CN109957155A - A kind of preparation method of the modified polyisoprene surgical operation gloves of graphene oxide - Google Patents
A kind of preparation method of the modified polyisoprene surgical operation gloves of graphene oxide Download PDFInfo
- Publication number
- CN109957155A CN109957155A CN201910214436.3A CN201910214436A CN109957155A CN 109957155 A CN109957155 A CN 109957155A CN 201910214436 A CN201910214436 A CN 201910214436A CN 109957155 A CN109957155 A CN 109957155A
- Authority
- CN
- China
- Prior art keywords
- gloves
- pvp
- graphene oxide
- polyisoprene
- fingerprint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B42/00—Surgical gloves; Finger-stalls specially adapted for surgery; Devices for handling or treatment thereof
- A61B42/10—Surgical gloves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/14—Dipping a core
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/34—Component parts, details or accessories; Auxiliary operations
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/042—Graphene or derivatives, e.g. graphene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/08—Ingredients agglomerated by treatment with a binding agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/48—Wearing apparel
- B29L2031/4842—Outerwear
- B29L2031/4864—Gloves
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Surgery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biomedical Technology (AREA)
- Heart & Thoracic Surgery (AREA)
- Medical Informatics (AREA)
- Molecular Biology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Gloves (AREA)
Abstract
The present invention relates to a kind of preparation methods of the modified polyisoprene surgical operation gloves of graphene oxide.Graphite oxide (GO) aqueous solution is prepared first, PVP is added in graphene oxide water solution, stirring, ultrasound, obtain PVP-GO dispersion liquid, PVP-GO dispersion liquid is added in polyisoprene latex, stirs, continuously adds surfactant, zinc oxide, sulphur, promotor, potassium hydroxide, deionized water, it is uniformly mixing to obtain latex impregnation liquid, immersing solidification liquid, drying, immerse latex impregnation liquid, vulcanization, demould fingerprint is to obtain final products.Gloves prepared by the present invention significantly improve the mechanical performance of gloves, and the bactericidal function of simultaneous oxidation graphene improves gloves period of storage, reduce application risk.
Description
Technical field
The present invention relates to the preparation method field of surgical operation gloves, in particular to a kind of modified poly- isoamyl of graphene oxide
The preparation method of diene surgical operation gloves.
Background technique
Most current surgical gloves are still made of Heveatex.Because natural rubber contains albumen, small part
User (especially white race crowd) skin will generate the allergic reactions such as erythema, itch, and have serious sense of discomfort.In order to drop
The risk of low patient and medical worker's allergy, someone develop polyisoprene (IR) surgical operation gloves.Polyisoprene hand
Set haves the defects that storage process physical property is lower, to solve this problem, using the modified polyisoprene of graphene oxide.
Graphene oxide (GO) is a kind of two-dimensional slice material with monatomic thickness.Graphene oxide has high bullet
The excellent properties such as property modulus, thermal conductivity and electron mobility, light transmittance, have been widely used for preparing high performance material.Patent
CN107022124A once reported the preparation method of graphene and graphene oxide modified natural rubber gloves, butyronitrile gloves etc..
However it is had not been reported with the modified polyisoprene surgical operation gloves of graphene oxide.Polyvinylpyrrolidone (PVP) is right
Graphene oxide is dispersed with stabilization, facilitates modification of the graphene oxide to polyisoprene.
Applicants have found that the mechanical performance of gloves can be significantly improved after the modified polyisoprene of graphene oxide,
Simultaneous oxidation graphene can bring bactericidal function, improve gloves period of storage, reduce application risk.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art to improve poly- isoamyl two using the characteristic of graphene oxide
Mechanical property, imparting gloves bacteriostasis antibiosis function of alkene gloves etc..
To solve the above problems, proposing a kind of side with the modified polyisoprene surgical operation gloves of redox graphene
Method, specifically:
(1) graphene oxide (GO) aqueous solution is prepared；
(2) PVP is added in graphene oxide water solution, stirring, ultrasound obtain PVP-GO dispersion liquid；
(3) PVP-GO dispersion liquid is added in polyisoprene latex, is stirred, continuously add surfactant, oxidation
Zinc, sulphur, promotor, potassium hydroxide, deionized water are uniformly mixing to obtain polyisoprene latex maceration extract；
(4) immersing solidification liquid, drying, immerse polyisoprene latex maceration extract, vulcanization, demould fingerprint is to obtain finally
Product.
