CN109904276A - A kind of GaN base Vertical collection opto chip and preparation method thereof - Google Patents
A kind of GaN base Vertical collection opto chip and preparation method thereof Download PDFInfo
- Publication number
- CN109904276A CN109904276A CN201910097597.9A CN201910097597A CN109904276A CN 109904276 A CN109904276 A CN 109904276A CN 201910097597 A CN201910097597 A CN 201910097597A CN 109904276 A CN109904276 A CN 109904276A
- Authority
- CN
- China
- Prior art keywords
- gan
- multiple quantum
- quantum wells
- substrate
- base vertical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Led Devices (AREA)
Abstract
The present invention relates to a kind of GaN base Vertical collection opto chip and preparation method thereof, solving existing GaN integrated opto-electronic integration density not can be further improved, performance cannot be optimal the technical issues of identical with horizontal structure structure.GaN base Vertical collection opto chip of the invention is able to achieve the optical communication between LED and PD, grown epitaxial layer is distinguished on two pieces of sapphires, and the structure of designed detector and light emitting diode is grown on epitaxial layer, then sapphire is thinned, there is no the one side of growth of device to be bonded together by Bonding two pieces of sapphires, it can be used for vertical direction and establish optical communication, further increase the integration density of GaN base material optic communication.This structure is by individually designing detector PD and Light-emitting diode LED, it can be achieved that the information between vertical structure device is transmitted.Present invention process is simple, low in cost, has broad application prospects.
Description
Technical field
The invention belongs to technical field of semiconductors, and in particular to a kind of GaN base Vertical collection opto chip and its preparation
Method.
Background technique
Integrated opto-electronic is in fields such as information communication, multimedia, personal consumption, measurement sensing, bio-sensing and military affairs
With important application prospects, compared to Si base integrated opto-electronic device, GaN base integrated opto-electronic has significant advantage, mainly
In terms of being embodied in following two: (1) Si is indirect bandgap material, and Si base light source problem is to restrict Si base optical electronic
The prominent question of development and application;(2) traditional Si material has very strong absorbability, SiO to visible light2Refractive Index of Material compared with
Small, light field limitation capability is poor, and GaN material does not absorb visible light, while having biggish refractive index.Theoretically, GaN base
Material is the excellent material for preparing visible light waveguide and Planar integration photonic device.
Currently, from the point of view of the development of GaN base integrated opto-electronic, in horizontal structure mainly by light emitting diode Led, modulation
The active devices such as device, detector PD are integrated on same substrate, and are connected with passive devices such as optical waveguide, isolator, couplers
It picks up to constitute micro photo electric system.At home, horizontal structure visible light communication InGaN/GaN multiple quantum wells diode is realized
It shines and detects, information rate can be transmitted and reach 20MHZ.However there are two the integrated opto-electronic disadvantages of this horizontal structure, the
Any is that the integration density of this planar structure not can be further improved, and second point, which is that this horizontal GaN structure is integrated, requires water
The identical detector PD of flat structure and Light-emitting diode LED cannot make the performance of the two be optimal in this way, influence Integrated Light
The transmission performance of electronic communication.
Summary of the invention
The invention solves GaN integrated opto-electronic integration densities in the prior art not can be further improved and horizontal structure knot
The technical issues of structure is identical, and performance cannot be optimal provides a kind of GaN base Vertical collection opto chip and its preparation side
Method.
In order to solve the above-mentioned technical problem, technical solution of the present invention is specific as follows:
A kind of GaN base Vertical collection opto chip, including multiple quantum wells diode (LED) part and multiple quantum wells detector
The part PD;
Multiple quantum wells diode (LED) part includes: substrate and multiple quantum wells LED structure;
The multiple quantum wells LED structure includes successively growing GaN epitaxial layer on substrate, n-GaN layers, In GaN/GaN
Layer and p-GaN layer;
The part multiple quantum wells detector PD includes: substrate and multiple quantum wells PD structure;
The multiple quantum wells PD structure includes successively growing GaN epitaxial layer on substrate, n-GaN layers, InG aN/GaN
Layer and p-GaN layer;
The one side of the non-growth of device of substrate of multiple quantum wells diode (LED) part and the multiple quantum wells detector PD
The non-growth of device of partial substrate is bonded together on one side;
The multiple quantum wells LED structure and the multiple quantum wells PD structure are coated with metal electrode respectively, and are packaged with lead.
In the above-mentioned technical solutions, the n-GaN is that Si is adulterated in GaN material, and p-GaN is adulterated in GaN material
Mg.
In the above-mentioned technical solutions, the substrate is sapphire.
In the above-mentioned technical solutions, the metal electrode is Ni, Au, Pt, Ni/Au, Ti/Al or Ti/Al/Ti/Au.
A kind of preparation method of GaN base Vertical collection opto chip, comprising the following steps:
Step 1: growing GaN epitaxial layer on substrate;
Step 2: growing n-GaN layers in GaN epitaxial layer;
Step 3: growing InGaN/GaN layers on n-GaN layer;
Step 4: carrying out photoetching, etching after the InGaN/GaN layer spin coating photoresist of step 3;
Step 5: growing p-GaN layer on InGaN/GaN layers, the preparation of multiple quantum wells LED structure is completed;
Step 6: repeating step 1 to five, multiple quantum wells PD structure is obtained;
It is thinned Step 7: the one side of the non-growth of device of above-mentioned two substrate is polished, is then bonded together;
Step 8: distinguishing evaporation metal electrode in the multiple quantum wells LED structure and the multiple quantum wells PD structure, then
Lead packages complete the preparation of GaN base Vertical collection opto chip.
In the above-mentioned technical solutions, using MOCVD technology growth GaN epitaxial layer, n-GaN layers, InGaN/GaN layers or p-
GaN layer.
In the above-mentioned technical solutions, photoresist described in step 4 is negative photoresist or the eurymeric with reverse speed characterisstic
Photoresist.
In the above-mentioned technical solutions, when metal electrode is Ni/Au combination electrode, annealing conditions temperature is taken the photograph for 400-600
Family name's degree, time are 3-15 minutes.
In the above-mentioned technical solutions, when metal electrode is Ti/Al combination electrode, annealing temperature is 500-700 degrees Celsius,
Time -5 minutes 30 seconds.
The beneficial effects of the present invention are:
GaN base Vertical collection opto chip of the invention is able to achieve the optical communication between LED and PD, in two pieces of sapphires
Upper grown epitaxial layer respectively, and the structure of designed detector and light emitting diode is grown on epitaxial layer, it then will be blue precious
Stone is thinned, and does not have the one side of growth of device to be bonded together by Bonding two pieces of sapphires, can be used for vertical direction and build
Vertical optical communication, further increases the integration density of GaN base material optic communication.And this structure passes through individually design detection
Device PD and Light-emitting diode LED distinguish grown epitaxial layer in two pieces of sapphires, and grow designed detector on epitaxial layer
And the structure of light emitting diode is, it can be achieved that the information between vertical structure device is transmitted, and can solve horizontal structure because of phase
Same PD and LED structure prevents the problem of optic communication performance is from being optimal.
GaN base Vertical collection opto chip of the invention further increases the integrated density of photonic device, reduces device
The difficulty and cost of preparation realize that device miniaturization is integrated.
The preparation method of GaN base Vertical collection opto chip of the invention, simple process and low cost have wide
Application prospect.
Detailed description of the invention
Invention is further described in detail with reference to the accompanying drawings and detailed description.
Fig. 1 is the structural schematic diagram of GaN base Vertical collection opto chip of the invention.
Fig. 2 is the preparation flow figure of GaN base Vertical collection opto chip of the invention.
Specific embodiment
The present invention provides a kind of GaN base Vertical collection opto chip, including multiple quantum wells diode (LED) part and volume
The part sub- well detector PD;Multiple quantum wells diode (LED) part includes: substrate and multiple quantum wells LED structure;The volume
Sub- trap LED structure includes GaN epitaxial layer, n-GaN layers, InGaN/GaN layers and the p-GaN layer successively grown on substrate;It is described
The part multiple quantum wells detector PD includes: substrate and multiple quantum wells PD structure;The multiple quantum wells PD structure includes successively growing
GaN epitaxial layer, n-GaN layers, InGaN/GaN layers and p-GaN layer on substrate;Multiple quantum wells diode (LED) part
The non-growth of device of substrate and the part multiple quantum wells detector PD the non-growth of device of substrate while be bonded in one
It rises;The multiple quantum wells LED structure and the multiple quantum wells PD structure are coated with metal electrode respectively, and are packaged with lead.It is preferred that
The n-GaN is that Si is adulterated in GaN material, and p-GaN is that Mg is doped in GaN material;The substrate is sapphire;It is described
Metal electrode is Ni, Au, Pt, Ni/Au, Ti/Al or Ti/Al/Ti/Au.
