CN109942976A - 一种耐黄变、高白度abs树脂制备方法 - Google Patents
一种耐黄变、高白度abs树脂制备方法 Download PDFInfo
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- CN109942976A CN109942976A CN201910210839.0A CN201910210839A CN109942976A CN 109942976 A CN109942976 A CN 109942976A CN 201910210839 A CN201910210839 A CN 201910210839A CN 109942976 A CN109942976 A CN 109942976A
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- resin
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- reaction kettle
- high whiteness
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- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 69
- 239000000843 powder Substances 0.000 claims abstract description 22
- 239000000178 monomer Substances 0.000 claims abstract description 12
- 238000002360 preparation method Methods 0.000 claims abstract description 11
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 5
- 239000010452 phosphate Substances 0.000 claims abstract description 5
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- 238000001125 extrusion Methods 0.000 claims description 28
- 239000003999 initiator Substances 0.000 claims description 22
- 230000018044 dehydration Effects 0.000 claims description 21
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- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 14
- 238000001035 drying Methods 0.000 claims description 14
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 14
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- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 7
- 239000005062 Polybutadiene Substances 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- YQHLDYVWEZKEOX-UHFFFAOYSA-N cumene hydroperoxide Chemical compound OOC(C)(C)C1=CC=CC=C1 YQHLDYVWEZKEOX-UHFFFAOYSA-N 0.000 claims description 7
- BNKAXGCRDYRABM-UHFFFAOYSA-N ethenyl dihydrogen phosphate Chemical compound OP(O)(=O)OC=C BNKAXGCRDYRABM-UHFFFAOYSA-N 0.000 claims description 7
- 239000011790 ferrous sulphate Substances 0.000 claims description 7
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 7
- 238000005189 flocculation Methods 0.000 claims description 7
- 230000016615 flocculation Effects 0.000 claims description 7
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 7
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 7
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 7
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 7
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- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 229920002857 polybutadiene Polymers 0.000 claims description 7
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 7
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 7
- 229940048086 sodium pyrophosphate Drugs 0.000 claims description 7
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- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 7
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- 239000002245 particle Substances 0.000 claims description 5
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
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- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 239000003792 electrolyte Substances 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 4
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 4
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 229960001484 edetic acid Drugs 0.000 claims description 3
- FXBLJWDJXBQLEL-UHFFFAOYSA-N ethenyl dimethyl phosphate Chemical compound COP(=O)(OC)OC=C FXBLJWDJXBQLEL-UHFFFAOYSA-N 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
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- 235000021317 phosphate Nutrition 0.000 claims description 3
- YSANTBHMCWZEQJ-UHFFFAOYSA-N C[Si](C)(C)OP(=O)(O)OC=C Chemical class C[Si](C)(C)OP(=O)(O)OC=C YSANTBHMCWZEQJ-UHFFFAOYSA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 239000002174 Styrene-butadiene Substances 0.000 claims description 2
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 239000008103 glucose Substances 0.000 claims description 2
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 229920001195 polyisoprene Polymers 0.000 claims description 2
- 239000001103 potassium chloride Substances 0.000 claims description 2
- 235000011164 potassium chloride Nutrition 0.000 claims description 2
- 229940096992 potassium oleate Drugs 0.000 claims description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 2
- 235000019394 potassium persulphate Nutrition 0.000 claims description 2
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 239000011780 sodium chloride Substances 0.000 claims description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 claims description 2
- 239000011115 styrene butadiene Substances 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
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- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- LDMIKSKELVYBIZ-UHFFFAOYSA-N 2-methoxy-1,3,2$l^{5}-dioxaphospholane 2-oxide Chemical compound COP1(=O)OCCO1 LDMIKSKELVYBIZ-UHFFFAOYSA-N 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
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- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
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Abstract
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021127935A1 (zh) * | 2019-12-23 | 2021-07-01 | 万华化学集团股份有限公司 | 一种低杂质含量abs胶粉及其制备方法和abs树脂 |
CN113637268A (zh) * | 2020-04-27 | 2021-11-12 | 深圳市汇进智能产业有限公司 | 一种适用于电气领域的介电性能好的组合物及其制备方法 |
CN113637115A (zh) * | 2021-08-24 | 2021-11-12 | 长春工业大学 | 一种asa高胶粉的制备方法 |
CN113980188A (zh) * | 2021-12-02 | 2022-01-28 | 长春工业大学 | 核壳型高分子附聚剂及其制备方法与应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60250022A (ja) * | 1984-05-25 | 1985-12-10 | Nissin Electric Co Ltd | Abs樹脂組成物 |
CN102924840A (zh) * | 2012-10-09 | 2013-02-13 | 大连理工大学 | 苯乙烯-丁二烯-异戊二烯三元共聚物集成胶乳基于乳液接枝法制备abs树脂方法 |
CN107434838A (zh) * | 2016-05-27 | 2017-12-05 | 台光电子材料股份有限公司 | 含磷烯烃聚合物、其制备方法及其组合物与成品 |
-
2019
- 2019-03-20 CN CN201910210839.0A patent/CN109942976B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60250022A (ja) * | 1984-05-25 | 1985-12-10 | Nissin Electric Co Ltd | Abs樹脂組成物 |
CN102924840A (zh) * | 2012-10-09 | 2013-02-13 | 大连理工大学 | 苯乙烯-丁二烯-异戊二烯三元共聚物集成胶乳基于乳液接枝法制备abs树脂方法 |
CN107434838A (zh) * | 2016-05-27 | 2017-12-05 | 台光电子材料股份有限公司 | 含磷烯烃聚合物、其制备方法及其组合物与成品 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021127935A1 (zh) * | 2019-12-23 | 2021-07-01 | 万华化学集团股份有限公司 | 一种低杂质含量abs胶粉及其制备方法和abs树脂 |
CN113637268A (zh) * | 2020-04-27 | 2021-11-12 | 深圳市汇进智能产业有限公司 | 一种适用于电气领域的介电性能好的组合物及其制备方法 |
CN113637268B (zh) * | 2020-04-27 | 2024-03-26 | 深圳市汇进智能产业股份有限公司 | 一种适用于电气领域的介电性能好的组合物及其制备方法 |
CN113637115A (zh) * | 2021-08-24 | 2021-11-12 | 长春工业大学 | 一种asa高胶粉的制备方法 |
CN113637115B (zh) * | 2021-08-24 | 2023-05-05 | 长春工业大学 | 一种asa高胶粉的制备方法 |
CN113980188A (zh) * | 2021-12-02 | 2022-01-28 | 长春工业大学 | 核壳型高分子附聚剂及其制备方法与应用 |
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