CN103773090A - Glass reinforced plastic composite coating material with good anti-corrosion effect and preparation method thereof - Google Patents
Glass reinforced plastic composite coating material with good anti-corrosion effect and preparation method thereof Download PDFInfo
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- CN103773090A CN103773090A CN201410016878.4A CN201410016878A CN103773090A CN 103773090 A CN103773090 A CN 103773090A CN 201410016878 A CN201410016878 A CN 201410016878A CN 103773090 A CN103773090 A CN 103773090A
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Abstract
The invention discloses a glass reinforced plastic composite coating material with a good anti-corrosion effect. The glass reinforced plastic composite coating material is characterized by being prepared from the following raw materials in parts by weight: 30-34 parts of E-12 epoxy resin, 9-12 parts of styrene, 6-10 parts of alpha-methyl styrene, 12-14 parts of organic silicon resin, 2-3 parts of polytetrafluoroethylene, 1-2 parts of silane coupling agent KH-550, 2-5 parts of tetrabutylammonium bromide, 15-18 parts of dipropylene glycol diacrylate, 25-29 parts of chopped fiber glass, 5-8 parts of ceramic powder, 10-13 parts of methyl ethyl ketone peroxide, 2-4 parts of KJP-1002 epoxy resin curing agent, 3-5 parts of vaseline, 2-5 parts of tetrabutyl ammonium bromide, 2-4 parts of dipropylene glycol acrylate and 1-2 parts of additive. The glass reinforced plastic composite coating material has good physical performance and mechanical performance due to addition of the additive; the glass reinforced plastic composite coating material has a good anti-corrosion effect and is light in weight, non-toxic, low in cost and suitable for industrial production; a production technology is simple.
Description
Technical field
The present invention relates to a kind of composite coating material and preparation method thereof, glass reinforced plastic composite coating material that particularly a kind of anticorrosion ability is good and preparation method thereof.
Background technology
Glass-reinforced plastic material is embedded in curing thermosetting resin or be wrapped to form the material of composite structure by it by glass fibre reinforcement.The glass-reinforced plastic material of production and application adopts resin infiltration woven fiber glass material to carry out moulding more in the market.The method effect of impregnation is good, and prepared content of glass fiber is high.But owing to being subject to the restriction of woven fiber glass volume and shape, make it be not suitable with especially the product that is difficult for uniform-compression for such as tube stub, tee pipe fitting, bend pipe tools etc.In addition, its impact resistance of glass-reinforced plastic material prepared by the method is poor, and layering easily occurs laminated face.In order to address the above problem, there is investigator that glass fibre is cut into glass fiber powder, then glass fiber powder is put in the mixed solution being formed by epoxy resin, softening agent etc., in ball mill, stir again and add filler, solidifying agent, be prepared into thus a kind of glass-reinforced plastic material that does not contain woven fiber glass laying.Although the glass-reinforced plastic material that the method provides has overcome the defect that woven fiber glass itself causes, because glass fibre is cut into powdery, thereby the peculiar physical property of its fiber itself is also weakened greatly.
Summary of the invention
The object of this invention is to provide glass reinforced plastic composite coating material that a kind of anticorrosion ability is good and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
The glass reinforced plastic composite coating material that anticorrosion ability is good, is made up of the raw material of following weight part: E-12 epoxy resin 30-34, vinylbenzene 9-12, alpha-methyl styrene 6-10, silicone resin 12-14, tetrafluoroethylene 2-3, silane resin acceptor kh-550 1-2, Tetrabutyl amonium bromide 2-5, propylene glycol diacrylate 15-18, short glass fiber 25-29, ceramics powder 5-8, methylethyl ketone peroxide 10-13, KJP-1002 epoxy curing agent 2-4, Vaseline 3-5, Tetrabutyl amonium bromide 2-5, propylene glycol diacrylate 2-4, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight part: iron powder 10-13, zinc acetate 5-7, light calcined magnesia 4-6, medical stone 3-4, talcum powder 3-5, peat 2-3, tri (propylene glycol) diacrylate 2-3, morpholine 1-2, xitix 2-3, silicon carbide 3-4, chitosan 1-2, methyl acrylate 3-4; Iron powder, peat, medical stone, light calcined magnesia are put into calcining furnace by preparation method, at 550-570 ℃, calcine 4-5 hour, take out, mix with talcum powder, xitix, silicon carbide, chitosan, be ground to and obtain 300-400 order powder, then, add again tri (propylene glycol) diacrylate, morpholine, xitix, methyl acrylate to mix, continue to grind 40-50 minute, to fully disperseing, then add other remaining component, continue to grind after 30-45 minute, under 1400-1600 rev/min, stir 15-30 minute, obtain auxiliary agent.
The glass reinforced plastic composite coating material that anticorrosion ability of the present invention is good, made by following concrete steps:
(1) E-12 epoxy resin, vinylbenzene, alpha-methyl styrene, silicone resin, tetrafluoroethylene, silane resin acceptor kh-550 are put into reactor and be heated to while stirring molten state, obtain A material;
(2) short glass fiber is put into ball mill and grind, mix with ceramics powder, zinc acetate, Tetrabutyl amonium bromide, propylene glycol diacrylate, stir 13-16 minute, obtain B material;
(3) A material is mixed with B material, add auxiliary agent and all the other remaining components, under the speed of 450-600 rev/min, stir 20-25 minute, cast, curing.
Advantage of the present invention is: the present invention adds auxiliary agent, makes material have good physicals and mechanical property; The features such as that this material has is acidproof, alkaline-resisting, high temperature resistant, long service life, and there is good anticorrosion ability, light weight, nontoxic, production technique is simple, and cost is low, is applicable to suitability for industrialized production.
Embodiment
Below by specific examples, the present invention is described in detail.
The glass reinforced plastic composite coating material that anticorrosion ability is good, by following weight part (kilogram) raw material make: E-12 epoxy resin 30, vinylbenzene 9, alpha-methyl styrene 6, silicone resin 12, tetrafluoroethylene 2, silane resin acceptor kh-550 1, Tetrabutyl amonium bromide 2, propylene glycol diacrylate 15, short glass fiber 25, ceramics powder 5, methylethyl ketone peroxide 10, KJP-1002 epoxy curing agent 2, Vaseline 3, Tetrabutyl amonium bromide 2, propylene glycol diacrylate 2, auxiliary agent 1;
Described auxiliary agent by following weight part (kilogram) raw material make: iron powder 10, zinc acetate 5, light calcined magnesia 4, medical stone 3, talcum powder 3, peat 2, tri (propylene glycol) diacrylate 2, morpholine 1, xitix 2, silicon carbide 3, chitosan 1, methyl acrylate 3; Iron powder, peat, medical stone, light calcined magnesia are put into calcining furnace by preparation method, at 550-570 ℃, calcine 4-5 hour, take out, mix with talcum powder, xitix, silicon carbide, chitosan, be ground to and obtain 300-400 order powder, then, add again tri (propylene glycol) diacrylate, morpholine, xitix, methyl acrylate to mix, continue to grind 40-50 minute, to fully disperseing, then add other remaining component, continue to grind after 30-45 minute, under 1400-1600 rev/min, stir 15-30 minute, obtain auxiliary agent.
The glass reinforced plastic composite coating material that anticorrosion ability of the present invention is good, made by following concrete steps:
(1) E-12 epoxy resin, vinylbenzene, alpha-methyl styrene, silicone resin, tetrafluoroethylene, silane resin acceptor kh-550 are put into reactor and be heated to while stirring molten state, obtain A material;
(2) short glass fiber is put into ball mill and grind, mix with ceramics powder, zinc acetate, Tetrabutyl amonium bromide, propylene glycol diacrylate, stir 13-16 minute, obtain B material;
(3) A material is mixed with B material, add auxiliary agent and all the other remaining components, under the speed of 450-600 rev/min, stir 20-25 minute, cast, curing.
The tensile strength of the glass-reinforced plastic material of the embodiment of the present invention is 243 Mpa.
Claims (2)
1. the glass reinforced plastic composite coating material that anticorrosion ability is good, it is characterized in that, raw material by following weight part is made: E-12 epoxy resin 30-34, vinylbenzene 9-12, alpha-methyl styrene 6-10, silicone resin 12-14, tetrafluoroethylene 2-3, silane resin acceptor kh-550 1-2, Tetrabutyl amonium bromide 2-5, propylene glycol diacrylate 15-18, short glass fiber 25-29, ceramics powder 5-8, methylethyl ketone peroxide 10-13, KJP-1002 epoxy curing agent 2-4, Vaseline 3-5, Tetrabutyl amonium bromide 2-5, propylene glycol diacrylate 2-4, auxiliary agent 1-2,
Described auxiliary agent is made up of the raw material of following weight part: iron powder 10-13, zinc acetate 5-7, light calcined magnesia 4-6, medical stone 3-4, talcum powder 3-5, peat 2-3, tri (propylene glycol) diacrylate 2-3, morpholine 1-2, xitix 2-3, silicon carbide 3-4, chitosan 1-2, methyl acrylate 3-4; Iron powder, peat, medical stone, light calcined magnesia are put into calcining furnace by preparation method, at 550-570 ℃, calcine 4-5 hour, take out, mix with talcum powder, xitix, silicon carbide, chitosan, be ground to and obtain 300-400 order powder, then, add again tri (propylene glycol) diacrylate, morpholine, xitix, methyl acrylate to mix, continue to grind 40-50 minute, to fully disperseing, then add other remaining component, continue to grind after 30-45 minute, under 1400-1600 rev/min, stir 15-30 minute, obtain auxiliary agent.
2. the glass reinforced plastic composite coating material that anticorrosion ability is good according to claim 1, is characterized in that, is made up of following concrete steps:
(1) E-12 epoxy resin, vinylbenzene, alpha-methyl styrene, silicone resin, tetrafluoroethylene, silane resin acceptor kh-550 are put into reactor and be heated to while stirring molten state, obtain A material;
(2) short glass fiber is put into ball mill and grind, mix with ceramics powder, zinc acetate, Tetrabutyl amonium bromide, propylene glycol diacrylate, stir 13-16 minute, obtain B material;
(3) A material is mixed with B material, add auxiliary agent and all the other remaining components, under the speed of 450-600 rev/min, stir 20-25 minute, cast, curing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410016878.4A CN103773090A (en) | 2014-01-15 | 2014-01-15 | Glass reinforced plastic composite coating material with good anti-corrosion effect and preparation method thereof |
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| CN201410016878.4A CN103773090A (en) | 2014-01-15 | 2014-01-15 | Glass reinforced plastic composite coating material with good anti-corrosion effect and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104387921A (en) * | 2014-11-21 | 2015-03-04 | 芜湖市宝艺游乐科技设备有限公司 | Fire-resistant anti-corrosion coating and method for preparing same |
| CN104945964A (en) * | 2015-06-30 | 2015-09-30 | 无锡阳工机械制造有限公司 | Corrosion-resistant paint for pump valves |
| CN105017728A (en) * | 2015-06-30 | 2015-11-04 | 苏州博利迈新材料科技有限公司 | High temperature-resistant radiation-resistant glass fiber, and preparation method thereof |
| CN106479288A (en) * | 2016-09-30 | 2017-03-08 | 合肥华运机械制造有限公司 | A kind of anticorrosive coating for chemical pump liner |
| CN107151494A (en) * | 2017-05-14 | 2017-09-12 | 南通德瑞森复合材料有限公司 | A kind of Anti-corrosion glass steel composite coating material |
| CN111559872A (en) * | 2020-05-27 | 2020-08-21 | 苏州思迪机电有限公司 | Glass sight glass with anticorrosive coating and preparation method thereof |
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| JPH01141960A (en) * | 1987-11-27 | 1989-06-02 | Furukawa Electric Co Ltd:The | Epoxy resin powder coating composition |
| CN102373010A (en) * | 2010-08-16 | 2012-03-14 | 南通市通州区金晨涂料厂 | High-temperature resistant paint |
| CN102443338A (en) * | 2010-10-13 | 2012-05-09 | 中国科学院金属研究所 | Cracking resistant fiber reinforced epoxy paint for ship ballast tank and preparation method thereof |
| CN102559007A (en) * | 2011-12-19 | 2012-07-11 | 烟台德邦科技有限公司 | Composition for manufacturing corrosion-resistant and abrasion-resistant coating as well as preparation method and application thereof |
| CN103113810A (en) * | 2013-02-01 | 2013-05-22 | 深圳市长园长通新材料有限公司 | Modified solvent free epoxy wear-resisting coating for glass fiber reinforced plastic and preparation method thereof |
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Patent Citations (5)
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| JPH01141960A (en) * | 1987-11-27 | 1989-06-02 | Furukawa Electric Co Ltd:The | Epoxy resin powder coating composition |
| CN102373010A (en) * | 2010-08-16 | 2012-03-14 | 南通市通州区金晨涂料厂 | High-temperature resistant paint |
| CN102443338A (en) * | 2010-10-13 | 2012-05-09 | 中国科学院金属研究所 | Cracking resistant fiber reinforced epoxy paint for ship ballast tank and preparation method thereof |
| CN102559007A (en) * | 2011-12-19 | 2012-07-11 | 烟台德邦科技有限公司 | Composition for manufacturing corrosion-resistant and abrasion-resistant coating as well as preparation method and application thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104387921A (en) * | 2014-11-21 | 2015-03-04 | 芜湖市宝艺游乐科技设备有限公司 | Fire-resistant anti-corrosion coating and method for preparing same |
| CN104945964A (en) * | 2015-06-30 | 2015-09-30 | 无锡阳工机械制造有限公司 | Corrosion-resistant paint for pump valves |
| CN105017728A (en) * | 2015-06-30 | 2015-11-04 | 苏州博利迈新材料科技有限公司 | High temperature-resistant radiation-resistant glass fiber, and preparation method thereof |
| CN106479288A (en) * | 2016-09-30 | 2017-03-08 | 合肥华运机械制造有限公司 | A kind of anticorrosive coating for chemical pump liner |
| CN107151494A (en) * | 2017-05-14 | 2017-09-12 | 南通德瑞森复合材料有限公司 | A kind of Anti-corrosion glass steel composite coating material |
| CN111559872A (en) * | 2020-05-27 | 2020-08-21 | 苏州思迪机电有限公司 | Glass sight glass with anticorrosive coating and preparation method thereof |
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Application publication date: 20140507 |
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