CN109956704A - A kind of layering generates the quartz and preparation method of anion - Google Patents

A kind of layering generates the quartz and preparation method of anion Download PDF

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Publication number
CN109956704A
CN109956704A CN201910294746.0A CN201910294746A CN109956704A CN 109956704 A CN109956704 A CN 109956704A CN 201910294746 A CN201910294746 A CN 201910294746A CN 109956704 A CN109956704 A CN 109956704A
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anion
layer
mixed
quartz
cloth
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冯伟坚
何海光
练旺
覃雄基
欧阳柏夫
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Guangdong Zhongqi New Materials Co Ltd
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Guangdong Zhongqi New Materials Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/06—Acrylates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/12—Condensation polymers of aldehydes or ketones
    • C04B26/122—Phenol-formaldehyde condensation polymers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/14—Polyepoxides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/16—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/18—Polyesters; Polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017—Aspects relating to the protection of the environment
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00025—Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612—Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Abstract

The invention discloses the quartzs that a kind of layering generates anion, including blanket layer and anion layer, anion layer is laid in the lower section of blanket layer, and anion layer includes the following raw material: particulate material 55~65%, silica flour 20~30%, colored pigment 0.01~10%, silane coupling agent 0.1~1%, unsaturated polyester resin 8~14%, curing agent 0.8~1.4%, negative ion powder 0.5~5%；Negative ion powder includes tourmaline 95~98%, cerium oxide 1~3%, aluminium oxide 1~3%.Cloth is in the lower section of blanket layer when making anion layer cloth, quartzite slate can be made to have effects that discharge anion, the effect for purifying air is obvious, it can reach close with the effect of substance that addition can generate anion in quartzy stone substrate, the cost for making anion layer is lower relative to being added in quartz entire body, cost substantially reduces, and good anti-bacterial effect.

Description

A kind of layering generates the quartz and preparation method of anion
Technical field
The present invention relates to quartz and preparations that quartzite slate production field more particularly to a kind of layering generate anion Method.
Background technique
Currently, standard of living steps up at present, more and more people more focus on environmental health.Ecological air Anion, beneficial to being the unjust fact, is tested and is shown as negative ion concentration < 250/cm to human health3When, environment is empty Gas is second-rate, can give the feeling of people's discomfort；When negative ion concentration is in 250~400/cm3When, ambient air quality is general； When negative ion concentration is in 400~1000/cm3When, ambient air quality is preferable, comfortably feels to people；Work as negative ion concentration > 1000/cm3When, ambient air quality is excellent, belongs to health care concentration range, can be played by neurohumor metabolic activity immune The effect of defence
But it is existing can releasing negative oxygen ion quartzite slate, negative oxygen ion release concentration about 200-400/ cm3Between, ambient air quality is general, unobvious to the improvement environment in room.
If the material that can produce negative oxygen ion is added in the entire body of quartz, the effect for generating anion can reach, but The mechanical property of quartzy stone substrate can be impacted, and production cost is higher, is unfavorable for promoting the use of.
Summary of the invention
It is an object of the invention to propose that a kind of layering generates the quartz of anion.
To achieve this purpose, the present invention adopts the following technical scheme:
A kind of layering generates the quartz of anion, which is characterized in that including blanket layer and anion layer, the anion Layer is laid in the lower section of the blanket layer, and the anion layer includes the following raw material: particulate material 55~65%, silica flour 20~ 30%, colored pigment 0.01~10%, silane coupling agent 0.1~1%, unsaturated polyester resin 8~14%, curing agent 0.8~ 1.4%, negative ion powder 0.5~5%；
The negative ion powder includes tourmaline 95~98%, cerium oxide 1~3%, aluminium oxide 1~3%.
Anion layer is made, cloth can make quartzite slate have release anion in the lower section of blanket layer in cloth The effect of, so that the burst size of anion is greater than 1.87 × 103ions/socm2, the effect for purifying air is obvious, only need to make bear from Sublayer cloth in cloth can reach in the lower section of blanket layer and the substance that can generate anion be added in quartzy stone substrate Effect it is close, the cost for making anion layer is lower relative to being added in quartz entire body, and cost substantially reduces, and bear from The releasing effect of son is good, and the aluminium oxide added in negative ion powder enhances the anion burst size of negative ion powder, and improves The mechanical strength of antibacterial anionic layer.
Preferably, according to weight percent, the blanket layer includes the following raw material: particulate material 55~65%, silica flour 20~30%, colored pigment 0.01~10%, silane coupling agent 0.1~1%, unsaturated polyester resin 8~14%, curing agent 0.8~1.4%.
Using particulate material, silica flour, colored pigment, silane coupling agent, unsaturated polyester resin and curing agent as raw material system Make quartzite slate blanket layer, guarantees that the mechanical property of quartz meets the requirements.
Preferably, the particle size of the particulate material is 0.075~5mm, and the particle size of the silica flour is 0.005 ~0.045mm.
The particulate material and silica flour of common particle size are selected, production cost is low.
Preferably, the colored pigment is one or more, the inorganic pigment of inorganic pigment, organic pigment, mill base For titanium white, medium chrome yellow, iron oxide yellow, iron oxide red, iron oxide black it is one or more, the organic pigment is pigment scarlet powder, dark green, phthalocyanine blue It is one or more, the mill base be white slurry, black wash, it is bright red slurry, dark green slurry, phthalocyanine blue starch it is one or more.
Colored pigment is used to deploy the designs and varieties of quartz pattern, keeps the various colors of quartz colorful；Titanium white, middle chromium There are the performances such as sun-proof, heat-resisting, weather-proof and solvent resistance is good, the strong covering power of pigment in Huang, iron oxide yellow, iron oxide red and iron oxide black；Pigment scarlet powder, The lovely luster of dark green and phthalocyanine blue, strong coloring force, properties are excellent；The favorable reproducibility of color, uniform coloring mitigate dirty Dye, light resistance, weatherability are good, it is difficult to occur fading and powder phenomenon-tion.
Preferably, the unsaturated polyester resin is epoxy resin, in phenolic resin, acrylic resin, polyurethane resin It is one or more.
The function admirable of unsaturated polyester resin, processing performance is flexible, unsaturated polyester resin be used for feed particles and The solidification of silica flour, the mechanical property after solidification are good.
Preferably, the curing agent is peroxidating (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, perbenzoic acid One of the tert-butyl ester, dibenzoyl peroxide, fat polyamine are a variety of.
Curing agent is added for solidification to unsaturated polyester resin, using can be to unsaturated polyester resin normal temperature cure Curing agent.
Preferably, the silane coupling agent is γ-methacryloxypropyl trimethoxy silane, γ-(2,3- epoxies Third oxygen) propyl trimethoxy silicane, N- β (aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, N- (β-aminoethyl)-γ- Aminopropyl triethoxysilane, N- β (aminoethyl)-γ-aminopropyltrimethoxysilane, anilinomethyl triethoxysilane, γ- Aminopropyl triethoxysilane, vinyltriethoxysilane, vinyltrimethoxysilane and γ-chloropropyl triethoxy silicon One of alkane is a variety of.
Silane coupling agent improves the bond properties of resin, enhances the mechanical property of plate for the surface treatment to resin.
A kind of layering generates the quartz of anion, which comprises the following steps:
(1) each component is weighed according to blank layer formula and anion layer formula respectively, the blank layer formula is granular raw Expect 60~63%, silica flour 22~26%, colored pigment 1~1.2%, silane coupling agent 0.3~0.7%, unsaturated polyester (UP) tree Rouge 10~13%, curing agent 1~1.2%, the formula of the antimicrobial coating be particulate material 55~65%, silica flour 20~ 30%, colored pigment 0.01~10%, silane coupling agent 0.1~1%, unsaturated polyester resin 8~14%, curing agent 0.8~ 1.4%, negative ion powder 0.5~5%；
(2) it stirs: will be according to the weighed quartz particles of the blank layer formula, glass particle, silane coupling agent in duplicate rows It is pre-mixed in planetary agitator；The unsaturated polyester resin mixed, curing agent and colored pigment are poured into double planetary to stir It mixes in bucket and is mixed, silica flour is then added and is mixed.15~55Hz of stirring frequency, 300~500s of mixing time；
Weighed quartz particles, glass particle, silane coupling agent will be formulated according to the anion layer to stir in double planetary It mixes in bucket and is pre-mixed；The unsaturated polyester resin mixed, curing agent, colored pigment and Zinc oxide antibacterial agent are poured into double It is mixed in planetary agitator, silica flour is then added and is mixed.15~55Hz of stirring frequency, mixing time 300~ 500s；
(3) cloth: the material mixed feeding beater is further broken up respectively, after breaing up, is entered through electronic measurement The lower layer of cloth in material distributing machine, cloth is anion layer, and upper layer is blanket layer；
(4) it suppresses: after cloth is completed, repressed vibration equipment compression moulding, pressure under the vacuum condition of -0.1Mpa 50~200t, 30~55Hz of vibration frequency, 60~600s of time；
(5) heat cure: after vibration compacting, into curing apparatus, 80~130 DEG C at a temperature of solidify, curing time It is 30~180 minutes；
(6) after the completion of solidifying, the room temperature completely rear plate thicknessing machine that enters to be cooled determines thickness, sets using water mill polishing It is standby to be polished.
Anion layer is made, cloth can make quartzite slate have release anion in the lower section of blanket layer in cloth The effect of, so that the burst size of anion is greater than 1.87 × 103ions/socm2, the effect for purifying air is obvious, only need to make bear from Sublayer cloth in cloth can reach in the lower section of blanket layer and the substance that can generate anion be added in quartzy stone substrate Effect it is close, the cost for making anion layer is lower relative to being added in quartz entire body, and cost substantially reduces, and bear from The releasing effect of son is good；In solidification, solidification temperature is too low to will lead to that solidification effect is poor, the mechanical property of plate is influenced, if solid It is excessively high to change temperature, then can reduce the burst size of anion, therefore solidification temperature is selected as 80~130 DEG C, guarantee releasing for anion High-volume and the mechanical property of plate.
The invention has the benefit that production anion layer, in cloth, cloth can make quartz in the lower section of blanket layer Plate has effects that release anion, and the burst size of anion is made to be greater than 1.87 × 103ions/socm2, purify the effect of air Fruit is obvious, only need to make anion layer cloth in cloth and can reach in the lower section of blanket layer and is added in quartzy stone substrate The effect that the substance of anion can be generated is close, and the cost for making anion layer is lower relative to being added in quartz entire body, Cost substantially reduces, and the releasing effect of anion is good.
Specific embodiment
Embodiment 1
(1) each component is weighed according to blank layer formula and anion layer formula respectively, the blank layer formula is granular raw Expect 60%, silica flour 24%, colored pigment 1.1%, silane coupling agent 0.7%, unsaturated polyester resin 13%, curing agent 1.2%, the formula of the anion layer is particulate material 60%, silica flour 23.58%, colored pigment 1.2%, silane coupling agent 0.42%, unsaturated polyester resin 13%, curing agent 1.3%, negative ion powder 0.5%；Wherein, negative ion powder is by tourmaline 98%, cerium oxide 1%, aluminium oxide 1% is mixed；
(2) it stirs: will be according to the weighed quartz particles of the blank layer formula, glass particle, silane coupling agent in duplicate rows It is pre-mixed in planetary agitator；The unsaturated polyester resin mixed, curing agent and colored pigment are poured into double planetary to stir It mixes in bucket and is mixed, silica flour is then added and is mixed.15~55Hz of stirring frequency, 300~500s of mixing time；
Weighed quartz particles, glass particle, silane coupling agent will be formulated according to the anion layer to stir in double planetary It mixes in bucket and is pre-mixed；The unsaturated polyester resin mixed, curing agent, colored pigment and Zinc oxide antibacterial agent are poured into double It is mixed in planetary agitator, silica flour is then added and is mixed.15~55Hz of stirring frequency, mixing time 300~ 500s；
(3) cloth: the material mixed feeding beater is further broken up respectively, after breaing up, is entered through electronic measurement The lower layer of cloth in material distributing machine, cloth is anion layer, and upper layer is blanket layer；
(4) it suppresses: after cloth is completed, repressed vibration equipment compression moulding, pressure under the vacuum condition of -0.1Mpa 50~200t, 30~55Hz of vibration frequency, 60~600s of time；
(5) heat cure: after vibration compacting, into curing apparatus, 80~130 DEG C at a temperature of solidify, curing time It is 30~180 minutes；
(6) after the completion of solidifying, the room temperature completely rear plate thicknessing machine that enters to be cooled determines thickness, sets using water mill polishing It is standby to be polished；
To anion quartz made from embodiment 1, according to GB/T 28628-2018, " material induces air ion and measures examination Method " it static determination and carries out dynamic method and determines its amount for generating anion, result is as follows:
The negative aeroion amount of inducing of 1 quartzite slate of embodiment is measured by static determination are as follows: 4.27 × 103ions/socm2；
The negative aeroion amount of inducing of 1 quartzite slate of embodiment is measured by dynamic method are as follows: 1200ions/m3；
The quantity of plate generation anion can be made to get a promotion it is found that anion layer is added by measurement result, according to weight Percentage, when the amount of anion layer addition negative ion powder is 0.5%, the negative aeroion amount of inducing of quartzite slate are as follows: 4.27×103ions/socm2, the effect for generating negative aeroion is obvious.
The mechanics that anion quartz made from embodiment 1 is carried out bending strength, impact flexibility and anti-ball falling impact is real It tests, the results are shown in Table 1；
Table 1
As shown in Table 1, according to weight percent, when the amount of anion layer negative ion powder is 0.5%, the bending of plate is strong Degree, impact flexibility and anti-ball falling impact performance meet mechanical requirements, therefore, to the mechanical property shadow of plate after addition anion layer Sound is little.
Embodiment 2
(1) each component is weighed according to blank layer formula and anion layer formula respectively, the blank layer formula is granular raw Expect 60%, silica flour 24%, colored pigment 1.1%, silane coupling agent 0.7%, unsaturated polyester resin 13%, curing agent 1.2%, the formula of the anion layer is particulate material 60%, silica flour 23.08%, colored pigment 1.2%, silane coupling agent 0.42%, unsaturated polyester resin 13%, curing agent 1.3%, negative ion powder 1%；Wherein, according to weight percent, anion Powder is mixed by tourmaline 98%, cerium oxide 1%, aluminium oxide 1%；
(2) it stirs: will be according to the weighed quartz particles of the blank layer formula, glass particle, silane coupling agent in duplicate rows It is pre-mixed in planetary agitator；The unsaturated polyester resin mixed, curing agent and colored pigment are poured into double planetary to stir It mixes in bucket and is mixed, silica flour is then added and is mixed.15~55Hz of stirring frequency, 300~500s of mixing time；
Weighed quartz particles, glass particle, silane coupling agent will be formulated according to the anion layer to stir in double planetary It mixes in bucket and is pre-mixed；The unsaturated polyester resin mixed, curing agent, colored pigment and Zinc oxide antibacterial agent are poured into double It is mixed in planetary agitator, silica flour is then added and is mixed.15~55Hz of stirring frequency, mixing time 300~ 500s；
(3) cloth: the material mixed feeding beater is further broken up respectively, after breaing up, is entered through electronic measurement The lower layer of cloth in material distributing machine, cloth is anion layer, and upper layer is blanket layer；
(4) it suppresses: after cloth is completed, repressed vibration equipment compression moulding, pressure under the vacuum condition of -0.1Mpa 50~200t, 30~55Hz of vibration frequency, 60~600s of time；
(5) heat cure: after vibration compacting, into curing apparatus, 80~130 DEG C at a temperature of solidify, curing time It is 30~180 minutes；
(6) after the completion of solidifying, the room temperature completely rear plate thicknessing machine that enters to be cooled determines thickness, sets using water mill polishing It is standby to be polished；
The negative aeroion amount of inducing of 2 quartzite slate of embodiment is measured by static determination are as follows: 5.48 × 103ions/socm2；
The negative aeroion amount of inducing of 2 quartzite slate of embodiment is measured by dynamic method are as follows: 3000ions/m3；
The quantity of plate generation anion can be made to get a promotion it is found that negative ion powder is added by measurement result, according to weight Percentage, when the amount for adding negative ion powder is 1%, the negative aeroion amount of inducing of quartzite slate are as follows: 5.48 × 103ions/socm2, the effect for generating negative aeroion is obvious.
The mechanics that anion quartz made from embodiment 2 is carried out bending strength, impact flexibility and anti-ball falling impact is real It tests, the results are shown in Table 2；
Table 2
As shown in Table 2, according to weight percent, when the amount that negative ion powder adds in anion layer is 1%, plate it is curved Qu Qiangdu, impact flexibility and impact flexibility meet mechanical requirements, therefore, after the amount increase of negative ion powder is added, to the power of plate It is little to learn performance influence.
Embodiment 3
(1) each component is weighed according to blank layer formula and anion layer formula respectively, the blank layer formula is granular raw Expect 60%, silica flour 24%, colored pigment 1.1%, silane coupling agent 0.7%, unsaturated polyester resin 13%, curing agent 1.2%, the formula of the anion layer is particulate material 55%, silica flour 30%, colored pigment 2.6%, silane coupling agent 1%, unsaturated polyester resin 8%, curing agent 1.4%, negative ion powder 2%；Wherein, according to weight percent, negative ion powder by Tourmaline 98%, cerium oxide 1%, aluminium oxide 1% are mixed；
(2) it stirs: will be according to the weighed quartz particles of the blank layer formula, glass particle, silane coupling agent in duplicate rows It is pre-mixed in planetary agitator；The unsaturated polyester resin mixed, curing agent and colored pigment are poured into double planetary to stir It mixes in bucket and is mixed, silica flour is then added and is mixed.15~55Hz of stirring frequency, 300~500s of mixing time；
Weighed quartz particles, glass particle, silane coupling agent will be formulated according to the anion layer to stir in double planetary It mixes in bucket and is pre-mixed；The unsaturated polyester resin mixed, curing agent, colored pigment and Zinc oxide antibacterial agent are poured into double It is mixed in planetary agitator, silica flour is then added and is mixed.15~55Hz of stirring frequency, mixing time 300~ 500s；
(3) cloth: the material mixed feeding beater is further broken up respectively, after breaing up, is entered through electronic measurement The lower layer of cloth in material distributing machine, cloth is anion layer, and upper layer is blanket layer；
(4) it suppresses: after cloth is completed, repressed vibration equipment compression moulding, pressure under the vacuum condition of -0.1Mpa 50~200t, 30~55Hz of vibration frequency, 60~600s of time；
(5) heat cure: after vibration compacting, into curing apparatus, 80~130 DEG C at a temperature of solidify, curing time It is 30~180 minutes；
(6) after the completion of solidifying, the room temperature completely rear plate thicknessing machine that enters to be cooled determines thickness, sets using water mill polishing It is standby to be polished；
To anion quartz made from embodiment 3, according to GB/T 28628-2018, " material induces air ion and measures examination Method " it static determination and carries out dynamic method and determines its amount for generating anion, result is as follows:
The negative aeroion amount of inducing of 3 quartzite slate of embodiment is measured by static determination are as follows: 1.87 × 103ions/socm2；
The negative aeroion amount of inducing of 3 quartzite slate of embodiment is measured by dynamic method are as follows: 2100ions/m3；
The quantity of plate generation anion can be made to get a promotion it is found that negative ion powder is added by measurement result, according to weight Percentage, when the amount for adding negative ion powder is 2%, the negative aeroion amount of inducing of quartzite slate are as follows: 1.87 × 103ions/socm2, generate when the amount of negative aeroion than the amount for adding anion is 1% and reduced.
The mechanics that anion quartz made from embodiment 3 is carried out bending strength, impact flexibility and anti-ball falling impact is real It tests, the results are shown in Table 3；
Table 3
As shown in Table 3, according to weight percent, when the amount of negative ion powder is 2%, the bending strength of plate, impact are tough Property and impact flexibility meet mechanical requirements, therefore, after the amount increase of negative ion powder is added, very to the Effect on Mechanical Properties of plate It is micro-.
Embodiment 4
(1) each component is weighed according to blank layer formula and anion layer formula respectively, the blank layer formula is granular raw Expect 60%, silica flour 24%, colored pigment 1.1%, silane coupling agent 0.7%, unsaturated polyester resin 13%, curing agent 1.2%, the formula of the anion layer is particulate material 65%, silica flour 20%, colored pigment 0.8%, silane coupling agent 0.1%, unsaturated polyester resin 8.3%, curing agent 0.8%, negative ion powder 5%；Wherein, negative ion powder by tourmaline 98%, Cerium oxide 1%, aluminium oxide 1% is mixed；
(2) it stirs: will be according to the weighed quartz particles of the blank layer formula, glass particle, silane coupling agent in duplicate rows It is pre-mixed in planetary agitator；The unsaturated polyester resin mixed, curing agent and colored pigment are poured into double planetary to stir It mixes in bucket and is mixed, silica flour is then added and is mixed.15~55Hz of stirring frequency, 300~500s of mixing time；
Weighed quartz particles, glass particle, silane coupling agent will be formulated according to the anion layer to stir in double planetary It mixes in bucket and is pre-mixed；The unsaturated polyester resin mixed, curing agent, colored pigment and Zinc oxide antibacterial agent are poured into double It is mixed in planetary agitator, silica flour is then added and is mixed.15~55Hz of stirring frequency, mixing time 300~ 500s；
(3) cloth: the material mixed feeding beater is further broken up respectively, after breaing up, is entered through electronic measurement The lower layer of cloth in material distributing machine, cloth is anion layer, and upper layer is blanket layer；
(4) it suppresses: after cloth is completed, repressed vibration equipment compression moulding, pressure under the vacuum condition of -0.1Mpa 50~200t, 30~55Hz of vibration frequency, 60~600s of time；
(5) heat cure: after vibration compacting, into curing apparatus, 80~130 DEG C at a temperature of solidify, curing time It is 30~180 minutes；
(6) after the completion of solidifying, the room temperature completely rear plate thicknessing machine that enters to be cooled determines thickness, sets using water mill polishing It is standby to be polished；
The negative aeroion amount of inducing of 4 quartzite slate of embodiment is measured by static determination are as follows: 8.4 × 103ions/ socm2；
The negative aeroion amount of inducing of 4 quartzite slate of embodiment is measured by dynamic method are as follows: 5700ions/m3；
The quantity of plate generation anion can be made to get a promotion it is found that negative ion powder is added by measurement result, according to weight Percentage, when the amount for adding negative ion powder is 5% and negative ion powder includes tourmaline 98%, cerium oxide 1%, aluminium oxide 1%, The negative aeroion amount of inducing of quartzite slate are as follows: 8.40 × 103ions/socm2, the effect for generating negative aeroion is obvious.
The mechanics that anion quartz made from embodiment 4 is carried out bending strength, impact flexibility and anti-ball falling impact is real It tests, the results are shown in Table 4；
Embodiment 4
Bending strength/Mpa 52.5
Elasticity modulus/Gpa 41
Impact flexibility/kj/m2 3.19
Ball falling impact/cm 41
Plate thickness/mm 12.5
Table 4
As shown in Table 4, according to weight percent, when the amount of negative ion powder is 5%, the bending strength of plate, impact are tough Property and impact flexibility meet mechanical requirements, therefore, anion layer be added negative ion powder amount increase after, to the mechanical property of plate It influences little.
Embodiment 5
According to weight percent, anion layer includes the following raw material: particulate material 60~63%, silica flour 22~26%, Colored pigment 1~1.2%, silane coupling agent 0.3~0.7%, unsaturated polyester resin 10~13%, curing agent 1~1.3%, Negative ion powder 2~4%.
Preparation method includes the following steps:
(1) each component is weighed according to blank layer formula and anion layer formula respectively, the blank layer formula is granular raw Expect 60%, silica flour 24%, colored pigment 1.1%, silane coupling agent 0.7%, unsaturated polyester resin 13%, curing agent 1.2%, the formula of the anion layer is particulate material 60%, silica flour 22%, colored pigment 1.2%, silane coupling agent 0.3%, unsaturated polyester resin 11.2%, curing agent 1.3%, negative ion powder 4%；Wherein, according to weight percent, anion Powder is mixed by tourmaline 95%, cerium oxide 2%, aluminium oxide 3%；
(2) it stirs: will be according to the weighed quartz particles of the blank layer formula, glass particle, silane coupling agent in duplicate rows It is pre-mixed in planetary agitator；The unsaturated polyester resin mixed, curing agent and colored pigment are poured into double planetary to stir It mixes in bucket and is mixed, silica flour is then added and is mixed.15~55Hz of stirring frequency, 300~500s of mixing time；
Weighed quartz particles, glass particle, silane coupling agent will be formulated according to the anion layer to stir in double planetary It mixes in bucket and is pre-mixed；The unsaturated polyester resin mixed, curing agent, colored pigment and Zinc oxide antibacterial agent are poured into double It is mixed in planetary agitator, silica flour is then added and is mixed.15~55Hz of stirring frequency, mixing time 300~ 500s；
(3) cloth: the material mixed feeding beater is further broken up respectively, after breaing up, is entered through electronic measurement The lower layer of cloth in material distributing machine, cloth is anion layer, and upper layer is blanket layer；
(4) it suppresses: after cloth is completed, repressed vibration equipment compression moulding, pressure under the vacuum condition of -0.1Mpa 50~200t, 30~55Hz of vibration frequency, 60~600s of time；
(5) heat cure: after vibration compacting, into curing apparatus, 80~130 DEG C at a temperature of solidify, curing time It is 30~180 minutes；
(6) after the completion of solidifying, the room temperature completely rear plate thicknessing machine that enters to be cooled determines thickness, sets using water mill polishing It is standby to be polished；
To anion quartz made from embodiment 5, according to GB/T 28628-2018, " material induces air ion and measures examination Method " it static determination and carries out dynamic method and determines its amount for generating anion, result is as follows:
The negative aeroion amount of inducing of 5 quartzite slate of embodiment is measured by static determination are as follows: 6.5 × 103ions/ socm2；
The negative aeroion amount of inducing of 5 quartzite slate of embodiment is measured by dynamic method are as follows: 4100ions/m3；
The quantity of plate generation anion can be made to get a promotion it is found that negative ion powder is added by measurement result, according to weight Percentage, when the amount for adding negative ion powder is 4% and negative ion powder includes tourmaline 95%, cerium oxide 2%, aluminium oxide 3% When, the negative aeroion amount of inducing of quartzite slate are as follows: 6.5 × 103ions/socm2, the effect for generating negative aeroion is obvious. Anion quartz made from embodiment 5 is carried out to the experiment of machanics of bending strength, impact flexibility and anti-ball falling impact, as a result such as Shown in table 5；
Table 5
As shown in Table 5, according to weight percent, when the amount of negative ion powder is 4%, the bending strength of plate, impact are tough Property and impact flexibility meet mechanical requirements, therefore, when be added negative ion powder amount be 4% when, to the Effect on Mechanical Properties of plate It is little.
Embodiment 6
(1) each component is weighed according to blank layer formula and anion layer formula respectively, the blank layer formula is granular raw Expect 60%, silica flour 24%, colored pigment 1.1%, silane coupling agent 0.7%, unsaturated polyester resin 13%, curing agent 1.2%, the formula of the anion layer is particulate material 60%, silica flour 19.08%, colored pigment 1.2%, silane coupling agent 0.42%, unsaturated polyester resin 13%, curing agent 1.3%, negative ion powder 5%；Wherein, negative ion powder by tourmaline 96%, Cerium oxide 3%, aluminium oxide 1% is mixed；
(2) it stirs: will be according to the weighed quartz particles of the blank layer formula, glass particle, silane coupling agent in duplicate rows It is pre-mixed in planetary agitator；The unsaturated polyester resin mixed, curing agent and colored pigment are poured into double planetary to stir It mixes in bucket and is mixed, silica flour is then added and is mixed.15~55Hz of stirring frequency, 300~500s of mixing time；
Weighed quartz particles, glass particle, silane coupling agent will be formulated according to the anion layer to stir in double planetary It mixes in bucket and is pre-mixed；The unsaturated polyester resin mixed, curing agent, colored pigment and Zinc oxide antibacterial agent are poured into double It is mixed in planetary agitator, silica flour is then added and is mixed.15~55Hz of stirring frequency, mixing time 300~ 500s；
(3) cloth: the material mixed feeding beater is further broken up respectively, after breaing up, is entered through electronic measurement The lower layer of cloth in material distributing machine, cloth is anion layer, and upper layer is blanket layer；
(4) it suppresses: after cloth is completed, repressed vibration equipment compression moulding, pressure under the vacuum condition of -0.1Mpa 50~200t, 30~55Hz of vibration frequency, 60~600s of time；
(5) heat cure: after vibration compacting, into curing apparatus, 80~130 DEG C at a temperature of solidify, curing time It is 30~180 minutes；
(6) after the completion of solidifying, the room temperature completely rear plate thicknessing machine that enters to be cooled determines thickness, sets using water mill polishing It is standby to be polished；
To anion quartz made from embodiment 6, according to GB/T 28628-2018, " material induces air ion and measures examination Method " it static determination and carries out dynamic method and determines its amount for generating anion, result is as follows:
The negative aeroion amount of inducing of 6 quartzite slate of embodiment is measured by static determination are as follows: 7.7 × 103ions/ socm2；
The negative aeroion amount of inducing of 6 quartzite slate of embodiment is measured by dynamic method are as follows: 5200ions/m3；
The quantity of plate generation anion can be made to get a promotion it is found that negative ion powder is added by measurement result, according to weight Percentage, when the amount for adding negative ion powder is 5% and negative ion powder includes tourmaline 96%, cerium oxide 3%, aluminium oxide 1% When, the negative aeroion amount of inducing of quartzite slate are as follows: 7.7 × 103ions/socm2, the effect for generating negative aeroion is obvious.
The mechanics that anion quartz made from embodiment 6 is carried out bending strength, impact flexibility and anti-ball falling impact is real It tests, the results are shown in Table 6；
Table 6
As shown in Table 6, according to weight percent, when the amount of negative ion powder is 5%, and negative ion powder is by tourmaline 96%, when cerium oxide 3%, aluminium oxide 1% is mixed, bending strength, impact flexibility and the impact flexibility of plate meet mechanics It is required that therefore, it is little to the Effect on Mechanical Properties of plate.
Embodiment 7
(1) each component is weighed according to blank layer formula and anion layer formula respectively, the blank layer formula is granular raw Expect 60%, silica flour 24%, colored pigment 1.1%, silane coupling agent 0.7%, unsaturated polyester resin 13%, curing agent 1.2%, the formula of the anion layer is particulate material 60%, silica flour 21.08%, colored pigment 1.2%, silane coupling agent 0.42%, unsaturated polyester resin 13%, curing agent 1.3%, negative ion powder 3%；Wherein, negative ion powder by tourmaline 98%, Cerium oxide 1%, aluminium oxide 1% is mixed；
(2) it stirs: will be according to the weighed quartz particles of the blank layer formula, glass particle, silane coupling agent in duplicate rows It is pre-mixed in planetary agitator；The unsaturated polyester resin mixed, curing agent and colored pigment are poured into double planetary to stir It mixes in bucket and is mixed, silica flour is then added and is mixed.15~55Hz of stirring frequency, 300~500s of mixing time；
Weighed quartz particles, glass particle, silane coupling agent will be formulated according to the anion layer to stir in double planetary It mixes in bucket and is pre-mixed；The unsaturated polyester resin mixed, curing agent, colored pigment and Zinc oxide antibacterial agent are poured into double It is mixed in planetary agitator, silica flour is then added and is mixed.15~55Hz of stirring frequency, mixing time 300~ 500s；
(3) cloth: the material mixed feeding beater is further broken up respectively, after breaing up, is entered through electronic measurement The lower layer of cloth in material distributing machine, cloth is anion layer, and upper layer is blanket layer；
(4) it suppresses: after cloth is completed, repressed vibration equipment compression moulding, pressure under the vacuum condition of -0.1Mpa 50~200t, 30~55Hz of vibration frequency, 60~600s of time；
(5) heat cure: after vibration compacting, into curing apparatus, 80~130 DEG C at a temperature of solidify, curing time It is 30~180 minutes；
(6) after the completion of solidifying, the room temperature completely rear plate thicknessing machine that enters to be cooled determines thickness, sets using water mill polishing It is standby to be polished；
To anion quartz made from embodiment 7, according to GB/T 28628-2018, " material induces air ion and measures examination Method " it static determination and carries out dynamic method and determines its amount for generating anion, result is as follows:
The negative aeroion amount of inducing of 7 quartzite slate of embodiment is measured by static determination are as follows: 3.22 × 103ions/socm2；
The negative aeroion amount of inducing of 7 quartzite slate of embodiment is measured by dynamic method are as follows: 2500ions/m3；
The quantity of plate generation anion can be made to get a promotion it is found that negative ion powder is added by measurement result, according to weight Percentage, when the amount for adding negative ion powder is 3%, the negative aeroion amount of inducing of quartzite slate are as follows: 3.22 × 103ions/socm2, generate when the amount of negative aeroion than the amount for adding anion is 1% and reduced.
The mechanics that anion quartz made from embodiment 7 is carried out bending strength, impact flexibility and anti-ball falling impact is real It tests, the results are shown in Table 7；
Embodiment 7
Bending strength/Mpa 52.3
Elasticity modulus/Gpa 42
Impact flexibility/kj/m2 3.17
Ball falling impact/cm 39
Plate thickness/mm 13.9
Table 7
As shown in Table 7, according to weight percent, when the amount of negative ion powder is 3%, the bending strength of plate, impact are tough Property and impact flexibility meet mechanical requirements, therefore, after the amount increase of negative ion powder is added, very to the Effect on Mechanical Properties of plate It is micro-.
Comparative example 1
(1) each component is weighed according to following weight percent: particulate material 60%, silica flour 24.08%, colored pigment 1.2%, silane coupling agent 0.42%, unsaturated polyester resin 13%, curing agent 1.3%.
(2) it stirs: weighed particulate material, silane coupling agent is pre-mixed in double planetary agitator；It will mix Good unsaturated polyester resin, curing agent, decoration colored pigment and Zinc oxide antibacterial agent pour into double planetary agitator into Then row mixing is added silica flour and is mixed.15~55Hz of stirring frequency, 180~600s of mixing time；
(3) cloth: the material mixed feeding beater is further broken up, after breaing up, enters cloth through electronic measurement Cloth in machine；
(4) it suppresses: after cloth is completed, repressed vibration equipment compression moulding, pressure under the vacuum condition of -0.1Mpa 50~200t, 30~55Hz of vibration frequency, 60~600s of time；
(5) heat cure: after vibration compacting, into curing apparatus, 80~130 DEG C at a temperature of solidify, curing time It is 30~180 minutes；
(6) after the completion of solidifying, the room temperature completely rear plate thicknessing machine that enters to be cooled determines thickness, sets using water mill polishing It is standby to be polished.
To anion quartz made from comparative example 1, according to GB/T 28628-2018, " material induces air ion amount Test method " it static determination and carries out dynamic method and determines its amount for generating anion, result is as follows:
As static determination measure comparative example 1 made from quartzite slate the negative aeroion amount of inducing are as follows: 1.23×103ions/socm2；
As dynamic method measure comparative example 1 made from quartzite slate the negative aeroion amount of inducing are as follows: 200ions/m2；
The quantity of plate generation anion can be made to get a promotion it is found that negative ion powder is added by measurement result, according to weight Percentage, when not adding negative ion powder, the negative aeroion amount of inducing of quartzite slate are as follows: 2 × 103ions/socm2, generate The amount of negative aeroion is less.
Quartz made from comparative example 1 is carried out to the experiment of machanics of bending strength, impact flexibility and anti-ball falling impact, The results are shown in Table 8；
Comparative example 1
Bending strength/Mpa 51
Elasticity modulus/Gpa 32.4
Impact flexibility/kj/m2 3.07
Ball falling impact/cm 45
Plate thickness/mm 13.6
Table 8
It can verify that from test data, the quantity that the addition of negative ion powder can make plate generate anion gets a promotion, by reality Example 1~7 is applied it is found that according to weight percent, when the additive amount of negative ion powder in anion layer is 0.5~5%, quartz slate Material can produce a large amount of anion and smaller to the Effect on Mechanical Properties of plate；
By embodiment 4~6 it is found that according to weight percent hundred, when the negative ion powder in anion layer by tourmaline 95~ 98%, when cerium oxide 1~3%, aluminium oxide 1~3% form, the amount for generating anion is more, wherein when negative ion powder is by electrical When stone 98%, cerium oxide 1%, aluminium oxide 1%, the effect for generating anion is best, and to the mechanical property shadow of quartzite slate Sound is smaller.
By comparative example 1 it is found that when plate does not add negative ion powder, quartzite slate obtained generates anion Negligible amounts；
Therefore the amount for selecting negative ion powder is 0.5~10%, and the group of negative ion powder becomes tourmaline 95~98%, oxidation When cerium 1~3%, aluminium oxide 1~3%, guarantee the good mechanical properties of quartzite slate produced；Since negative ion powder need to only add Enter into anion layer and cloth expects the lower section of blanket layer, therefore the total amount for adding negative ion powder is added in quartzy stone substrate It compares, production cost is greatly saved, be conducive to large-scale popularization use.
The technical principle of the invention is described above in combination with a specific embodiment.These descriptions are intended merely to explain of the invention Principle, and shall not be construed in any way as a limitation of the scope of protection of the invention.Based on the explanation herein, the technology of this field Personnel can associate with other specific embodiments of the invention without creative labor, these modes are fallen within Within protection scope of the present invention.

Claims (8)

1. the quartz that a kind of layering generates anion, which is characterized in that including blanket layer and anion layer, the anion layer It is laid in the lower section of the blanket layer, the anion layer includes the following raw material: particulate material 55~65%, silica flour 20~ 30%, colored pigment 0.01~10%, silane coupling agent 0.1~1%, unsaturated polyester resin 8~14%, curing agent 0.8~ 1.4%, negative ion powder 0.5~5%；
The negative ion powder includes tourmaline 95~98%, cerium oxide 1~3%, aluminium oxide 1~3%.
2. the quartz that a kind of layering according to claim 1 generates anion, which is characterized in that according to weight percent Than the blanket layer includes the following raw material: particulate material 55~65%, silica flour 20~30%, colored pigment 0.01~10%, Silane coupling agent 0.1~1%, unsaturated polyester resin 8~14%, curing agent 0.8~1.4%.
3. the quartz that a kind of layering according to claim 1 generates anion, which is characterized in that the particulate material Particle size is 0.075~5mm, and the particle size of the silica flour is 0.005~0.045mm.
4. the quartz that a kind of layering according to claim 1 generates anion, which is characterized in that the colored pigment is Inorganic pigment, organic pigment, mill base it is one or more, the inorganic pigment is titanium white, medium chrome yellow, iron oxide yellow, iron oxide red, iron oxide black It is one or more, the organic pigment be pigment scarlet powder, dark green, phthalocyanine blue it is one or more, the mill base be it is white slurry, it is black Slurry, bright red slurry, dark green slurry, phthalocyanine blue are starched one or more.
5. the quartz that a kind of layering according to claim 1 generates anion, which is characterized in that the unsaturated polyester (UP) Resin is one of epoxy resin, phenolic resin, acrylic resin, polyurethane resin or a variety of.
6. the quartz that a kind of layering according to claim 1 generates anion, which is characterized in that the curing agent was It is more to aoxidize (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate, dibenzoyl peroxide, fat One of first amine is a variety of.
7. the quartz that a kind of layering according to claim 1 generates anion, which is characterized in that the silane coupling agent For γ-methacryloxypropyl trimethoxy silane, γ-(2,3- the third oxygen of epoxy) propyl trimethoxy silicane, N- β (ammonia Ethyl)-γ-aminopropyltriethoxy dimethoxysilane, N- (β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N- β (ammonia second Base)-γ-aminopropyltrimethoxysilane, anilinomethyl triethoxysilane, gamma-aminopropyl-triethoxy-silane, vinyl three One of Ethoxysilane, vinyltrimethoxysilane and γ-chloropropyl triethoxysilane are a variety of.
8. the quartz that a kind of layering generates anion, which comprises the following steps:
(1) each component is weighed according to blank layer formula and anion layer formula respectively, the blank layer formula is particulate material 60 ~63%, silica flour 22~26%, colored pigment 1~1.2%, silane coupling agent 0.3~0.7%, unsaturated polyester resin 10 ~13%, the formula of curing agent 1~1.2%, the antimicrobial coating is particulate material 55~65%, silica flour 20~30%, has Color pigment 0.01~10%, unsaturated polyester resin 8~14%, curing agent 0.8~1.4%, is born silane coupling agent 0.1~1% Ion powder 0.5~5%；
(2) it stirs: will be according to the weighed quartz particles of the blank layer formula, glass particle, silane coupling agent in double planetary It is pre-mixed in agitator；The unsaturated polyester resin mixed, curing agent and colored pigment are poured into double planetary agitator In mixed, then be added silica flour mixed, 15~55Hz of stirring frequency, 300~500s of mixing time；
Weighed quartz particles, glass particle, silane coupling agent will be formulated according to the anion layer in double planetary agitator Middle premixing；The unsaturated polyester resin mixed, curing agent, colored pigment and Zinc oxide antibacterial agent are poured into double-planet It is mixed in formula agitator, silica flour is then added and is mixed, 15~55Hz of stirring frequency, 300~500s of mixing time；
(3) cloth: the material mixed feeding beater is further broken up respectively, after breaing up, enters cloth through electronic measurement The lower layer of cloth in machine, cloth is anion layer, and upper layer is blanket layer；
(4) it suppresses: after cloth is completed, the repressed vibration equipment compression moulding under the vacuum condition of -0.1Mpa, pressure 50~ 200t, 30~55Hz of vibration frequency, 60~600s of time；
(5) heat cure: after vibration compacting, into curing apparatus, 80~130 DEG C at a temperature of solidify, curing time 30 ~180 minutes；
(6) after the completion of solidifying, room temperature it is to be cooled completely after enter the fixed thickness of plate thicknessing machine, using water mill polissoir into Row polishing.
CN201910294746.0A 2019-04-12 2019-04-12 A kind of layering generates the quartz and preparation method of anion Pending CN109956704A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008081988A1 (en) * 2006-12-28 2008-07-10 Fujifilm Corporation Curable composition, color filter, and manufacturing method of the same
CN103232219A (en) * 2013-04-24 2013-08-07 华南理工大学 Inorganic artificial stone with negative ion function and preparation method thereof
CN104961383A (en) * 2015-06-10 2015-10-07 安徽广燕新材料科技有限责任公司 Impact and bending resistant environmentally-friendly rostone sheet
CN107117866A (en) * 2017-05-19 2017-09-01 广东中旗新材料科技有限公司 A kind of High-strength artificial quartz stone plate and preparation method thereof
CN207332184U (en) * 2017-07-31 2018-05-08 肇庆乐华陶瓷洁具有限公司 A kind of wide reason stone of new wax
CN108484224A (en) * 2017-12-09 2018-09-04 王贵锋 One kind can make material surface generate negative oxygen ion composition and surface treatment method

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008081988A1 (en) * 2006-12-28 2008-07-10 Fujifilm Corporation Curable composition, color filter, and manufacturing method of the same
CN103232219A (en) * 2013-04-24 2013-08-07 华南理工大学 Inorganic artificial stone with negative ion function and preparation method thereof
CN104961383A (en) * 2015-06-10 2015-10-07 安徽广燕新材料科技有限责任公司 Impact and bending resistant environmentally-friendly rostone sheet
CN107117866A (en) * 2017-05-19 2017-09-01 广东中旗新材料科技有限公司 A kind of High-strength artificial quartz stone plate and preparation method thereof
CN207332184U (en) * 2017-07-31 2018-05-08 肇庆乐华陶瓷洁具有限公司 A kind of wide reason stone of new wax
CN108484224A (en) * 2017-12-09 2018-09-04 王贵锋 One kind can make material surface generate negative oxygen ion composition and surface treatment method

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