The present invention also provides a kind of preparation methods of GaN base Vertical collection opto chip, comprising the following steps:
Step 1: growing GaN epitaxial layer on substrate;
Step 2: growing n-GaN layers in GaN epitaxial layer;
Step 3: growing InGaN/GaN layers on n-GaN layer;
Step 4: carrying out photoetching, etching after the InGaN/GaN layer spin coating photoresist of step 3;
Step 5: growing p-GaN layer on InGaN/GaN layers, the preparation of multiple quantum wells LED structure is completed;
Step 6: repeating step 1 to five, multiple quantum wells PD structure is obtained;
It is thinned Step 7: the one side of the non-growth of device of above-mentioned two substrate is polished, is then bonded together;
Step 8: distinguishing evaporation metal electrode in the multiple quantum wells LED structure and the multiple quantum wells PD structure, then
Lead packages complete the preparation of GaN base Vertical collection opto chip.
Photoresist described in preferred steps four is negative photoresist or the positive photo glue with reverse speed characterisstic.
Preferably, substrate needed for growth GaN material is the typical substrates such as sapphire, silicon, silicon carbide, and growing method is gold
Belong to Organic Vapor Deposition method (MOCVD), the especially method of high temperature MOCVD.
Preferably, photoresist used in photoetching is negative photoresist or the positive photo glue with reverse speed characterisstic.
Preferably, the method for preparing electrode is electron beam evaporation or thermal evaporation, the type of electrode material is Ni, Au, Pt,
Ni/Au, Ti/Al or Ti/Al/Ti/Au etc., can be formed with GaN Schottky or ohm-type half same metal contacted or
The different types of metal of person.
Preferably, the condition annealed when preparing electrode is depending on metal species, when metal electrode is Ni/Au compound electric
Pole, annealing conditions temperature are 400-600 degrees Celsius, and the time is 3-15 minutes;When metal electrode be Ti/Al combination electrode,
Annealing temperature is 500-700 degrees Celsius, the time -5 minutes 30 seconds.
Preferably, the condition of Sapphire Substrate polishing thickness is depending on design requirement.
Present embodiment is described with reference to the drawings, Fig. 2 is the preparation flow of GaN base Vertical collection opto chip of the invention
Figure, comprising:
(1) Sapphire Substrate (number 1) is cleaned, with being dried with nitrogen.
(2) GaN epitaxial layer is grown on a sapphire substrate before this using MOCVD method, then grow in GaN epitaxial layer
N-GaN layers, then InGaN/GaN layers (alternatively referred to as MQWs layers) is grown on n-GaN layer, and by adjusting the In in InGaN
Component ratio improves the emission wavelength of multiple quantum wells LED.
(3) photoresist is coated on InGaN/GaN layers and carries out photoetching development, will use covering of having customized in exposure process
Graphics field on mask plate is completely disposed above chip, sets the time for exposure of 7s, by exposure technique, will set by film version
The pattern transfer on mask plate counted is to photoresist layer.Device after exposure develops, and comes out graphical display.
Development mainly uses 3038 developer solutions, is cleaned and is dried with nitrogen with clear water after development, then dry steam on hot plate, so far
Complete photoetching development step.It also needs to carry out structure of the ICP nitride etch to form device after photoetching development, be dried in cleaning
It is dry.Then p-GaN layer is grown on the InGaN/GaN layer after photoetching, etching, completes the preparation of multiple quantum wells LED structure;
(4) since Sapphire Substrate (number 1) is too thick, it would be desirable to substrate polishing be thinned to reduce the propagation road of light
Diameter.
(5) Sapphire Substrate (number 2) is cleaned, with being dried with nitrogen.
(6) GaN epitaxial layer is grown on a sapphire substrate before this using MOCVD method, then grow in GaN epitaxial layer
N-GaN layers, then InGaN/GaN layers are grown on n-GaN layer.
(7) photoresist is coated on InGaN/GaN layers and carries out photoetching development, will use covering of having customized in exposure process
Graphics field on mask plate is completely disposed above chip, sets the time for exposure of 7s, by exposure technique, will set by film version
The waveguiding structure counted on mask plate is transferred to photoresist layer.Chip after exposure develops, and goes out graphical display
Come.Development mainly uses 3038 developer solutions, is cleaned and is dried with nitrogen with clear water after development, then dries steam on hot plate,
So far photoetching development step is completed.It also needs to carry out structure of the ICP nitride etch to form device after photoetching development, clean
Drying.Then p-GaN layer is grown on the InGaN/GaN layer after photoetching, etching, completes the preparation of multiple quantum wells PD structure;
(8) Sapphire Substrate (number 2) polishing is carried out to be thinned.
(9) by the one side of Sapphire Substrate (number 1) non-growth of device and Sapphire Substrate (number 2) non-growth of device
It is bonded together on one side by Bonding, using electron beam evaporation technique, respectively multiple quantum wells LED structure and multiple quantum wells
PD structure plates metal electrode, and GaN base Vertical collection opto chip is prepared in package lead.
Referring to Fig.1, in conjunction with specific embodiments to GaN base Vertical collection opto chip of the invention further specifically
It is bright as follows:
The required substrate of GaN material is selected, the present invention selects sapphire as substrate.
Multiple quantum wells LED structure is prepared using multistep growth method, utilizes high temperature MOCVD technology growth GaN epitaxial layer, n-
GaN layer, InGaN/GaN layers and p-GaN layer, the especially method of high temperature MOCVD, do not have particular/special requirement, root to the thickness of each layer
It is designed according to actual needs.N-GaN is that Si is adulterated in GaN material, and InGaN/GaN layers are by InGaN and GaN according to certain
The group of ratio is grouped as structure obtained from growth, the light of the wavelength emitted needed for being set according to the In component in InGaN, p-
GaN is that Mg is doped in GaN material.
The present invention utilizes photoetching technique, carves the integrated waveguide design configuration on mask plate.
Using electron beam evaporation technique, Schottky contact electrode Ni/Au composite layer is evaporated in p-GaN layer, with a thickness of
10-300 nanometers.
Using quick anneal oven, anneal under nitrogen atmosphere to Ni/Au Schottky contact electrode, annealing temperature 400-
600 degrees Celsius, the time is 3-15 minutes.
It repeats the above steps and multiple quantum wells PD structure is prepared.
By passing through on one side for the non-growth of device of Sapphire Substrate of multiple quantum wells LED structure and multiple quantum wells PD structure
Bonding is bonded together, lead packages.
Present invention will be further explained below with reference to the attached drawings and examples, but the present invention is not limited to these Examples.
Embodiment 1
(1) Sapphire Substrate (number 1) is cleaned, with being dried with nitrogen.
(2) GaN epitaxial layer is grown on a sapphire substrate before this using MOCVD method, then grow in GaN epitaxial layer
N-GaN layers, then InGaN/GaN layers (alternatively referred to as MQWs layers) is grown on n-GaN layer.
(3) photoresist is coated on InGaN/GaN layers and carries out photoetching development, will use covering of having customized in exposure process
Graphics field on mask plate is completely disposed above chip, sets the time for exposure of 7s, by exposure technique, will set by film version
The pattern transfer on mask plate counted is to photoresist layer.Device after exposure develops, and comes out graphical display.
Development mainly uses 3038 developer solutions, is cleaned and is dried with nitrogen with clear water after development, then dry steam on hot plate, so far
Complete photoetching development step.It also needs to carry out structure of the ICP nitride etch to form device after photoetching development, be dried in cleaning
It is dry.Then p-GaN layer is grown on the InGaN/GaN layer after photoetching, etching, completes the preparation of multiple quantum wells LED structure;
N-GaN is that Si is adulterated in GaN material, and p-GaN is that Mg is doped in GaN material;
(4) metal electrode Ni/Au is prepared in multiple quantum wells LED structure by being evaporated in vacuo, with a thickness of 100 nanometers, so
After annealing, annealing temperature are 500 degrees Celsius, and the time is 10 minutes;
(5) since Sapphire Substrate (number 1) is too thick, it would be desirable to substrate polishing be thinned to reduce the propagation road of light
Diameter.
(6) Sapphire Substrate (number 2) is cleaned, with being dried with nitrogen.
(7) GaN epitaxial layer is grown on a sapphire substrate before this using MOCVD method, then grow in GaN epitaxial layer
N-GaN layers, then InGaN/GaN layers are grown on n-GaN layer, and volume is improved by the component ratio of adjusting InGaN/GaN
The luminous efficiency of sub- trap PD.
(8) photoresist is coated on InGaN/GaN layers and carries out photoetching development, will use covering of having customized in exposure process
Graphics field on mask plate is completely disposed above chip, sets the time for exposure of 7s, by exposure technique, will set by film version
The waveguiding structure counted on mask plate is transferred to photoresist layer.Chip after exposure develops, and goes out graphical display
Come.Development mainly uses 3038 developer solutions, is cleaned and is dried with nitrogen with clear water after development, then dries steam on hot plate,
So far photoetching development step is completed.It also needs to carry out structure of the ICP nitride etch to form device after photoetching development, clean
Drying.Then p-GaN layer is grown on the InGaN/GaN layer after photoetching, etching, completes the preparation of multiple quantum wells PD structure;
(9) metal electrode Ni/Au is prepared in multiple quantum wells PD structure by being evaporated in vacuo, with a thickness of 100 nanometers, then
Annealing, annealing temperature are 500 degrees Celsius, and the time is 10 minutes;
(10) Sapphire Substrate (number 2) polishing is carried out to be thinned.
(11) by the one side of Sapphire Substrate (number 1) non-growth of device and Sapphire Substrate (number 2) non-growth of device
One side be bonded together by Bonding, GaN base Vertical collection photoelectron core shown in FIG. 1 can be obtained in package lead
Piece.
Embodiment 2
(1) Sapphire Substrate (number 1) is cleaned, with being dried with nitrogen.
(2) GaN epitaxial layer is grown on a sapphire substrate before this using MOCVD method, then grow in GaN epitaxial layer
N-GaN layers, then InGaN/GaN layers (alternatively referred to as MQWs layers) is grown on n-GaN layer.
(3) photoresist is coated on InGaN/GaN layers and carries out photoetching development, will use covering of having customized in exposure process
Graphics field on mask plate is completely disposed above chip, sets the time for exposure of 7s, by exposure technique, will set by film version
The pattern transfer on mask plate counted is to photoresist layer.Device after exposure develops, and comes out graphical display.
Development mainly uses 3038 developer solutions, is cleaned and is dried with nitrogen with clear water after development, then dry steam on hot plate, so far
Complete photoetching development step.It also needs to carry out structure of the ICP nitride etch to form device after photoetching development, be dried in cleaning
It is dry.Then p-GaN layer is grown on the InGaN/GaN layer after photoetching, etching, completes the preparation of multiple quantum wells LED structure;
N-GaN is that Si is adulterated in GaN material, and p-GaN is that Mg is doped in GaN material;
(4) metal electrode Ti/Al is prepared in multiple quantum wells LED structure by being evaporated in vacuo, with a thickness of 50 nanometers, then
Annealing, annealing temperature are 600 degrees Celsius, and the time is 2 minutes;
(5) since Sapphire Substrate (number 1) is too thick, it would be desirable to substrate polishing be thinned to reduce the propagation road of light
Diameter.
(6) Sapphire Substrate (number 2) is cleaned, with being dried with nitrogen.
(7) GaN epitaxial layer is grown on a sapphire substrate before this using MOCVD method, then grow in GaN epitaxial layer
N-GaN layers, then InGaN/GaN layers are grown on n-GaN layer, and volume is improved by the component ratio of adjusting InGaN/GaN
The luminous efficiency of sub- trap PD.
(8) photoresist is coated on InGaN/GaN layers and carries out photoetching development, will use covering of having customized in exposure process
Graphics field on mask plate is completely disposed above chip, sets the time for exposure of 7s, by exposure technique, will set by film version
The waveguiding structure counted on mask plate is transferred to photoresist layer.Chip after exposure develops, and goes out graphical display
Come.Development mainly uses 3038 developer solutions, is cleaned and is dried with nitrogen with clear water after development, then dries steam on hot plate,
So far photoetching development step is completed.It also needs to carry out structure of the ICP nitride etch to form device after photoetching development, clean
Drying.Then p-GaN layer is grown on the InGaN/GaN layer after photoetching, etching, completes the preparation of multiple quantum wells PD structure;
(9) metal electrode Ti/Al is prepared in multiple quantum wells PD structure by being evaporated in vacuo, with a thickness of 50 nanometers, then
Annealing, annealing temperature are 600 degrees Celsius, and the time is 2 minutes;
(10) Sapphire Substrate (number 2) polishing is carried out to be thinned.
(11) by the one side of Sapphire Substrate (number 1) non-growth of device and Sapphire Substrate (number 2) non-growth of device
One side be bonded together by Bonding, GaN base Vertical collection photoelectron core shown in FIG. 1 can be obtained in package lead
Piece.
Metal electrode in above-described embodiment may be replaced by other metal electrodes of above-mentioned restriction, here no longer one by one
It enumerates.
Multiple quantum wells LED structure of the invention has good luminous efficiency and detection effect with multiple quantum wells PD structure
Rate, by the performance etc. for adjusting the adjustable device of In component.The dislocation density of Sapphire Substrate and GaN material is small.Nanoparticle
The density and dislocation density of son are close.The type of GaN Schottky contact electrode is Ni, Au, Pt or Ni/Au, Ti/Al, Ti/
The condition of composite materials multilayer film such as Al/Ti/Au etc., electrode anneal can be depending on specific metal species, such as Ni/
Au combination electrode, annealing conditions temperature are 400-600 degree, and the time is 3-15 points;If the annealing temperature of Ti/Al is 500-700 degree,
Time -5 minutes 30 seconds.
The method of the present invention is not limited to the above embodiments, and GaN base Vertical collection opto chip structure of the present invention is relative to biography
The advantages of Horizontal collection waveguiding structure of system, is that GaN first and sapphire will not all absorb the light that light source is issued, this is
It is determined by the band gap of material.The most important be this structure can with individually designed LED, PD multi-quantum pit structure,
LED, PD performance is set to respectively reach optimal performance, this is that conventional flat structure is not achieved.From the perspective of long term growth,
It can produce three-dimensional photoelectricity interacted system when this Vertical collection waveguide and current Horizontal collection waveguide are combined, favorably
In the integrated of photoelectricity interconnection, possess potential commercial value.
Obviously, the above embodiments are merely examples for clarifying the description, and does not limit the embodiments.It is right
For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of variation or
It changes.There is no necessity and possibility to exhaust all the enbodiments.And it is extended from this it is obvious variation or
It changes still within the protection scope of the invention.
Claims (9)
1. a kind of GaN base Vertical collection opto chip, which is characterized in that including multiple quantum wells diode (LED) part and volume
The part sub- well detector PD;
Multiple quantum wells diode (LED) part includes: substrate and multiple quantum wells LED structure;
The multiple quantum wells LED structure include successively grow GaN epitaxial layer on substrate, n-GaN layers, InGaN/GaN layers and
P-GaN layer;
The part multiple quantum wells detector PD includes: substrate and multiple quantum wells PD structure;
The multiple quantum wells PD structure includes successively growing GaN epitaxial layer on substrate, n-GaN layers, InGaN/GaN layers and p-
GaN layer;
The one side of the non-growth of device of substrate of multiple quantum wells diode (LED) part and the part multiple quantum wells detector PD
Substrate non-growth of device be bonded together on one side;
The multiple quantum wells LED structure and the multiple quantum wells PD structure are coated with metal electrode respectively, and are packaged with lead.
2. GaN base Vertical collection opto chip according to claim 1, which is characterized in that the n-GaN is in GaN
Si is adulterated in material, p-GaN is that Mg is doped in GaN material.
3. GaN base Vertical collection opto chip according to claim 1, which is characterized in that the substrate be sapphire,
Silicon or silicon carbide.
4. GaN base Vertical collection opto chip according to claim 1, which is characterized in that the metal electrode be Ni,
Au, Pt, Ni/Au, Ti/Al or Ti/Al/Ti/Au.
5. the preparation method of GaN base Vertical collection opto chip, feature described in a kind of claim 1-4 any one exist
In, comprising the following steps:
Step 1: growing GaN epitaxial layer on substrate;
Step 2: growing n-GaN layers in GaN epitaxial layer;
Step 3: growing InGaN/GaN layers on n-GaN layer;
Step 4: carrying out photoetching, etching after the InGaN/GaN layer spin coating photoresist of step 3;
Step 5: growing p-GaN layer on InGaN/GaN layers, the preparation of multiple quantum wells LED structure is completed;
Step 6: repeating step 1 to five, multiple quantum wells PD structure is obtained;
It is thinned Step 7: the one side of the non-growth of device of above-mentioned two substrate is polished, is then bonded together;
Step 8: distinguish evaporation metal electrode in the multiple quantum wells LED structure and the multiple quantum wells PD structure, then lead
The preparation of GaN base Vertical collection opto chip is completed in encapsulation.
6. the preparation method of GaN base Vertical collection opto chip according to claim 5, which is characterized in that use
MOCVD technology growth GaN epitaxial layer, n-GaN layers, InGaN/GaN layers or p-GaN layer.
7. the preparation method of GaN base Vertical collection opto chip according to claim 5, which is characterized in that step 4
Described in photoresist be negative photoresist or the positive photo glue with reverse speed characterisstic.
8. the preparation method of GaN base Vertical collection opto chip according to claim 5, which is characterized in that work as metal
Electrode is Ni/Au combination electrode, and annealing conditions temperature is 400-600 degrees Celsius, and the time is 3-15 minutes.
9. the preparation method of GaN base Vertical collection opto chip according to claim 5, which is characterized in that work as metal
Electrode is Ti/Al combination electrode, and annealing temperature is 500-700 degrees Celsius, the time -5 minutes 30 seconds.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910097597.9A CN109904276B (en) | 2019-01-31 | 2019-01-31 | GaN-based vertical integrated optoelectronic chip and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910097597.9A CN109904276B (en) | 2019-01-31 | 2019-01-31 | GaN-based vertical integrated optoelectronic chip and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN109904276A true CN109904276A (en) | 2019-06-18 |
CN109904276B CN109904276B (en) | 2021-01-26 |
Family
ID=66944505
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201910097597.9A Active CN109904276B (en) | 2019-01-31 | 2019-01-31 | GaN-based vertical integrated optoelectronic chip and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN109904276B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114400262A (en) * | 2022-01-18 | 2022-04-26 | 南京邮电大学 | Gallium nitride photoelectron integrated chip and preparation method thereof |
RU2810635C1 (en) * | 2023-07-25 | 2023-12-28 | Акционерное общество "НПО "Орион" | Method for manufacturing dual-spectral photosensitive element based on schottky barrier using mesa technology |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1649147A (en) * | 2004-12-16 | 2005-08-03 | 南通富士通微电子股份有限公司 | Back-to-back packaging integrated circuit and its producing method |
CN101558348A (en) * | 2006-09-29 | 2009-10-14 | 佛罗里达大学研究基金公司 | Method and apparatus for infrared detection and display |
CN102347518A (en) * | 2011-06-24 | 2012-02-08 | 中国科学院上海微系统与信息技术研究所 | Micro-energy system with high energy density per unit volume and fabrication method thereof |
CN103515467A (en) * | 2012-06-26 | 2014-01-15 | 北京大学 | Delta E-E nuclear radiation detector based on substrate bonding and preparation method thereof |
CN103839931A (en) * | 2012-11-26 | 2014-06-04 | 西安威正电子科技有限公司 | Double-faced packaging structure of double chips |
WO2015057771A1 (en) * | 2013-10-15 | 2015-04-23 | The Penn State Research Foundation | Light emitting diodes and photodetectors |
CN105428305A (en) * | 2015-11-20 | 2016-03-23 | 南京邮电大学 | Suspended LED optical waveguide and photoelectric detector monolithic integrated device and preparation method thereof |
CN107482031A (en) * | 2017-08-09 | 2017-12-15 | 南京邮电大学 | GaN base micron order LED array and preparation method thereof |
WO2018063438A1 (en) * | 2016-09-29 | 2018-04-05 | The Regents Of The University Of California | Visible light communication system-on-a-chip |
CN108735852A (en) * | 2017-04-21 | 2018-11-02 | 株式会社村田制作所 | Optical sensor |
CN108964762A (en) * | 2018-07-23 | 2018-12-07 | 京东方科技集团股份有限公司 | Visible light communication device and its driving method, door lock and visible light communication method |
-
2019
- 2019-01-31 CN CN201910097597.9A patent/CN109904276B/en active Active
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1649147A (en) * | 2004-12-16 | 2005-08-03 | 南通富士通微电子股份有限公司 | Back-to-back packaging integrated circuit and its producing method |
CN101558348A (en) * | 2006-09-29 | 2009-10-14 | 佛罗里达大学研究基金公司 | Method and apparatus for infrared detection and display |
CN102347518A (en) * | 2011-06-24 | 2012-02-08 | 中国科学院上海微系统与信息技术研究所 | Micro-energy system with high energy density per unit volume and fabrication method thereof |
CN103515467A (en) * | 2012-06-26 | 2014-01-15 | 北京大学 | Delta E-E nuclear radiation detector based on substrate bonding and preparation method thereof |
CN103839931A (en) * | 2012-11-26 | 2014-06-04 | 西安威正电子科技有限公司 | Double-faced packaging structure of double chips |
WO2015057771A1 (en) * | 2013-10-15 | 2015-04-23 | The Penn State Research Foundation | Light emitting diodes and photodetectors |
CN105428305A (en) * | 2015-11-20 | 2016-03-23 | 南京邮电大学 | Suspended LED optical waveguide and photoelectric detector monolithic integrated device and preparation method thereof |
WO2018063438A1 (en) * | 2016-09-29 | 2018-04-05 | The Regents Of The University Of California | Visible light communication system-on-a-chip |
CN108735852A (en) * | 2017-04-21 | 2018-11-02 | 株式会社村田制作所 | Optical sensor |
CN107482031A (en) * | 2017-08-09 | 2017-12-15 | 南京邮电大学 | GaN base micron order LED array and preparation method thereof |
CN108964762A (en) * | 2018-07-23 | 2018-12-07 | 京东方科技集团股份有限公司 | Visible light communication device and its driving method, door lock and visible light communication method |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114400262A (en) * | 2022-01-18 | 2022-04-26 | 南京邮电大学 | Gallium nitride photoelectron integrated chip and preparation method thereof |
RU2810635C1 (en) * | 2023-07-25 | 2023-12-28 | Акционерное общество "НПО "Орион" | Method for manufacturing dual-spectral photosensitive element based on schottky barrier using mesa technology |
Also Published As
Publication number | Publication date |
---|---|
CN109904276B (en) | 2021-01-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US10386574B2 (en) | Integrated photonic device comprising hollowed silicon substrate-based LED and optical waveguide and manufacturing method thereof | |
US8034647B2 (en) | LED with substrate modifications for enhanced light extraction and method of making same | |
US8546819B2 (en) | Light emitting device and fabrication method thereof | |
JP5130437B2 (en) | Semiconductor light emitting device and manufacturing method thereof | |
CN106374020B (en) | A kind of production method and its thin film chip of thin film chip | |
US9000414B2 (en) | Light emitting diode having heterogeneous protrusion structures | |
CN112563302B (en) | Micro-nano composite structure photonic integrated chip and preparation method thereof | |
TWI262607B (en) | Semiconductor light emitting device | |
CN106981497A (en) | A kind of high pressure flip LED chips structure and its manufacture method | |
WO2021035676A1 (en) | Ultra-thin structure deep ultraviolet led and manufacturing method therefor | |
KR100697829B1 (en) | Manufacturing method of light emitting element and light emitting element manufactured by this method | |
WO2020011117A1 (en) | Ultraviolet light emitting diode chip for improving light extraction efficiency, and manufacturing method therefor | |
CN109904276A (en) | A kind of GaN base Vertical collection opto chip and preparation method thereof | |
CN107068825B (en) | A kind of high pressure flip LED chips structure and its manufacturing method | |
WO2011143919A1 (en) | Light emitting diode and manufacturing method thereof | |
WO2018137337A1 (en) | Thin-film type light-emitting diode and manufacturing method therefor | |
CN108133989A (en) | GaN transverse direction LED preparation methods based on multiple quantum wells | |
CN109713091B (en) | Method for improving optical coupling efficiency of GaN-based integrated waveguide by adopting high-reflection film | |
CN109920727A (en) | The method that autoregistration forms figure and prepares epitaxial material on epitaxial lateral overgrowth film | |
CN108054250A (en) | Based on the four color LED preparation methods laterally arranged | |
KR100765236B1 (en) | Method of fabricating patterned substrate for light emitting diode and light emitting diode employing the same | |
KR20060057855A (en) | Gan-based compound semiconductor light emitting device and method thereof | |
TW200536159A (en) | Group III nitride semiconductor light-emitting device and producing method thereof | |
CN108123015A (en) | The device architecture of GaN transverse directions LED based on multiple quantum wells | |
CN108054248A (en) | The preparation method of new GaN base LED |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |