, antimony pentoxide with
And antimony tetroxide；
Component A is Vingon；Component B is antimony pentoxide and organic phosphorus sulfate, by weight, regenerated fiber
Element, Vingon, antimony pentoxide and organic phosphorus sulfate are respectively 100Kg, 60Kg, 20Kg and 10Kg.
In an alternative embodiment, the preparation method of regenerated celulose fibre, specific steps are as follows:
S1, it weighs to put into beating equipment after the corresponding regenerated cellulose of dry weight by weight and is beaten, obtain
Cellulose pulp C；
S2, component A is weighed by weight, obtain raw material D；Component B is weighed by weight, obtains raw material E；
S3, it will be stirred in component B addition blender, and component A be at the uniform velocity added in blender and stirs to get mixing
Object F；
S4, mixture F and cellulose pulp C is put into uniform stirring in mixing tank, obtains mixture G；Further, it mixes
Batch can selects 5000kg grades of large-scale mixing tank, keeps the revolving speed stirring of 25~28r/min；
S5, mixture G and dilute alkaline soln are subjected to cross jet flow high pressure mixing, obtain mixture H；And again by mixture H
Secondary progress cross jet flow high pressure mixing, obtains mixture I；
S6, the viscosity for mixture I being sent into storage tank and being added into storage tank dilute alkaline soln adjustment mixture I, obtain
To mixture J；Again de-soak twice is filtered to mixture J three times, obtains mixture K；Mixture K is added in ageing can body
And the revolving speed uniform stirring of 10r/min is kept, obtain mixture L；
S6, mixture L and carbon disulfide are acted on, obtains mixture M；
S7, spinning is carried out to mixture M and is solidified in acid solution, obtain tow N；
S8, to tow N carry out refining removal of impurities obtain product O；Product O is successively dried, is done temperature at 135~155 DEG C
Drawing-off and secondary retraction, regain are balanced, crumple, shear and are packaged, and obtain product P.
In an alternative embodiment, product N also carries out spinneret drawing-off, plasticity drawing-off and the processing of fiber retraction.
It should be noted that wherein the control of spinneret degree of draft is at 1.05~1.35 times；Plasticity drawing-off is controlled 1.8~2.3
Times；Fiber retraction control is 15%~35%；The elongation at break control of fiber 12%~23%,；Dry temperature degree of draft control
At 1.05~1.15 times；Retraction control twice is 5%~10%；
In an alternative embodiment, the mixing speed of blender is 39~41r/min, mixing time 30min；
Component A is sent into blender with the speed of 5kg/min；Blender continues stirring 22 minutes after the completion of component A is added；Preferably, group
Divide the partial size of A and component B no more than 0.4um.
Embodiment 5
A kind of regenerated celulose fibre proposed by the present invention, including following components: regenerated cellulose, component A and component B；
Component A is one or more of polyvinyl chloride, Vingon and polyvinyl bromide；Component B is the oxygen of antimony
The mixture of the oxide and organophosphorous fire retardant of compound or antimony；The oxide of antimony include antimony oxide, antimony pentoxide with
And antimony tetroxide；
Component A is polyvinyl chloride；Component B is antimony pentoxide and antimony oxide, and by weight, regenerated cellulose gathers
Vinyl chloride, antimony pentoxide and antimony oxide are respectively 100Kg, 80Kg, 36Kg and 20Kg.
In an alternative embodiment, the preparation method of regenerated celulose fibre, specific steps are as follows:
S1, it weighs to put into beating equipment after the corresponding regenerated cellulose of dry weight by weight and is beaten, obtain
Cellulose pulp C；
S2, component A is weighed by weight, obtain raw material D；Component B is weighed by weight, obtains raw material E；
S3, it will be stirred in component B addition blender, and component A be at the uniform velocity added in blender and stirs to get mixing
Object F；
S4, mixture F and cellulose pulp C is put into uniform stirring in mixing tank, obtains mixture G；Further, it mixes
Batch can selects 5000kg grades of large-scale mixing tank, keeps the revolving speed stirring of 25~28r/min；
S5, mixture G and dilute alkaline soln are subjected to cross jet flow high pressure mixing, obtain mixture H；And again by mixture H
Secondary progress cross jet flow high pressure mixing, obtains mixture I；
S6, the viscosity for mixture I being sent into storage tank and being added into storage tank dilute alkaline soln adjustment mixture I, obtain
To mixture J；Again de-soak twice is filtered to mixture J three times, obtains mixture K；Mixture K is added in ageing can body
And the revolving speed uniform stirring of 10r/min is kept, obtain mixture L；
S6, mixture L and carbon disulfide are acted on, obtains mixture M；
S7, spinning is carried out to mixture M and is solidified in acid solution, obtain tow N；
S8, to tow N carry out refining removal of impurities obtain product O；Product O is successively dried, is done temperature at 135~155 DEG C
Drawing-off and secondary retraction, regain are balanced, crumple, shear and are packaged, and obtain product P.
In an alternative embodiment, product N also carries out spinneret drawing-off, plasticity drawing-off and the processing of fiber retraction.
It should be noted that wherein the control of spinneret degree of draft is at 1.05~1.35 times；Plasticity drawing-off is controlled 1.8~2.3
Times；Fiber retraction control is 15%~35%；The elongation at break control of fiber 12%~23%,；Dry temperature degree of draft control
At 1.05~1.15 times；Retraction control twice is 5%~10%；
In an alternative embodiment, the mixing speed of blender is 39~41r/min, mixing time 30min；
Component A is sent into blender with the speed of 5kg/min；Blender continues stirring 22 minutes after the completion of component A is added；Preferably, group
Divide the partial size of A and component B no more than 0.4um.
It should be noted that the regenerated cellulose in the present invention in embodiment selects the regenerated cellulose of synthetic cotton；It is artificial
The regenerated cellulose of cotton is changed to the vegetative fibers element such as Modal fibre element, Lyocell fibers element, bamboo fibre cellulose, does not influence
Case effect；
Organic phosphorus sulfate is only preferred, other fire retardants also can be used；The addition of other fire retardants is not required
, phosphorus system, bromine system, organic silicon-type, inorganic silicon, nitrogen system and silicon nitrogenated flame retardant can be added as needed, adjust fabric
Flame retarding reaction under different ignition modes；But the sb oxide in the present invention is only the fire retardant of core；
To regenerated cellulose obtained in above-described embodiment according to GB/T5454-2014 test fiber limit oxygen index,
Tensile break strength, tension fracture elongation rate and regain, specific data are as shown in table 1 below；
Regenerated celulose fibre made from above-described embodiment is mixed with non-flame resistant fiber respectively, and is obtained after testing mixing
The limit oxygen index of mixture, test data see the table below 2；
Table 1
Table 2
As shown in Table 1, the limit oxygen index of regenerated celulose fibre obtained is not less than 28 through the foregoing embodiment；Again
The physical property of raw cellulose fibre is substantially similar with common regenerated celulose fibre, have it is basic can textile performance；
As shown in Table 2, through the foregoing embodiment regenerated celulose fibre obtained respectively according to certain proportion and non-resistance
The limit oxygen index for the fiber that combustion fiber is mixed to prepare is more than 28, with preferable flame retardant property；
Wherein, reactive dye or intellectual circle's dyestuff one-bath dyeing can be used for the mixture 4 in table 2, two kinds of fibers
Form and aspect are approximate, reach 4~5 grades, color separation do not occur；6040 fabric can be washed with reference to conventional cotton for the mixture 5 in table 2
Dyeing carries out long vehicle dyeing, the dyeing cost of inflaming retarding fabric can be greatly lowered, and convenient for being widely applied.
It should be understood that above-mentioned specific embodiment of the invention is used only for exemplary illustration or explains of the invention
Principle, but not to limit the present invention.Therefore, that is done without departing from the spirit and scope of the present invention is any
Modification, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.In addition, appended claims purport of the present invention
Covering the whole variations fallen into attached claim scope and boundary or this range and the equivalent form on boundary and is repairing
Change example.
Claims (9)
1. a kind of regenerated celulose fibre, which is characterized in that including following component: regenerated cellulose, component A and component B；Its
In, component A is one or more of polyvinyl chloride, Vingon and polyvinyl bromide；Component B be antimony oxide or
The mixture of the oxide of antimony and organic phosphorus combustion agent；
The dry weight of regenerated cellulose and the mass ratio of component A are 100:10~80；The mass ratio of component A and component B is
100:2~70.
2. a kind of regenerated celulose fibre according to claim 1, which is characterized in that component A is polyvinyl chloride；Component B
For antimony oxide；By weight, regenerated cellulose, component A and component B are respectively 100 parts, 80 parts and 1.6 parts.
3. a kind of regenerated celulose fibre according to claim 1, which is characterized in that component A is polyvinyl chloride；Component B
For antimony oxide；By weight, regenerated cellulose, component A and component B are respectively 100 parts, 10 parts and 7 parts.
4. a kind of regenerated celulose fibre according to claim 1, which is characterized in that component A is polyvinyl chloride；Component B
For antimony oxide；By weight, regenerated cellulose, component A and component B are respectively 100 parts, 50 parts and 35 parts.
5. a kind of regenerated celulose fibre according to claim 1, which is characterized in that component A is Vingon；Component
B is antimony pentoxide and organic phosphorus sulfate；By weight, regenerated cellulose, component A, antimony pentoxide and organic phosphorus sulphur
Hydrochlorate is respectively 100 parts, 60 parts, 20 parts 10 parts.
6. a kind of regenerated celulose fibre according to claim 1, which is characterized in that component A is polyvinyl chloride；Component B
For antimony pentoxide and antimony oxide；By weight, regenerated cellulose, component A, antimony pentoxide and antimony oxide point
It Wei not be 100 parts, 80 parts, 36 parts and 20 parts.
7. a kind of regenerated celulose fibre according to claim 1, which is characterized in that the preparation side of regenerated celulose fibre
Method specific steps are as follows:
S1, it weighs to put into beating equipment after regenerated cellulose corresponding to dry weight by weight and is beaten, obtain fibre
Tie up plain pulp C；
S2, component A is weighed by weight, obtain raw material D；Component B is weighed by weight, obtains raw material E；
S3, it will be stirred in component B addition blender, and component A be at the uniform velocity added in blender and stirs to get mixture F；
S4, mixture F and cellulose pulp C is put into uniform stirring in mixing tank, obtains mixture G；
S5, mixture G and dilute alkaline soln are subjected to cross jet flow high pressure mixing, obtain mixture H；And by mixture H again into
Row cross jet flow high pressure mixing, obtains mixture I；
S6, the viscosity for mixture I being sent into storage tank and being added into storage tank dilute alkaline soln adjustment mixture I, are mixed
Close object J；Again de-soak twice is filtered to mixture J three times, obtains mixture K；Mixture K is added in ageing can body and equal
Even stirring obtains mixture L；
S6, mixture L and carbon disulfide are acted on, obtains mixture M；
S7, spinning is carried out to mixture M and is solidified in acid solution, obtain tow N；
S8, to tow N carry out refining removal of impurities obtain product O；Product O is successively dried, is done temperature drawing-off at 135~155 DEG C
It balances, crumple, shear and is packaged with secondary retraction, regain, obtain product P.
8. a kind of regenerated celulose fibre according to claim 7, which is characterized in that product N also carries out spinneret drawing-off, modeling
Property drawing-off and fiber retraction processing.
9. a kind of regenerated celulose fibre according to claim 7, which is characterized in that the mixing speed of blender be 39~
41r/min, mixing time 30min；Component A is sent into blender with the speed of 5kg/min；Blender after the completion of component A is added
Continue stirring 22 minutes.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112981663A (en) * | 2021-02-18 | 2021-06-18 | 天津市元生泰科技有限公司 | Novel magnetic balance garment and production method thereof |
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| CN105473775A (en) * | 2013-08-23 | 2016-04-06 | 株式会社钟化 | Flame-retardant fabric, method for producing same and fire protective clothes comprising same |
| CN107636217A (en) * | 2015-06-01 | 2018-01-26 | 株式会社钟化 | Flame-retardant fabric and the protective garment for having used it |
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| US3575898A (en) * | 1968-06-20 | 1971-04-20 | Beaunit Corp | Polyvinyl chloride-antimony oxide flame-retardant mixtures for cellulosic spinning dopes |
| US4123398A (en) * | 1977-05-25 | 1978-10-31 | International Telephone And Telegraph Corporation | Flame resistant cellulosic product containing antimony pentoxide and polyvinyl bromide |
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Application publication date: 20190730 |