CN109806186B - Full-soap-base pearlescent shower gel and preparation method thereof - Google Patents
Full-soap-base pearlescent shower gel and preparation method thereof Download PDFInfo
- Publication number
- CN109806186B CN109806186B CN201910241519.1A CN201910241519A CN109806186B CN 109806186 B CN109806186 B CN 109806186B CN 201910241519 A CN201910241519 A CN 201910241519A CN 109806186 B CN109806186 B CN 109806186B
- Authority
- CN
- China
- Prior art keywords
- solution
- agent
- pearlescent
- fatty acid
- shower gel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Abstract
The invention discloses a full-soap base pearlescent shower gel and a preparation method thereof. The shower gel comprises the following components: 16-20% of fatty acid, 0.05-0.15% of chelating agent, 2-4% of dispersing agent, 0.2-0.3% of emulsifier, 1-3% of pearling agent, 14-18% of surfactant, 1.0-2.0% of thickening agent, 0.5-1.5% of emollient, 5-6% of cation conditioner, 0-proper amount of essence, 0-proper amount of pigment, 0-proper amount of preservative, and the amount of neutralizer is calculated according to the amount of just completely neutralizing fatty acid. The total soap base total neutralization shower gel is prepared by adopting a twice neutralization method, partial neutralization is carried out at high temperature for the first time, the residual fatty acid is just neutralized for the second time, the potassium hydroxide is not excessive, and the prepared shower gel has strong pearlescent appearance, stable property, easy washing and cleanness, is mild and less irritant to skin and has excellent market prospect.
Description
Technical Field
The invention belongs to the field of daily chemical articles, and particularly relates to a full-soap base pearlescent shower gel and a preparation method thereof.
Background
The shower gel products on the market are roughly divided into two types, one type is prepared by compounding various surfactants, and the system has simple process and good stability, and has the defects of greasiness during washing and seems to have the feeling of unclean washing. One is prepared by compounding soap base and sodium laureth sulfate and other surfactants, solves the problem of unclean feeling after washing, and has fresh and natural skin after use. However, the soap-based shower gel has the defects of complex process, poor stability, sensitivity to temperature and insufficient natural smooth feeling during washing.
The soap base is compounded with the sodium acetate amphoteric and the amino acid surfactant to prepare the fully-soap-base fully-neutralized pearlescent shower gel, which is very easy to spread on skin, can generate elastic fine foam, is smooth and clean, is very easy to wash clean, does not leave residues, is mild and less irritant to skin, and is particularly suitable for people with oily skin in summer in the south. Therefore, the fully soap-based fully-neutralized pearlescent shower gel prepared can meet the trend of market demands and meet the individual needs of specific people.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provide the full-soap base pearlescent shower gel.
The invention also aims to provide a preparation method of the full-soap base pearlescent shower gel.
The purpose of the invention is realized by the following technical scheme:
the total-soap-base pearlescent shower gel comprises the following components in percentage by mass: 16-20% of fatty acid, 0.05-0.15% of chelating agent, 2-4% of dispersing agent, 0.2-0.3% of emulsifier, 1-3% of pearling agent, 14-18% of surfactant, 0.65-2.0% of thickening agent, 0.5-1.5% of emollient, 5-6% of cation conditioner, 0-proper amount of essence, 0-proper amount of pigment, 0-proper amount of preservative, and the amount of neutralizer is calculated according to the amount of just completely neutralizing fatty acid; preferably comprises the following components in percentage by mass: 18% of fatty acid, 0.1% of chelating agent, 3% of dispersing agent, 0.25% of emulsifying agent, 2% of pearling agent, 16% of surfactant, 1.15-1.65% of thickening agent, 1% of emollient, 5.5% of cation conditioning agent, 0-proper amount of essence, 0-proper amount of pigment, 0-proper amount of preservative and the amount of neutralizing agent is calculated according to the amount of just completely neutralizing fatty acid.
The pH value of the full-soap base pearlescent shower gel is preferably 9.7-10.0.
The full-soap base pearlescent shower gel also comprises water, and the balance of the water. The balance means that the sum of the amount of water and the amount of other ingredients is 100%.
The fatty acid is preferably at least one of lauric acid, myristic acid and palmitic acid; more preferably lauric acid, myristic acid and palmitic acid in a mass ratio of 9.6: 7.2: 1.2 the fatty acid obtained by proportioning.
The chelating agent is preferably at least one of EDTA-2Na and EDTA-4 Na.
The dispersant is preferably propylene glycol.
The emulsifier is preferably cocamide MEA; more preferably, COMPERLAN 100C.
The pearling agent is preferably ethylene glycol stearate; more preferably one or both of ethylene glycol monostearate and ethylene glycol distearate.
The surfactant is preferably at least one of disodium lauroamphoacetate diacetate, sodium cocoyl methyl taurate and cocamidopropyl hydroxysultaine; more preferably disodium lauroyl amphoacetate diacetate, sodium cocoyl methyl taurate and cocamidopropyl hydroxysultaine in a mass ratio of 3: 7: 6, and mixing the components to obtain the surfactant.
The disodium lauroamphoacetate diacetate is preferably TC-MAB 40 LDL.
The sodium cocoyl methyl taurate is preferably DIAPONK K-SG.
The cocamidopropyl hydroxysultaine is preferably Ucefactant CSB (I).
The thickener is preferably at least one of a water-soluble polymer compound and an inorganic salt; more preferably, the water-soluble polymer compound and the inorganic salt are mixed in a mass ratio of 3: (3.5-13.5) proportioning to obtain a thickening agent; most preferably, the weight ratio of the water-soluble high molecular compound to the inorganic salt is 3: (8.5-13.5) mixing to obtain the thickening agent.
The water-soluble polymer compound is preferably hydroxypropyl methylcellulose.
The inorganic salt is preferably potassium chloride.
The emollient is preferably polyglycerol decanoate; more preferably one or both of polyglycerol-4 decanoate and polyglycerol-3 decanoate.
The preferred polyglyceryl-4 decanoate is joleee 7931.
The cationic conditioning agent is preferably polyquaternium; more preferably one or two of polyquaternium-7 and polyquaternium-39; most preferably polyquaternium-7 and polyquaternium-39 in a mass ratio of 2.2: 3.3, obtaining the cationic conditioner.
The polyquaternium-7 is preferably MERQUAT 550L POLYMER.
The polyquaternium-39 is preferably POLYQUAT 330.
The neutralizing agent is alkali; one or both of sodium hydroxide and potassium hydroxide are preferred.
The amount of said neutralizing agent is preferably calculated as the hydroxide equivalent in base: the carboxylic acid group equivalent of the fatty acid is 1: 1 proportion.
The proper amount refers to the amount meeting the national, industrial and product requirements.
The preservative is preferably methylisothiazolinone; more preferably Neolone 950.
The using amount of the preservative is preferably 0.05-0.15% by mass; more preferably 0.05% by mass.
The essence is preferably FH318022 pink charming essence.
The using amount of the essence is preferably 0.4-0.6% by mass; more preferably 0.5%.
The preparation method of the full-soap base pearlescent shower gel comprises the following steps:
(1) under the heating condition, stirring the fatty acid until the fatty acid is completely melted to obtain a solution A;
(2) uniformly mixing a chelating agent, a dispersing agent, a part of neutralizing agent and part of water to obtain a solution B;
(3) uniformly mixing components other than inorganic salt in the thickening agent with part of water to obtain a solution C;
(4) dissolving part of neutralizing agent in part of water to obtain solution D;
(5) adding the solution A into the solution B, and performing first saponification to obtain solution E;
(6) adding an emulsifier, a pearling agent and a surfactant into the solution E under the stirring condition of 80-90 ℃ to obtain solution F;
(7) adding the solution C into the solution F, and uniformly mixing; if the thickening agent contains inorganic salt, adding part of the inorganic salt in the thickening agent; obtaining a G liquid;
(8) when the temperature of the solution G is 35-45 ℃, adding the solution D for second saponification to obtain a solution H;
(9) adding emollient, cationic conditioner, essence, pigment and antiseptic into solution H, and mixing; if the viscosity is lower than 3000cps, adding inorganic salt to adjust viscosity, and stirring; obtaining the complete soap base pearlescent shower gel.
The heating temperature in the step (1) is preferably 80-90 ℃; more preferably 85 deg.c.
The mixing temperature in the step (2) is preferably 85-95 ℃; more preferably 90 deg.c.
The neutralizing agent in the step (2) and the neutralizing agent in the step (4) are preferably selected from the following components in a mass ratio of (85-95): (5-15) proportioning; more preferably 88: 12 proportion.
The saponification condition in the step (5) is preferably that the saponification is stirred and reacted for at least 30 minutes at 80-90 ℃; preferably stirring and reacting for 20-40 minutes at 80-90 ℃; more preferably, the reaction is stirred at 85 ℃ for 30 minutes.
The stirring speed in the step (6) is preferably 80-100 rpm; more preferably 90 rpm.
The stirring time in the step (6) is preferably 5-15 minutes; more preferably 10 minutes.
The stirring temperature in the step (6) is preferably 85 ℃.
The saponification in the step (8) is carried out under stirring conditions, and the slower the stirring speed, the more favorable the pearl formation.
The saponification condition is preferably that the mixture is stirred for 10 to 30 minutes at the rotating speed of less than 100 rpm; more preferably, the mixture is stirred for 10 to 30 minutes at 50 to 70 rpm; most preferably at 60rpm for 20 minutes.
The temperature of the saponification in the step (8) is preferably 40 ℃.
The viscosity in the step (9) of adding inorganic salt to adjust the viscosity is preferably 3000-5000 cps; more preferably 3000 to 4000 cps.
Compared with the prior art, the invention has the following advantages and effects:
(1) the shower gel is fully neutralized by the two-time neutralization soap base, has strong pearlescent appearance, has viscosity of about 3500cps, and is easy to spread on skin.
(2) The stability is good: the high temperature resistance test of 30 days at 42 ℃ does not delaminate, the normal temperature is recovered for 30 days at-10 ℃ and good fluidity is obtained, and the jelly does not appear at 30 days at 5 ℃ and has good fluidity.
(3) Has excellent smooth feeling during washing, is easy to wash and clean, does not remain on the skin, and is mild and less irritant to the skin.
(4) The foam is rich, fine and elastic.
Drawings
Fig. 1 is a photographic image of the body wash prepared in example 1.
Fig. 2 is a photographic image of the body wash prepared in example 2.
Fig. 3 is a photographic image of the body wash prepared in example 3.
Fig. 4 is a photographic image of the body wash prepared in example 4.
Fig. 5 is a photographic image of the body wash prepared in example 5.
Detailed Description
The present invention will be described in further detail with reference to examples and drawings, but the embodiments of the present invention are not limited thereto.
Examples 1 to 5
The compositions of the first embodiment 1 to 5 are shown in Table 1:
TABLE 1
Among the above raw materials, lauric acid, myristic acid, palmitic acid are fatty acids from Simuli, EDTA-4Na from Acksonobel, propylene glycol from Dupont, potassium hydroxide (90% by weight) from Tianjinolide, COMPERLAN 100C from Pasteur, PROX 3237DS from Poda, TC-MAB 40LDL from Guangzhou Tiancii, DIAPOLYNK K-SG was from Nissan oil Co., Ltd., Ucefactant CSB (I) (50% content) from Guangzhou Star corporation, HPMC from Asian-Latch corporation, Potassium chloride (analytically pure) from Guangzhou Annona fortification Co., Ltd., JOLEE 7931 from French Eurolaammonium, MERQUAT 550L POLYMER from Lumboo, POLYQUAT 330 from Guangzhou Tiancici, Neolone 950 from Dow, FH318022 Pink Phantom essence from Guangzhou Fenghao Co., Ltd.
Second, the preparation method of examples 1 to 5 is as follows:
(1) preparation of phase A: lauric acid, myristic acid and palmitic acid were placed in a beaker and heated to 85 ℃ with stirring until completely melted.
(2) Preparation of phase B: adding EDTA-4Na, propylene glycol and potassium hydroxide into a beaker, adding water, heating to 90 ℃, and stirring until the EDTA-4Na, the propylene glycol and the potassium hydroxide are completely dissolved.
(3) Preparation of phase D: HPMC was dispersed in water until completely wetted.
(4) Preparation of phase E: adding potassium hydroxide into water, and stirring until the potassium hydroxide is completely dissolved. Example 3 this step was omitted and water in phase E was added in step (2).
(5) The A phase was added to the B phase with stirring at 120rpm, and the mixture was saponified while maintaining the temperature at 85 ℃ and stirring at 90rpm for 30 minutes.
(6) COMPERLAN 100C, PROX 3237DS, TC-MAB 40LDL, DIAPONK K-SG, and Ucefactant CSB (I) were added in this order, and the mixture was stirred at 90rpm for 10 minutes while maintaining the temperature at 85 ℃.
(7) Add the prepared phase D and stir until completely dissolved.
(8) Potassium chloride was added, stirred until completely dissolved, stirred at 85 ℃ for 10 minutes at 90rpm and then cooled with water.
(9) When the temperature drops to 40 ℃, the E phase which has been prepared is added and stirred for 20 minutes at 60 rpm.
(10) Adding JOLEE 7931, MERQUAT 550L POLYMER, POLYQUAT 330, Neolon 950, and FH318022 essence in sequence, and stirring at 60rpm for 15 min; and then adding potassium chloride to adjust the viscosity, and stirring at 60rpm for 15 minutes to obtain the pearlescent soap base shower gel.
Third, the test results are shown in table 2:
TABLE 2
Fourthly, conclusion:
from example 1, the fatty acid is neutralized twice, about 90% of the fatty acid is neutralized in the first high temperature state, about 10% of the fatty acid is neutralized in the second time, the neutralization ratio is about 100%, and the appearance, the stability and the trial result meet the market requirements.
From example 2, it can be seen that when the fatty acids of the whole soap based body wash are neutralized, they are cold-10 ℃ and cold-5 ℃ and then form a paste, because the fatty acids are separated out, which results in the stability not being passed.
From example 3, it is found that when the soap base bath cream is fully neutralized at a time at a high temperature, the appearance is slightly transparent, good pearly luster cannot be displayed, and the appearance does not meet the requirement.
From example 4, it follows that, although two neutralizations are possible, the excess of neutralizing agent, in particular already in the first high-temperature state, is exactly neutralized, has a slightly transparent appearance, does not exhibit good pearlescence, does not have the desired appearance, and is markedly irritating to the skin.
From example 5, although two neutralizations were obtained and the first high temperature state was already partially neutralized, the overall excess neutralization was clearly irritating to the skin.
From the comparison data, the total soap base shower gel can only neutralize about 100 percent of the total soap base shower gel, partially neutralize the rest fatty acid at the first high temperature, and neutralize the rest fatty acid at the second high temperature, and the potassium hydroxide is not excessive, so that the prepared product can meet the market requirement only if the process conditions are met.
The above embodiments are preferred embodiments of the present invention, but the present invention is not limited to the above embodiments, and any other changes, modifications, substitutions, combinations, and simplifications which do not depart from the spirit and principle of the present invention should be construed as equivalents thereof, and all such changes, modifications, substitutions, combinations, and simplifications are intended to be included in the scope of the present invention.
Claims (9)
1. The soap-based pearlescent shower gel is characterized by comprising the following components in percentage by mass: 16-20% of fatty acid, 0.05-0.15% of chelating agent, 2-4% of dispersing agent, 0.2-0.3% of emulsifier, 1-3% of pearling agent, 14-18% of surfactant, 0.65-2.0% of thickening agent, 0.5-1.5% of emollient, 5-6% of cation conditioner, 0-proper amount of essence, 0-proper amount of pigment, 0-proper amount of preservative, 0-proper amount of water and neutralizer, wherein the amount of the neutralizer is calculated according to the amount of just completely neutralizing the fatty acid;
the full-soap base pearlescent shower gel is prepared by the following preparation method:
(1) under the heating condition, stirring the fatty acid until the fatty acid is completely melted to obtain a solution A;
(2) uniformly mixing a chelating agent, a dispersing agent, a part of neutralizing agent and part of water to obtain a solution B;
(3) uniformly mixing components other than inorganic salt in the thickening agent with part of water to obtain a solution C;
(4) dissolving part of neutralizing agent in part of water to obtain solution D;
(5) adding the solution A into the solution B, and performing first saponification to obtain solution E;
(6) adding an emulsifier, a pearling agent and a surfactant into the solution E under the stirring condition of 80-90 ℃ to obtain solution F;
(7) adding the solution C into the solution F, and uniformly mixing; if the thickening agent contains inorganic salt, adding part of the inorganic salt in the thickening agent; obtaining a G liquid;
(8) when the temperature of the solution G is 35-45 ℃, adding the solution D for second saponification to obtain a solution H;
(9) adding emollient, cationic conditioner, essence, pigment and antiseptic into solution H, and mixing; if the viscosity is lower than 3000cps, adding inorganic salt to adjust the viscosity, and stirring uniformly to obtain the full-soap base pearlescent shower gel;
the neutralizing agent in the step (2) and the neutralizing agent in the step (4) are prepared from the following components in percentage by mass (85-95): (5-15).
2. The full-soap base pearlescent shower gel according to claim 1, which is characterized by comprising the following components in percentage by mass: 18% of fatty acid, 0.1% of chelating agent, 3% of dispersing agent, 0.25% of emulsifying agent, 2% of pearling agent, 16% of surfactant, 1.15-1.65% of thickening agent, 1% of emollient, 5.5% of cation conditioning agent, 0-proper amount of essence, 0-proper amount of pigment, 0-proper amount of preservative, 0-proper amount of water and neutralizing agent, wherein the amount of the neutralizing agent is calculated according to the amount of the fatty acid which is just completely neutralized.
3. The all-soap pearlescent body wash of claim 1, characterized in that:
the fatty acid is at least one of lauric acid, myristic acid and palmitic acid;
the chelating agent is at least one of EDTA-2Na and EDTA-4 Na;
the dispersant is propylene glycol;
the emulsifier is cocamide MEA;
the pearling agent is ethylene glycol stearate;
the surfactant is at least one of disodium lauroamphoacetate diacetate, sodium cocoyl methyl taurate and cocamidopropyl hydroxysultaine;
the thickening agent is at least one of water-soluble high molecular compound and inorganic salt;
the emollient is polyglycerol decanoate;
the cationic conditioner is polyquaternium;
the preservative is methylisothiazolinone;
the neutralizing agent is alkali.
4. The all-soap pearlescent body wash of claim 3, characterized in that:
the water-soluble high molecular compound is hydroxypropyl methyl cellulose;
the inorganic salt is potassium chloride;
the ethylene glycol stearate is at least one of ethylene glycol monostearate and ethylene glycol distearate;
the polyglycerol decanoate is at least one of polyglycerol-4 decanoate and polyglycerol-3 decanoate;
the polyquaternium is at least one of polyquaternium-7 and polyquaternium-39;
the alkali is one or two of sodium hydroxide and potassium hydroxide.
5. The all-soap pearlescent body wash of claim 3, characterized in that:
the fatty acid is lauric acid, myristic acid and palmitic acid according to a mass ratio of 9.6: 7.2: 1.2, obtaining fatty acid;
the surfactant is composed of disodium lauroamphoacetate diacetate, sodium cocoyl methyl taurate and cocoamidopropyl hydroxysulfobetaine according to a mass ratio of 3: 7: 6, preparing the surfactant;
the thickening agent is a water-soluble high molecular compound and inorganic salt according to the mass ratio of 3: 3.5-13.5, and mixing to obtain a thickening agent;
the cationic conditioner is a polyquaternium-7 and a polyquaternium-39 according to the mass ratio of 2.2: 3.3, obtaining the cationic conditioner.
6. The all-soap pearlescent body wash of claim 1, characterized in that:
the using amount of the essence is 0.4-0.6% by mass.
7. The all-soap base pearlescent body wash according to any one of claims 1 to 6, characterized in that: the pH value of the full-soap base pearlescent shower gel is 9.7-10.0.
8. The preparation method of the all-soap base pearlescent shower gel according to any one of claims 1 to 7, which is characterized by comprising the following steps:
(1) under the heating condition, stirring the fatty acid until the fatty acid is completely melted to obtain a solution A;
(2) uniformly mixing a chelating agent, a dispersing agent, a part of neutralizing agent and part of water to obtain a solution B;
(3) uniformly mixing components other than inorganic salt in the thickening agent with part of water to obtain a solution C;
(4) dissolving part of neutralizing agent in part of water to obtain solution D;
(5) adding the solution A into the solution B, and performing first saponification to obtain solution E;
(6) adding an emulsifier, a pearling agent and a surfactant into the solution E under the stirring condition of 80-90 ℃ to obtain solution F;
(7) adding the solution C into the solution F, and uniformly mixing; if the thickening agent contains inorganic salt, adding part of the inorganic salt in the thickening agent; obtaining a G liquid;
(8) when the temperature of the solution G is 35-45 ℃, adding the solution D for second saponification to obtain a solution H;
(9) adding emollient, cationic conditioner, essence, pigment and antiseptic into solution H, and mixing; if the viscosity is lower than 3000cps, adding inorganic salt to adjust the viscosity, and stirring uniformly to obtain the full-soap base pearlescent shower gel;
the neutralizing agent in the step (2) and the neutralizing agent in the step (4) are prepared from the following components in percentage by mass (85-95): (5-15).
9. The preparation method of the full-soap base pearlescent body wash according to claim 8, characterized in that:
the heating temperature in the step (1) is 80-90 ℃;
the mixing temperature in the step (2) is 85-95 ℃;
the saponification condition in the step (5) is that the saponification is stirred and reacts for at least 30 minutes at 80-90 ℃;
stirring conditions in the step (6) are that stirring is carried out at 80-100 rpm for 5-15 minutes;
the saponification condition in the step (8) is that the stirring is carried out for 10-30 minutes at a rotating speed of less than 100 rpm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910241519.1A CN109806186B (en) | 2019-03-28 | 2019-03-28 | Full-soap-base pearlescent shower gel and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910241519.1A CN109806186B (en) | 2019-03-28 | 2019-03-28 | Full-soap-base pearlescent shower gel and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109806186A CN109806186A (en) | 2019-05-28 |
| CN109806186B true CN109806186B (en) | 2022-04-12 |
Family
ID=66610735
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910241519.1A Active CN109806186B (en) | 2019-03-28 | 2019-03-28 | Full-soap-base pearlescent shower gel and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109806186B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111265432B (en) * | 2020-02-27 | 2023-01-17 | 广州玥颜化妆品有限公司 | Refreshing skin-moistening shower gel and preparation method thereof |
| CN113876685B (en) * | 2021-11-11 | 2023-09-01 | 上海蜂花日用品有限公司 | Bath foam with fine and refreshing foam and moisturizing function |
| CN114931521A (en) * | 2022-06-06 | 2022-08-23 | 广州一一生物技术有限公司 | Deep-cleaning soap-based shower gel capable of being continuously produced and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106333873A (en) * | 2016-08-29 | 2017-01-18 | 澳宝化妆品（惠州）有限公司 | Soap-based body wash |
| CN107375063A (en) * | 2017-07-14 | 2017-11-24 | 曾万祥 | A kind of shower cream and preparation method |
-
2019
- 2019-03-28 CN CN201910241519.1A patent/CN109806186B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106333873A (en) * | 2016-08-29 | 2017-01-18 | 澳宝化妆品（惠州）有限公司 | Soap-based body wash |
| CN107375063A (en) * | 2017-07-14 | 2017-11-24 | 曾万祥 | A kind of shower cream and preparation method |
Non-Patent Citations (2)
| Title |
|---|
| 广州市娇兰化妆品有限公司.广州市娇兰化妆品有限公司.《国产非特殊用途化妆品备案信息服务平台》.2018,网页全文. * |
| 广州市娇兰化妆品有限公司;广州市娇兰化妆品有限公司;《国产非特殊用途化妆品备案信息服务平台》;20180702;网页全文 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109806186A (en) | 2019-05-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109806186B (en) | Full-soap-base pearlescent shower gel and preparation method thereof | |
| JP5908841B2 (en) | Viscous liquid cleaning composition comprising sulfonated fatty acids, esters or salts thereof, and betaine or sultaine | |
| CN108066164B (en) | Transparent composite cleaning composition and preparation method thereof | |
| CN107384636B (en) | A kind of relatively mild Transparent soap base cleaning formulation | |
| JPS61277607A (en) | Flowable pearly bright condensate | |
| JP2004143072A (en) | Cleaner composition | |
| WO1997027279A1 (en) | Body soap composition | |
| JPH07258698A (en) | Fluid soap composition | |
| CN114921296A (en) | Soap-based self-thickening cleansing compositions | |
| JP2796364B2 (en) | Detergent composition | |
| JP2002173694A (en) | Transparent detergent | |
| WO2013133328A1 (en) | Skin washing composition | |
| JPWO2014129257A1 (en) | Viscous detergent composition | |
| JP2979285B2 (en) | Detergent composition | |
| JP4345144B2 (en) | Cleaning composition | |
| CN116098821B (en) | Cleaning composition containing surfactant system and application thereof | |
| JP4931287B2 (en) | Liquid detergent composition | |
| JP5554902B2 (en) | Skin cleanser composition | |
| CN109172409B (en) | Thickener aiming at amino acid surfactant, application thereof and shampoo | |
| JPH07310091A (en) | Liquid detergent composition | |
| JPH07258699A (en) | Pearl-like fluid detergent composition | |
| JP3473092B2 (en) | Detergent composition | |
| JP3417075B2 (en) | Detergent composition | |
| JPH08325595A (en) | Detergent composition | |
| JPH0320213A (en) | Liquid detergent composition for body cleaning |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |