CN110041701B - 一种球形聚苯胺/石墨烯复合膜材料及其制备方法与应用 - Google Patents
一种球形聚苯胺/石墨烯复合膜材料及其制备方法与应用 Download PDFInfo
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- CN110041701B CN110041701B CN201910336529.3A CN201910336529A CN110041701B CN 110041701 B CN110041701 B CN 110041701B CN 201910336529 A CN201910336529 A CN 201910336529A CN 110041701 B CN110041701 B CN 110041701B
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- polyaniline
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- aniline
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- 229920000767 polyaniline Polymers 0.000 title claims abstract description 69
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 68
- 239000002131 composite material Substances 0.000 title claims abstract description 54
- 239000012528 membrane Substances 0.000 title claims abstract description 31
- 239000000463 material Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 35
- 239000002904 solvent Substances 0.000 claims abstract description 33
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000007772 electrode material Substances 0.000 claims abstract description 10
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 70
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 34
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- 239000000243 solution Substances 0.000 claims description 17
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 16
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 14
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 13
- 239000007800 oxidant agent Substances 0.000 claims description 13
- 230000001590 oxidative effect Effects 0.000 claims description 13
- 239000011259 mixed solution Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000003995 emulsifying agent Substances 0.000 claims description 9
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 8
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 7
- 229960005070 ascorbic acid Drugs 0.000 claims description 7
- 235000010323 ascorbic acid Nutrition 0.000 claims description 7
- 239000011668 ascorbic acid Substances 0.000 claims description 7
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 7
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 4
- 229940071870 hydroiodic acid Drugs 0.000 claims description 4
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 4
- 229920000053 polysorbate 80 Polymers 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 3
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims description 3
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 claims description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 3
- 239000000945 filler Substances 0.000 abstract description 5
- 230000007547 defect Effects 0.000 abstract description 4
- 238000010556 emulsion polymerization method Methods 0.000 abstract description 2
- -1 polytetrafluoroethylene Polymers 0.000 description 8
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 8
- 239000004810 polytetrafluoroethylene Substances 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 7
- 239000010410 layer Substances 0.000 description 7
- 230000014759 maintenance of location Effects 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000003990 capacitor Substances 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 239000011229 interlayer Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 238000005411 Van der Waals force Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 230000021615 conjugation Effects 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/026—Wholly aromatic polyamines
- C08G73/0266—Polyanilines or derivatives thereof
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Abstract
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CN201910336529.3A CN110041701B (zh) | 2019-04-25 | 2019-04-25 | 一种球形聚苯胺/石墨烯复合膜材料及其制备方法与应用 |
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CN201910336529.3A CN110041701B (zh) | 2019-04-25 | 2019-04-25 | 一种球形聚苯胺/石墨烯复合膜材料及其制备方法与应用 |
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CN110041701A CN110041701A (zh) | 2019-07-23 |
CN110041701B true CN110041701B (zh) | 2021-11-19 |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1667021A (zh) * | 2005-03-23 | 2005-09-14 | 南京大学 | 聚苯胺纳米结构的可控合成方法和用途 |
CN101798462A (zh) * | 2010-03-26 | 2010-08-11 | 武汉工程大学 | 石墨烯/导电高分子复合膜及其制备方法 |
CN105504277A (zh) * | 2015-12-30 | 2016-04-20 | 上海应用技术学院 | 一种高度有序多孔的石墨烯/聚苯胺复合材料及其制备方法 |
CN109535419A (zh) * | 2018-12-05 | 2019-03-29 | 中国科学技术大学 | 聚苯胺微球及其制备方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6569651B1 (en) * | 1999-06-16 | 2003-05-27 | The United States Of America As Represented By The Secretary Of The Army | Enzymatic polymerization of anilines or phenols around a template |
US8497225B2 (en) * | 2007-08-27 | 2013-07-30 | Nanotek Instruments, Inc. | Method of producing graphite-carbon composite electrodes for supercapacitors |
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2019
- 2019-04-25 CN CN201910336529.3A patent/CN110041701B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1667021A (zh) * | 2005-03-23 | 2005-09-14 | 南京大学 | 聚苯胺纳米结构的可控合成方法和用途 |
CN101798462A (zh) * | 2010-03-26 | 2010-08-11 | 武汉工程大学 | 石墨烯/导电高分子复合膜及其制备方法 |
CN105504277A (zh) * | 2015-12-30 | 2016-04-20 | 上海应用技术学院 | 一种高度有序多孔的石墨烯/聚苯胺复合材料及其制备方法 |
CN109535419A (zh) * | 2018-12-05 | 2019-03-29 | 中国科学技术大学 | 聚苯胺微球及其制备方法 |
Non-Patent Citations (2)
Title |
---|
Hierarchical assembly of graphene/polyaniline nanostructures to synthesize free-standing supercapacitor electrode;Mahbub Hassan等;《Composites science and technology》;20140424;第98卷;第1-8页 * |
Vertically oriented polyaniline-graphene nanocomposite based on functionalized graphene for supercapacitor electrode;Zhao qiang等;《J. APPL. POLYM. SCI.》;20170116;第134卷(第19期);44808 * |
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