CN102352539B - Manufacturing method of silicon-nitrogen containing environmental protection and flame retardant viscose staple fiber - Google Patents
Manufacturing method of silicon-nitrogen containing environmental protection and flame retardant viscose staple fiber Download PDFInfo
- Publication number
- CN102352539B CN102352539B CN2011102119632A CN201110211963A CN102352539B CN 102352539 B CN102352539 B CN 102352539B CN 2011102119632 A CN2011102119632 A CN 2011102119632A CN 201110211963 A CN201110211963 A CN 201110211963A CN 102352539 B CN102352539 B CN 102352539B
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- CN
- China
- Prior art keywords
- retardant
- viscose
- silicon
- fire retardant
- glue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000297 Rayon Polymers 0.000 title claims abstract description 77
- 239000003063 flame retardant Substances 0.000 title claims abstract description 44
- 239000000835 fiber Substances 0.000 title claims abstract description 43
- UMVBXBACMIOFDO-UHFFFAOYSA-N [N].[Si] Chemical compound [N].[Si] UMVBXBACMIOFDO-UHFFFAOYSA-N 0.000 title claims abstract description 31
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 230000007613 environmental effect Effects 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 57
- 238000000034 method Methods 0.000 claims abstract description 20
- 238000009987 spinning Methods 0.000 claims abstract description 20
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 17
- 238000002156 mixing Methods 0.000 claims abstract description 13
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000008234 soft water Substances 0.000 claims abstract description 7
- 238000002166 wet spinning Methods 0.000 claims abstract description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000003292 glue Substances 0.000 claims description 56
- 239000000243 solution Substances 0.000 claims description 47
- 238000002485 combustion reaction Methods 0.000 claims description 17
- 239000003112 inhibitor Substances 0.000 claims description 16
- 238000005406 washing Methods 0.000 claims description 15
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 12
- 239000012757 flame retardant agent Substances 0.000 claims description 12
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 12
- 238000001914 filtration Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 229920006335 epoxy glue Polymers 0.000 claims description 9
- 238000006477 desulfuration reaction Methods 0.000 claims description 8
- 230000023556 desulfurization Effects 0.000 claims description 8
- 238000012805 post-processing Methods 0.000 claims description 8
- 238000004061 bleaching Methods 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 238000002347 injection Methods 0.000 claims description 6
- 239000007924 injection Substances 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 6
- 235000011152 sodium sulphate Nutrition 0.000 claims description 6
- 235000010265 sodium sulphite Nutrition 0.000 claims description 6
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 6
- 229960001763 zinc sulfate Drugs 0.000 claims description 6
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 6
- 230000035800 maturation Effects 0.000 claims description 4
- 238000002203 pretreatment Methods 0.000 claims description 4
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 3
- 206010033546 Pallor Diseases 0.000 claims description 2
- 238000009897 hydrogen peroxide bleaching Methods 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 claims description 2
- 239000004753 textile Substances 0.000 abstract description 8
- 238000005520 cutting process Methods 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 238000000465 moulding Methods 0.000 abstract 1
- 230000000979 retarding effect Effects 0.000 abstract 1
- 230000005070 ripening Effects 0.000 abstract 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 abstract 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 230000009970 fire resistant effect Effects 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 239000012744 reinforcing agent Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000003197 gene knockdown Methods 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Abstract
Description
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2011102119632A CN102352539B (en) | 2011-07-27 | 2011-07-27 | Manufacturing method of silicon-nitrogen containing environmental protection and flame retardant viscose staple fiber |
Applications Claiming Priority (1)
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CN2011102119632A CN102352539B (en) | 2011-07-27 | 2011-07-27 | Manufacturing method of silicon-nitrogen containing environmental protection and flame retardant viscose staple fiber |
Publications (2)
Publication Number | Publication Date |
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CN102352539A CN102352539A (en) | 2012-02-15 |
CN102352539B true CN102352539B (en) | 2013-05-29 |
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CN2011102119632A Expired - Fee Related CN102352539B (en) | 2011-07-27 | 2011-07-27 | Manufacturing method of silicon-nitrogen containing environmental protection and flame retardant viscose staple fiber |
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CN (1) | CN102352539B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106012073A (en) * | 2016-07-26 | 2016-10-12 | 北京赛欧兰阻燃纤维有限公司 | Production method and production line of silicon-nitrogen flame retardant viscose fiber |
Families Citing this family (14)
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---|---|---|---|---|
CN103668522B (en) * | 2013-12-12 | 2015-09-09 | 青岛大学 | A kind of preparation method of water-insoluble calcium silicates Fire resistant viscose fiber |
CN103696030B (en) * | 2013-12-12 | 2015-09-02 | 青岛大学 | A kind of preparation method of water-insoluble zirconium silicate fire-resistant viscose fiber |
CN103789858B (en) * | 2014-01-27 | 2015-12-30 | 刘承修 | A kind of environment-friendly type thermostable durable flame-retardant fiber and preparation method thereof |
CN104141224B (en) * | 2014-08-06 | 2016-02-10 | 宜宾海丝特纤维有限责任公司 | A kind of spinning cake quick wash technique |
CN105350132B (en) * | 2015-09-28 | 2017-03-29 | 北京赛欧兰阻燃纤维有限公司 | The blending of organic silazane fire retardant viscose short filament and aramid fiber 1313 |
CN105350131B (en) * | 2015-09-28 | 2017-03-01 | 北京赛欧兰阻燃纤维有限公司 | Organic silazane fire retardant viscose short filament and the blending of flame-retardant acrylic fibre |
CN105350133B (en) * | 2015-09-28 | 2017-04-05 | 北京赛欧兰阻燃纤维有限公司 | The blending of organic silazane fire retardant viscose short filament and polyimides |
CN105113079B (en) * | 2015-09-28 | 2017-03-29 | 北京赛欧兰阻燃纤维有限公司 | The blending of organic silazane fire retardant viscose short filament, Pilus Caprae seu Oviss and conductive fiber |
CN106012074B (en) * | 2016-07-26 | 2018-12-18 | 北京赛欧兰阻燃纤维有限公司 | Silicon-nitrogenated flame retardant method is added before a kind of spinning |
CN106222805B (en) * | 2016-07-26 | 2018-09-28 | 北京赛欧兰阻燃纤维有限公司 | A method of reducing organic silazane fire resistance fibre residual sulfur content |
CN107475794B (en) * | 2017-08-18 | 2021-10-29 | 山东银鹰化纤有限公司 | Silicon-nitrogen flame-retardant high-wet-modulus viscose fiber and preparation method thereof |
CN107557890B (en) * | 2017-09-05 | 2020-04-03 | 宜宾海丝特纤维有限责任公司 | Production process of nitrogen-phosphorus flame-retardant viscose filament yarn |
CN109440474B (en) * | 2018-11-03 | 2021-06-08 | 阜宁澳洋科技有限责任公司 | Low-specific-gravity flame-retardant viscose fiber and manufacturing method thereof |
CN111534874B (en) * | 2020-04-24 | 2021-08-13 | 江南大学 | Preparation method of low-smoke anti-melting flame-retardant fiber |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1989009649A1 (en) * | 1988-04-05 | 1989-10-19 | Shinkohjinkasei Co., Ltd. | Highly functional regenerated cellulose composition |
CN100494524C (en) * | 2007-05-17 | 2009-06-03 | 山东海龙股份有限公司 | Method for preparing cellulose and silicon dioxide composite coloured fiber and coloured fiber made thereby |
KR101175330B1 (en) * | 2007-09-07 | 2012-08-20 | 코오롱인더스트리 주식회사 | Flame-retardant cellulose filament fiber, tire cord, and method for preparing the same |
CN101387013A (en) * | 2008-05-14 | 2009-03-18 | 中原工学院 | Environment friendly flame-retardant viscose fiber manufacturing technology |
CN101724926A (en) * | 2009-11-18 | 2010-06-09 | 马晓宁 | Spinning process of environment-friendly flame retarding flat viscose yarn |
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- 2011-07-27 CN CN2011102119632A patent/CN102352539B/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106012073A (en) * | 2016-07-26 | 2016-10-12 | 北京赛欧兰阻燃纤维有限公司 | Production method and production line of silicon-nitrogen flame retardant viscose fiber |
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CN102352539A (en) | 2012-02-15 |
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C06 | Publication | ||
PB01 | Publication | ||
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ASS | Succession or assignment of patent right |
Free format text: FORMER OWNER: ZHENG RUIMIN Effective date: 20120524 Owner name: HANGZHOU AUTOON SCIENCE AND TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: HANGZHOU AUTOON SPECIAL FIBRE TECHNOLOGY CO., LTD. Effective date: 20120524 |
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C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20120524 Address after: 310012, Hangzhou, Zhejiang Province, Zhejiang Province, Hangzhou City, Xihu District ancient Pier Road No. 98, Xicheng new seat, 6 A-3 Applicant after: Hangzhou Autoon Technology Co.,Ltd. Address before: 310012, Hangzhou, Zhejiang Province, 98 ancient Pier Road, Xicheng new seat, 6 floor, A-3, Xihu District Applicant before: HANGZHOU AUTOON FIBRE TECHNOLOGY Co.,Ltd. Co-applicant before: Zheng Ruimin |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee | ||
CP01 | Change in the name or title of a patent holder |
Address after: 310012, Hangzhou, Zhejiang Province, 98 ancient Pier Road, Xicheng new seat, 6 floor, A-3, Xihu District Patentee after: HANGZHOU AUTOON ENVIRONMENTAL TECHNOLOGY STOCK Corp. Address before: 310012, Hangzhou, Zhejiang Province, 98 ancient Pier Road, Xicheng new seat, 6 floor, A-3, Xihu District Patentee before: Hangzhou Autoon Technology Co.,Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130529 Termination date: 20210727 |