CN110050110B - 延长NOx固定来源的排放系统中老化的SCR催化剂床使用寿命的方法 - Google Patents

延长NOx固定来源的排放系统中老化的SCR催化剂床使用寿命的方法 Download PDF

Info

Publication number
CN110050110B
CN110050110B CN201780074385.8A CN201780074385A CN110050110B CN 110050110 B CN110050110 B CN 110050110B CN 201780074385 A CN201780074385 A CN 201780074385A CN 110050110 B CN110050110 B CN 110050110B
Authority
CN
China
Prior art keywords
catalyst
exhaust gas
ammonia
nitrogen
scr
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201780074385.8A
Other languages
English (en)
Chinese (zh)
Other versions
CN110050110A (zh
Inventor
P·J·安德森
K·多拉
C·克哈拉夫
D·雷普
T·叶
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Publication of CN110050110A publication Critical patent/CN110050110A/zh
Application granted granted Critical
Publication of CN110050110B publication Critical patent/CN110050110B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D25/00—Component parts, details, or accessories, not provided for in, or of interest apart from, other groups
    • F01D25/30—Exhaust heads, chambers, or the like
    • F01D25/305—Exhaust heads, chambers, or the like with fluid, e.g. liquid injection
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N13/00—Exhaust or silencing apparatus characterised by constructional features
    • F01N13/009—Exhaust or silencing apparatus characterised by constructional features having two or more separate purifying devices arranged in series
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/105—General auxiliary catalysts, e.g. upstream or downstream of the main catalyst
    • F01N3/106—Auxiliary oxidation catalysts
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
    • F01N3/206—Adding periodically or continuously substances to exhaust gases for promoting purification, e.g. catalytic material in liquid form, NOx reducing agents
    • F01N3/2066—Selective catalytic reduction [SCR]
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2370/00—Selection of materials for exhaust purification
    • F01N2370/02—Selection of materials for exhaust purification used in catalytic reactors
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2370/00—Selection of materials for exhaust purification
    • F01N2370/02—Selection of materials for exhaust purification used in catalytic reactors
    • F01N2370/04—Zeolitic material
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2450/00—Methods or apparatus for fitting, inserting or repairing different elements
    • F01N2450/40—Retrofitting exhaust apparatus
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/18—Ammonia
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2590/00—Exhaust or silencing apparatus adapted to particular use, e.g. for military applications, airplanes, submarines
    • F01N2590/10—Exhaust or silencing apparatus adapted to particular use, e.g. for military applications, airplanes, submarines for stationary applications
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2610/00—Adding substances to exhaust gases
    • F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Exhaust Gas After Treatment (AREA)
CN201780074385.8A 2016-12-01 2017-11-29 延长NOx固定来源的排放系统中老化的SCR催化剂床使用寿命的方法 Active CN110050110B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662428589P 2016-12-01 2016-12-01
US62/428,589 2016-12-01
PCT/GB2017/053599 WO2018100368A1 (en) 2016-12-01 2017-11-29 METHOD OF EXTENDING THE USEFUL LIFE OF AN AGED SCR CATALYST BED IN AN EXHAUST SYSTEM OF A STATIONARY SOURCE OF NOx

Publications (2)

Publication Number Publication Date
CN110050110A CN110050110A (zh) 2019-07-23
CN110050110B true CN110050110B (zh) 2021-07-06

Family

ID=60812092

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201780074385.8A Active CN110050110B (zh) 2016-12-01 2017-11-29 延长NOx固定来源的排放系统中老化的SCR催化剂床使用寿命的方法

Country Status (7)

Country Link
US (1) US10961871B2 (enExample)
EP (1) EP3548720B1 (enExample)
JP (1) JP7624802B2 (enExample)
KR (1) KR20190086544A (enExample)
CN (1) CN110050110B (enExample)
GB (1) GB2570831A (enExample)
WO (1) WO2018100368A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110449181A (zh) * 2019-08-16 2019-11-15 中国汽车技术研究中心有限公司 一种分子筛催化涂层剩余浆料重复再利用方法及其在scr中的应用
BR112022020204A2 (pt) * 2020-04-09 2022-11-22 Basf Corp Catalisador para a oxidação de no, método para preparar um catalisador para a oxidação de no, uso de um catalisador e sistema de tratamento de gases de escape
CN113713608A (zh) * 2021-08-26 2021-11-30 复旦大学 一种用于CO和NOx同时去除的催化剂联用方法
US11635010B1 (en) 2021-10-05 2023-04-25 Umicore Ag & Co. Kg Combustion turbine and heat recovery system combination with SCR reactor assembly, and methods of assembling and using the same

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008132452A3 (en) * 2007-04-26 2009-02-26 Johnson Matthey Plc Transition metal/zeolite scr catalysts
WO2011045252A1 (en) * 2009-10-14 2011-04-21 Basf Se Copper containing levyne molecular sieve for selective reduction of nox
CN103702745A (zh) * 2011-05-31 2014-04-02 庄信万丰股份有限公司 双功能催化过滤器
WO2014083431A2 (en) * 2012-11-30 2014-06-05 Johnson Matthey Public Limited Company Ammonia oxidation catalyst
WO2014085354A1 (en) * 2012-11-30 2014-06-05 Corning Incorporated Method, apparatus, and system to control selective catalytic reduction (scr) catalyst ammonia slip during high temperature transitions
CN104847460A (zh) * 2014-02-14 2015-08-19 道依茨股份公司 用于净化柴油发动机废气的方法
WO2015017516A3 (en) * 2013-07-30 2015-09-03 Johnson Matthey Public Limited Company Ammonia slip catalyst
CN105358250A (zh) * 2013-01-29 2016-02-24 庄信万丰股份有限公司 氨氧化催化剂
GB2538132A (en) * 2015-02-20 2016-11-09 Johnson Matthey Plc Exhaust system for power generating apparatus

