CN109881199A - A kind of regenerating alkaline etching liquid and its copper recovery system - Google Patents
A kind of regenerating alkaline etching liquid and its copper recovery system Download PDFInfo
- Publication number
- CN109881199A CN109881199A CN201910285485.6A CN201910285485A CN109881199A CN 109881199 A CN109881199 A CN 109881199A CN 201910285485 A CN201910285485 A CN 201910285485A CN 109881199 A CN109881199 A CN 109881199A
- Authority
- CN
- China
- Prior art keywords
- copper
- supporting plate
- alkaline etching
- electrolysis unit
- recovery system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Electrolytic Production Of Metals (AREA)
Abstract
The invention discloses a kind of regenerating alkaline etching liquid and its copper recovery systems, including a board and a controller, an electrolysis unit and a bronze medal recycling and processing device are formed on the board, and the electrolysis unit is respectively communicated to a waste liquid tank and a regenerated liquid regulating tank, the copper recycling and processing device includes the pickling neutralization chamber being set in electrolysis unit a side, at least rinsing bowl being set on pickling neutralization chamber side and the primary antibody oxidation trough being set on rinsing bowl side.Regenerating alkaline etching liquid and its copper recovery system provided by the invention, the high efficiente callback of the circular regeneration and copper of alkaline etching liquid can be achieved, cathode plate purity is high, non-oxidation and the light of acquisition, the effective area of copper is big on cathode plate, copper is evenly distributed, consistency of thickness removes copper convenient for subsequent.
Description
Technical field
The present invention relates to etching solution process field more particularly to a kind of regenerating alkaline etching liquids and its copper recovery system.
Background technique
Etching work procedure in wiring board manufacturing process is one of important procedure of wiring board manufacture, produces in this process
Raw waste liquid is a kind of waste liquid (cupric 110-160 grams per liter) of high copper.To this etching waste liquor, most traditional way be by
Local qualified recycling company pulls away waste liquid, then using the copper in chemical method (neutralisation or displacement method) Recycling of waste liquid
It is made into copper sponge or copper sulphate.These method and processes fall behind, and copper recycling is not thorough, and the economic benefit of processing is unobvious, has mentioned copper
The direct outlet of waste liquid afterwards, causes " secondary pollution ", causes local water ecosystem compared with havoc.
Therefore, occur numerous etching solution copper recovery systems on the market, cathode plate is obtained by the way of electrolysis, though
So there is further effect to copper recycling, but still remain following deficiency:
(1) cathode plate surface is easily oxidized, and is blacked, and purity is low；
(2) on cathode plate surrounding can long copper, and copper is unevenly distributed, and surrounding is wrapped up in by very thick copper-clad, and intermediate thin, thick
Spend inconsistent, the effective area of copper is small on cathode plate, causes subsequent to be difficult to remove copper；
(3) during electrolysis, the pernicious gas volatilized overflows, and is harmful to the human body；
(4) it needs manual handling to convey cathode plate, consumes many manpowers, and low efficiency.
Summary of the invention
It in view of the above deficiencies, can the purpose of the present invention is to provide a kind of regenerating alkaline etching liquid and its copper recovery system
Realize the high efficiente callback of the circular regeneration and copper of alkaline etching liquid, cathode plate purity is high, non-oxidation and the light of acquisition, yin
The effective area of copper is big on pole plate, and copper is evenly distributed, consistency of thickness, removes copper convenient for subsequent.
The technical scheme adopted by the invention to achieve the purpose is as follows:
A kind of regenerating alkaline etching liquid and its copper recovery system, including a board and a controller, form on the board
There are an electrolysis unit and a bronze medal recycling and processing device, and the electrolysis unit is respectively communicated to a waste liquid tank and a regenerated liquid is adjusted
Slot, which is characterized in that the copper recycling and processing device includes the pickling neutralization chamber being set in electrolysis unit a side, setting
In at least rinsing bowl on pickling neutralization chamber side and the primary antibody oxidation trough being set on rinsing bowl side.
As a further improvement of the present invention, there is an air knife two inner side edge tops of the anti-oxidant slot are horizontal respectively,
It is formed with the wind chamber for being connected to external air blower inside the air knife, is offered on the air knife side and is connected to the several of wind chamber
Bar shaped air outlet, and the opening direction of the bar shaped air outlet is diagonally downward.
As a further improvement of the present invention, being added in the anti-oxidant slot has antioxidant solution, in the pickling
Being added in neutralization chamber has acid solution, and being added in the rinsing bowl has clear water, and the quantity of the rinsing bowl is two.
As a further improvement of the present invention, the electrolysis unit includes several electrolytic cells being formed on board, setting
An anode plate in electrolytic cell and the cathode plate for being set in electrolytic cell and being located at anode plate two sides, wherein at this
Two longitudinal bar shaped slots being from top to bottom inserted into for cathode plate end are respectively formed on the inside of electrolytic cell both ends, and this two vertical
It is distributed in bar shaped slot on the two sides of electrolytic cell end, after which is inserted into longitudinal bar shaped slot, the yin
Pole plate lateral surface and electrolytic cell inner wall are mutually close.
As a further improvement of the present invention, it is all around equipped with a wall in the electrolysis unit, it is opposite in the wall
It is respectively formed with that several pocket sets, the pocket set include being caught in for anode plate end correspondingly with electrolytic cell on two sides
Card slot and the side bayonet slot for being located at middle card slot two sides and being caught in for cathode plate end in one.
As a further improvement of the present invention, if bottom offers and is connected with external exhaust fan in the electrolytic cell
Dry tap stomata, and bottom is provided with the air inlet pipe being connected with external blower in the electrolytic cell, opens in the air inlet pipe
Equipped with several air inlets；Meanwhile several interior seal grooves are concavely provided in the wall, interior sealing is provided in the interior seal groove
Item is equipped with glass cover in one to fit with interior sealing strip in the wall upper cover；On the board and it is located at outside electrolysis unit
It encloses and is recessed with an external seal slot, be provided with external seal strip in the external seal slot, on the board and be located at electrolysis unit periphery
It is covered with the outer glass cover to fit with external seal strip.
