CN110038575B - 通过捏合和浸渍制备特定的选择性加氢催化剂的方法 - Google Patents

通过捏合和浸渍制备特定的选择性加氢催化剂的方法 Download PDF

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CN110038575B
CN110038575B CN201910035628.8A CN201910035628A CN110038575B CN 110038575 B CN110038575 B CN 110038575B CN 201910035628 A CN201910035628 A CN 201910035628A CN 110038575 B CN110038575 B CN 110038575B
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acid
catalyst
precursor
organic compound
nickel
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CN110038575A (zh
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M.布阿莱
A-C.迪布勒伊
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IFP Energies Nouvelles IFPEN
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/48—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/36—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
CN201910035628.8A 2018-01-15 2019-01-15 通过捏合和浸渍制备特定的选择性加氢催化剂的方法 Active CN110038575B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1850281A FR3076746B1 (fr) 2018-01-15 2018-01-15 Procede de preparation d'un catalyseur particulier d'hydrogenation selective par malaxage et impregnation
FR1850281 2018-01-15

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CN110038575A CN110038575A (zh) 2019-07-23
CN110038575B true CN110038575B (zh) 2023-10-10

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Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3099390B1 (fr) * 2019-07-31 2021-10-29 Ifp Energies Now Catalyseur comprenant une phase active de nickel sous forme de petites particules et un alliage nickel cuivre
FR3099388B1 (fr) * 2019-07-31 2021-07-16 Ifp Energies Now Catalyseur comprenant une phase active de nickel sous forme de petites particules repartie en croute et un alliage nickel cuivre
FR3099391B1 (fr) * 2019-07-31 2021-10-29 Ifp Energies Now Catalyseur comprenant une phase active de nickel sous forme de petites particules repartie en croute
FR3099389B1 (fr) * 2019-07-31 2021-07-16 Ifp Energies Now Catalyseur comprenant une phase active de nickel soufre repartie en croute
FR3099387B1 (fr) * 2019-07-31 2021-10-29 Ifp Energies Now Catalyseur comprenant une phase active de nickel repartie en croute
FR3099386B1 (fr) * 2019-07-31 2021-07-16 Ifp Energies Now Catalyseur comprenant une phase active de nickel repartie en croute et un alliage nickel cuivre
CN112742424B (zh) * 2019-10-29 2022-11-08 中国石油化工股份有限公司 一种重质油加氢处理催化剂制备方法
FR3104461B1 (fr) * 2019-12-17 2022-06-17 Ifp Energies Now Catalyseur d’hydrogenation selective obtenu a partir de sels fondus et d’un additif organique
FR3104462B1 (fr) * 2019-12-17 2022-06-10 Ifp Energies Now Catalyseur pour l’hydrogenation de composes aromatiques obtenu a partir de sels fondus et d’un additif organique
CN112221504A (zh) * 2020-11-12 2021-01-15 北京旭阳科技有限公司 己内酰胺加氢精制催化剂的制备方法、催化剂以及使用其精制己内酰胺的方法

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4016108A (en) * 1976-01-05 1977-04-05 Exxon Research And Engineering Company Preparation of catalysts of predetermined pore size distribution and pore volume
CN101172233A (zh) * 2006-11-01 2008-05-07 中国石油化工股份有限公司 一种溶剂油加氢精制催化剂及其制备方法
CN102056664A (zh) * 2008-04-11 2011-05-11 埃克森美孚研究工程公司 负载型加氢工艺催化剂的再生和复原
CN103501902A (zh) * 2011-03-18 2014-01-08 Ifp新能源公司 包含来自viii和vib族的金属的用于加氢处理的催化剂，和使用柠檬酸和琥珀酸c1-c4二烷基酯的制备方法
CN103801287A (zh) * 2012-11-05 2014-05-21 北京低碳清洁能源研究所 一种负载型耐硫甲烷化催化剂的制备方法
CN104053502A (zh) * 2011-12-21 2014-09-17 Ifp新能源公司 制备使用至少一种有机添加剂制备的基于第viii族金属的催化剂的方法、以及使用所述催化剂的选择性加氢方法
CN106457236A (zh) * 2014-03-10 2017-02-22 日本凯琴株式会社 加氢处理催化剂、制备所述催化剂的方法以及使用所述催化剂进行的烃油的加氢处理方法
CN106604907A (zh) * 2014-06-13 2017-04-26 Ifp 新能源公司 具有高连通度的非晶中孔氧化铝和其制备方法
CN106604978A (zh) * 2014-06-13 2017-04-26 Ifp 新能源公司 具有大于300纳米中值大孔直径的中孔和大孔共混镍活性相的催化剂及其在氢化中的用途
CN106660019A (zh) * 2014-06-13 2017-05-10 Ifp 新能源公司 通过共研获得的具有活性相的介孔与大孔催化剂 、其制备方法及其用于渣油的加氢处理的用途
CN107454860A (zh) * 2014-06-13 2017-12-08 Ifp 新能源公司 具有50至300纳米中值大孔直径的中孔和大孔共混镍活性相催化剂及其在氢化中的用途

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2963344B1 (fr) * 2010-07-29 2012-07-27 IFP Energies Nouvelles Procede d'hydrogenation selective en presence d'un catalyseur a base d'un metal du groupe viii prepare au moyen d'au moins un oligosaccharide cyclique
FR3022162B1 (fr) * 2014-06-13 2021-05-07 Ifp Energies Now Catalyseur a base de nickel mesoporeux et macroporeux ayant un diametre median macroporeux compris entre 50 nm et 200 nm et son utilisation en hydrogenation

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4016108A (en) * 1976-01-05 1977-04-05 Exxon Research And Engineering Company Preparation of catalysts of predetermined pore size distribution and pore volume
CN101172233A (zh) * 2006-11-01 2008-05-07 中国石油化工股份有限公司 一种溶剂油加氢精制催化剂及其制备方法
CN102056664A (zh) * 2008-04-11 2011-05-11 埃克森美孚研究工程公司 负载型加氢工艺催化剂的再生和复原
CN103501902A (zh) * 2011-03-18 2014-01-08 Ifp新能源公司 包含来自viii和vib族的金属的用于加氢处理的催化剂，和使用柠檬酸和琥珀酸c1-c4二烷基酯的制备方法
CN104053502A (zh) * 2011-12-21 2014-09-17 Ifp新能源公司 制备使用至少一种有机添加剂制备的基于第viii族金属的催化剂的方法、以及使用所述催化剂的选择性加氢方法
CN103801287A (zh) * 2012-11-05 2014-05-21 北京低碳清洁能源研究所 一种负载型耐硫甲烷化催化剂的制备方法
CN106457236A (zh) * 2014-03-10 2017-02-22 日本凯琴株式会社 加氢处理催化剂、制备所述催化剂的方法以及使用所述催化剂进行的烃油的加氢处理方法
CN106604907A (zh) * 2014-06-13 2017-04-26 Ifp 新能源公司 具有高连通度的非晶中孔氧化铝和其制备方法
CN106604978A (zh) * 2014-06-13 2017-04-26 Ifp 新能源公司 具有大于300纳米中值大孔直径的中孔和大孔共混镍活性相的催化剂及其在氢化中的用途
CN106660019A (zh) * 2014-06-13 2017-05-10 Ifp 新能源公司 通过共研获得的具有活性相的介孔与大孔催化剂 、其制备方法及其用于渣油的加氢处理的用途
CN107454860A (zh) * 2014-06-13 2017-12-08 Ifp 新能源公司 具有50至300纳米中值大孔直径的中孔和大孔共混镍活性相催化剂及其在氢化中的用途

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FR3076746B1 (fr) 2022-07-01
CN110038575A (zh) 2019-07-23

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