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3935417B2 (ja) 2002-11-01 2007-06-20 中国電力株式会社 脱硝触媒管理方法および脱硝触媒管理装置
US7390471B2 (en) 2005-11-17 2008-06-24 Siemens Power Generation, Inc. Apparatus and method for catalytic treatment of exhaust gases
US7727499B2 (en) 2007-09-28 2010-06-01 Basf Catalysts Llc Ammonia oxidation catalyst for power utilities
GB0809841D0 (en) * 2008-05-30 2008-07-09 Johnson Matthey Plc System for treating a gas stream
US8329127B2 (en) 2010-09-15 2012-12-11 Johnson Matthey Public Limited Company Combined slip catalyst and hydrocarbon exotherm catalyst
CN104220710B (zh) * 2012-03-29 2017-11-14 沃尔沃建筑设备公司 诊断选择性催化还原催化剂的方法
US8997467B2 (en) * 2013-03-15 2015-04-07 Caterpillar Inc. System and method for post-shutdown temperature management and purge
US9517437B2 (en) 2015-03-02 2016-12-13 General Electric Company Systems and methods for controlling aftertreatment systems
RU2017137625A (ru) 2015-03-30 2019-04-30 Басф Корпорейшн Катализированные фильтры с концевым покрытием для выхлопного газа двигателя, работающего на обедненной топливной смеси
US9937489B2 (en) * 2015-06-18 2018-04-10 Johnson Matthey Public Limited Company Exhaust system without a DOC having an ASC acting as a DOC in a system with an SCR catalyst before the ASC
BR112017027173B1 (pt) * 2015-06-18 2021-09-28 Johnson Matthey Public Limited Company Catalisador de vazamento de amônia, método para melhorar o rendimento de n2 de amônia em um gás de escape, e, método para reduzir a formação de n2o de nh3 em um gás de escape

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008132452A3 (en) * 2007-04-26 2009-02-26 Johnson Matthey Plc Transition metal/zeolite scr catalysts
WO2011045252A1 (en) * 2009-10-14 2011-04-21 Basf Se Copper containing levyne molecular sieve for selective reduction of nox
CN103702745A (zh) * 2011-05-31 2014-04-02 庄信万丰股份有限公司 双功能催化过滤器
WO2014083431A2 (en) * 2012-11-30 2014-06-05 Johnson Matthey Public Limited Company Ammonia oxidation catalyst
WO2014085354A1 (en) * 2012-11-30 2014-06-05 Corning Incorporated Method, apparatus, and system to control selective catalytic reduction (scr) catalyst ammonia slip during high temperature transitions
CN105358250A (zh) * 2013-01-29 2016-02-24 庄信万丰股份有限公司 氨氧化催化剂
WO2015017516A3 (en) * 2013-07-30 2015-09-03 Johnson Matthey Public Limited Company Ammonia slip catalyst
CN105555403A (zh) * 2013-07-30 2016-05-04 庄信万丰股份有限公司 氨逸出催化剂
CN104847460A (zh) * 2014-02-14 2015-08-19 道依茨股份公司 用于净化柴油发动机废气的方法
GB2538132A (en) * 2015-02-20 2016-11-09 Johnson Matthey Plc Exhaust system for power generating apparatus

Also Published As

Publication number Publication date
CN110050110A (zh) 2019-07-23
US10961871B2 (en) 2021-03-30
GB2570831A (en) 2019-08-07
EP3548720B1 (en) 2021-03-17
GB201906751D0 (en) 2019-06-26
EP3548720A1 (en) 2019-10-09
JP2020515752A (ja) 2020-05-28
WO2018100368A1 (en) 2018-06-07
KR20190086544A (ko) 2019-07-22
JP7624802B2 (ja) 2025-02-07
US20190383174A1 (en) 2019-12-19

Similar Documents

Publication Publication Date Title
EP3142773B1 (en) Catalytic article for treating exhaust gas
EP3463629B1 (en) Method and system for treating nox in exhaust gas from stationary emission sources
US9597636B2 (en) Zoned catalyst for treating exhaust gas
US9579638B2 (en) Ammonia slip catalyst
EP2318764B1 (en) A REACTOR SYSTEM FOR REDUCING NOx EMISSIONS FROM BOILERS
JP2008531260A (ja) 炭化水素またはアルコールにより排気流中の窒素酸化物を還元するための触媒および方法
US11819828B2 (en) Multi-function catalyst article for treating both CO and NOx in stationary emission source exhaust gas
KR20160036586A (ko) 텅스텐/티타니아 산화 촉매
BR112019019507A2 (pt) artigo catalisador, sistema de tratamento de emissões, e, método para tratar um fluxo de um gás de escape de combustão.
JP7624802B2 (ja) ＮＯｘの固定汚染源の排気システムにおける劣化したＳＣＲ触媒床の使用寿命を延ばす方法
GB2538414A (en) Catalytic article for treating exhaust gas
HK40063889A (en) Multi-function catalyst article for treating both co and nox in stationary emission source exhaust gas
KR20240004113A (ko) 가스터빈 복합화력 발전소에서 기동 및 정지시 및 정상운전시발생하는 질소산화물 제거 촉매
RU2772861C2 (ru) Каталитическое изделие для обработки выхлопных газов

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant