CN109852286A - A kind of high-intensity weather-proof high ceramic tile gum and preparation method thereof - Google Patents

A kind of high-intensity weather-proof high ceramic tile gum and preparation method thereof Download PDF

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Publication number
CN109852286A
CN109852286A CN201910048847.XA CN201910048847A CN109852286A CN 109852286 A CN109852286 A CN 109852286A CN 201910048847 A CN201910048847 A CN 201910048847A CN 109852286 A CN109852286 A CN 109852286A
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CN
China
Prior art keywords
ceramic tile
parts
tile gum
thickener
intensity weather
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Pending
Application number
CN201910048847.XA
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Chinese (zh)
Inventor
龚瑾
廖国胜
付毅群
余璇
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Wuhan University of Science and Engineering WUSE
Wuhan University of Science and Technology WHUST
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Wuhan University of Science and Engineering WUSE
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Priority to CN201910048847.XA priority Critical patent/CN109852286A/en
Publication of CN109852286A publication Critical patent/CN109852286A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of high-intensity weather-proof high ceramic tile gum and preparation method thereof, the high-intensity weather-proof high ceramic tile gum is comprised the following components in parts by weight: 30-60 parts of styrene-butadiene emulsion, 20-50 parts of quartz sand, 5-25 parts of slag micropowder, 5-10 parts of silicon ash, 1-3 parts of thickener and 0.1-0.8 parts of preservative.The problems such as present invention provides a kind of high-intensity weather-proof high ceramic tile gum and preparation method thereof, and high-intensity weather-proof high ceramic tile gum flexibility produced by the present invention is good, and curing shrinkage is small, and bonding effect is good, durable, avoids hollowing and falls brick.

Description

A kind of high-intensity weather-proof high ceramic tile gum and preparation method thereof
Technical field
The present invention relates to ceramic tile gum fields.It is more particularly related to a kind of high-intensity weather-proof high ceramic tile gum And preparation method thereof.
Background technique
Ceramic tile gum is a kind of novel bonding material applied to the ceramic tile back side, its cohesive force is in addition to from cement bonded sand Slurry penetrates into other than the mechanical anchoring force that basal plane pore is formed, the also molecule long-chain with polymeric material penetrates into basal plane The secured pulling force that pore is formed.The surface tension in ceramic tile face can not only be effectively reduced, and can be promoted and cement (sand) layer Cementability has very strong cohesive force and enough flexibilities, it is sufficient to resist because of the destruction of climate change bring, Yi Jigao The slight vibration of floor space, while ceramic tile can be made permanently to bond securely efficiently solves hollowing, phenomena such as ceramic tile falls off.
As ceramic tile water absorption rate is lower and lower, adhesive surface also more and more smooth densification, using traditional cement mortar paving Bonding has been unable to satisfy to require.Especially vitrified tile, polished bricks Material Strength are higher, and sensitive to temperature change, the temperature difference is asynchronous, Different from the thermal expansion coefficient of cement, there are thermal (temperature difference) stress after big specification tile laying, seasonal temperature difference oscillation will cause viscous Connect strength reduction, destroy the adhesion strength of brick body and matrix, result between ceramic tile and structure sheaf will because pasting, in conjunction with loosely There is hollowing.And ceramic tile gum product on the market is very different, part ceramic tile gum is made of pressure sensitive adhesive, its main feature is that water-fast Property, high temperature resistance are poor, can not resist because expanding with heat and contract with cold or moisture expansion and drying shrinkage bring falls off.
Summary of the invention
In view of the deficiencies of the prior art, the object of the present invention is to provide a kind of high-intensity weather-proof high ceramic tile gum and its preparations Method.
In order to realize these purposes and other advantages according to the present invention, a kind of high-intensity weather-proof high ceramic tile back is provided Glue comprises the following components in parts by weight:
30-60 parts of styrene-butadiene emulsion, 20-50 parts of quartz sand, 5-25 parts of slag micropowder, 5-10 parts of silicon ash, 1-3 parts of thickener and 0.1-0.8 parts of preservative.
Preferably, in a kind of high-intensity weather-proof high ceramic tile gum, the quartz sand is 70-120 mesh quartz sand.
Preferably, in a kind of high-intensity weather-proof high ceramic tile gum, the slag micropowder is S95 grades of miberal powders.
Preferably, in a kind of high-intensity weather-proof high ceramic tile gum, the silicon ash is encryption silicon ash.
Preferably, in a kind of high-intensity weather-proof high ceramic tile gum, the thickener is polyurethane thickener.
The present invention also provides a kind of preparation methods of high-intensity weather-proof high ceramic tile gum described in any of the above embodiments, including with Lower step:
Step 1: the quartz sand, silicon ash and the slag micropowder that are formulated part are uniformly mixed, mixed powder is obtained, it is spare;
Step 2: the thickener for being formulated part is diluted with water in mass ratio for 1:3-5, and after mixing evenly, it is made Thickener slurries, it is spare;
Step 3: the obtained thickener slurries in step 2 are added in the styrene-butadiene emulsion of formula part, After mixing evenly, mixed powder obtained in step 1 is added, after mixing evenly, mixed serum is made, it is spare;
Step 4: the preservative of formula part is added in the mixed serum obtained in step 3, stir evenly Afterwards, the high-intensity weather-proof high ceramic tile gum is obtained.
Preferably, in a kind of preparation method of high-intensity weather-proof high ceramic tile gum, the step 2 will be formulated The thickener of part is to be placed in dispersion machine after 1:3-5 is diluted with water in the item that revolving speed is 400-800r/min in mass ratio It is stirred 3-5 minutes under part, obtains the thickener slurries.
It preferably, will step in the step 3 in a kind of preparation method of high-intensity weather-proof high ceramic tile gum After the obtained thickener slurries in rapid two are added in the styrene-butadiene emulsion of formula part, it is placed in dispersion machine in revolving speed After stirring 3-5 minutes under conditions of 400-800r/min, mixed powder obtained in step 1 is added.
Preferably, it in a kind of preparation method of high-intensity weather-proof high ceramic tile gum, is added in the step 3 After mixed powder obtained in step 1, stirring 5-8 minutes under conditions of revolving speed is 400-800r/min are placed in dispersion machine, i.e., The mixed serum is made.
The beneficial effects of the present invention are:
(1) high-intensity weather-proof high ceramic tile gum of the invention, flexibility is good, and curing shrinkage is small, and bonding effect is very good, warp It is durable long, the problems such as avoiding hollowing and fall brick;
(2) in high-intensity weather-proof high ceramic tile gum of the invention, polyurethane thickener provides the effect of water conservation and thickening;
(3) high-intensity weather-proof high ceramic tile gum of the invention provides the slag micropowder for increasing ceramic tile gum cohesive force, increases Quarry-tile gum just sticks intensity and weather resistance;The silicon ash for increasing ceramic tile gum cohesive force is provided, later period ceramic tile gum is increased With the extent of reaction of screed;
(4) high-intensity weather-proof high ceramic tile gum of the invention, easy for construction, i.e., brush pastes.
Further advantage, target and feature of the invention will be partially reflected by the following instructions, and part will also be by this The research and practice of invention and be understood by the person skilled in the art.
Specific embodiment
The present invention will be further described in detail below with reference to the embodiments, to enable those skilled in the art referring to specification Text can be implemented accordingly.
<embodiment 1>
A kind of high-intensity weather-proof high ceramic tile gum, comprises the following components in parts by weight:
40 parts of styrene-butadiene emulsion, 50 parts of quartz sand, 5 parts of slag micropowder, 5 parts of silicon ash, 1.1 parts of thickener and 0.2 part of preservative.
Wherein, the quartz sand is 70 mesh quartz sands.
Wherein, the slag micropowder is S95 grades of miberal powders.
Wherein, the silicon ash is encryption silicon ash.
Wherein, the thickener is polyurethane thickener.
The present embodiment also provides the preparation method of above-mentioned high-intensity weather-proof high ceramic tile gum, comprising the following steps:
Step 1: the quartz sand, silicon ash and the slag micropowder that are formulated part are uniformly mixed, mixed powder is obtained, it is spare;
Step 2: the thickener for being formulated part is diluted with water in mass ratio for 1:4.5, it is placed in dispersion machine in revolving speed To stir 3 minutes under conditions of 800r/min, obtained thickener slurries are spare;
Step 3: the obtained thickener slurries in step 2 are added in the styrene-butadiene emulsion of formula part, It is placed in dispersion machine and after stirring 3 minutes, adds mixed powder obtained in step 1 under conditions of revolving speed is 800r/min, set It is stirred under conditions of revolving speed is 800r/min after five minutes in dispersion machine, mixed serum is made, it is spare;
Step 4: the preservative of formula part is added in the mixed serum obtained in step 3, stir evenly Afterwards, the high-intensity weather-proof high ceramic tile gum is obtained.
<embodiment 2>
A kind of high-intensity weather-proof high ceramic tile gum, comprises the following components in parts by weight:
45 parts of styrene-butadiene emulsion, 25 parts of quartz sand, 20 parts of slag micropowder, 10 parts of silicon ash, 1.5 parts of thickener and preservative 0.3 Part.
Wherein, the quartz sand is 80 mesh quartz sands.
Wherein, the slag micropowder is S95 grades of miberal powders.
Wherein, the silicon ash is encryption silicon ash.
Wherein, the thickener is polyurethane thickener.
The present embodiment also provides the preparation method of above-mentioned high-intensity weather-proof high ceramic tile gum, comprising the following steps:
Step 1: the quartz sand, silicon ash and the slag micropowder that are formulated part are uniformly mixed, mixed powder is obtained, it is spare;
Step 2: the thickener for being formulated part is diluted with water in mass ratio for 1:3.5, it is placed in dispersion machine in revolving speed To stir 4 minutes under conditions of 600r/min, obtained thickener slurries are spare;
Step 3: the obtained thickener slurries in step 2 are added in the styrene-butadiene emulsion of formula part, It is placed in dispersion machine and after stirring 4 minutes, adds mixed powder obtained in step 1 under conditions of revolving speed is 600r/min, set In dispersion machine under conditions of revolving speed is 600r/min after stirring 6 minutes, mixed serum is made, it is spare;
Step 4: the preservative of formula part is added in the mixed serum obtained in step 3, stir evenly Afterwards, the high-intensity weather-proof high ceramic tile gum is obtained.
<embodiment 3>
A kind of high-intensity weather-proof high ceramic tile gum, comprises the following components in parts by weight:
50 parts of styrene-butadiene emulsion, 35 parts of quartz sand, 8 parts of slag micropowder, 7 parts of silicon ash, 1.5 parts of thickener and 0.4 part of preservative.
Wherein, the quartz sand is 90 mesh quartz sands.
Wherein, the slag micropowder is S95 grades of miberal powders.
Wherein, the silicon ash is encryption silicon ash.
Wherein, the thickener is polyurethane thickener.
The present embodiment also provides the preparation method of above-mentioned high-intensity weather-proof high ceramic tile gum, comprising the following steps:
Step 1: the quartz sand, silicon ash and the slag micropowder that are formulated part are uniformly mixed, mixed powder is obtained, it is spare;
Step 2: the thickener for being formulated part is diluted with water in mass ratio for 1:4, it is placed in dispersion machine and is in revolving speed It is stirred 5 minutes under conditions of 800r/min, thickener slurries is made, it is spare;
Step 3: the obtained thickener slurries in step 2 are added in the styrene-butadiene emulsion of formula part, It is placed in dispersion machine and is stirred after five minutes under conditions of revolving speed is 700r/min, add mixed powder obtained in step 1, set In dispersion machine under conditions of revolving speed is 700r/min after stirring 7 minutes, mixed serum is made, it is spare;
Step 4: the preservative of formula part is added in the mixed serum obtained in step 3, stir evenly Afterwards, the high-intensity weather-proof high ceramic tile gum is obtained.
<embodiment 4>
A kind of high-intensity weather-proof high ceramic tile gum, comprises the following components in parts by weight:
55 parts of styrene-butadiene emulsion, 25 parts of quartz sand, 15 parts of slag micropowder, 5 parts of silicon ash, 1.6 parts of thickener and preservative 0.5 Part.
Wherein, the quartz sand is 100 mesh quartz sands.
Wherein, the slag micropowder is S95 grades of miberal powders.
Wherein, the silicon ash is encryption silicon ash.
Wherein, the thickener is polyurethane thickener.
The present embodiment also provides the preparation method of above-mentioned high-intensity weather-proof high ceramic tile gum, comprising the following steps:
Step 1: the quartz sand, silicon ash and the slag micropowder that are formulated part are uniformly mixed, mixed powder is obtained, it is spare;
Step 2: the thickener for being formulated part is diluted with water in mass ratio for 1:4.3, it is placed in dispersion machine in revolving speed To stir 3 minutes under conditions of 800r/min, obtained thickener slurries are spare;
Step 3: the obtained thickener slurries in step 2 are added in the styrene-butadiene emulsion of formula part, It is placed in dispersion machine and after stirring 3 minutes, adds mixed powder obtained in step 1 under conditions of revolving speed is 800r/min, set It is stirred under conditions of revolving speed is 800r/min after five minutes in dispersion machine, mixed serum is made, it is spare;
Step 4: the preservative of formula part is added in the mixed serum obtained in step 3, stir evenly Afterwards, the high-intensity weather-proof high ceramic tile gum is obtained.
<embodiment 5>
A kind of high-intensity weather-proof high ceramic tile gum, comprises the following components in parts by weight:
60 parts of styrene-butadiene emulsion, 20 parts of quartz sand, 5 parts of slag micropowder, 10 parts of silicon ash, 1.6 parts of thickener and preservative 0.3 Part.
Wherein, the quartz sand is 120 mesh quartz sands.
Wherein, the slag micropowder is S95 grades of miberal powders.
Wherein, the silicon ash is encryption silicon ash.
Wherein, the thickener is polyurethane thickener.
The present embodiment also provides the preparation method of above-mentioned high-intensity weather-proof high ceramic tile gum, comprising the following steps:
Step 1: the quartz sand, silicon ash and the slag micropowder that are formulated part are uniformly mixed, mixed powder is obtained, it is spare;
Step 2: the thickener for being formulated part is diluted with water in mass ratio for 1:5, it is placed in dispersion machine and is in revolving speed It is stirred 5 minutes under conditions of 800r/min, thickener slurries is made, it is spare;
Step 3: the obtained thickener slurries in step 2 are added in the styrene-butadiene emulsion of formula part, It is placed in dispersion machine and is stirred after five minutes under conditions of revolving speed is 800r/min, add mixed powder obtained in step 1, set In dispersion machine under conditions of revolving speed is 800r/min after stirring 8 minutes, mixed serum is made, it is spare;
Step 4: the preservative of formula part is added in the mixed serum obtained in step 3, stir evenly Afterwards, the high-intensity weather-proof high ceramic tile gum is obtained.
<test example 1>
Corresponding ceramic tile gum is produced by the method for embodiment 1-4 and comparative example 1, and to obtained ceramic tile gum progressive It can test, ceramic tile gum is tested for the property referring to the criterion of JC/T 547-2017 " ceramic wall and floor bricks adhesive ", As a result as shown in the table:
As can be seen from the above table, the adhesion strength under each curing condition of high-intensity weather-proof high ceramic tile gum of the invention is high, Heat ageing and Frozen-thawed cycled post-tensioning adhesion strength remain to reach 1.0MPa or more, because of heat expansion when can effectively cope with tile bonding Hollowing caused by shrinkage, the problems such as flaking, falling off, and construction is simple.
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited In specific details and embodiment shown and described herein.

Claims (9)

1. a kind of high-intensity weather-proof high ceramic tile gum, which is characterized in that comprise the following components in parts by weight:
30-60 parts of styrene-butadiene emulsion, 20-50 parts of quartz sand, 5-25 parts of slag micropowder, 5-10 parts of silicon ash, 1-3 parts of thickener and anti-corrosion 0.1-0.8 parts of agent.
2. a kind of high-intensity weather-proof high ceramic tile gum as described in claim 1, which is characterized in that the quartz sand is 70-120 Mesh quartz sand.
3. a kind of high-intensity weather-proof high ceramic tile gum as described in claim 1, which is characterized in that the slag micropowder is S95 Grade miberal powder.
4. a kind of high-intensity weather-proof high ceramic tile gum as described in claim 1, which is characterized in that the silicon ash is encryption silicon Ash.
5. a kind of high-intensity weather-proof high ceramic tile gum as described in claim 1, which is characterized in that the thickener is polyurethane Thickener.
6. a kind of preparation method of high-intensity weather-proof high ceramic tile gum as described in any one in claim 1-5, which is characterized in that The following steps are included:
Step 1: the quartz sand, silicon ash and the slag micropowder that are formulated part are uniformly mixed, mixed powder is obtained, it is spare;
Step 2: the thickener for being formulated part is diluted with water in mass ratio for 1:3-5, and after mixing evenly, thickening is made Agent slurries, it is spare;
Step 3: the obtained thickener slurries in step 2 are added in the styrene-butadiene emulsion of formula part, stirring After uniformly, mixed powder obtained in step 1 is added, after mixing evenly, mixed serum is made, it is spare;
Step 4: the preservative of formula part is added in the mixed serum obtained in step 3, after mixing evenly, i.e., The high-intensity weather-proof high ceramic tile gum is made.
7. a kind of preparation method of high-intensity weather-proof high ceramic tile gum as described in right wants 6, which is characterized in that the step 2 It is in mass ratio after 1:3-5 is diluted with water by the thickener for being formulated part, being placed in dispersion machine in revolving speed is 400-800r/ It is stirred 3-5 minutes under conditions of min, obtains the thickener slurries.
8. a kind of preparation method of high-intensity weather-proof high ceramic tile gum as described in right wants 6, which is characterized in that the step 3 After the middle obtained thickener slurries by step 2 are added in the styrene-butadiene emulsion of formula part, it is placed in dispersion machine Under conditions of revolving speed is 400-800r/min after stirring 3-5 minutes, mixed powder obtained in step 1 is added.
9. a kind of preparation method of high-intensity weather-proof high ceramic tile gum as described in right wants 6, which is characterized in that the step 3 After mixed powder obtained in middle addition step 1, it is placed in dispersion machine and stirs 5-8 under conditions of revolving speed is 400-800r/min Minute, obtain the mixed serum.
CN201910048847.XA 2019-01-18 2019-01-18 A kind of high-intensity weather-proof high ceramic tile gum and preparation method thereof Pending CN109852286A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114702937A (en) * 2022-03-31 2022-07-05 华润水泥技术研发有限公司 High-strength ceramic tile gum

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU7220501A (en) * 2000-07-14 2002-01-30 Davco Construction Materials P Mortar composition and method
CN106893530A (en) * 2017-04-25 2017-06-27 无锡市福享天下科技有限公司 Senior water-proof adhesive
CN108485564A (en) * 2018-03-27 2018-09-04 盐城雨辰新型建材有限公司 One pack system ceramic tile gum and preparation method thereof
CN108793899A (en) * 2018-09-18 2018-11-13 熊应发 A kind of ceramic tile gum and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU7220501A (en) * 2000-07-14 2002-01-30 Davco Construction Materials P Mortar composition and method
CN106893530A (en) * 2017-04-25 2017-06-27 无锡市福享天下科技有限公司 Senior water-proof adhesive
CN108485564A (en) * 2018-03-27 2018-09-04 盐城雨辰新型建材有限公司 One pack system ceramic tile gum and preparation method thereof
CN108793899A (en) * 2018-09-18 2018-11-13 熊应发 A kind of ceramic tile gum and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114702937A (en) * 2022-03-31 2022-07-05 华润水泥技术研发有限公司 High-strength ceramic tile gum

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