CN109856111A - A kind of array structure Raman spectrometer - Google Patents

A kind of array structure Raman spectrometer Download PDF

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Publication number
CN109856111A
CN109856111A CN201711242661.5A CN201711242661A CN109856111A CN 109856111 A CN109856111 A CN 109856111A CN 201711242661 A CN201711242661 A CN 201711242661A CN 109856111 A CN109856111 A CN 109856111A
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CN
China
Prior art keywords
fibre
optical
narrow linewidth
array
detecting plate
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711242661.5A
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Chinese (zh)
Inventor
吴砺
李俊梅
林磊
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Photop Technologies Inc
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Photop Technologies Inc
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Publication date
Application filed by Photop Technologies Inc filed Critical Photop Technologies Inc
Priority to CN201711242661.5A priority Critical patent/CN109856111A/en
Publication of CN109856111A publication Critical patent/CN109856111A/en
Pending legal-status Critical Current

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Abstract

The present invention discloses a kind of array structure Raman spectrometer, it includes narrow linewidth LD array, detecting plate, CCD receiving array, multiple narrow linewidth output optical fibres and multiple signal reception optical fibers, narrow linewidth LD array is connect with one end of multiple narrow linewidth output optical fibres respectively, multiple fibre-optical probes are intervally distributed on detecting plate, the other end of each narrow linewidth output optical fibre is connected respectively a fibre-optical probe, each fibre-optical probe is connect with a signal reception optical fiber one end, and the other end close-packed arrays of multiple signal reception optical fibers access CCD receiving array afterwards in line.Greater number of the present invention improves Raman spectrum pumping point quantity and improves one or several orders of magnitude to improve Raman spectrum total light intensity.Sample 7 will not be burnt by separating light source, i.e., single-point light intensity is still normal light intensity.

Description

A kind of array structure Raman spectrometer
Technical field
The present invention relates to optical instrument field more particularly to a kind of array structure Raman spectrometers.
Background technique
Current Raman spectroscopy instrument all financial resourcess concept is single light source, single sensing point.Sometimes light source intensity is too strong, causes Sample is burnt.
Summary of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of array structure Raman spectrometers.
The technical solution adopted by the present invention is that:
A kind of array structure Raman spectrometer comprising narrow linewidth LD array, detecting plate, CCD receiving array, multiple narrow linewidths are defeated Optical fiber and multiple signal reception optical fibers, narrow linewidth LD array are connect with one end of multiple narrow linewidth output optical fibres respectively out, detection Multiple fibre-optical probes are intervally distributed on plate, the other end of each narrow linewidth output optical fibre is connected respectively an optical fiber and visits Head, each fibre-optical probe are connect with a signal reception optical fiber one end, the other end close-packed arrays of multiple signal reception optical fibers at One straight line is followed by into CCD receiving array.
Further, multiple fibre-optical probes are evenly spaced on detecting plate.
Further, detecting plate is divided into multiple detection submodules, and each detection submodule includes multiple is spaced apart Fibre-optical probe.
Further, detecting plate is divided into 5 detection submodules, and each detection submodule includes 20 fibre-optical probes.
Further, narrow linewidth output optical fibre and signal reception optical fiber use rectangle fiber optic bundle, to improve pump light utilization Rate.
Further, waveguide pack is equipped between narrow linewidth output optical fibre and fibre-optical probe.
Further, the invention also includes micro- hole sample box corresponding with detecting plate, micro- hole sample box be equipped with it is each The corresponding miniature accommodating chamber of fibre-optical probe.
The invention adopts the above technical scheme, exports N number of narrow linewidth optical fiber output laser conduct using narrow linewidth LD array Raman spectrum pumping source, and be distributed and sample is detected in multiple fibre-optical probes on detecting plate by being spaced apart, then by Multiple signal reception optical fibers obtain the Raman spectrum of detection, and the output end of multiple signal reception optical fibers for receiving Raman spectrum is tight It is received after the close straight line that forms a line by ccd array, measures its Raman spectrum.Greater number of the present invention improves Raman spectrum and pumps point Quantity improves one or several orders of magnitude to improve Raman spectrum total light intensity.Sample will not be burnt by separating light source, i.e. single-point light It is by force still normal light intensity.
Detailed description of the invention
The present invention is described in further details below in conjunction with the drawings and specific embodiments;
Fig. 1 is a kind of structural schematic diagram of array structure Raman spectrometer of the present invention;
Fig. 2 is a kind of micro- hole sample box structural schematic diagram of array structure Raman spectrometer of the present invention.
Specific embodiment
As shown in the figures 1 and 2, the invention discloses a kind of array structure Raman spectrometers comprising narrow linewidth LD array 1, Detecting plate 2, CCD receiving array 6, multiple narrow linewidth output optical fibres 3 and multiple signal reception optical fibers 5, narrow linewidth LD array 1 are distinguished It is connect with one end of multiple narrow linewidth output optical fibres 3, multiple fibre-optical probes 4 is intervally distributed on detecting plate 2, each narrow linewidth is defeated The other end of optical fiber 3 is connected respectively a fibre-optical probe 4, each fibre-optical probe 4 and 5 one end of signal reception optical fiber out Connection, the other end close-packed arrays of multiple signal reception optical fibers 5 access CCD receiving array 6 afterwards in line.
Further, multiple fibre-optical probes 4 are evenly spaced on detecting plate 2.WeChat ID is drawn in multi-probe setting Graceful spectrum rapid survey also has obvious benefit, if 1 sample 7 needs for a long time such as a hour integral, 60 are popped one's head in one minute It can be completed.When not allowing long-time laser irradiation especially for the biological sample 7 having, big quantity probe then shortens the time, There is stronger measurement advantage.
Further, detecting plate 2 divides for multiple detection submodules, and each detection submodule includes multiple is spaced apart Fibre-optical probe 4.Further, detecting plate 2 divides for 5 detection submodules, and each detection submodule includes 20 fibre-optical probes 4.It is arranged using modularization, user can detect submodule according to practical increase and decrease, so that optical system is not too large, only needing will be N number of Detect the signal Integral Processing again of submodule.
Further, narrow linewidth output optical fibre 3 and signal reception optical fiber 5 use rectangle fiber optic bundle, to improve pump light benefit With rate.
Further, waveguide pack is equipped between narrow linewidth output optical fibre 3 and fibre-optical probe 4.
Further, the invention also includes micro- hole sample box 8 corresponding with detecting plate 2, micro- hole sample box 8 be equipped with it is every The corresponding miniature accommodating chamber 81 of a fibre-optical probe 4.Micro- hole sample box 8, it is more convenient to measurement liquid surface, can with chemical reagent at It arranges syringe and automates tapping body, with automatic detection, liquid lacks Shi Yike;In addition, solid powder also can be used.
The invention adopts the above technical scheme, exports N number of narrow linewidth optical fiber output laser conduct using narrow linewidth LD array 1 Raman spectrum pumping source, and be distributed and sample 7 is detected in multiple fibre-optical probes 4 on detecting plate 2 by being spaced apart, then The Raman spectrum that detection is obtained by multiple signal reception optical fibers 5, by the output of multiple signal reception optical fibers 5 for receiving Raman spectrum It is received after the close straight line that forms a line in end by ccd array, measures its Raman spectrum.Greater number of the present invention improves Raman spectrum pump Pu point quantity improves one or several orders of magnitude to improve Raman spectrum total light intensity.Sample 7 will not be burnt by separating light source, i.e., singly Point light intensity is still normal light intensity.

Claims (7)

1. a kind of array structure Raman spectrometer, it is characterised in that: it includes narrow linewidth LD array, detecting plate, CCD reception battle array Column, multiple narrow linewidth output optical fibres and multiple signal reception optical fibers, narrow linewidth LD array respectively with multiple narrow linewidth output optical fibres One end connection, be intervally distributed with multiple fibre-optical probes on detecting plate, the other end of each narrow linewidth output optical fibre respectively corresponds Connect a fibre-optical probe, each fibre-optical probe is connect with a signal reception optical fiber one end, multiple signal reception optical fibers it is another One end close-packed arrays access CCD receiving array afterwards in line.
2. a kind of array structure Raman spectrometer according to claim 1, it is characterised in that: the multiple fibre-optical probe is equal It is even to be distributed on detecting plate.
3. a kind of array structure Raman spectrometer according to claim 1, it is characterised in that: the detecting plate is divided into multiple Submodule is detected, each detection submodule includes multiple fibre-optical probes being spaced apart.
4. a kind of array structure Raman spectrometer according to claim 3, it is characterised in that: the detecting plate is divided into 5 Submodule is detected, each detection submodule includes 20 fibre-optical probes.
5. a kind of array structure Raman spectrometer according to claim 1, it is characterised in that: the narrow linewidth output optical fibre Rectangle fiber optic bundle is used with signal reception optical fiber.
6. a kind of array structure Raman spectrometer according to claim 1, it is characterised in that: the narrow linewidth output optical fibre Waveguide pack is equipped between fibre-optical probe.
7. a kind of array structure Raman spectrometer according to claim 1, it is characterised in that: it further includes and detecting plate pair The micro- hole sample box answered, micro- hole sample box are equipped with miniature accommodating chamber corresponding with each fibre-optical probe.
CN201711242661.5A 2017-11-30 2017-11-30 A kind of array structure Raman spectrometer Pending CN109856111A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711242661.5A CN109856111A (en) 2017-11-30 2017-11-30 A kind of array structure Raman spectrometer

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Application Number Priority Date Filing Date Title
CN201711242661.5A CN109856111A (en) 2017-11-30 2017-11-30 A kind of array structure Raman spectrometer

Publications (1)

Publication Number Publication Date
CN109856111A true CN109856111A (en) 2019-06-07

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113295652A (en) * 2021-05-19 2021-08-24 中央民族大学 High-flux array scanning type LSPR sensing detection system

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6351306B1 (en) * 1999-10-19 2002-02-26 Kaiser Optical Systems, Inc. Optical measurement probe calibration configurations
US20040233426A1 (en) * 2003-03-25 2004-11-25 Riken And Machida Endoscope Co., Ltd. Raman probe and Raman spectrum measuring apparatus utilizing the same
CN101459313A (en) * 2008-12-31 2009-06-17 华南理工大学 Multiple wavelength outputting ultra-narrow wire single frequency optical fiber laser
CN101975770A (en) * 2010-10-15 2011-02-16 厦门大学 Integrated miniature Raman fiber optic spectrometer
CN102980658A (en) * 2012-11-14 2013-03-20 天津理工大学 Micro optical fiber spectrograph
CN103837235A (en) * 2012-11-21 2014-06-04 福州高意通讯有限公司 Raman spectrometer probe and Raman spectrometer system
WO2014089858A1 (en) * 2012-12-13 2014-06-19 华南理工大学 Tunable narrow-linewidth array single-frequency fiber laser
WO2015085978A1 (en) * 2013-12-09 2015-06-18 Friedrich-Schiller-Universität Jena Device with a raman probe, and method using said device
CN105004707A (en) * 2015-07-06 2015-10-28 浙江大学 CCD array on-line Raman spectrometer spectra standardization method
CN105997000A (en) * 2016-05-30 2016-10-12 福建师范大学 Raman spectrum detection device based on fibrescope and implementation method of detection device
CN106290300A (en) * 2016-08-04 2017-01-04 同方威视技术股份有限公司 Portable raman spectrometer

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6351306B1 (en) * 1999-10-19 2002-02-26 Kaiser Optical Systems, Inc. Optical measurement probe calibration configurations
US20040233426A1 (en) * 2003-03-25 2004-11-25 Riken And Machida Endoscope Co., Ltd. Raman probe and Raman spectrum measuring apparatus utilizing the same
CN101459313A (en) * 2008-12-31 2009-06-17 华南理工大学 Multiple wavelength outputting ultra-narrow wire single frequency optical fiber laser
CN101975770A (en) * 2010-10-15 2011-02-16 厦门大学 Integrated miniature Raman fiber optic spectrometer
CN102980658A (en) * 2012-11-14 2013-03-20 天津理工大学 Micro optical fiber spectrograph
CN103837235A (en) * 2012-11-21 2014-06-04 福州高意通讯有限公司 Raman spectrometer probe and Raman spectrometer system
WO2014089858A1 (en) * 2012-12-13 2014-06-19 华南理工大学 Tunable narrow-linewidth array single-frequency fiber laser
WO2015085978A1 (en) * 2013-12-09 2015-06-18 Friedrich-Schiller-Universität Jena Device with a raman probe, and method using said device
CN105004707A (en) * 2015-07-06 2015-10-28 浙江大学 CCD array on-line Raman spectrometer spectra standardization method
CN105997000A (en) * 2016-05-30 2016-10-12 福建师范大学 Raman spectrum detection device based on fibrescope and implementation method of detection device
CN106290300A (en) * 2016-08-04 2017-01-04 同方威视技术股份有限公司 Portable raman spectrometer

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113295652A (en) * 2021-05-19 2021-08-24 中央民族大学 High-flux array scanning type LSPR sensing detection system

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Application publication date: 20190607