CN104961383A - Impact and bending resistant environmentally-friendly rostone sheet - Google Patents
Impact and bending resistant environmentally-friendly rostone sheet Download PDFInfo
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- CN104961383A CN104961383A CN201510315869.XA CN201510315869A CN104961383A CN 104961383 A CN104961383 A CN 104961383A CN 201510315869 A CN201510315869 A CN 201510315869A CN 104961383 A CN104961383 A CN 104961383A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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Abstract
The invention discloses an impact and bending resistant environmentally-friendly rostone sheet. Raw materials of the sheet comprise, by weight, 8-12 parts of aluminum hydroxide powder, 3-7 parts of quartz sand, 50-60 parts of granite powder, 0.3-0.5 parts of gamma-trimethoxysilyl propyl methacrylate, 30-40 parts of isophthalic acid-neopentylene glycol resin, 5-9 parts of modified negative ion powder, 6-8 parts of glass fibers, 0.4-0.6 parts of cobalt isooctoate, 0.7-1 part of methylethyl ketone peroxide, 0.2-1 part of a higher alcohol fatty acid ester complex, 0.5-1.5 parts of an antioxidant 1010 and 0.3-0.7 parts of a pigment. The rostone sheet has strong impact and bending resistance, and can purify air to realize an environmental protection effect.
Description
Technical field
The present invention relates to building material technical field, particularly relate to the counter-bending environmental protection artificial slabstone of a kind of shock resistance.
Background technology
At present, the produced quantity of grouan is increasing, when to processing of stone, annual produces about 400,000 tons of waste stone dust and building stones, the transport of these waste stone dust and building stones and store up and create larger pollution to environment, and brings serious storage problem.
In building decoration field, rostone is with its cost and performance advantage, one of primary decoration material becoming construction and decoration gradually, but in use, still there is the shortcomings such as acid resistance difference, intensity is low, resistance to bend is poor, shock resistance is poor in rostone, and most of Engineered stone products adopts unsaturated polyester as binder material, produce, processing, existence is in various degree certain in use procedure atmospheric pollution, do not meet the environment-friendly and green building standard that country advocates.Therefore need to prepare a kind of shock resistance, counter-bending and can purify air, the rostone of environmental protection.
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes the counter-bending environmental protection artificial slabstone of a kind of shock resistance, shock resistance of the present invention, bending resistance by force, can purify air, play the effect of environmental protection.
The counter-bending environmental protection artificial slabstone of a kind of shock resistance that the present invention proposes, its raw material comprises by weight: aluminium hydrate powder 8-12 part, quartz sand 3-7 part, granite powder 50-60 part, γ-methacryloxypropyl trimethoxy silane 0.3-0.5 part, m-phthalic acid-neopentyl glycol resins 30-40 part, modified negative-ion powder 5-9 part, glass fibre 6-8 part, cobalt iso-octoate 0.4-0.6 part, methylethyl ketone peroxide 0.7-1 part, higher alcohols fatty acid ester compounded thing 0.2-1 part, antioxidant 1010 0.5-1.5 part, pigment 0.3-0.7 part;
Wherein, the preparation method of modified negative-ion powder is as follows: 1.1-1.5 part TH-361 polycarboxylate and 45-55 part deionized water are mixed by weight and obtain material A; 45-55 part tourmaline powder and 13-17 part cerium oxide are mixed and obtains material B; Material A added in material B, be warming up to 60-80 DEG C, stir 70-90min with the stirring velocity of 100-300r/min and obtain material C, grinding material C5-7h obtains modified negative-ion powder, and wherein tourmaline powder and cerium oxide are 900-1300 order.
Preferably, the weight ratio 9-11:4-6:55-60:0.35-0.45 of aluminium hydrate powder, quartz sand, granite powder and γ-methacryloxypropyl trimethoxy silane, wherein aluminium hydrate powder, quartz sand are 500 orders.
Preferably, the particle diameter of granite powder is 25-160 μm, wherein, particle diameter to be granite powder, the particle diameter of 150-160 μm be granite powder, the particle diameter of 60-70 μm the be granite powder of 45-50 μm and particle diameter are the weight ratio of the granite powder of 25-30 μm is 1:1-2:1-3:1-6.