Wherein surfactant be neopelex or lauryl sodium sulfate, promotor ZDBC, ZDEC or
One of DPG or a variety of is used in combination.
Further, in PVP-GO solution, graphene oxide solution concentration is 0.5-3g/L, the matter of graphene oxide and PVP
Amount is than being 1:1-5.
Above-mentioned steps take 1L polyisoprene latex in (3), and the PVP-GO solution of 1L is added, stirring, then plus 0.5-1 parts
Sulphur, 0.8-1.2 part zinc oxide, 0.1-0.2 parts ZDBC, 0.1-0.2 parts ZDEC, 0.1-0.2 parts of DPG, 1 part of detergent alkylate sulphur
Sour sodium and 0.2 part of potassium hydroxide, 300ml deionized water
Be immersed in solidification liquid after fingerprint is heated to 110 DEG C in above-mentioned steps (4), the solidification liquid be calcium nitrate type+
Precipitated calcium carbonate configuration.
Wherein drying is to dry fingerprint 3-5 minutes under the conditions of 70-120 DEG C.
The vulcanization vulcanizes 25-40 minutes at 150 DEG C to touch hand.
The gloves of above method preparation are also claimed in the present invention, and tensile strength has bactericidal in 24Mpa or more
Function.
The purposes of the gloves of above method preparation is also claimed in the present invention, is used for surgical operation gloves.
Polyisoprene surgical operation gloves prepared by the present invention, good mechanical property have good bacteria resistance.
Specific embodiment
This part will disclose specific embodiment of the invention.The embodiment disclosed herein is example of the invention, can be with
It embodies in different forms.Therefore, the disclosed detailed content including specific structure and function details is not intended to limit the present invention, and
It is merely possible to the basis of claim.The application is come in the whole text with the meaning of permission using word " can with " rather than compulsory meaning
Justice.Similarly, unless otherwise indicated, word "include", "comprise" and " group becomes " expression " including but not limited to ".Word
" one " or "one" expression "at least one", word " multiple " indicate more than one.When using abbreviation or technical term,
These terms indicate known in the technical field and are generally accepted meaning.
Embodiment 1:
1) graphene oxide solution that 1L concentration is 1g/L is prepared, 3g PVP is added, ultrasonic disperse 2 hours, obtains PVP-
GO solution.
2) 1L polyisoprene latex is taken, the PVP-GO solution of 1L is added, is stirred, then plus 0.5 part of sulphur, 0.8 part of oxidation
Zinc, 0.1 part of ZDBC, 0.1 part of ZDEC, 0.2 part of DPG, 1 part of neopelex and 0.2 part of potassium hydroxide, 300ml go from
Sub- water stirs 6 hours, obtains Dipped latex.
3) under the conditions of 25-30 DEG C, stirring is placed 48 hours.
4) fingerprint is heated to being immersed in after 110 DEG C in calcium nitrate type+precipitated calcium carbonate configuration solidification liquid, is stopped 10 seconds
After take out, fingerprint is dried 3 minutes under the conditions of 100 DEG C.
5) fingerprint of drying is cooled to 70 DEG C, be immersed in the latex cured, taken out after stopping 10 seconds, hand is touched
Vulcanize 40 minutes at 150 DEG C.
6) gloves vulcanizated are removed from mold by surface treatment.
7) it is detected according to LST EN 455-4-2009.As a result it see the table below
Embodiment 2:
1) graphene oxide solution that 1L concentration is 3g/L is prepared, 3g PVP is added, ultrasonic disperse 2 hours, obtains PVP-
GO solution.
2) 1L polyisoprene latex is taken, the PVP-GO solution of 1L is added, is stirred, then plus 0.5 part of sulphur, 0.8 part of oxidation
Zinc, 0.1 part of ZDBC, 0.1 part of ZDEC, 0.2 part of DPG, 1 part of neopelex and 0.2 part of potassium hydroxide, 300ml go from
Sub- water stirs 6 hours, obtains Dipped latex,
3) under the conditions of 25-30 DEG C, stirring is placed 48 hours.