As a further improvement of the present invention, it is connected between the electrolysis unit and waste liquid tank by a waste liquid inlet tube,
The water pump being electrically connected with the controller is provided on the waste liquid inlet tube.
As a further improvement of the present invention, electrolyte density detection dress is provided on the electrolysis unit side
It sets, which includes a test chamber and hang in test chamber and be electrically connected to the one of controller
Densimeter is provided with a feed liquor endplate and an outlet end partition in the test chamber, the feed liquor endplate and outlet end every
Plate will test inside cavity and be divided into a detection zone, the feed liquor area on the outside of feed liquor endplate and be located at outside outlet end partition
The one of side goes out liquid zone, which is located in detection zone, which, which is reserved with, is connected in feed liquor area with detection zone
A logical side opening, the outlet end partition upper end are reserved with the upper opening that liquid zone out is connected with detection zone；Meanwhile at this
It is connected with a detection inlet tube between feed liquor area side top and electrolysis unit, is provided on the detection inlet tube and controller
One electrically operated valve of electrical connection；Go out liquid zone side lower part and be provided with an outlet tube at this.
As a further improvement of the present invention, sliding rack is equipped with a copper sheet conveying device on the board, and the copper sheet is defeated
Sending device includes the bracket being set up on board, the rotary electric machine for being set to pedestal upper end, the electricity through rotary electric machine
Machine shaft, the copper sheet being connected between machine shaft both ends lifting drive component and are connected to copper sheet lifting and drive under component
Several copper sheets hook at end, wherein it includes the left set axis for being sheathed on machine shaft left end, winding that copper sheet lifting, which drives component,
A Zola in left set axis periphery stretch belt, the right set axis for being sheathed on machine shaft right end, be wound in right set axis periphery one
It is right stretch belt and be connected to Zola stretch belt ends and it is right stretch belt ends between one lifting driven rod, the copper sheet hang
Hook connects are on lifting driven rod；The bracket mainly by a upper supporting plate, the left longitudinal supporting plate that is connected to upper supporting plate left end lower part,
And it is connected to a right longitudinal supporting plate composition of upper supporting plate right end lower part, the rotary electric machine, machine shaft, left set axis and right set axis point
Be not set on upper supporting plate, the Zola stretch belt and right stretchings belt pass through upper supporting plate towards left longitudinal supporting plate and right longitudinal direction supporting plate it
Between extend vertically downward；It is respectively arranged with a longitudinal slide rail in left longitudinal supporting plate and right longitudinal supporting plate inner side edge, in the liter
Drop driven rod both ends are respectively arranged with the lifting pulley slided in longitudinal slide rail；Divide on the opposite two sides in the board upper end
It is not provided with a translation sliding rail, left longitudinal supporting plate and right longitudinal supporting plate lower end pass through several translating pulleys respectively and slide on translation
On sliding rail；It is provided on left longitudinal supporting plate or right longitudinal supporting plate side and is electrically connected to rotary electric machine and controls rotary electric machine just
Several buttons of reversion.
As a further improvement of the present invention, it is separated between the waste liquid tank and regenerated liquid regulating tank by a partition, and
The liquidometer in regenerated liquid regulating tank is provided on the partition side；Meanwhile it being adjusted in the waste liquid tank and regenerated liquid
A cooling coil is respectively arranged in slot.
The invention has the benefit that
(1) by adding anti-oxidant slot, anti-oxidant treatment is carried out to the cathode plate formed after electrolysis, so that in tough cathode
Plate surface adhere to anti oxidation layer, effectively prevent cathode plate oxidizing blackening, as a result, obtain high-purity, non-oxidation, light cathode
Copper sheet；Meanwhile air knife is added in the opening of anti-oxidant slot, high speed winds can be blown out, cathode plate surface is dried up, is effectively prevent
Cathode plate surface is oxidized, and antioxygenic property is improved, to further increase the purity and brightness of cathode plate；
(2) by adding the longitudinal bar shaped slot being caught in for cathode plate end on electrolytic cell, then in cathode plate end table
Exist between face and longitudinal bar shaped slot inner wall and between cathode plate lateral surface and electrolytic cell inner wall almost without copper ion, as a result,
Long copper is seldom on cathode plate end surface (on keeping to the side) and cathode plate lateral surface, or even not long copper, and only in cathode plate
One layer of copper is appended on side surface (in addition to end surface), and copper is evenly distributed, consistency of thickness, the effective area of copper on cathode plate
Greatly, copper is removed convenient for subsequent, has effectively prevented the generation of layers of copper surrounding thickness, intermediate thin phenomenon on cathode plate；
(3) it is combined by being added on electrolytic cell by structures such as aspirating hole, air inlet pipe with air inlet, forms air and follow
The pernicious gas generated in electrolytic cell can be extracted out quickly and effectively, and bring external ozone into electrolytic cell by ring channel
It is interior, as a result, when electrolysis unit of the operator close to opening state, it not will receive the pollution of pernicious gas；Meanwhile in electrolysis
In the process, it is combined, entire electrolysis unit is carried out dual close with external seal strip by interior glass cover, interior sealing strip, outer glass cover
Envelope, prevents the pernicious gas generated in electrolytic process from overflowing external, harm is generated to human body, to improve the safety of production；
(4) by adding semi-automatic copper sheet conveying device, to replace manual handling convey, realize to cathode plate into
Row mechanical handing transmission process saves manpower, so that needing 3 specialized labors to see machine originally, being reduced to only needs 1 people,
Improve the purpose of working efficiency；
(5) by adding electrolyte density detection device for electrolysis unit, to the electrolyte liquid medicine specific gravity in electrolytic cell into
Row detection, it is too low when there is content of copper ion to know the content of copper ion in electrolyte liquid medicine, addition etching can be controlled in time
Waste liquid guarantees being normally carried out for electrolytic process so that the content of copper ion meets the requirements in electrolyte liquid medicine；Moreover, often separating
It is one or two hour only addition a few minutes, more accurate than traditional flow control addition manner, significantly save electric power, reduce at
This；
(6) the complete circular regeneration of etching waste liquor can be achieved, and obtain the electrolysis copper products of high economic value.Entirely produced
Journey is closed cycle, is generated substantially without waste water and gas, realizes that clean manufacturing and circular economy have the meaning of milestone to PCB industry
Justice.
