CN109970387A - A kind of paste ceramic tile bond and preparation method thereof - Google Patents
A kind of paste ceramic tile bond and preparation method thereof Download PDFInfo
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- CN109970387A CN109970387A CN201910126721.XA CN201910126721A CN109970387A CN 109970387 A CN109970387 A CN 109970387A CN 201910126721 A CN201910126721 A CN 201910126721A CN 109970387 A CN109970387 A CN 109970387A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/30—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds
- C04B26/32—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Other silicon-containing organic compounds; Boron-organic compounds containing silicon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
- C04B2111/00646—Masonry mortars
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Finishing Walls (AREA)
Abstract
The present invention relates to ceramic tile bond fields, a kind of paste ceramic tile bond is provided, by weight, raw material includes at least, 50-100 parts of lotions, 100-250 parts of solvents, 1-6 parts of coalescing agents, 0.5-4 parts of defoaming agents, 1-10 parts of cellulose ethers, 0.1-2 parts of butylol polyethers, 300-400 parts of fillers, 300-400 parts of quartz sands.
Description
Technical field
The present invention relates to ceramic tile bond field, a kind of paste ceramic tile bond and preparation method thereof is further related to.
Background technique
Ceramic tile bond, also known as tile adhesives or glue for tile are mainly used for pasting the decoration materials such as ceramic tile, face brick, floor tile
Material, is widely used in the facing decoration places of the buildings such as inside and outside metope, ground, bathroom, kitchen.Ceramic tile bond is between ceramic tile
With the substance for playing a kind of cementation between metope, ground etc., it is desirable that have certain adhesion strength, shear strength, resist it is general
The performances such as alkali, ageing-resistant.Traditional tile paste method mostly uses cement mortar, i.e., is mixed and made into sand and cement scene simply
Cement mortar, this mortar be coated in preimpregnation or pre-wet the ceramic tile back side, the ceramic tile for being coated with mortar is pressed onto be soaked in advance
On surface, ceramic tile is then touched, to guarantee that ceramic tile has consistent flatness.The main purpose of this process is to be compacted mortar,
Enter cement granules inside the porous back side of ceramic tile and in porous substrate.The shortcomings that this mortar is that cohesive force is weak, durable
Property it is poor, be easy peel off, construction material dosage it is big.Meanwhile mortar must also in proper proportions, consistency mixed, and pasted
It before brick, needs to coat suitable mortar at the back side of ceramic tile, this just needs to rely on the qualification and sense of responsibility of skilled worker.
So construction quality is difficult to ensure.
Decylene glycol ester is a kind of common coalescing agent in ceramic tile bond, and decylene glycol ester is a kind of effective film forming
Auxiliary agent can substantially reduce minimum film formation temperature, hence it is evident that improve filming performance, improve the glossiness, intensity and anti-powder of paint film
Change performance, promote levelability, assigns adhesive with good toughness and elasticity, and freeze-thaw stability can be improved, but at
It needs to be added in two portions in film auxiliary agent decylene glycol ester addition system, is also easy to generate gelatin phenomenon.In the composition of ceramic tile bond
In, cellulose ether is that a kind of additive amount is very low, but can significantly improve the important addition of wet mortar mix and working performance
Agent, and it is capable of providing other performances of fresh mortar.The chemical parameters such as molecular weight, granularity, the degree of substitution of cellulose ether can
The water-retaining property etc. for influencing mortar, so that it will not separate, Qinshui phenomenon, the rapid development of ceramic tile bond is the exploitation of cellulose ether
Opportunities and challenges are provided with application, but when the cellulose ether level in ceramic tile bond is excessive, will lead to binder
Flexural strength can weaken.
Summary of the invention
In order to solve the above technical problems, the first aspect of the invention provides a kind of paste ceramic tile bond, presses
Parts by weight meter, raw material include at least, 50-100 parts of lotions, 100-250 parts of solvents, 1-6 parts of coalescing agents, 0.5-4 parts of defoaming agents,
1-10 parts of cellulose ethers, 0.1-2 parts of butylol polyethers, 300-400 parts of fillers, 300-400 parts of quartz sands.
As a kind of perferred technical scheme, heretofore described paste ceramic tile bond, by weight, raw material is at least
It include 60-90 parts of lotions, 140-220 parts of solvents, 2-5 parts of coalescing agents, 1-3 parts of defoaming agents, 2-8 parts of cellulose ethers, 1-1.6
Part butylol polyether, 330-370 parts of fillers, 340-360 parts of quartz sands.
As a kind of perferred technical scheme, heretofore described cellulose ether is selected from hydroxyethyl ether cellulose, hydroxypropyl
One of cellulose ether, methyl hydroxyethylcellulose, modified cellulose ethers or a variety of combinations.
As a kind of perferred technical scheme, heretofore described modified cellulose ethers are the modified gas phase dioxy of cellulose ether
SiClx.
As a kind of perferred technical scheme, heretofore described butylol polyether is PPG-26- butylol polyether -26.
As a kind of perferred technical scheme, heretofore described lotion is selected from polyacrylate dispersion, styrene-propene
One of acid esters lotion, pure-acrylic emulsion, silicone resin emulsion, acrylate and vinyl acetate emulsion, silicone acrylic emulsion or a variety of combinations.
As a kind of perferred technical scheme, heretofore described solvent is selected from water, ethyl alcohol, 1- propyl alcohol, propylene glycol, fourth two
One of alcohol, ethyl alcohol or a variety of combinations.
As a kind of perferred technical scheme, heretofore described filler is selected from talcum powder, titanium dioxide, kaolin, dioxy
One of SiClx, nano aluminium oxide, coarse whiting, bentonite, mica powder, ceramic powder, barium sulfate, magnesium fluosilicate or a variety of groups
It closes.
As a kind of perferred technical scheme, the granularity of heretofore described coarse whiting is 100-400 mesh.
The second aspect of the invention provides the preparation method of paste ceramic tile bond described in one kind, include at least with
Lower step:
(1) it is separately added into defoaming agent, coalescing agent, cellulose ether in a solvent, stirs 5~10 minutes；
(2) filler and quartz sand is then added, stirs 15~30 minutes, adds lotion, stirs 10~20 minutes；
(3) it is eventually adding butylol polyether, is stirred for 15~30 minutes, is filled into bucket then to get finished product.
The utility model has the advantages that
The present invention is to provide a kind of paste ceramic tile bonds of non-cement-based, using the modified gas phase titanium dioxide of cellulose ether
Silicon can solve the phenomenon that anti-folding, compression strength reduce after cellulose ether is added, and make the anti-of heretofore described ceramic tile bond
Folding, compression strength are remarkably reinforced, meanwhile, butylol polyether is introduced in ceramic tile bond raw material of the present invention, is prepared in binder
During coalescing agent decylene glycol ester do not need to be added in two portions, avoid the generation of gelatin phenomenon, for the present invention provides
Excellent beneficial effect.
Content and other special, aspects and advantage above-mentioned in the application are easier to understand with reference to following details.
Specific embodiment
Unless otherwise indicated, from context cues or belong to the convention of the prior art, otherwise number all in the application
It is all based on weight with percentage, and test and characterizing method used is all synchronous with the submission date of the application.If existing
There is defining for the concrete term disclosed in technology inconsistent with any definition provided herein, then with provided herein
Subject to term definition.
It is further clear, complete that the technical characteristic work in technical solution is provided to the present invention With reference to embodiment
Description, not to the limitation of its protection scope.
Word " preferred ", " preferably ", " preferred " in the present invention etc. refer to, can provide certain in some cases
The embodiment of the present invention of a little beneficial effects.However, other embodiments may also under identical circumstances or in the case of other
It is preferred.In addition, not implying that other embodiments are unavailable to the statement of one or more preferred embodiments, it is not yet
It is intended to exclude other embodiments except the scope of the present invention.The source of unmentioned component is commercially available in the present invention.
The first aspect of the invention provides a kind of paste ceramic tile bond, and by weight, raw material includes at least,
50-100 parts of lotions, 100-250 parts of solvents, 1-6 parts of coalescing agents, 0.5-4 parts of defoaming agents, 1-10 parts of cellulose ethers, 0.1-2 parts
Butylol polyether, 300-400 parts of fillers, 300-400 parts of quartz sands.
In some embodiments, heretofore described paste ceramic tile bond, by weight, raw material includes at least,
60-90 parts of lotions, 140-220 parts of solvents, 2-5 parts of coalescing agents, 1-3 parts of defoaming agents, 2-8 parts of cellulose ethers, 1-1.6 parts of butanol
Polyethers, 330-370 parts of fillers, 340-360 parts of quartz sands.
In some preferred embodiments, heretofore described paste ceramic tile bond, by weight, raw material is at least
It include 70-80 parts of lotions, 160-200 parts of solvents, 3-4 parts of coalescing agents, 1.5-2.5 parts of defoaming agents, 4-6 parts of cellulose ethers,
1.2-1.4 parts of butylol polyethers, 340-360 parts of fillers, 345-355 parts of quartz sands.
In some preferred embodiments, heretofore described paste ceramic tile bond, by weight, raw material is extremely
It less include 75 parts of lotions, 180 parts of solvents, 3.5 parts of coalescing agents, 2 parts of defoaming agents, 5 parts of cellulose ethers, 1.3 parts of butylol polyethers,
350 parts of fillers, 350 parts of quartz sands.
Cellulose ether
In some embodiments, heretofore described cellulose ether is selected from hydroxyethyl ether cellulose, hydroxypropyl cellulose
One of ether, methyl hydroxyethylcellulose, modified cellulose ethers or a variety of combinations；Preferably, the cellulose ether is selected from
One of methyl hydroxyethylcellulose, modified cellulose ethers or a variety of combinations；It is furthermore preferred that the cellulose ether is to be modified
Cellulose ether.
No. CAS of the hydroxyethyl ether cellulose is 9004-62-0；No. CAS of the hydroxypropylcelluloether ether is 9004-
64-2；No. CAS of the methyl hydroxyethylcellulose is 9032-42-2.
In some embodiments, heretofore described modified cellulose ethers are the modified fumed silica of cellulose ether.
In some embodiments, the modified fumed silica of heretofore described cellulose ether the preparation method is as follows:
A: by 2-8 parts of fumed silicas, 3-8 parts of water, 1-5 parts of dehydrated alcohols, 2-7 parts of silane coupling agents, 1-7 part 12
Sodium alkyl benzene sulfonate and 0.5-2 parts of calcium carbonate are uniformly mixed, and are carried out after being mixed 2-10 hours at 40-80 DEG C, and filtering takes
Solid 1 out；
B: being first diluted to solution for Instant cellulose ether with deionized water, and with the solution impregnation solid 1, solid after infiltration
Body 1 is put into hydrochloric acid and stirs 20-50 minutes, takes out drying, obtains solid 2；The pH value of the hydrochloric acid is 2-6；
C: solid 2 being put into sodium hydroxide solution and is stirred 5-25 minutes, take out drying to get；The sodium hydroxide is molten
The pH value of liquid is 8-10.
In some preferred embodiments, the preparation method of the modified fumed silica of heretofore described cellulose ether
It is as follows:
A: by 5-6 parts of fumed silicas, 5-6 parts of water, 1.5-3 parts of dehydrated alcohols, 3-5 parts of silane coupling agents, 3-5 part ten
Dialkyl benzene sulfonic acids sodium and 0.8-1.5 parts of calcium carbonate are uniformly mixed, and are carried out after being mixed 4-8 hours at 50-60 DEG C, mistake
Solid 1 is taken out in filter；
B: being first diluted to solution for Instant cellulose ether with deionized water, and with the solution impregnation solid 1, solid after infiltration
Body 1 is put into hydrochloric acid and stirs 25-40 minutes, takes out drying, obtains solid 2；The pH value of the hydrochloric acid is 3-5；
C: solid 2 being put into sodium hydroxide solution and is stirred 10-20 minutes, take out drying to get；The sodium hydroxide is molten
The pH value of liquid is 9.
In some preferred embodiments, the preparation side of the modified fumed silica of heretofore described cellulose ether
Method is as follows:
A: by 5 parts of fumed silicas, 5.5 parts of water, 2.1 parts of dehydrated alcohols, 4.2 parts of silane coupling agents, 3.8 parts of dodecanes
Base benzene sulfonic acid sodium salt and 1.1 parts of calcium carbonate are uniformly mixed, and are carried out after being mixed 6 hours at 60 DEG C, and solid 1 is taken out in filtering；
B: being first diluted to solution for Instant cellulose ether with deionized water, and with the solution impregnation solid 1, solid after infiltration
Body 1 is put into hydrochloric acid and stirs 30 minutes, takes out drying, obtains solid 2；The pH value of the hydrochloric acid is 4；
C: solid 2 being put into sodium hydroxide solution and is stirred 15 minutes, take out drying to get；The sodium hydroxide solution
PH value be 9.
The present invention is to provide a kind of paste ceramic tile bonds, are non-cement-based, after being added excessively due to cellulose ether
Anti- folding, compression strength show the trend of reduction, are that cellulose ether is porous flexible polymer in the hole because of adhesive,
Measuring body ability cannot be played, and affects the aquation of adhesive.And using the modified gas phase dioxy of cellulose ether in the present invention
SiClx can solve the phenomenon that anti-folding, compression strength reduce after cellulose ether is added, make heretofore described ceramic tile bond
Anti- folding, compression strength is remarkably reinforced.Speculate that its possible cause is due to using the modified gas phase of cellulose ether in the present invention
Silica can solve the phenomenon that anti-folding, compression strength reduce after cellulose ether is added.The reason is that gas phase titanium dioxide
Silicon can provide the effect of skeleton, and the porous performance of fumed silica can be alleviated because cellulose ether adsorbs to form film
Influence the aquation of adhesive；Because the presence of fumed silica can destroy this film.
The Instant cellulose ether is to be surface-treated with glyoxal to cellulose ether；It can buy from Shanghai and hate smelting
Industrial Co., Ltd. can also buy from other companies.
Butylol polyether
In some embodiments, heretofore described butylol polyether is PPG-26- butylol polyether -26.
No. CAS of the PPG-26- butylol polyether -26 is 9038-95-3.
Applicant has been surprisingly found that in the present invention, during ceramic tile bond preparation, is added after butylol polyether, film forming
Auxiliary agent decylene glycol ester does not need to be added in two portions, and will not generate gelatin phenomenon.
Lotion
In some embodiments, heretofore described lotion is selected from, styrene-acrylate emulsion, pure-acrylic emulsion, has
One of machine resin emulsion, acrylate and vinyl acetate emulsion, silicone acrylic emulsion or a variety of combinations；Preferably, the lotion is selected from polypropylene
One of acid esters lotion, styrene-acrylate emulsion, pure-acrylic emulsion, silicone acrylic emulsion or a variety of combinations；It is furthermore preferred that
The lotion is selected from one of styrene-acrylate emulsion, pure-acrylic emulsion, silicone acrylic emulsion or a variety of combinations；It is the most excellent
Choosing, the lotion is selected from styrene-acrylate emulsion.
Solvent
In some embodiments, heretofore described solvent is selected from the solvent and is selected from water, ethyl alcohol, 1- propyl alcohol, the third two
One of alcohol, butanediol or a variety of combinations；Preferably, the solvent is selected from one of water, ethyl alcohol, 1- propyl alcohol or a variety of
Combination；It is furthermore preferred that the solvent is selected from one of water, ethyl alcohol or a variety of combinations；Highly preferred, the solvent is
Water.
In some embodiments, heretofore described water is deionized water.
Filler
In some embodiments, heretofore described filler is selected from talcum powder, titanium dioxide, kaolin, silica, receives
One of rice aluminium oxide, coarse whiting, bentonite, mica powder, ceramic powder, barium sulfate, magnesium fluosilicate or a variety of combinations；It is preferred that
, the filler is selected from one of talcum powder, kaolin, silica, coarse whiting, barium sulfate or a variety of combinations；More preferably
, the filler is selected from one of kaolin, silica, coarse whiting or a variety of combinations；Highly preferred, the filler is
Coarse whiting.
In some embodiments, the granularity of heretofore described coarse whiting is 100-400 mesh；Preferably, the coarse whiting
Granularity is 120-350 mesh；It is furthermore preferred that the granularity of the coarse whiting is 200-325 mesh；It is highly preferred, the granularity of the coarse whiting
For 325 mesh.
Heretofore described coarse whiting can be bought from Changxing Qing Shenggai industry Co., Ltd, can also be bought from other companies.
Quartz sand
In some embodiments, the granularity of heretofore described quartz sand is 50-300 mesh；Preferably, the quartz sand
Granularity be 70-260 mesh；It is furthermore preferred that the granularity of the quartz sand is 120-200 mesh；It is further preferred that the quartz sand
Granularity be 140 mesh.
Heretofore described quartz sand can be bought from Hailing District Yikang fire resistant heat preserving building materials agency, can also be bought
From other sources.
Coalescing agent
In some embodiments, heretofore described coalescing agent does not do particular determination；General commercially available coalescing agent
It is all applied to the present invention；Preferably, the coalescing agent is selected from alcohol ester 12, propylene glycol oleate, diisopropanol adipic acid
At least one of ester, water-soluble silicon oil；It is furthermore preferred that the coalescing agent is alcohol ester 12.
Defoaming agent
In some embodiments, heretofore described defoaming agent does not do particular determination；General commercially available defoaming agent all may be used
Applied to the present invention；Preferably, heretofore described defoaming agent is selected from organic silicon defoamer, mineral oil antifoam agent, modified metal
One of soaps defoaming agent or any one；It is furthermore preferred that heretofore described defoaming agent is mineral oil antifoam agent.
The second aspect of the invention provides the preparation method of paste ceramic tile bond described in one kind, include at least with
Lower step:
(1) it is separately added into defoaming agent, coalescing agent, cellulose ether in a solvent, stirs 5~10 minutes；
(2) filler and quartz sand is then added, stirs 15~30 minutes, adds lotion, stirs 10~20 minutes；
(3) it is eventually adding butylol polyether, is stirred for 15~30 minutes, is filled into bucket then to get finished product.
In some preferred embodiments, the preparation method of the paste ceramic tile bond includes at least following step
It is rapid:
(1) it is separately added into defoaming agent, coalescing agent, cellulose ether in a solvent, stirs 7~9 minutes；
(2) filler and quartz sand is then added, stirs 17~19 minutes, adds lotion, stirs 14~18 minutes；
(3) it is eventually adding butylol polyether, is stirred for 20~26 minutes, is filled into bucket then to get finished product.
In some preferred embodiments, the preparation method of the paste ceramic tile bond is included at least following
Step:
(1) it is separately added into defoaming agent, coalescing agent, cellulose ether in a solvent, stirs 8 minutes；
(2) filler and quartz sand is then added, stirs 18 minutes, adds lotion, stirs 16 minutes；
(3) it is eventually adding butylol polyether, is stirred for 23 minutes, is filled into bucket then to get finished product.
The present invention is specifically described below by embodiment, once embodiment is only used for the present invention and does further
Illustrate, can not be interpreted as the limitation that the present invention protects, professional and technical personnel in the field makes according to the content of foregoing invention
Nonessential correction and adjustment, still fall within the range of protection of the invention.
The modified fumed silica of present invention cellulose ether described in embodiment 1-12 the preparation method is as follows:
A: by 5 parts of fumed silicas, 5.5 parts of water, 2.1 parts of dehydrated alcohols, 4.2 parts of silane coupling agents, 3.8 parts of dodecanes
Base benzene sulfonic acid sodium salt and 1.1 parts of calcium carbonate are uniformly mixed, and are carried out after being mixed 6 hours at 60 DEG C, and solid 1 is taken out in filtering；
B: being first diluted to solution for Instant cellulose ether with deionized water, and with the solution impregnation solid 1, solid after infiltration
Body 1 is put into hydrochloric acid and stirs 30 minutes, takes out drying, obtains solid 2；The pH value of the hydrochloric acid is 4；
C: solid 2 being put into sodium hydroxide solution and is stirred 15 minutes, take out drying to get；The sodium hydroxide solution
PH value be 9.
Embodiment 1
A kind of paste ceramic tile bond, by weight, raw material include 75 parts of lotions, 180 parts of solvents, and 3.5 parts of film forming help
Agent, 2 parts of defoaming agents, 5 parts of cellulose ethers, 1.3 parts of butylol polyethers, 350 parts of fillers, 350 parts of quartz sands；
The preparation method of the paste ceramic tile bond, comprising the following steps:
(1) it is separately added into defoaming agent, coalescing agent, cellulose ether in a solvent, stirs 8 minutes；
(2) filler and quartz sand is then added, stirs 18 minutes, adds lotion, stirs 16 minutes；
(3) it is eventually adding butylol polyether, is stirred for 23 minutes, is filled into bucket then to get finished product；
The cellulose ether is the modified fumed silica of cellulose ether；The butylol polyether is PPG-26- butylol polyether-
26；The lotion is styrene-acrylate emulsion, and from Guangzhou Zhen Cheng Chemical Co., Ltd., the trade mark is ECO 338 for purchase；
The solvent is deionized water；The filler is coarse whiting, and the granularity of the coarse whiting is 325 mesh；The granularity of the quartz sand is 140
Mesh；The coalescing agent is alcohol ester 12；The defoaming agent is NXZ, is bought from Guangzhou Run Hong Chemical Co., Ltd..
Embodiment 2
A kind of paste ceramic tile bond, by weight, raw material includes at least, 50 parts of lotions, 100 parts of solvents, 1 part of film forming
Auxiliary agent, 0.5 part of defoaming agent, 1 part of cellulose ether, 0.1 part of butylol polyether, 300 parts of fillers, 300 parts of quartz sands；
The preparation method of the paste ceramic tile bond, at least includes the following steps:
(1) it is separately added into defoaming agent, coalescing agent, cellulose ether in a solvent, stirs 5 minutes；
(2) filler and quartz sand is then added, stirs 15 minutes, adds lotion, stirs 10 minutes；
(3) it is eventually adding butylol polyether, is stirred for 15 minutes, is filled into bucket then to get finished product；
The cellulose ether is the modified fumed silica of cellulose ether；The butylol polyether is PPG-26- butylol polyether-
26；The lotion is pure-acrylic emulsion, and S-05 pure-acrylic emulsion is bought from Nantong Shengda Chemical Co., Ltd.；The solvent be go from
Sub- water；The filler is coarse whiting, and the granularity of the coarse whiting is 100 mesh；The granularity of the quartz sand is 50 mesh；The coalescing agent
For alcohol ester 12；The defoaming agent is NXZ, is bought from Guangzhou Run Hong Chemical Co., Ltd..
Embodiment 3
A kind of paste ceramic tile bond, by weight, raw material includes at least, 100 parts of lotions, 250 parts of solvents, 6 parts at
Film auxiliary agent, 4 parts of defoaming agents, 10 parts of cellulose ethers, 2 parts of butylol polyethers, 400 parts of fillers, 400 parts of quartz sands；
The preparation method of the paste ceramic tile bond, at least includes the following steps:
(1) it is separately added into defoaming agent, coalescing agent, cellulose ether in a solvent, stirs 10 minutes；
(2) filler and quartz sand is then added, stirs 15 minutes, adds lotion, stirs 10 minutes；
(3) it is eventually adding butylol polyether, is stirred for 15 minutes, is filled into bucket then to get finished product；
The cellulose ether is the modified fumed silica of cellulose ether；The butylol polyether is PPG-26- butylol polyether-
26；The lotion is styrene-acrylate emulsion, and from Guangzhou Zhen Cheng Chemical Co., Ltd., the trade mark is ECO 338 for purchase；
The solvent is deionized water；The filler is coarse whiting, and the granularity of the coarse whiting is 400 mesh；The granularity of the quartz sand is 300
Mesh；The coalescing agent is alcohol ester 12；The defoaming agent is NXZ, is bought from Guangzhou Run Hong Chemical Co., Ltd..
Embodiment 4
A kind of paste ceramic tile bond, by weight, raw material includes at least, 70 parts of lotions, 160 parts of solvents, 3 parts of film forming
Auxiliary agent, 1.5 parts of defoaming agents, 4 parts of cellulose ethers, 1.2 parts of butylol polyethers, 340 parts of fillers, 345 parts of quartz sands；
The preparation method of the paste ceramic tile bond, at least includes the following steps:
(1) it is separately added into defoaming agent, coalescing agent, cellulose ether in a solvent, stirs 7 minutes；
(2) filler and quartz sand is then added, stirs 17 minutes, adds lotion, stirs 18 minutes；
(3) it is eventually adding butylol polyether, is stirred for 20 minutes, is filled into bucket then to get finished product；
The cellulose ether is the modified fumed silica of cellulose ether；The butylol polyether is PPG-26- butylol polyether-
26；The lotion is silicone resin emulsion, is bought from Anhui Zhong En Chemical Co., Ltd., trade mark WC-SA108；It is described molten
Agent is deionized water；The filler is coarse whiting, and the granularity of the coarse whiting is 350 mesh；The granularity of the quartz sand is 120 mesh；Institute
Stating coalescing agent is alcohol ester 12；The defoaming agent is NXZ, is bought from Guangzhou Run Hong Chemical Co., Ltd..
Embodiment 5
A kind of paste ceramic tile bond, by weight, raw material includes at least, 80 parts of lotions, 200 parts of solvents, 4 parts of film forming
Auxiliary agent, 2.5 parts of defoaming agents, 6 parts of cellulose ethers, 1.4 parts of butylol polyethers, 360 parts of fillers, 355 parts of quartz sands；
The preparation method of the paste ceramic tile bond, at least includes the following steps:
(1) it is separately added into defoaming agent, coalescing agent, cellulose ether in a solvent, stirs 9 minutes；
(2) filler and quartz sand is then added, stirs 19 minutes, adds lotion, stirs 18 minutes；
(3) it is eventually adding butylol polyether, is stirred for 26 minutes, is filled into bucket then to get finished product；
The cellulose ether is the modified fumed silica of cellulose ether；The butylol polyether is PPG-26- butylol polyether-
26；The lotion is styrene-acrylate emulsion, and from Guangzhou Zhen Cheng Chemical Co., Ltd., the trade mark is ECO 338 for purchase；
The solvent is deionized water；The filler is coarse whiting, and the granularity of the coarse whiting is 325 mesh；The granularity of the quartz sand is 200
Mesh；The coalescing agent is alcohol ester 12；The defoaming agent is NXZ, is bought from Guangzhou Run Hong Chemical Co., Ltd..
Embodiment 6
A kind of paste ceramic tile bond, by weight, raw material includes at least, 75 parts of lotions, 180 parts of solvents, 3.5 parts at
Film auxiliary agent, 2 parts of defoaming agents, 1.3 parts of butylol polyethers, 350 parts of fillers, 350 parts of quartz sands；
The preparation method of the paste ceramic tile bond, at least includes the following steps:
(1) it is separately added into defoaming agent, coalescing agent in a solvent, stirs 8 minutes；
(2) filler and quartz sand is then added, stirs 18 minutes, adds lotion, stirs 16 minutes；
(3) it is eventually adding butylol polyether, is stirred for 23 minutes, is filled into bucket then to get finished product；
The butylol polyether is PPG-26- butylol polyether -26；The lotion is styrene-acrylate emulsion, and purchase is certainly
Guangzhou Zhen Cheng Chemical Co., Ltd., the trade mark are ECO 338；The solvent is deionized water；The filler is coarse whiting, described heavy
The granularity of calcium is 325 mesh；The granularity of the quartz sand is 140 mesh；The coalescing agent is alcohol ester 12；The defoaming agent is
NXZ is bought from Guangzhou Run Hong Chemical Co., Ltd..
Embodiment 7
A kind of paste ceramic tile bond, by weight, raw material includes at least, 75 parts of lotions, 180 parts of solvents, 3.5 parts at
Film auxiliary agent, 2 parts of defoaming agents, 5 parts of cellulose ethers, 1.3 parts of butylol polyethers, 350 parts of fillers, 350 parts of quartz sands；
The preparation method of the paste ceramic tile bond, at least includes the following steps:
(1) it is separately added into defoaming agent, coalescing agent, cellulose ether in a solvent, stirs 8 minutes；
(2) filler and quartz sand is then added, stirs 18 minutes, adds lotion, stirs 16 minutes；
(3) it is eventually adding butylol polyether, is stirred for 23 minutes, is filled into bucket then to get finished product；
The cellulose ether is general fibre element ether, is bought from Shanghai Shun Shui Chemical Co., Ltd., cellulose ether SR250；
The butylol polyether is PPG-26- butylol polyether -26；The lotion is styrene-acrylate emulsion, and purchase is attained from Guangzhou
Sincere Chemical Co., Ltd., the trade mark are ECO 338；The solvent is deionized water；The filler is coarse whiting, the granularity of the coarse whiting
For 325 mesh；The granularity of the quartz sand is 140 mesh；The coalescing agent is alcohol ester 12；The defoaming agent is NXZ, and purchase is certainly
Guangzhou Run Hong Chemical Co., Ltd..
Embodiment 8
A kind of paste ceramic tile bond, by weight, raw material includes at least, 75 parts of lotions, 180 parts of solvents, 3.5 parts at
Film auxiliary agent, 2 parts of defoaming agents, 0.1 part of cellulose ether, 1.3 parts of butylol polyethers, 350 parts of fillers, 350 parts of quartz sands；
The preparation method of the paste ceramic tile bond, at least includes the following steps:
(1) it is separately added into defoaming agent, coalescing agent, cellulose ether in a solvent, stirs 8 minutes；
(2) filler and quartz sand is then added, stirs 18 minutes, adds lotion, stirs 16 minutes；
(3) it is eventually adding butylol polyether, is stirred for 23 minutes, is filled into bucket then to get finished product；
The cellulose ether is methyl hydroxyethylcellulose ether；The butylol polyether is PPG-26- butylol polyether -26；Institute
Stating lotion is styrene-acrylate emulsion, and from Guangzhou Zhen Cheng Chemical Co., Ltd., the trade mark is ECO 338 for purchase；It is described molten
Agent is deionized water；The filler is coarse whiting, and the granularity of the coarse whiting is 325 mesh；The granularity of the quartz sand is 140 mesh；Institute
Stating coalescing agent is alcohol ester 12；The defoaming agent is NXZ, is bought from Guangzhou Run Hong Chemical Co., Ltd..
Embodiment 9
A kind of paste ceramic tile bond, by weight, raw material includes at least, 75 parts of lotions, 180 parts of solvents, 3.5 parts at
Film auxiliary agent, 2 parts of defoaming agents, 5 parts of cellulose ethers, 20 parts of butylol polyethers, 350 parts of fillers, 350 parts of quartz sands；
The preparation method of the paste ceramic tile bond, at least includes the following steps:
(1) it is separately added into defoaming agent, coalescing agent, cellulose ether in a solvent, stirs 8 minutes；
(2) filler and quartz sand is then added, stirs 18 minutes, adds lotion, stirs 16 minutes；
(3) it is eventually adding butylol polyether, is stirred for 23 minutes, is filled into bucket then to get finished product；
The cellulose ether is hydroxyethyl ether cellulose；The butylol polyether is PPG-26- butylol polyether -26；The cream
Liquid is styrene-acrylate emulsion, is bought from Guangzhou Zhen Cheng Chemical Co., Ltd., trade mark ECO338；The solvent is
Deionized water；The filler is coarse whiting, and the granularity of the coarse whiting is 325 mesh；The granularity of the quartz sand is 140 mesh；It is described at
Film auxiliary agent is alcohol ester 12；The defoaming agent is NXZ, is bought from Guangzhou Run Hong Chemical Co., Ltd..
Embodiment 10
A kind of paste ceramic tile bond, by weight, raw material includes at least, 75 parts of lotions, 180 parts of solvents, 3.5 parts at
Film auxiliary agent, 2 parts of defoaming agents, 5 parts of cellulose ethers, 350 parts of fillers, 350 parts of quartz sands；
The preparation method of the paste ceramic tile bond, at least includes the following steps:
(1) it is separately added into defoaming agent, coalescing agent, cellulose ether in a solvent, stirs 8 minutes；
(2) filler and quartz sand is then added, stirs 18 minutes, adds lotion, stirs 16 minutes；
(3) it is stirred for 23 minutes, is filled into bucket then to get finished product；
The cellulose ether is the modified fumed silica of cellulose ether；The lotion is styrene-acrylate emulsion,
From Guangzhou Zhen Cheng Chemical Co., Ltd., the trade mark is ECO 338 for purchase；The solvent is deionized water；The filler is coarse whiting,
The granularity of the coarse whiting is 325 mesh；The granularity of the quartz sand is 140 mesh；The coalescing agent is alcohol ester 12；The defoaming
Agent is NXZ, is bought from Guangzhou Run Hong Chemical Co., Ltd..
Embodiment 11
A kind of paste ceramic tile bond, by weight, raw material includes at least, 75 parts of lotions, 180 parts of solvents, 3.5 parts at
Film auxiliary agent, 2 parts of defoaming agents, 5 parts of cellulose ethers, 5 parts of butylol polyethers, 350 parts of fillers, 350 parts of quartz sands；
The preparation method of the paste ceramic tile bond, at least includes the following steps:
(1) it is separately added into defoaming agent, coalescing agent, cellulose ether in a solvent, stirs 8 minutes；
(2) filler and quartz sand is then added, stirs 18 minutes, adds lotion, stirs 16 minutes；
(3) it is eventually adding butylol polyether, is stirred for 23 minutes, is filled into bucket then to get finished product；
The cellulose ether is the modified fumed silica of cellulose ether；The butylol polyether is PPG-26- butylol polyether-
26；The lotion is styrene-acrylate emulsion, and from Guangzhou Zhen Cheng Chemical Co., Ltd., the trade mark is ECO 338 for purchase；
The solvent is deionized water；The filler is coarse whiting, and the granularity of the coarse whiting is 325 mesh；The granularity of the quartz sand is 140
Mesh；The coalescing agent is alcohol ester 12；The defoaming agent is NXZ, is bought from Guangzhou Run Hong Chemical Co., Ltd..
Embodiment 12
A kind of paste ceramic tile bond, by weight, raw material includes at least, 75 parts of lotions, 180 parts of solvents, 3.5 parts at
Film auxiliary agent, 2 parts of defoaming agents, 5 parts of cellulose ethers, 0.05 part of butylol polyether, 350 parts of fillers, 350 parts of quartz sands；
The preparation method of the paste ceramic tile bond, at least includes the following steps:
(1) it is separately added into defoaming agent, coalescing agent, cellulose ether in a solvent, stirs 8 minutes；
(2) filler and quartz sand is then added, stirs 18 minutes, adds lotion, stirs 16 minutes；
(3) it is eventually adding butylol polyether, is stirred for 23 minutes, is filled into bucket then to get finished product；
The cellulose ether is the modified fumed silica of cellulose ether；The butylol polyether is PPG-26- butylol polyether-
26；The lotion is styrene-acrylate emulsion, and from Guangzhou Zhen Cheng Chemical Co., Ltd., the trade mark is ECO 338 for purchase；
The solvent is deionized water；The filler is coarse whiting, and the granularity of the coarse whiting is 325 mesh；The granularity of the quartz sand is 140
Mesh；The coalescing agent is alcohol ester 12；The defoaming agent is NXZ, is bought from Guangzhou Run Hong Chemical Co., Ltd..
Performance test
1. reference standard JC/T547-2017 is tested for the property paste ceramic tile bond prepared by embodiment 1-12,
Test result is as shown in table 1；
2. judging whether occur in preparation process using paste ceramic tile bond prepared by embodiment 1-12 as test object
Gelatin phenomenon, the results are shown in Table 1.
1 the performance test results of table
Example above-mentioned is merely illustrative, some features of the feature for explaining the disclosure.The attached claims
It is intended to the range as wide as possible for requiring to be contemplated that, and embodiments as presented herein is only according to all possible embodiment
Combined selection embodiment explanation.Therefore, the purpose of applicant is that the attached claims are not illustrated the present invention
Feature exemplary selectional restriction.And the progress in science and technology will be formed language express it is inaccurate due to and not
The possible equivalent being presently considered or son replacement, and these variations should also be interpreted in the conceived case by appended
Claim covering.
Claims (10)
1. a kind of paste ceramic tile bond, which is characterized in that by weight, raw material includes at least, 50-100 parts of lotions, 100-
250 parts of solvents, 1-6 parts of coalescing agents, 0.5-4 parts of defoaming agents, 1-10 parts of cellulose ethers, 0.1-2 parts of butylol polyethers, 300-400
Part filler, 300-400 parts of quartz sands.
2. paste ceramic tile bond as described in claim 1, which is characterized in that by weight, raw material includes at least, 60-
90 parts of lotions, 140-220 parts of solvents, 2-5 parts of coalescing agents, 1-3 parts of defoaming agents, 2-8 parts of cellulose ethers, 1-1.6 parts of butanol are poly-
Ether, 330-370 parts of fillers, 340-360 parts of quartz sands.
3. such as paste ceramic tile bond claimed in claims 1-2, which is characterized in that the cellulose ether is selected from hydroxy ethyl fiber
One of plain ether, hydroxypropylcelluloether ether, methyl hydroxyethylcellulose, modified cellulose ethers or a variety of combinations.
4. paste ceramic tile bond as claimed in claim 3, which is characterized in that the modified cellulose ethers change for cellulose ether
Property fumed silica.
5. such as paste ceramic tile bond claimed in claims 1-2, which is characterized in that the butylol polyether is PPG-26- butanol
Polyethers -26.
6. such as paste ceramic tile bond claimed in claims 1-2, which is characterized in that the lotion is selected from polyacrylate cream
One of liquid, styrene-acrylate emulsion, pure-acrylic emulsion, silicone resin emulsion, acrylate and vinyl acetate emulsion, silicone acrylic emulsion are more
The combination of kind.
7. such as paste ceramic tile bond claimed in claims 1-2, which is characterized in that the solvent is selected from water, ethyl alcohol, 1- third
One of alcohol, propylene glycol, butanediol or a variety of combinations.
8. such as paste ceramic tile bond claimed in claims 1-2, which is characterized in that the filler be selected from talcum powder, titanium dioxide,
One of kaolin, silica, nano aluminium oxide, coarse whiting, bentonite, mica powder, ceramic powder, barium sulfate, magnesium fluosilicate
Or a variety of combination.
9. paste ceramic tile bond as claimed in claim 8, which is characterized in that the granularity of the coarse whiting is 100-400 mesh.
10. a kind of preparation method of such as described in any item paste ceramic tile bonds of claim 1-9, which is characterized in that at least
The following steps are included:
(1) it is separately added into defoaming agent, coalescing agent, cellulose ether in a solvent, stirs 5~10 minutes；
(2) filler and quartz sand is then added, stirs 15~30 minutes, adds lotion, stirs 10~20 minutes；
(3) it is eventually adding butylol polyether, is stirred for 15~30 minutes, is filled into bucket then to get finished product.
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| CN201910126721.XA CN109970387B (en) | 2019-02-20 | 2019-02-20 | Paste ceramic tile binder and preparation method thereof |
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| CN112707696A (en) * | 2019-10-24 | 2021-04-27 | 王爱忠 | Bonding mortar |
| CN114804753A (en) * | 2022-01-24 | 2022-07-29 | 东方雨虹砂粉科技集团有限公司 | Tile glue for pasting and joint filling and preparation method thereof |
| CN114876144A (en) * | 2021-06-08 | 2022-08-09 | 上海牛元工贸有限公司 | Dry-hanging installation process for rock plate |
| CN115557747A (en) * | 2022-09-26 | 2023-01-03 | 苏州金螳螂建筑装饰股份有限公司 | Double-component bonding material and preparation method and construction method thereof |
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