4) fingerprint is heated to being immersed in after 110 DEG C in calcium nitrate type+precipitated calcium carbonate configuration solidification liquid, is stopped 10 seconds
After take out, fingerprint is dried 3 minutes under the conditions of 100 DEG C.
5) fingerprint of drying is cooled to 70 DEG C, be immersed in the latex cured, taken out after stopping 10 seconds, hand is touched
Vulcanize 40 minutes at 150 DEG C.
6) gloves vulcanizated are removed from mold by surface treatment.
7) it is detected according to LST EN 455-4-2009.As a result it see the table below
Embodiment 3:
1) graphene oxide solution that 1L concentration is 0.5g/L is prepared, 2g PVP is added, ultrasonic disperse 2 hours, obtains
PVP-GO solution.
2) 1L polyisoprene latex is taken, the PVP-GO solution of 1L is added, is stirred, then plus 0.5 part of sulphur, 0.8 part of oxidation
Zinc, 0.1 part of ZDBC, 0.1 part of ZDEC, 0.2 part of DPG, 1 part of neopelex and 0.2 part of potassium hydroxide, 300ml go from
Sub- water stirs 6 hours, obtains Dipped latex,
3) under the conditions of 25-30 DEG C, stirring is placed 48 hours.
4) fingerprint is heated to being immersed in after 110 DEG C in calcium nitrate type+precipitated calcium carbonate configuration solidification liquid, is stopped 10 seconds
After take out, fingerprint is dried 3 minutes under the conditions of 100 DEG C.
5) fingerprint of drying is cooled to 70 DEG C, be immersed in the latex cured, taken out after stopping 10 seconds, hand is touched
Vulcanize 40 minutes at 150 DEG C.
6) gloves vulcanizated are removed from mold by surface treatment.
7) it is detected according to LST EN 455-4-2009.As a result it see the table below
Comparative example
1) 1L polyisoprene latex is taken, stirs, adds 0.5 part of sulphur, 0.8 part of zinc oxide, 0.1 part of ZDBC, 0.1 part
ZDEC, 0.2 part of DPG, 1 part of neopelex and 0.2 part of potassium hydroxide, 300ml deionized water are stirred 6 hours, are obtained
Dipped latex, under the conditions of 25-30 DEG C, stirring is placed 48 hours.
2) fingerprint is heated to being immersed in after 110 DEG C in calcium nitrate type+precipitated calcium carbonate configuration solidification liquid, is stopped 10 seconds
After take out, fingerprint is dried 3 minutes under the conditions of 100 DEG C.
3) fingerprint of drying is cooled to 70 DEG C, be immersed in the latex cured, taken out after stopping 10 seconds, hand is touched
Vulcanize 40 minutes at 150 DEG C.
4) gloves vulcanizated are removed from mold by surface treatment.
5) it is detected according to LST EN 455-4-2009.As a result it see the table below
Mechanical performance detects table
Antibacterial bacteriostatic detection
| Escherichia coli | Staphylococcus aureus | |
| Embodiment 1 | 93% | 94% |
| Embodiment 2 | 98% | 98% |
| Embodiment 3 | 92% | 91% |
| Comparative example | 5% | 7% |
It should be appreciated that the preferred embodiment of the present embodiment is not to limit the invention to disclosed specific form,
Present invention encompasses all modifications fallen into the range of specification describes and the attached claims limit, equivalent
And alternative.
Claims (10)
1. a kind of method with the modified polyisoprene gloves of redox graphene, comprises the following steps:
(1) graphene oxide (GO) aqueous solution is prepared；
(2) PVP is added in graphene oxide water solution, stirring, ultrasound obtain PVP-GO dispersion liquid；
(3) PVP-GO dispersion liquid is added in polyisoprene latex, stirs, continuously adds surfactant, zinc oxide, sulphur
Sulphur, promotor, potassium hydroxide, deionized water are uniformly mixing to obtain polyisoprene latex maceration extract；
(4) immersing solidification liquid, drying, immerse polyisoprene latex maceration extract, vulcanization, demould fingerprint is finally to be produced
Product.
2. according to the method described in claim 1, it is characterized by: surfactant is neopelex or dodecane
Base sodium sulphate, one of promotor ZDBC, ZDEC or DPG or a variety of are used in combination.
3. according to the method described in claim 1, it is characterized by: in PVP-GO solution, graphene oxide solution concentration is
The mass ratio of 0.5-3g/L, graphene oxide and PVP are 1:1-5.
4. according to the method described in claim 1, being added it is characterized by: take 1L polyisoprene latex in above-mentioned steps (3)
The PVP-GO solution of 1L, stirring, then plus 0.5-1 parts of sulphur, 0.8-1.2 parts of zinc oxide, 0.1-0.2 parts ZDBC, 0.1-0.2 parts
ZDEC, 0.1-0.2 parts of DPG, 1 part of neopelex and 0.2 part of potassium hydroxide, 300ml deionized water.
5. according to the method described in claim 1, it is characterized by: being immersed after fingerprint is heated to 110 DEG C in above-mentioned steps (4)
Into solidification liquid.
6. according to the method described in claim 1, it is characterized by: drying is that fingerprint is dried 3-5 under the conditions of 70-120 DEG C
Minute.
7. according to the method described in claim 1, it is characterized by: vulcanization vulcanizes 25-40 minutes at 150 DEG C to touch hand.
8. a kind of gloves of any one of claim 1-7 the method preparation.
9. gloves according to claim 8, it is characterised in that: the gloves are polyisoprene gloves.
10. the purposes of gloves described in claim 8 or 9, it is characterised in that: be used for surgical operation gloves.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910214436.3A CN109957155A (en) | 2019-03-20 | 2019-03-20 | A kind of preparation method of the modified polyisoprene surgical operation gloves of graphene oxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910214436.3A CN109957155A (en) | 2019-03-20 | 2019-03-20 | A kind of preparation method of the modified polyisoprene surgical operation gloves of graphene oxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109957155A true CN109957155A (en) | 2019-07-02 |
Family
ID=67024643
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910214436.3A Pending CN109957155A (en) | 2019-03-20 | 2019-03-20 | A kind of preparation method of the modified polyisoprene surgical operation gloves of graphene oxide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109957155A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111741607A (en) * | 2020-06-19 | 2020-10-02 | 辽宁格莱菲尔健康科技有限公司 | Method for compositely integrating reduced graphene oxide high-sensitivity sensing circuit and latex |
| CN112341646A (en) * | 2020-11-16 | 2021-02-09 | 广州双一乳胶制品有限公司 | Self-antibacterial anti-mildew household glove and preparation method thereof |
| CN112480494A (en) * | 2020-11-16 | 2021-03-12 | 广州双一乳胶制品有限公司 | Self-antibacterial medical gloves and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104558708A (en) * | 2015-01-19 | 2015-04-29 | 南京理工大学 | Multifunctional vulcanized rubber containing polyvinylpyrrolidone-modified graphene oxide and preparation method of multifunctional vulcanized rubber |
| CN105295090A (en) * | 2015-11-23 | 2016-02-03 | 辽宁兰晶科技有限公司 | Method for preparing high-strength and high-isolation medical gloves by using modified graphene/latex composite material |
| CN105623013A (en) * | 2016-03-22 | 2016-06-01 | 镇江华扬乳胶制品有限公司 | Preparation method of high-strength, high-elongation, antibacterial and soft graphene rubber product |
| CN106065095A (en) * | 2016-06-08 | 2016-11-02 | 上海史墨希新材料科技有限公司 | Functional high-strength protective gloves of Graphene latex and preparation method thereof |
| WO2018084694A1 (en) * | 2016-11-03 | 2018-05-11 | Karex Holdings Sdn Bhd. | Polyisoprene latex graphene composites and methods of making them |
| CN109265772A (en) * | 2018-07-24 | 2019-01-25 | 黄山市尚义橡塑制品有限公司 | A kind of graphene rubber composite material and preparation method thereof |
-
2019
- 2019-03-20 CN CN201910214436.3A patent/CN109957155A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104558708A (en) * | 2015-01-19 | 2015-04-29 | 南京理工大学 | Multifunctional vulcanized rubber containing polyvinylpyrrolidone-modified graphene oxide and preparation method of multifunctional vulcanized rubber |
| CN105295090A (en) * | 2015-11-23 | 2016-02-03 | 辽宁兰晶科技有限公司 | Method for preparing high-strength and high-isolation medical gloves by using modified graphene/latex composite material |
| CN105623013A (en) * | 2016-03-22 | 2016-06-01 | 镇江华扬乳胶制品有限公司 | Preparation method of high-strength, high-elongation, antibacterial and soft graphene rubber product |
| CN106065095A (en) * | 2016-06-08 | 2016-11-02 | 上海史墨希新材料科技有限公司 | Functional high-strength protective gloves of Graphene latex and preparation method thereof |
| CN107022124A (en) * | 2016-06-08 | 2017-08-08 | 南通强生安全防护科技股份有限公司 | High-strength protective gloves of graphene latex feature and preparation method thereof |
| WO2018084694A1 (en) * | 2016-11-03 | 2018-05-11 | Karex Holdings Sdn Bhd. | Polyisoprene latex graphene composites and methods of making them |
| CN109265772A (en) * | 2018-07-24 | 2019-01-25 | 黄山市尚义橡塑制品有限公司 | A kind of graphene rubber composite material and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111741607A (en) * | 2020-06-19 | 2020-10-02 | 辽宁格莱菲尔健康科技有限公司 | Method for compositely integrating reduced graphene oxide high-sensitivity sensing circuit and latex |
| CN112341646A (en) * | 2020-11-16 | 2021-02-09 | 广州双一乳胶制品有限公司 | Self-antibacterial anti-mildew household glove and preparation method thereof |
| CN112480494A (en) * | 2020-11-16 | 2021-03-12 | 广州双一乳胶制品有限公司 | Self-antibacterial medical gloves and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109957155A (en) | A kind of preparation method of the modified polyisoprene surgical operation gloves of graphene oxide | |
| EP1128776B1 (en) | Elastomeric gloves | |
| US10787561B2 (en) | Nitrile rubber article | |
| JP7071285B2 (en) | Elastomer articles, compositions, and methods of making them | |
| DE60317787T2 (en) | METHOD FOR MANUFACTURING A GLOVE WITH IMPROVED ATTACHMENT FEATURES | |
| EP2068666B1 (en) | An elastomeric flexible article with absorbant polymer and manufacturing method | |
| US20090255033A1 (en) | Surface modification of elastomeric articles | |
| KR20070100765A (en) | Application of an antimicrobial agent on an elastomeric article | |
| CN103980562A (en) | Rubber glove with antimicrobial and skin care functions | |
| AU2014351059A1 (en) | Polymeric compositions comprising polyisoprene | |
| CN103980566A (en) | Rubber glove with antimicrobial function | |
| WO2001090236A1 (en) | Polymer blends and articles produced therewith | |
| KR20170060793A (en) | Latex composition for dip-forming and the product prepared thereby | |
| CN106633223A (en) | Medical antibacterial glove and preparation method thereof | |
| KR100665719B1 (en) | Method for produce of Rubber gloves contain Nano silver | |
| US20060057320A1 (en) | Accelerator-free carboxylated latex compositions and articles | |
| CN114736406A (en) | Preparation process of low-temperature-resistant gloves with antibacterial effect | |
| CN111321593A (en) | Natural sterilization and deodorization fiber and preparation method thereof | |
| KR102135399B1 (en) | Composition For Dip-forming comprising carboxylic acid modified latex and method of manufacturing dip-formed article | |
| CN114031827A (en) | Butyronitrile gloves with good wearability and no allergic component and preparation method thereof | |
| JP7493620B2 (en) | Synthetic rubber latex composition containing ionic liquid for elastic gloves | |
| KR20170062730A (en) | Latex composition for dip-forming and the product prepared thereby | |
| KR100679120B1 (en) | Rubber Gloves contained Aluminium hydroxide-Manganese Nano Mixture and Process for Preparation of the Same | |
| JP2023526005A (en) | Synthetic rubber latex composition containing ionic liquid for elastic gloves | |
| KR20080046834A (en) | Functional latex glove with porousness and antibiosis and method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190702 |