Above-mentioned is the general introduction of inventive technique scheme, below in conjunction with attached drawing and specific embodiment, is done further to the present invention
Explanation.
Detailed description of the invention
Fig. 1 is overall structure diagram of the invention；
Fig. 2 is the structural schematic diagram of anti-oxidant slot in the present invention；
Fig. 3 is the external structure schematic diagram of air knife in the present invention；
Fig. 4 is the partial structure diagram of electrolysis unit in the present invention；
Fig. 5 is the structural schematic diagram of electrolyte density detection device in the present invention；
Fig. 6 is the structural schematic diagram of copper sheet conveying device in the present invention.
Specific embodiment
Further to illustrate the present invention to reach the technical means and efficacy that predetermined purpose is taken, below in conjunction with attached drawing
And preferred embodiment, detailed description of specific embodiments of the present invention.
Please refer to Fig. 1, the embodiment of the present invention provides a kind of regenerating alkaline etching liquid and its copper recovery system, including a board
1 and a controller, an electrolysis unit 2 and a bronze medal recycling and processing device 3 are formed on the board 1, and the electrolysis unit 2 is distinguished
It is connected to a waste liquid tank 4 and a regenerated liquid regulating tank 5, the copper recycling and processing device 3 includes being set to 2 a side of electrolysis unit
On a pickling neutralization chamber 31, at least rinsing bowl 32 that is set on 31 side of pickling neutralization chamber and be set to rinsing bowl 32
Primary antibody oxidation trough 33 on side.Specifically, the present embodiment is added in the anti-oxidant slot 33 antioxidant solution, in institute
It states to be added in pickling neutralization chamber 31 and has acid solution, for example, weak sulfuric acid solution, being added in the rinsing bowl 32 has clear water, and
The quantity of the rinsing bowl 32 is two, that is, carries out washing step twice.
The present embodiment carries out Direct Electrolysis to the alkaline etching liquid (etching work procedure generation) in waste liquid tank 4 by electrolysis unit 2,
Obtain cathode plate.Meanwhile subsequent processing is carried out to cathode plate by copper recycling and processing device 3, first cathode plate is put into
In pickling neutralization chamber 31, cathode plate alkaline solution remained on surface is neutralized；Then, cathode plate is put into rinsing bowl
In 32, cathode plate surface is washed；Finally, cathode plate is put into anti-oxidant slot 33, to cathode plate surface
Anti-oxidant treatment is carried out, so that adhering to anti oxidation layer on cathode plate surface, effectively prevent cathode plate oxidizing blackening (non-oxidation
Copper generate), as a result, obtain high-purity, non-oxidation, light cathode plate.
In order to further increase the antioxygenic property of cathode plate, as shown in Figure 2 and Figure 3, the present embodiment is in the antioxygen
Two inner side edge tops of change slot 33 are horizontal respectively an air knife 331, is formed with inside the air knife 331 and is connected to external air blower
One wind chamber offers several bar shaped air outlets 3311 for being connected to wind chamber, and the bar shaped air outlet on 331 side of air knife
3311 opening direction is diagonally downward, preferential, and the opening direction of the bar shaped air outlet 3311 tilts down 30 °.Work as tough cathode
After plate is put into anti-oxidant slot 33, from air blower to the intracavitary air blast of the wind of air knife 331, then blown out by several bar shaped air outlets 3311
High speed winds dry up cathode plate surface, and cathode plate surface is effectively prevent to be oxidized, and antioxygenic property are improved, to improve
The purity and brightness of cathode plate.
In the present embodiment, as best shown in figs. 1 and 4, the electrolysis unit 2 includes several electrolysis being formed on board 1
It slot 21, the anode plate 22 being set in electrolytic cell 21 and is set in electrolytic cell 21 and is located at 22 two sides of anode plate
One cathode plate 23, when electrolysis, copper is formed on 23 surface of cathode plate, forms cathode plate.
It is uniformly distributed and the copper of consistency of thickness in order to be formed in 23 single side surface of cathode plate, in order to subsequent stripping
From the present embodiment is respectively formed with two longitudinal directions being from top to bottom inserted into for 23 end of cathode plate on the inside of 21 both ends of electrolytic cell
Bar shaped slot 211, and this two longitudinal bar shaped slots 211 are distributed on the two sides of 21 end of electrolytic cell, 23 liang of the cathode plate
After end is inserted into longitudinal bar shaped slot 211,23 lateral surface of cathode plate and 21 inner wall of electrolytic cell are mutually close, and close to patch
It closes, it is preferred that it is optimal state that 23 lateral surface of cathode plate, which is contacted with 21 inner wall of electrolytic cell when being adjacent to, then at this time outside cathode plate 23
It is seamless between 21 inner wall of side and electrolytic cell.Since 23 end of cathode plate is inserted into longitudinal bar shaped slot 211, then cathode
Almost without gap between 211 inner wall of 23 end surface of plate and longitudinal bar shaped slot, meanwhile, 23 lateral surface of cathode plate and electrolytic cell
Also almost without gap between 21 inner walls, therefore, between 23 end surface of cathode plate and longitudinal 211 inner wall of bar shaped slot and
Electrolyte liquid medicine is seldom between 21 inner wall of 23 lateral surface of cathode plate and electrolytic cell, almost without being electrolysed that is, at the two positions
Liquid exchange capacity is seldom, even without that is, without the presence of copper ion at the two positions.As a result, in 23 end surface of cathode plate
Long copper is seldom on (on keeping to the side) and 23 lateral surface of cathode plate, or even not long copper, and only (removes on 23 inner surface of cathode plate
End surface) append one layer of copper, and copper is evenly distributed, consistency of thickness, the effective area of copper is big on cathode plate, convenient for subsequent
Copper is removed, the generation of layers of copper surrounding thickness, intermediate thin phenomenon on cathode plate 23 has effectively been prevented.
Meanwhile being put into and taking out for the ease of anode plate 22 and cathode plate 23, as shown in figure 4, the present embodiment is described
Electrolysis unit 2 is all around equipped with a wall 24, is respectively formed on the opposite two sides of the wall 24 with electrolytic cell 21 one by one
Corresponding several pocket sets 241, the pocket set 241 include card slot 2411 and difference position in one be caught in for 22 end of anode plate
In middle 2411 two sides of card slot and the side bayonet slot 2412 that is caught in for 23 end of cathode plate.
As further improvement of this embodiment, electrolyte liquid medicine issues pernicious gas (such as ammonia) to people in order to prevent
Body damages, if as shown in figure 4, the present embodiment bottom in the electrolytic cell 21 offers and is connected with external exhaust fan
Dry tap stomata 212, and bottom is provided with the air inlet pipe 213 being connected with external blower in the electrolytic cell 21, this into
Several air inlets 2131 are offered on tracheae 213.After the completion of electrolysis, after the electrolyte liquid medicine in electrolytic cell 21 is taken away, adopt
The pernicious gas in electrolytic cell 21 is extracted out by aspirating hole 212 with external exhaust fan, meanwhile, air inlet is passed through by external blower
Several air inlets 2131 on pipe 213 bring external ozone in electrolytic cell 21 into, as a result, when operator is close to open shape
When the electrolysis unit 2 of state, the pollution of pernicious gas not will receive.
Meanwhile several interior seal grooves 242 are concavely provided in the wall 24, it is provided in the interior seal groove 242 interior close
Strip of paper used for sealing is equipped with glass cover in one to fit with interior sealing strip in 24 upper cover of wall；On the board 1 and it is located at electrolysis dress
It sets 2 peripheries and is recessed with an external seal slot 11, be provided with external seal strip in the external seal slot 11, on the board 1 and be located at electricity
Solution 2 periphery of device is covered with the outer glass cover to fit with external seal strip.During electrolysis, by interior glass cover, interior close
Strip of paper used for sealing, outer glass cover are combined with external seal strip, are carried out dual-seal to entire electrolysis unit 2, are prevented from generating in electrolytic process
Pernicious gas overflow external, harm is generated to human body, to improve the safety of production.
In the present embodiment, it is connected between the electrolysis unit 2 and waste liquid tank 4 by a waste liquid inlet tube, in the waste liquid
The water pump being electrically connected with the controller is provided on inlet tube.
As further improvement of this embodiment, in order to guarantee that content of copper ion meets the requirements in electrolyte liquid medicine, this reality
It applies example and is provided with an electrolyte density detection device 6 on 2 side of electrolysis unit, as shown in figure 5, for the ease of showing
Internal structure feature, Fig. 5 is the view after removing front side board, specifically, the electrolyte density detection device 6 includes an inspection
It surveys cavity 61 and hangs in test chamber 61 and be electrically connected to a densimeter 62 of controller, set in the test chamber 61
It is equipped with a feed liquor endplate 63 and an outlet end partition 64, the feed liquor endplate 63 and outlet end partition 64 will test in cavity 61
Part is at a detection zone 65, one positioned at a feed liquor area 66 in 63 outside of feed liquor endplate and on the outside of outlet end partition 64
Liquid zone 67 out, the densimeter 62 are located in detection zone 65, which is reserved with feed liquor area 66 and detection zone
65 side openings 631 being connected, 64 upper end of outlet end partition are reserved with one that liquid zone 67 out is connected with detection zone 65
Upper opening 641；Meanwhile it being connected with a detection inlet tube 68 between the 66 side top of feed liquor area and electrolysis unit 2, in the inspection
It surveys on inlet tube 68 and is provided with the electrically operated valve being electrically connected with the controller；This go out 67 side lower part of liquid zone be provided with one go out liquid
Pipe 69.
Under normal conditions, it when content of copper ion is 25-35g/L in electrolyte liquid medicine, meets the requirements.Due in etching waste liquor
The content of copper ion is 110-160g/L, therefore, when content of copper ion is lower than 25-35g/L in electrolyte liquid medicine, can be passed through
The mode of etching waste liquor is added, content of copper ion in electrolyte liquid medicine is adjusted to and meets range.When specific detection, electrolysis unit
Electrolyte liquid medicine in 2 enters feed liquor area 66 by detection inlet tube 68, meanwhile, detection zone 65 is entered by side opening 631,
Detected by specific gravity of the densimeter 62 to 65 electrolyte inside liquid medicine of detection zone, and in electrolyte liquid medicine containing a certain amount of copper from
Son illustrates that content of copper ion in predetermined range, is then said when detecting that the specific gravity of electrolyte liquid medicine is in predetermined range
Content of copper ion meets the requirements within the scope of 25-35g/L in bright electrolyte liquid medicine；And when the specific gravity for detecting electrolyte liquid medicine
When lower than within the scope of this, illustrate content of copper ion lower than prescribed limit, then illustrates that content of copper ion is lower than 25- in electrolyte liquid medicine
Etching waste liquor in waste liquid tank 4 is then added in electrolysis unit 2 by controller control water pump, until densimeter by 35g/L range
62 detect that content of copper ion meets the requirements in electrolyte liquid medicine, just stop that etching waste liquor is added.Meanwhile when in detection zone 65
When the liquid level of electrolyte liquid medicine reaches upper opening 641, electrolyte liquid medicine enters out liquid zone 67 by upper opening 641, and by going out liquid
Pipe 69 is discharged.
As further improvement of this embodiment, the present embodiment sliding rack on the board 1 is equipped with copper sheet conveying dress
7 are set, carrying conveying manually is carried out to the copper sheet of generation to replace, reaches reduction manpower, improves the purpose of working efficiency.Specifically
, as shown in fig. 6, the copper sheet conveying device 7 includes the bracket 71 being set up on board 1, is set to the one of 71 upper end of bracket
Rotary electric machine 72, through rotary electric machine 72 a machine shaft 73, be connected between 73 both ends of machine shaft a copper sheet lifting
It drives component 74 and is connected to several copper sheets hook 75 that copper sheet lifting drives 74 lower end of component, wherein copper sheet lifting drives
Component 74 stretches belt including being sheathed on a left set axis 741 of 72 left end of machine shaft, being wound in the peripheral Zola of left set axis 741
742, be sheathed on a right set axis 743 of 73 right end of machine shaft, be wound in 743 periphery of right set axis a right stretching belt 744 and
It is connected to Zola and stretches 742 end of belt and the right lifting driven rod 745 stretched between 744 end of belt, copper sheet hook 75
It is connected on lifting driven rod 745.The bracket 71 mainly by a upper supporting plate 711, be connected to the one left of 711 left end lower part of upper supporting plate
Longitudinal supporting plate 712 and the right longitudinal supporting plate 713 for being connected to 711 right end lower part of upper supporting plate form, the rotary electric machine 72, motor
Shaft 73, left set axis 741 and right set axis 743 are respectively arranged on upper supporting plate 711, which stretches belt 742 and right stretching belt
744 extend across upper supporting plate 711 towards left longitudinal supporting plate 712 and right longitudinal supporting plate 713 vertically downward；In left longitudinal supporting plate
712 are respectively arranged with a longitudinal slide rail 7121 with right longitudinal 713 inner side edge of supporting plate, distinguish at 745 both ends of lifting driven rod
It is provided with the lifting pulley 7451 slided in longitudinal slide rail 7121；It is respectively set on the opposite two sides in 1 upper end of board
There is a translation sliding rail 12, which passes through several translating pulleys 7132 with 713 lower end of right longitudinal supporting plate respectively and slide
In on translation sliding rail 12；It is provided on 713 side of left longitudinal supporting plate 712 or right longitudinal supporting plate and is electrically connected to rotary electric machine 72
And control several buttons 714 of 72 positive and negative rotation of rotary electric machine.
Washing is moved to when needing cathode plate being moved to another slot from a slot, such as from pickling neutralization chamber 31
Slot 32, concrete operations are as follows: global copper plate conveying device 7 is pushed to 31 top of pickling neutralization chamber, by lower button 714, starting turns
Dynamic motor 72 rotates forward, then drives machine shaft 73 to rotate forward, then Zola stretches belt 742 and progressively disengages from left set axis 741, right stretching
Belt 744 is progressively disengaged from right set axis 743, and lifting driven rod 745 gravity under, lifting driven rod 745 with
Copper sheet hook 75 moves down, and Zola stretches belt 742 and the synchronous elongation downwards of right stretching belt 744；When copper sheet hook 75 drops to hook
Firmly when cathode plate, button 714 is pinned again, inverts rotary electric machine 72, then drives machine shaft 73 to invert, then drive Zola
It stretches belt 742 and right stretching belt 744 moves up and is wound in left set axis 741 on right set axis 743, Zola stretches belt 742 and the right side
It stretches belt 744 and gradually moves up shortening, then lifting driven rod 745 is driven to move up with copper sheet hook 75, until copper sheet hook 75 is hung
The cathode plate risen is detached from pickling neutralization chamber 31, then presses lower button 714, the motor 72 that stops operating work again.It then, will be whole
Copper sheet conveying device 7 is pushed to 32 top of rinsing bowl, by lower button 714, is again started up the rotating forward of rotary electric machine 72, then drives motor
Shaft 73 rotate forward, then Zola stretches belt 742 and progressively disengages from left set axis 741, right stretching belt 744 from right set axis 743 by
It is gradually detached from, and under the gravity of lifting driven rod 745, lifting driven rod 745 is under copper sheet hook 75 and cathode plate
It moves, Zola stretches belt 742 and the synchronous elongation downwards of right stretching belt 744, when cathode plate declines and enters in rinsing bowl 32
Later, copper sheet hook 75 is detached from cathode plate.
In the present embodiment, copper ion reduces in the electrolyte liquid medicine after electrolysis, can be formed again by redistribution again
Raw etching solution, is re-applied on etching work procedure.Between waste liquid tank 4 and regenerated liquid regulating tank 5 described in the present embodiment by one every
Plate 8 separates, and is provided with the liquidometer in regenerated liquid regulating tank 5 on 8 side of partition.Waste liquid tank 4 is connected to electricity
Device 2 is solved, etching waste liquor is transported in electrolysis unit 2, meanwhile, regenerated liquid regulating tank 5 is also connected to electrolysis unit 2, electrolysis
Electrolyte liquid medicine afterwards is discharged in regenerated liquid regulating tank 5, when liquidometer detects that liquid reaches certain in regenerated liquid regulating tank 5
After water level, the liquid in regenerated liquid regulating tank 5 is taken away allotment, to obtain required regeneration etching solution.Meanwhile in the waste liquid
It is respectively arranged with a cooling coil 9 in slot 4 and regenerated liquid regulating tank 5, in order to cool down internal liquid, especially
Liquid in regenerated liquid regulating tank 5 derives from electrolysis unit 2, and electrolysis is carried out in electrolysis unit 2 and generates heat, liquid out
Temperature is higher, first cools to certain value and takes away again.
The above described is only a preferred embodiment of the present invention, be not intended to limit the scope of the present invention,
Therefore technical characteristic same as or similar to the above embodiments of the present invention is used, and obtained other structures, in guarantor of the invention
Within the scope of shield.
Claims (10)
1. a kind of regenerating alkaline etching liquid and its copper recovery system, including a board and a controller, are formed on the board
One electrolysis unit and a bronze medal recycling and processing device, and the electrolysis unit is respectively communicated to a waste liquid tank and a regenerated liquid regulating tank,
It is characterized in that, the copper recycling and processing device includes the pickling neutralization chamber being set in electrolysis unit a side, is set to
An at least rinsing bowl on pickling neutralization chamber side and the primary antibody oxidation trough being set on rinsing bowl side.
2. regenerating alkaline etching liquid according to claim 1 and its copper recovery system, which is characterized in that described anti-oxidant
Two inner side edge tops of slot are horizontal respectively an air knife, and the wind chamber for being connected to external air blower is formed with inside the air knife,
Several bar shaped air outlets for being connected to wind chamber are offered on the air knife side, and the opening direction of the bar shaped air outlet is tilted towards
Under.
3. regenerating alkaline etching liquid according to claim 1 and its copper recovery system, which is characterized in that described anti-oxidant
Being added in slot has antioxidant solution, and being added in the pickling neutralization chamber has acid solution, and being added in the rinsing bowl has
Clear water, and the quantity of the rinsing bowl is two.
4. regenerating alkaline etching liquid according to claim 1 and its copper recovery system, which is characterized in that the electrolysis unit
Including several electrolytic cells being formed on board, the anode plate being set in electrolytic cell and it is set in electrolytic cell and distinguishes
A cathode plate positioned at anode plate two sides, wherein be respectively formed on the inside of the electrolytic cell both ends for cathode plate end by up to
The longitudinal bar shaped slot of two of lower insertion, and this two longitudinal bar shaped slots are distributed on the two sides of electrolytic cell end, the yin
After pole plate both ends are inserted into longitudinal bar shaped slot, the cathode plate lateral surface and electrolytic cell inner wall are mutually close.
5. regenerating alkaline etching liquid according to claim 4 and its copper recovery system, which is characterized in that filled in the electrolysis
It sets and is all around equipped with a wall, be respectively formed on the opposite two sides of the wall and electrolytic cell several card slots correspondingly
Group, the pocket set include card slot and being located at middle card slot two sides and for cathode plate end in one be caught in for anode plate end
The side bayonet slot being caught in.
6. regenerating alkaline etching liquid according to claim 5 and its copper recovery system, which is characterized in that in the electrolytic cell
Interior bottom offers several aspirating holes being connected with external exhaust fan, and bottom is provided with and external air blast in the electrolytic cell
The air inlet pipe that machine is connected, offers several air inlets in the air inlet pipe；Meanwhile it being concavely provided in several in the wall
Seal groove is provided with interior sealing strip in the interior seal groove, is equipped with glass in one to fit with interior sealing strip in the wall upper cover
Glass lid；It is recessed with an external seal slot on the board and positioned at electrolysis unit periphery, is provided in the external seal slot outer close
Strip of paper used for sealing is covered with the outer glass cover to fit with external seal strip on the board and positioned at electrolysis unit periphery.
7. regenerating alkaline etching liquid according to claim 1 and its copper recovery system, which is characterized in that the electrolysis unit
It is connect between waste liquid tank by a waste liquid inlet tube, the water being electrically connected with the controller is provided on the waste liquid inlet tube
Pump.
8. regenerating alkaline etching liquid according to claim 1 and its copper recovery system, which is characterized in that filled in the electrolysis
It sets and is provided with an electrolyte density detection device on side, which includes a test chamber and suspension
In in test chamber and being electrically connected to a densimeter of controller, it is provided with a feed liquor endplate in the test chamber and goes out with one
Liquid endplate, the feed liquor endplate and outlet end partition will test inside cavity and be divided into a detection zone, be located at outside feed liquor endplate
One feed liquor area of side and one go out liquid zone on the outside of outlet end partition, which is located in detection zone, the feed liquor endplate
Side is reserved with the side opening that feed liquor area is connected with detection zone, which is reserved with liquid zone out and inspection
Survey the upper opening that area is connected；Meanwhile it being connected with a detection inlet tube between the feed liquor area side top and electrolysis unit,
The electrically operated valve being electrically connected with the controller is provided on the detection inlet tube；Go out liquid zone side lower part and be provided with one at this
Liquid pipe.
9. regenerating alkaline etching liquid according to claim 1 and its copper recovery system, which is characterized in that on the board
Sliding rack is equipped with a copper sheet conveying device, which includes the bracket being set up on board, is set on bracket
One rotary electric machine at end, the machine shaft through rotary electric machine, the copper sheet lifting belt that is connected between machine shaft both ends
It moves component and is connected to several copper sheets hook that copper sheet lifting drives component lower end, wherein the copper sheet goes up and down drive component and includes
Be sheathed on a left set axis of machine shaft left end, be wound in left set axis periphery a Zola stretch belt, be sheathed on machine shaft the right side
The one right set axis at end is wound in a right stretching belt of right set axis periphery and is connected to Zola and stretches belt ends and right stretching skin
With the lifting driven rod between end, copper sheet hook is connected on lifting driven rod；The bracket is mainly by a upper supporting plate, company
It is connected to a left longitudinal supporting plate of upper supporting plate left end lower part and is connected to a right longitudinal supporting plate composition of upper supporting plate right end lower part, it should
Rotary electric machine, machine shaft, left set axis and right set axis are respectively arranged on upper supporting plate, which stretches belt and wear with right stretching belt
Upper supporting plate is crossed to extend vertically downward towards between left longitudinal supporting plate and right longitudinal supporting plate；In left longitudinal supporting plate and right longitudinal supporting plate
Side is respectively arranged with a longitudinal slide rail, is respectively arranged with one liter slided in longitudinal slide rail at the lifting driven rod both ends
Pulley drops；A translation sliding rail is respectively arranged on the opposite two sides in the board upper end, left longitudinal supporting plate and right longitudinal supporting plate
Lower end passes through several translating pulleys respectively and slides on translation sliding rail；It is arranged on left longitudinal supporting plate or right longitudinal supporting plate side
There are several buttons for being electrically connected to rotary electric machine and controlling rotary electric machine positive and negative rotation.
10. regenerating alkaline etching liquid according to claim 1 and its copper recovery system, which is characterized in that the waste liquid tank
One for being separated, and being provided on the partition side in regenerated liquid regulating tank by a partition between regenerated liquid regulating tank
Liquidometer；Meanwhile a cooling coil is respectively arranged in the waste liquid tank and regenerated liquid regulating tank.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910285485.6A CN109881199A (en) | 2019-04-10 | 2019-04-10 | A kind of regenerating alkaline etching liquid and its copper recovery system |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910285485.6A CN109881199A (en) | 2019-04-10 | 2019-04-10 | A kind of regenerating alkaline etching liquid and its copper recovery system |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109881199A true CN109881199A (en) | 2019-06-14 |
Family
ID=66936753
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910285485.6A Pending CN109881199A (en) | 2019-04-10 | 2019-04-10 | A kind of regenerating alkaline etching liquid and its copper recovery system |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109881199A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110468396A (en) * | 2019-08-28 | 2019-11-19 | 福建捷思金属科技发展有限公司 | A kind of copper sheet numerical control oxidation machine |
| CN111394729A (en) * | 2020-04-26 | 2020-07-10 | 江苏地一环保科技有限公司 | Electrolytic device and printed board acid etching waste liquid regeneration and copper recovery equipment thereof |
Citations (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0971891A (en) * | 1995-08-31 | 1997-03-18 | Sumitomo Metal Mining Co Ltd | Method for electrorefining metal |
| JP2000074810A (en) * | 1998-08-31 | 2000-03-14 | Morikawa Sangyo Kk | Liquid specific gravity measuring device |
| CN201534880U (en) * | 2009-11-27 | 2010-07-28 | 苏州天地环境科技有限公司 | Device for electrolyzing and recycling copper from low-concentration waste liquid with copper generated from microetching and pickling |
| CN201793745U (en) * | 2010-09-26 | 2011-04-13 | 佛山市三水侨锋电路版有限公司 | Etching waste liquid regeneration and copper recovery processing system |
| CN202107778U (en) * | 2011-05-06 | 2012-01-11 | 湖南维邦新能源有限公司 | Membrane type electrolytic cell |
| KR101188479B1 (en) * | 2012-04-06 | 2012-10-08 | 최광식 | Recovery apparatus of precious metal for electrolysis |
| CN103128273A (en) * | 2011-11-28 | 2013-06-05 | 重庆华浩冶炼有限公司 | Saponification method of copper powder production |
| CN103614741A (en) * | 2013-11-22 | 2014-03-05 | 中国环境科学研究院 | Method of decreasing, reutilizing and circulating heavy metal wastewater in subsequent section of electrolytic manganese electrolysis |
| CN104404575A (en) * | 2014-11-28 | 2015-03-11 | 阳谷祥光铜业有限公司 | Metallic electrolytic cell and metal electrolysis process |
| CN105154920A (en) * | 2015-09-17 | 2015-12-16 | 中国环境科学研究院 | In-situ removing device and method for electrolytes carried when zinc negative plate is taken out of bath |
| CN105483707A (en) * | 2015-12-29 | 2016-04-13 | 无锡市瑞思科环保科技有限公司 | Method for extracting copper for reuse from alkaline copper chloride etching waste liquid |
| CN105506670A (en) * | 2015-12-18 | 2016-04-20 | 阳谷祥光铜业有限公司 | Device for copper electrolysis or copper electrodeposition, and running method |
| CN106011929A (en) * | 2016-07-21 | 2016-10-12 | 无锡派乐科技有限公司 | Method for recycling copper extracted from alkaline copper chloride etching waste liquid |
| CN205710925U (en) * | 2016-06-28 | 2016-11-23 | 苏州卓融新能源科技有限公司 | A kind of annular electrolysis unit being applicable to PCB acid etching liquid |
| CN106929857A (en) * | 2017-04-01 | 2017-07-07 | 东莞市青玉环保设备科技有限公司 | Cupric acidity etching liquid recycling equipment for reclaiming and method |
| CN107059010A (en) * | 2017-04-01 | 2017-08-18 | 东莞市青玉环保设备科技有限公司 | Cupric alkaline etching liquid circular regeneration equipment for reclaiming and method |
| CN206692758U (en) * | 2017-03-29 | 2017-12-01 | 洛阳爱科麦钨钼科技股份有限公司 | It is a kind of with rare-earth smelting electrolytic cell |
| CN107473090A (en) * | 2017-08-31 | 2017-12-15 | 张家港联合铜业有限公司 | A kind of overhead traveling crane |
| CN207109135U (en) * | 2017-08-15 | 2018-03-16 | 东莞市同欣表面处理科技有限公司 | The main salt ion electrolytic recovery device of electroplating solution |
| CN108950606A (en) * | 2018-07-26 | 2018-12-07 | 北京矿冶科技集团有限公司 | A kind of reception system of electrodeposit metals cathode plate |
| CN109023374A (en) * | 2018-08-24 | 2018-12-18 | 德雅（深圳）环境科技有限公司 | A kind of acidity etching liquid recycling system and method |
| CN109161895A (en) * | 2018-08-27 | 2019-01-08 | 安徽绿洲危险废物综合利用有限公司 | Acid copper chloride etching liquid copper reclaiming system and reclaiming method |
| CN109881200A (en) * | 2019-04-10 | 2019-06-14 | 深圳市铿东科技有限公司 | A kind of regenerating alkaline etching liquid and its copper recovery method |
| CN210367911U (en) * | 2019-04-10 | 2020-04-21 | 深圳市铿东科技有限公司 | Alkaline etching solution regeneration and copper recovery system thereof |
-
2019
- 2019-04-10 CN CN201910285485.6A patent/CN109881199A/en active Pending
Patent Citations (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0971891A (en) * | 1995-08-31 | 1997-03-18 | Sumitomo Metal Mining Co Ltd | Method for electrorefining metal |
| JP2000074810A (en) * | 1998-08-31 | 2000-03-14 | Morikawa Sangyo Kk | Liquid specific gravity measuring device |
| CN201534880U (en) * | 2009-11-27 | 2010-07-28 | 苏州天地环境科技有限公司 | Device for electrolyzing and recycling copper from low-concentration waste liquid with copper generated from microetching and pickling |
| CN201793745U (en) * | 2010-09-26 | 2011-04-13 | 佛山市三水侨锋电路版有限公司 | Etching waste liquid regeneration and copper recovery processing system |
| CN202107778U (en) * | 2011-05-06 | 2012-01-11 | 湖南维邦新能源有限公司 | Membrane type electrolytic cell |
| CN103128273A (en) * | 2011-11-28 | 2013-06-05 | 重庆华浩冶炼有限公司 | Saponification method of copper powder production |
| KR101188479B1 (en) * | 2012-04-06 | 2012-10-08 | 최광식 | Recovery apparatus of precious metal for electrolysis |
| CN103614741A (en) * | 2013-11-22 | 2014-03-05 | 中国环境科学研究院 | Method of decreasing, reutilizing and circulating heavy metal wastewater in subsequent section of electrolytic manganese electrolysis |
| CN104404575A (en) * | 2014-11-28 | 2015-03-11 | 阳谷祥光铜业有限公司 | Metallic electrolytic cell and metal electrolysis process |
| CN105154920A (en) * | 2015-09-17 | 2015-12-16 | 中国环境科学研究院 | In-situ removing device and method for electrolytes carried when zinc negative plate is taken out of bath |
| CN105506670A (en) * | 2015-12-18 | 2016-04-20 | 阳谷祥光铜业有限公司 | Device for copper electrolysis or copper electrodeposition, and running method |
| CN105483707A (en) * | 2015-12-29 | 2016-04-13 | 无锡市瑞思科环保科技有限公司 | Method for extracting copper for reuse from alkaline copper chloride etching waste liquid |
| CN205710925U (en) * | 2016-06-28 | 2016-11-23 | 苏州卓融新能源科技有限公司 | A kind of annular electrolysis unit being applicable to PCB acid etching liquid |
| CN106011929A (en) * | 2016-07-21 | 2016-10-12 | 无锡派乐科技有限公司 | Method for recycling copper extracted from alkaline copper chloride etching waste liquid |
| CN206692758U (en) * | 2017-03-29 | 2017-12-01 | 洛阳爱科麦钨钼科技股份有限公司 | It is a kind of with rare-earth smelting electrolytic cell |
| CN106929857A (en) * | 2017-04-01 | 2017-07-07 | 东莞市青玉环保设备科技有限公司 | Cupric acidity etching liquid recycling equipment for reclaiming and method |
| CN107059010A (en) * | 2017-04-01 | 2017-08-18 | 东莞市青玉环保设备科技有限公司 | Cupric alkaline etching liquid circular regeneration equipment for reclaiming and method |
| CN207109135U (en) * | 2017-08-15 | 2018-03-16 | 东莞市同欣表面处理科技有限公司 | The main salt ion electrolytic recovery device of electroplating solution |
| CN107473090A (en) * | 2017-08-31 | 2017-12-15 | 张家港联合铜业有限公司 | A kind of overhead traveling crane |
| CN108950606A (en) * | 2018-07-26 | 2018-12-07 | 北京矿冶科技集团有限公司 | A kind of reception system of electrodeposit metals cathode plate |
| CN109023374A (en) * | 2018-08-24 | 2018-12-18 | 德雅（深圳）环境科技有限公司 | A kind of acidity etching liquid recycling system and method |
| CN109161895A (en) * | 2018-08-27 | 2019-01-08 | 安徽绿洲危险废物综合利用有限公司 | Acid copper chloride etching liquid copper reclaiming system and reclaiming method |
| CN109881200A (en) * | 2019-04-10 | 2019-06-14 | 深圳市铿东科技有限公司 | A kind of regenerating alkaline etching liquid and its copper recovery method |
| CN210367911U (en) * | 2019-04-10 | 2020-04-21 | 深圳市铿东科技有限公司 | Alkaline etching solution regeneration and copper recovery system thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110468396A (en) * | 2019-08-28 | 2019-11-19 | 福建捷思金属科技发展有限公司 | A kind of copper sheet numerical control oxidation machine |
| CN111394729A (en) * | 2020-04-26 | 2020-07-10 | 江苏地一环保科技有限公司 | Electrolytic device and printed board acid etching waste liquid regeneration and copper recovery equipment thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109881199A (en) | A kind of regenerating alkaline etching liquid and its copper recovery system | |
| CN210628335U (en) | Silicon wafer cleaning equipment | |
| CN103981564B (en) | Transmit full-automatic method of barrel electroplating and production line step by step | |
| CN110788063A (en) | Silicon wafer cleaning equipment | |
| CN106757294B (en) | A method of for supplementing copper sulphate in copper plating groove | |
| CN212494239U (en) | Cleaning equipment for polycrystalline silicon processing waste | |
| CN218884491U (en) | Drying tank, drying device and cleaning equipment | |
| CN210367911U (en) | Alkaline etching solution regeneration and copper recovery system thereof | |
| CN204029920U (en) | One is internalized into uses green plate pretreatment unit | |
| CN109881200B (en) | Regeneration of alkaline etching solution and copper recovery method thereof | |
| CN205341059U (en) | Centrifugation equipment of production citric acid | |
| CN106544718B (en) | A kind of automation electroplating assembly line | |
| CN204981150U (en) | Deaerator | |
| CN207227575U (en) | A kind of cooling cleaning device of tinned wird processing | |
| CN211100448U (en) | Silicon wafer cleaning equipment | |
| CN214088754U (en) | Hollow fiber membrane silk drying device | |
| CN212068294U (en) | Waste gas collecting and treating device and workpiece cleaning system | |
| CN114353537A (en) | Circulating air recovery device of air kiln | |
| CN205635803U (en) | Copper recovery device | |
| CN206580793U (en) | A kind of ginger oil extraction element | |
| CN206330803U (en) | A kind of high pure metal primary standard substance pretreating device | |
| CN209568173U (en) | A kind of semiconductor crystal wafer short annealing equipment | |
| CN103614781A (en) | Cold circulation type cocoon cooking machine | |
| CN110640989A (en) | Cable material quality inspection and impurity removal complete equipment for single-core cable extrusion molding | |
| CN203233999U (en) | Food drying device adopting radio frequency inductive discharge |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |