CN109810807A - A kind of glass cleaner and preparation method thereof - Google Patents

A kind of glass cleaner and preparation method thereof Download PDF

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Publication number
CN109810807A
CN109810807A CN201711159875.6A CN201711159875A CN109810807A CN 109810807 A CN109810807 A CN 109810807A CN 201711159875 A CN201711159875 A CN 201711159875A CN 109810807 A CN109810807 A CN 109810807A
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China
Prior art keywords
cleaning
glass
parts
weight
carbonate
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Pending
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CN201711159875.6A
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Chinese (zh)
Inventor
周群飞
蔡杰勇
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Lens Technology Changsha Co Ltd
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Lens Technology Changsha Co Ltd
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Priority to CN201711159875.6A priority Critical patent/CN109810807A/en
Publication of CN109810807A publication Critical patent/CN109810807A/en
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Abstract

The present invention provides a kind of glass cleaners, including water and following component: 8~15 parts by weight of carbonate;3~5 parts by weight of alcohols;4~8 parts by weight of bleeding agent;0.2~1 parts by weight of inorganic base;0.5~1 parts by weight of complexing agent.Carbonate, alcohols, bleeding agent, inorganic base and complexing agent provided by the invention combine specific proportion, clean effect can be well realized as glass cleaning, good to cleaning glass anti-scratch film print cleaning effect, cleanliness is high, stability is good, while it is heterochromatic not will cause product.

Description

A kind of glass cleaner and preparation method thereof
Technical field
The present invention relates to glass cleaner technical fields more particularly to a kind of glass cleaner and preparation method thereof.
Background technique
With social progress and development, glass is also to make rapid progress in the utilization of electronics industry.Due to cleaning up simultaneously The product examined silk-screen, spraying operation process in, the convex surface of product easily causes to touch scuffing, therefore in order to solve product Scuffing problem is touched in operation process, patch anti-scratch film is carried out to product convex surface before silk-screen, spraying, has pasted anti-scratch film Product by silk-screen, spraying high-temperature baking after, the organic substance residues on film on product surface, formed one layer of uniform film Print.
The prior art is poor to film print cleaning effect using neutral cleaners (pH=8~10), can't mostly is washed off clearly.And make It is cleaned with strong basicity lotion (pH=13~14), causes product integrally heterochromatic, exceeded colour table range, seriously affected product product Matter, and increase manpower and wipe cost.
Therefore in order to solve the problems, such as film print and reduce manual wipping cost urgent need to develop it is a kind of completely stable low foaming And the cleaning agent and its technique of environmental protection, to meet production requirement.
Summary of the invention
In view of this, the technical problem to be solved in the present invention is that provide a kind of glass cleaner, glass provided by the invention Glass cleaning agent is good to cleaning glass anti-scratch film print cleaning effect, and cleanliness is high, and stability is good.
The present invention provides a kind of glass cleaners, including water and following component:
Preferably, including water and following component:
Preferably, including water and following component:
Preferably, the carbonate is sodium carbonate or potassium carbonate;The alcohols be selected from ethyl alcohol, methanol and propyl alcohol one kind or It is several;The inorganic base is selected from the one or more of sodium hydroxide, potassium hydroxide and barium hydroxide.
Preferably, the bleeding agent is alkali-resistant penetrant OEP-70;The complexing agent is selected from tetrasodium ethylenediamine tetraacetate, second The one or more of edetate disodium, sodium gluconate and sodium citrate;.
The present invention provides a kind of preparation methods of glass cleaner described in above-mentioned technical proposal, comprising:
Carbonate, alcohols, bleeding agent, inorganic base and complexing agent mixing, obtain glass cleaner.
The present invention provides a kind of cleaning methods of glass, include the following steps:
A cleaning agent described in above-mentioned technical proposal) is heated to 80~85 DEG C, to glass using ultrasonic cleaning;
B glass is cleaned by ultrasonic using 60~65 DEG C of water after) being cleaned by ultrasonic;
C it is dried after) cleaning to obtain the final product.
Preferably, step A) power of the ultrasound is 40Hz;Electric current is 2~5A;Scavenging period is 3~5min.
Preferably, step B) power of the ultrasound is 40Hz;Electric current is 2~5A;Scavenging period is 3~5min.
Preferably, step C) temperature dried is 100~110 DEG C;Time is 3~5min.
Compared with prior art, the present invention provides a kind of glass cleaners, including water and following component: carbonate 8~ 15 parts by weight;3~5 parts by weight of alcohols;4~8 parts by weight of bleeding agent;0.2~1 parts by weight of inorganic base;0.5~1 weight of complexing agent Part.Carbonate, alcohols, bleeding agent, inorganic base and complexing agent provided by the invention combine specific proportion, and being used as glass cleaning can Good to cleaning glass anti-scratch film print cleaning effect to realize clean effect well, cleanliness is high, and stability is good, simultaneously It is heterochromatic product is not will cause.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described, Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all Belong to the scope of protection of the invention.
The present invention provides a kind of glass cleaners, including water and following component:
Glass cleaner provided by the invention includes water, and water is as solvent, when each component is added according to weight percent, Water is surplus.
Glass cleaner provided by the invention includes the carbonate of 8~15 parts by weight;Preferably include the carbon of 9~13 parts by weight Hydrochlorate;It more preferably include the carbonate of 10~12 parts by weight.
Carbonate of the present invention is preferably sodium carbonate or potassium carbonate;More preferably sodium carbonate.The present invention to its source not It is defined, can be commercially available.
Carbonate of the present invention is preferably analyzed pure;The raw material of reagent grade.Several times of mentioned reagent of carbonic acid of the present invention Salt especially sodium carbonate can enhance the decontamination of surfactant with surfactant coordinated;It can disperse dust, Dirty effect goes membrane removal print effect good.
Glass cleaner provided by the invention includes the alcohols of 3~5 parts by weight;Preferably include the alcohols of 4~5 parts by weight.
Alcohols of the present invention is preferably selected from the one or more of ethyl alcohol, methanol and propyl alcohol;More preferably methanol and second Alcohol;Most preferably ethyl alcohol.The present invention, without limiting, can be commercially available to this source.Ethyl alcohol of the present invention is preferably analyzed Pure or chromatographically pure.
Above-mentioned alcohols provided by the invention can be played good hydrotropy solution and be cleaned the effect of film print with dissolved organic matter Fruit.
Glass cleaner provided by the invention includes the bleeding agent of 4~8 parts by weight;Preferably include the infiltration of 5~8 parts by weight Agent;It more preferably include the bleeding agent of 5~7 parts by weight.
The present invention for the bleeding agent specific type without limit, it is well known to those skilled in the art, it is excellent It is selected as alkali-resistant penetrant OEP-70.The present invention for the bleeding agent source without limit, can be commercially available.
The above-mentioned bleeding agent of the present invention can cooperate remaining component, reach good clean effect, especially for silk-screen, Patch anti-scratch film is carried out to product convex surface before spraying, pasted the product of anti-scratch film by silk-screen, spraying high-temperature baking after, film On organic substance residues on product surface, form one layer of uniform film and print, be able to carry out good removal, while causing product It is whole heterochromatic.
Glass cleaner provided by the invention includes the inorganic base of 0.2~1 parts by weight;Preferably include 0.3~0.9 parts by weight Inorganic base;It more preferably include the inorganic base of 0.4~0.8 parts by weight.
Inorganic base of the present invention is preferably selected from the one or more of sodium hydroxide, potassium hydroxide and barium hydroxide;It is more excellent One or more of the choosing selected from sodium hydroxide, potassium hydroxide;Most preferably sodium hydroxide.
Inorganic base of the present invention preferably analyzes pure or chromatographically pure.It can be commercially available.
The above-mentioned inorganic base of the present invention can adjust the pH value of cleaning agent, so that cleaning effect is more preferably.
Glass cleaner provided by the invention includes the complexing agent of 0.5~1 parts by weight;Preferably include 0.5~0.9 parts by weight Complexing agent;It more preferably include the complexing agent of 0.6~0.9 parts by weight.
Complexing agent of the present invention is preferably selected from tetrasodium ethylenediamine tetraacetate, disodium ethylene diamine tetraacetate, sodium gluconate With the one or more of sodium citrate;It is more preferably selected from the one or more of disodium ethylene diamine tetraacetate and sodium citrate;It is optimal It is selected as sodium citrate.
Above-mentioned complexing agent complexing metal provided by the invention cooperates with remaining component, can remove the film print on glass, dirty Good cleaning effect is played in dirt etc..
Detergent described in the one of technical solution of the present invention includes water and following component:
Detergent described in the one of technical solution of the present invention includes water and following component:
The present invention provides a kind of glass cleaners, including water and following component: 8~15 parts by weight of carbonate;Alcohols 3~ 5 parts by weight;4~8 parts by weight of bleeding agent;0.2~1 parts by weight of inorganic base;0.5~1 parts by weight of complexing agent.Carbon provided by the invention Hydrochlorate, alcohols, bleeding agent, inorganic base and complexing agent combine specific proportion, and cleaning can be well realized as glass cleaning Effect, good to cleaning glass anti-scratch film print cleaning effect, cleanliness is high, and stability is good, while it is heterochromatic not will cause product.
Film print of the present invention refers to carrying out pasting anti-scratch film to product convex surface before silk-screen, spraying, has pasted anti-scratch The product of film by silk-screen, spraying high-temperature baking after, the organic substance residues on film on product surface, formed one layer it is uniform Film print.
Technical solution of the present invention solves neutral cleaners (pH=8~10) and can't is washed off clearly to film print, uses highly basic Property lotion (pH=13~14) clean, cause product integrally heterochromatic (dyestuff and alkali in ink react change colour caused by), ask Topic.
The present invention provides a kind of preparation methods of glass cleaner described in above-mentioned technical proposal, comprising:
Carbonate, alcohols, bleeding agent, inorganic base and complexing agent mixing, obtain glass cleaner.
Carbonate of the present invention, alcohols, bleeding agent, inorganic base and complexing agent weight ratio be preferably (8~15): (3~ 5): (4~8): (0.2~1): (0.5~1);More preferably (9~13): (4~5): (5~8): (0.3~0.9): (0.5~ 0.9);Most preferably (10~12): (4~5): (5~7): (0.4~0.8): (0.6~0.9).
The present invention is above-mentioned to its component and source to be clearly described, and is no longer limited herein.
The present invention to its order of addition and hybrid mode without limiting, it is well known to those skilled in the art.
The present invention provides a kind of cleaning methods of glass, include the following steps:
A cleaning agent described in above-mentioned technical proposal) is heated to 80~85 DEG C, to glass using ultrasonic cleaning;
B glass is cleaned by ultrasonic using 60~65 DEG C of water after) being cleaned by ultrasonic;
C it is dried after) cleaning to obtain the final product.
Present invention preferably employs above-mentioned cleaning agents to clean to glass.
Cleaning agent described in above-mentioned technical proposal is heated to 75~85 DEG C first by cleaning method of the present invention, to glass Using ultrasonic cleaning.
It is preferred that cleaning agent is specifically heated to 80~85 DEG C first;The present invention has had clearly above-mentioned cleaning agent Description, details are not described herein.
The heating temperature is preferably 81~84 DEG C.
The concentration of cleaning agent of the present invention is without limiting, stoste.
The power of the ultrasound is preferably 40Hz;Electric current is preferably 2~5A;Scavenging period is preferably 3~5min;More preferably For 3~4.5min.
Glass is cleaned by ultrasonic using 60~65 DEG C of water after ultrasonic cleaning.
Wherein, the power of the ultrasound is preferably 40Hz;Electric current is preferably 2~5A;Scavenging period is preferably 3~5min.
It is dried after cleaning to obtain the final product.
The temperature dried is preferably 100~110 DEG C;Time is preferably 3~5min.
Cleaning agent of the invention and cleaning process are stablized, and can be mass, easy to operate, at low cost, high-efficient, yield is steady It is fixed.
In order to further illustrate the present invention, with reference to embodiments to 3D glass cleaner provided by the invention and its preparation Method is described in detail.
Embodiment 1
A kind of glass cleaning agent prescription is provided: being grouped as by following groups based on 100 weight point: 8 parts of sodium carbonate, ethyl alcohol 3 Part, 4 parts of OPE-70,0.2 part of sodium hydroxide, 0.5 part of sodium citrate, surplus is water.
Sodium carbonate, ethyl alcohol, OPE-70, sodium hydroxide, water are dissolved into mixing respectively, obtain glass cleaner.
Embodiment 2
A kind of glass cleaning agent prescription is provided: being grouped as by following groups based on 100 weight point: 12 parts of sodium carbonate, ethyl alcohol 4 Part, 6 parts of OPE-70,0.6 part of sodium hydroxide, 0.7 part of sodium citrate, surplus is water.
Sodium carbonate, ethyl alcohol, OPE-70, sodium hydroxide, water are dissolved into mixing respectively, obtain glass cleaner.
Embodiment 3
A kind of glass cleaning agent prescription is provided: being grouped as by following groups based on 100 weight point: 15 parts of potassium carbonate, methanol 4 Part, 8 parts of OPE-70,1 part of potassium hydroxide, 1 part of sodium citrate, surplus is water.
Carbonic acid first, methanol, OPE-70, potassium hydroxide, water are dissolved into mixing respectively, obtain glass cleaner.
Comparative example 1
A kind of glass cleaning agent prescription is provided: being grouped as by following groups based on 100 weight point: 12 parts of sodium phosphate, ethyl alcohol 4 Part, 6 parts of OPE-70,0.6 part of sodium hydroxide, 0.7 part of sodium citrate, surplus is water.
Sodium carbonate, ethyl alcohol, OPE-70, sodium hydroxide, water are dissolved into mixing respectively, obtain glass cleaner.
Comparative example 2
A kind of glass cleaning agent prescription is provided: being grouped as by following groups based on 100 weight point: 12 parts of sodium phosphate, ethyl alcohol 4 Part, 6,503 6 parts, 0.6 part of sodium hydroxide, 0.7 part of sodium citrate, surplus is water.
Sodium phosphate, ethyl alcohol, 6503, sodium hydroxide, water are dissolved into mixing respectively, obtain glass cleaner.
The embodiment of the present invention and comparative example are measured, and the results are shown in Table 1, and wherein table 1 is the embodiment of the present invention and ratio Compared with the cleaning agent capacity measurement data of example.
Table 1 is the cleaning agent capacity measurement data of the embodiment of the present invention and comparative example
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (10)

1. a kind of glass cleaner, which is characterized in that including water and following component:
2. cleaning agent according to claim 1, which is characterized in that including water and following component:
3. cleaning agent according to claim 1, which is characterized in that including water and following component:
4. cleaning agent according to any one of claims 1 to 3, which is characterized in that the carbonate is sodium carbonate or carbon Sour potassium;The alcohols is selected from the one or more of ethyl alcohol, methanol and propyl alcohol;The inorganic base is selected from sodium hydroxide, potassium hydroxide With the one or more of barium hydroxide.
5. cleaning agent according to any one of claims 1 to 3, which is characterized in that the bleeding agent is alkali-resistant penetrant OEP-70;The complexing agent is selected from tetrasodium ethylenediamine tetraacetate, disodium ethylene diamine tetraacetate, sodium gluconate and sodium citrate It is one or more of.
6. a kind of preparation method of glass cleaner described in claim 1 characterized by comprising
Carbonate, alcohols, bleeding agent, inorganic base and complexing agent mixing, obtain glass cleaner.
7. a kind of cleaning method of glass, which comprises the steps of:
A cleaning agent described in Claims 1 to 5 any one) is heated to 80~85 DEG C, to glass using ultrasonic cleaning;
B glass is cleaned by ultrasonic using 60~65 DEG C of water after) being cleaned by ultrasonic;
C it is dried after) cleaning to obtain the final product.
8. cleaning method according to claim 7, which is characterized in that step A) power of the ultrasound is 40Hz;Electric current For 2~5A;Scavenging period is 3~5min.
9. cleaning method according to claim 7, which is characterized in that step B) power of the ultrasound is 40Hz;Electric current For 2~5A;Scavenging period is 3~5min.
10. cleaning method according to claim 7, which is characterized in that step C) temperature dried is 100~110 ℃;Time is 3~5min.
CN201711159875.6A 2017-11-20 2017-11-20 A kind of glass cleaner and preparation method thereof Pending CN109810807A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711159875.6A CN109810807A (en) 2017-11-20 2017-11-20 A kind of glass cleaner and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201711159875.6A CN109810807A (en) 2017-11-20 2017-11-20 A kind of glass cleaner and preparation method thereof

Publications (1)

Publication Number Publication Date
CN109810807A true CN109810807A (en) 2019-05-28

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104830549A (en) * 2015-04-13 2015-08-12 蓝思科技(长沙)有限公司 Cleaning agent for detergency after glass silk-screen printing
CN105419972A (en) * 2015-12-24 2016-03-23 东莞市安美润滑科技有限公司 High-cleanliness degree corrosion-resistant water-based optical glass cleaning compound and application method thereof
CN105695143A (en) * 2016-03-11 2016-06-22 三峡大学 Lac cleaning agent
CN106753873A (en) * 2017-01-13 2017-05-31 蓝思科技(长沙)有限公司 A kind of glass cleaner and its application method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104830549A (en) * 2015-04-13 2015-08-12 蓝思科技(长沙)有限公司 Cleaning agent for detergency after glass silk-screen printing
CN105419972A (en) * 2015-12-24 2016-03-23 东莞市安美润滑科技有限公司 High-cleanliness degree corrosion-resistant water-based optical glass cleaning compound and application method thereof
CN105695143A (en) * 2016-03-11 2016-06-22 三峡大学 Lac cleaning agent
CN106753873A (en) * 2017-01-13 2017-05-31 蓝思科技(长沙)有限公司 A kind of glass cleaner and its application method

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Application publication date: 20190528