Preferably, the weight ratio of m-phthalic acid-neopentyl glycol resins, modified negative-ion powder and glass fibre is 35-40:6-8:6.5-7.5, wherein, the acid-alcohol ratio in m-phthalic acid-neopentyl glycol resins is 1.04-1.06:1, and the length of glass fibre is 5-10cm.
Preferably, the weight ratio of cobalt iso-octoate and methylethyl ketone peroxide is 0.45-0.55:0.8-0.9.
Preferably, its raw material comprises by weight: aluminium hydrate powder 9-11 part, quartz sand 4-6 part, granite powder 55-60 part, γ-methacryloxypropyl trimethoxy silane 0.35-0.45 part, m-phthalic acid-neopentyl glycol resins 35-40 part, modified negative-ion powder 6-8 part, glass fibre 6.5-7.5 part, cobalt iso-octoate 0.45-0.55 part, methylethyl ketone peroxide 0.8-0.9 part, higher alcohols fatty acid ester compounded thing 0.5-0.7 part, antioxidant 1010 0.7-0.9 part, pigment 0.4-0.6 part.
Preferably, pigment is 200-300 order.
Preferably, the preparation method of modified negative-ion powder is as follows: 1.2-1.4 part TH-361 polycarboxylate and 48-52 part deionized water are mixed by weight and obtain material A; 48-52 part tourmaline powder and 14-16 part cerium oxide are mixed and obtains material B; Material A added in material B, be warming up to 65-75 DEG C, stir 75-85min with the stirring velocity of 150-250r/min and obtain material C, grinding material C5.5-6.5h obtains modified negative-ion powder, and wherein tourmaline powder and cerium oxide are 1100-1200 order.
Waste stone dust, barren rock material remaining when granite powder in the present invention is exploitation grouan.
Preparation method of the present invention is as follows: γ-methacryloxypropyl trimethoxy silane joined and obtain solution a to dissolve in γ-methacryloxypropyl trimethoxy silane weight part ethanol of 10 times that is benchmark; Aluminium hydrate powder, quartz sand and granite powder being joined temperature is in the fluidized-bed of 120 DEG C, and after stirring 30min with the stirring velocity of 500r/min, spray solution a, stirs 10min with the stirring velocity of 800r/min and obtain material b; M-phthalic acid-neopentyl glycol resins, modified negative-ion powder, glass fibre, cobalt iso-octoate, methylethyl ketone peroxide, the fatty acid ester compounded thing of higher alcohols, antioxidant 1010 and pigment are mixed, 30min is stirred with the stirring velocity of 2000r/min, add material b, continue to stir 20min, after vacuum defoamation, be cast in mould, obtain the counter-bending environmental protection artificial slabstone of shock resistance in 70 DEG C of solidifications, the demoulding, calmly thick, polishing.
The present invention selects the waste stone dust of granite powder, barren rock material as base-material, decreases the amount of making of quartz sand, aluminium hydrate powder, has saved cost of the present invention and the pollution decreased environment, aluminium hydrate powder not only can increase flame retardant resistance of the present invention as filler but also as fire retardant, γ-methacryloxypropyl trimethoxy silane and aluminium hydrate powder, quartz sand, granite powder and m-phthalic acid-neopentyl glycol resins cooperatively interact, greatly improve the affinity between each raw material of the present invention, increase bounding force of the present invention and intensity, and can greatly increase water tolerance of the present invention, rotproofness, tint permanence, intensity and impelling strength, the properties of m-phthalic acid-neopentyl glycol resins can be improved when wherein m-phthalic acid-neopentyl glycol resins has suitable acid-alcohol ratio, and then increase water tolerance of the present invention further, rotproofness, tint permanence, intensity and impelling strength, the burst size of negative ion in tourmalinite greatly can be increased after cerium oxide mixes with tourmalinite, carry out after modified abrasive obtains modified negative-ion powder with TH-361 polycarboxylate to cerium oxide and tourmalinite, modified negative-ion powder can be made evenly be dispersed in quartz sand, aluminium hydrate powder, granite powder and m-phthalic acid-neopentyl glycol resins, improve consistency, and then increase shock resistance of the present invention and bending resistance, and can purify air by even, a large amount of anion releasings, environmental protect, glass fibre, cobalt iso-octoate and methylethyl ketone peroxide interact can increase shock resistance of the present invention, bending resistance, and the glass fibre of suitable length is while increase toughness of the present invention, can also mix with unclassified stores, improve shock resistance of the present invention, bending resistance further, the fatty acid ester compounded thing of higher alcohols can eliminate foam makes the present invention smooth, smooth, and antioxidant 1010 can increase resistance of oxidation of the present invention, and different pigment can increase variation of the present invention.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
The counter-bending environmental protection artificial slabstone of a kind of shock resistance, its raw material comprises by weight: 500 object aluminium hydrate powders 8 parts, 500 object quartz sands 7 parts, granite powder 50 parts, γ-methacryloxypropyl trimethoxy silane 0.3 part, acid-alcohol ratio is the m-phthalic acid-neopentyl glycol resins 30 parts of 1.06:1,9 parts, modified negative-ion powder, length is 8 parts, the glass fibre of 5cm, cobalt iso-octoate 0.4 part, methylethyl ketone peroxide 1 part, the fatty acid ester compounded thing of higher alcohols 0.2 part, antioxidant 1010 1.5 parts, 200 object pigment 0.7 part;
Wherein, the particle diameter of granite powder is 25-160 μm, and the weight ratio of the granite powder that the granite powder that particle diameter is 150-160 μm, particle diameter are 60-70 μm, particle diameter to be the granite powder of 45-50 μm and particle diameter the be granite powder of 25-30 μm is 1:2:1:6;
The preparation method of modified negative-ion powder is as follows: 1.1 parts of TH-361 polycarboxylates and 55 parts of deionized waters are mixed by weight and obtain material A; 45 parts of tourmaline powders and 17 parts of cerium oxide are mixed and obtains material B; Material A added in material B, be warming up to 60 DEG C, stir 70min with the stirring velocity of 300r/min and obtain material C, grinding material C7h obtains modified negative-ion powder, and wherein tourmaline powder and cerium oxide are 900 orders.
Embodiment 2
The counter-bending environmental protection artificial slabstone of a kind of shock resistance, its raw material comprises by weight: 500 object aluminium hydrate powders 12 parts, 500 object quartz sands 3 parts, granite powder 60 parts, γ-methacryloxypropyl trimethoxy silane 0.5 part, acid-alcohol ratio is the m-phthalic acid-neopentyl glycol resins 40 parts of 1.04:1,5 parts, modified negative-ion powder, length is 6 parts, the glass fibre of 10cm, cobalt iso-octoate 0.6 part, methylethyl ketone peroxide 0.7 part, the fatty acid ester compounded thing of higher alcohols 1 part, antioxidant 1010 0.5 part, 300 object pigment 0.3 part;
Wherein, the particle diameter of granite powder is 25-160 μm, and the weight ratio of the granite powder that the granite powder that particle diameter is 150-160 μm, particle diameter are 60-70 μm, particle diameter to be the granite powder of 45-50 μm and particle diameter the be granite powder of 25-30 μm is 1:1:3:1;
The preparation method of modified negative-ion powder is as follows: 1.5 parts of TH-361 polycarboxylates and 45 parts of deionized waters are mixed by weight and obtain material A; 55 parts of tourmaline powders and 13 parts of cerium oxide are mixed and obtains material B; Material A added in material B, be warming up to 80 DEG C, stir 90min with the stirring velocity of 100r/min and obtain material C, grinding material C5h obtains modified negative-ion powder, and wherein tourmaline powder and cerium oxide are 1300 orders.
Embodiment 3
The counter-bending environmental protection artificial slabstone of a kind of shock resistance, its raw material comprises by weight: 500 object aluminium hydrate powders 9 parts, 500 object quartz sands 6 parts, granite powder 55 parts, γ-methacryloxypropyl trimethoxy silane 0.35 part, acid-alcohol ratio is the m-phthalic acid-neopentyl glycol resins 35 parts of 1.06:1,8 parts, modified negative-ion powder, length is 7.5 parts, the glass fibre of 7cm, cobalt iso-octoate 0.45 part, methylethyl ketone peroxide 0.9 part, the fatty acid ester compounded thing of higher alcohols 0.5 part, antioxidant 1010 0.9 part, 230 object pigment 0.6 part;
Wherein, the particle diameter of granite powder is 25-160 μm, and the weight ratio of the granite powder that the granite powder that particle diameter is 150-160 μm, particle diameter are 60-70 μm, particle diameter to be the granite powder of 45-50 μm and particle diameter the be granite powder of 25-30 μm is 1:1.8:1.5:4;
The preparation method of modified negative-ion powder is as follows: 1.2 parts of TH-361 polycarboxylates and 52 parts of deionized waters are mixed by weight and obtain material A; 48 parts of tourmaline powders and 16 parts of cerium oxide are mixed and obtains material B; Material A added in material B, be warming up to 65 DEG C, stir 75min with the stirring velocity of 250r/min and obtain material C, grinding material C6.5h obtains modified negative-ion powder, and wherein tourmaline powder and cerium oxide are 1100 orders.
Embodiment 4
The counter-bending environmental protection artificial slabstone of a kind of shock resistance, its raw material comprises by weight: 500 object aluminium hydrate powders 11 parts, 500 object quartz sands 4 parts, granite powder 59 parts, γ-methacryloxypropyl trimethoxy silane 0.45 part, acid-alcohol ratio is the m-phthalic acid-neopentyl glycol resins 39 parts of 1.04:1,6 parts, modified negative-ion powder, length is 6.5 parts, the glass fibre of 8cm, cobalt iso-octoate 0.55 part, methylethyl ketone peroxide 0.8 part, the fatty acid ester compounded thing of higher alcohols 0.7 part, antioxidant 1010 0.7 part, 270 object pigment 0.4 part;
Wherein, the particle diameter of granite powder is 25-160 μm, and the weight ratio of the granite powder that the granite powder that particle diameter is 150-160 μm, particle diameter are 60-70 μm, particle diameter to be the granite powder of 45-50 μm and particle diameter the be granite powder of 25-30 μm is 1:1.2:2.5:3;
The preparation method of modified negative-ion powder is as follows: 1.4 parts of TH-361 polycarboxylates and 48 parts of deionized waters are mixed by weight and obtain material A; 52 parts of tourmaline powders and 14 parts of cerium oxide are mixed and obtains material B; Material A added in material B, be warming up to 75 DEG C, stir 85min with the stirring velocity of 150r/min and obtain material C, grinding material C5.5h obtains modified negative-ion powder, and wherein tourmaline powder and cerium oxide are 1200 orders.
Embodiment 5
The counter-bending environmental protection artificial slabstone of a kind of shock resistance, its raw material comprises by weight: 500 object aluminium hydrate powders 10 parts, 500 object quartz sands 5 parts, granite powder 58 parts, γ-methacryloxypropyl trimethoxy silane 0.45 part, acid-alcohol ratio is the m-phthalic acid-neopentyl glycol resins 37 parts of 1.05:1,7 parts, modified negative-ion powder, length is 7 parts, the glass fibre of 7.5cm, cobalt iso-octoate 0.5 part, methylethyl ketone peroxide 0.7 part, the fatty acid ester compounded thing of higher alcohols 0.6 part, antioxidant 1010 0.8 part, 300 object pigment 0.5 part;
Wherein, the particle diameter of granite powder is 25-160 μm, and the weight ratio of the granite powder that the granite powder that particle diameter is 150-160 μm, particle diameter are 60-70 μm, particle diameter to be the granite powder of 45-50 μm and particle diameter the be granite powder of 25-30 μm is 1:1.5:2:3.5;
The preparation method of modified negative-ion powder is as follows: 1.3 parts of TH-361 polycarboxylates and 50 parts of deionized waters are mixed by weight and obtain material A; 50 parts of tourmaline powders and 15 parts of cerium oxide are mixed and obtains material B; Material A added in material B, be warming up to 70 DEG C, stir 80min with the stirring velocity of 200r/min and obtain material C, grinding material C6h obtains modified negative-ion powder, and wherein tourmaline powder and cerium oxide are 1200 orders.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (8)
1. the counter-bending environmental protection artificial slabstone of shock resistance, it is characterized in that, its raw material comprises by weight: aluminium hydrate powder 8-12 part, quartz sand 3-7 part, granite powder 50-60 part, γ-methacryloxypropyl trimethoxy silane 0.3-0.5 part, m-phthalic acid-neopentyl glycol resins 30-40 part, modified negative-ion powder 5-9 part, glass fibre 6-8 part, cobalt iso-octoate 0.4-0.6 part, methylethyl ketone peroxide 0.7-1 part, higher alcohols fatty acid ester compounded thing 0.2-1 part, antioxidant 1010 0.5-1.5 part, pigment 0.3-0.7 part;
Wherein, the preparation method of modified negative-ion powder is as follows: 1.1-1.5 part TH-361 polycarboxylate and 45-55 part deionized water are mixed by weight and obtain material A; 45-55 part tourmaline powder and 13-17 part cerium oxide are mixed and obtains material B; Material A added in material B, be warming up to 60-80 DEG C, stir 70-90min with the stirring velocity of 100-300r/min and obtain material C, grinding material C 5-7h obtains modified negative-ion powder, and wherein tourmaline powder and cerium oxide are 900-1300 order.
2. the counter-bending environmental protection artificial slabstone of shock resistance according to claim 1, it is characterized in that, the weight ratio 9-11:4-6:55-60:0.35-0.45 of aluminium hydrate powder, quartz sand, granite powder and γ-methacryloxypropyl trimethoxy silane, wherein aluminium hydrate powder, quartz sand are 500 orders.
3. according to claim 1 or 2 counter-bending environmental protection artificial slabstones of described shock resistance, it is characterized in that, the particle diameter of granite powder is 25-160 μm, wherein, particle diameter to be granite powder, the particle diameter of 150-160 μm be granite powder, the particle diameter of 60-70 μm the be granite powder of 45-50 μm and particle diameter are the weight ratio of the granite powder of 25-30 μm is 1:1-2:1-3:1-6.
4. the counter-bending environmental protection artificial slabstone of shock resistance according to any one of claim 1-3, it is characterized in that, the weight ratio of m-phthalic acid-neopentyl glycol resins, modified negative-ion powder and glass fibre is 35-40:6-8:6.5-7.5, wherein, acid-alcohol ratio in m-phthalic acid-neopentyl glycol resins is 1.04-1.06:1, and the length of glass fibre is 5-10cm.
5. the counter-bending environmental protection artificial slabstone of shock resistance according to any one of claim 1-4, is characterized in that, the weight ratio of cobalt iso-octoate and methylethyl ketone peroxide is 0.45-0.55:0.8-0.9.
6. the counter-bending environmental protection artificial slabstone of shock resistance according to any one of claim 1-5, it is characterized in that, its raw material comprises by weight: aluminium hydrate powder 9-11 part, quartz sand 4-6 part, granite powder 55-60 part, γ-methacryloxypropyl trimethoxy silane 0.35-0.45 part, m-phthalic acid-neopentyl glycol resins 35-40 part, modified negative-ion powder 6-8 part, glass fibre 6.5-7.5 part, cobalt iso-octoate 0.45-0.55 part, methylethyl ketone peroxide 0.8-0.9 part, higher alcohols fatty acid ester compounded thing 0.5-0.7 part, antioxidant 1010 0.7-0.9 part, pigment 0.4-0.6 part.
7. the counter-bending environmental protection artificial slabstone of shock resistance according to any one of claim 1-6, it is characterized in that, pigment is 200-300 order.
8. the counter-bending environmental protection artificial slabstone of shock resistance according to any one of claim 1-7, it is characterized in that, the preparation method of modified negative-ion powder is as follows: 1.2-1.4 part TH-361 polycarboxylate and 48-52 part deionized water are mixed by weight and obtain material A; 48-52 part tourmaline powder and 14-16 part cerium oxide are mixed and obtains material B; Material A added in material B, be warming up to 65-75 DEG C, stir 75-85min with the stirring velocity of 150-250r/min and obtain material C, grinding material C 5.5-6.5h obtains modified negative-ion powder, and wherein tourmaline powder and cerium oxide are 1100-1200 order.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510315869.XA CN104961383A (en) | 2015-06-10 | 2015-06-10 | Impact and bending resistant environmentally-friendly rostone sheet |
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| CN201510315869.XA CN104961383A (en) | 2015-06-10 | 2015-06-10 | Impact and bending resistant environmentally-friendly rostone sheet |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105217999A (en) * | 2015-10-14 | 2016-01-06 | 苏州法斯特信息科技有限公司 | A kind of high temperature resistant and wear-resisting composite resin material table top |
| CN106630948A (en) * | 2016-12-05 | 2017-05-10 | 苏州洛特兰新材料科技有限公司 | Impact-resisting and high-strength composite ceramic material for building and preparation method of impact-resisting and high-strength composite ceramic material |
| CN108558349A (en) * | 2018-05-25 | 2018-09-21 | 苗霞明 | A kind of preparation method of negative ion type function artificial stone |
| CN109942230A (en) * | 2019-04-12 | 2019-06-28 | 广东中旗新材料股份有限公司 | A kind of anion quartz and preparation method |
| CN109956704A (en) * | 2019-04-12 | 2019-07-02 | 广东中旗新材料股份有限公司 | A kind of layering generates the quartz and preparation method of anion |
| CN109956705A (en) * | 2019-04-12 | 2019-07-02 | 广东中旗新材料股份有限公司 | A kind of quartz and preparation method with antibacterial and anion coating |
| CN110002794A (en) * | 2019-04-12 | 2019-07-12 | 广东中旗新材料股份有限公司 | A kind of anion quartz and preparation method with antibacterial effect |
| CN110002791A (en) * | 2019-04-12 | 2019-07-12 | 广东中旗新材料股份有限公司 | A kind of quartz and preparation method equipped with anion coating |
| CN110002795A (en) * | 2019-04-12 | 2019-07-12 | 广东中旗新材料股份有限公司 | A kind of layering generates the antibacterial quartz and preparation method of anion |
| CN111134499A (en) * | 2020-01-10 | 2020-05-12 | 浙江宏都寝具有限公司 | Antibacterial anti-mite quilt and preparation method thereof |
| CN113045244A (en) * | 2021-04-21 | 2021-06-29 | 王起峰 | Artificial stone processing technology |
| CN113443855A (en) * | 2021-07-30 | 2021-09-28 | 广西利升石业有限公司 | Functional granite capable of releasing negative ions and preparation method thereof |
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- 2015-06-10 CN CN201510315869.XA patent/CN104961383A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105217999A (en) * | 2015-10-14 | 2016-01-06 | 苏州法斯特信息科技有限公司 | A kind of high temperature resistant and wear-resisting composite resin material table top |
| CN106630948A (en) * | 2016-12-05 | 2017-05-10 | 苏州洛特兰新材料科技有限公司 | Impact-resisting and high-strength composite ceramic material for building and preparation method of impact-resisting and high-strength composite ceramic material |
| CN108558349A (en) * | 2018-05-25 | 2018-09-21 | 苗霞明 | A kind of preparation method of negative ion type function artificial stone |
| CN110002794A (en) * | 2019-04-12 | 2019-07-12 | 广东中旗新材料股份有限公司 | A kind of anion quartz and preparation method with antibacterial effect |
| CN109956704A (en) * | 2019-04-12 | 2019-07-02 | 广东中旗新材料股份有限公司 | A kind of layering generates the quartz and preparation method of anion |
| CN109956705A (en) * | 2019-04-12 | 2019-07-02 | 广东中旗新材料股份有限公司 | A kind of quartz and preparation method with antibacterial and anion coating |
| CN109942230A (en) * | 2019-04-12 | 2019-06-28 | 广东中旗新材料股份有限公司 | A kind of anion quartz and preparation method |
| CN110002791A (en) * | 2019-04-12 | 2019-07-12 | 广东中旗新材料股份有限公司 | A kind of quartz and preparation method equipped with anion coating |
| CN110002795A (en) * | 2019-04-12 | 2019-07-12 | 广东中旗新材料股份有限公司 | A kind of layering generates the antibacterial quartz and preparation method of anion |
| CN111134499A (en) * | 2020-01-10 | 2020-05-12 | 浙江宏都寝具有限公司 | Antibacterial anti-mite quilt and preparation method thereof |
| CN111134499B (en) * | 2020-01-10 | 2021-10-19 | 浙江宏都寝具有限公司 | Antibacterial anti-mite quilt and preparation method thereof |
| CN113045244A (en) * | 2021-04-21 | 2021-06-29 | 王起峰 | Artificial stone processing technology |
| CN113443855A (en) * | 2021-07-30 | 2021-09-28 | 广西利升石业有限公司 | Functional granite capable of releasing negative ions and preparation method thereof |
| CN113443855B (en) * | 2021-07-30 | 2022-08-05 | 广西利升石业有限公司 | Functional granite capable of releasing negative ions and preparation method thereof |
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