CN109777641A - A kind of production method of diamond grinding liquid aqueous cleaning agent - Google Patents
A kind of production method of diamond grinding liquid aqueous cleaning agent Download PDFInfo
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- CN109777641A CN109777641A CN201711117501.8A CN201711117501A CN109777641A CN 109777641 A CN109777641 A CN 109777641A CN 201711117501 A CN201711117501 A CN 201711117501A CN 109777641 A CN109777641 A CN 109777641A
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- cleaning agent
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Abstract
The present invention provides a kind of production method of diamond grinding liquid aqueous cleaning agent, the dedicated aqueous cleaning agent of diamond grinding liquid includes the first cleaning agent and the second cleaning agent, the component of first cleaning agent includes: potassium hydroxide, additive for chrome-plating, cholamine, dispersing agent, compound surfactant, surplus is water, component in second cleaning agent includes: weak acid, corrosion inhibiter, surfactant, nanometer defoaming agent, water-soluble nano silica, and surplus is water.The preparation method comprises the following steps: additive for chrome-plating, potassium hydroxide and water is proportionally added, stirring allows it sufficiently to react, then cholamine, dispersing agent, compound surfactant are sequentially added, the first cleaning agent is stirred to get, weak acid and water is proportionally added, stirs evenly, sequentially add corrosion inhibiter, surfactant, nanometer defoaming agent and water-soluble nano silica, stirring obtains the second cleaning agent to being completely dissolved, and the first cleaning agent and the second cleaning agent form the dedicated aqueous cleaning agent of diamond grinding liquid.
Description
Technical field
The invention belongs to cleaning agent field of material technology, and in particular to a kind of production side of diamond grinding liquid aqueous cleaning agent
Method.
Background technique
Cleaning agent is the chemicals for taking out stains, and is generally divided into industrial cleaning agent and daily cleaning agent.It is raw in industry
It, often can there are dust, cutting object, abrasive material, lapping liquid, hand perspiration, salt mark, soda acid, animal and plant fat and mines on metallic article in production
The residues such as object oil, with the continuous improvement of science and technology, the kind of residue are more and more, to the degree of cleaning of cleaning agent
It is required that it is also higher and higher, nanoscale powder should be removed, metallic article can not be made to get rusty.Aqueous cleaning agent is according to application
The property of occasion, washing object and residue, washing mechanism is also more complicated, and general aqueous cleaning agent includes surface-active
Washing process, is generally divided into three parts by agent, corrosion inhibiter, pH adjusting agent, stabilizer, solvent and other auxiliary agents: first is that being impregnated with
Journey, second is that expansion, dispersion, floatingization and solubilized process, third is that the process of removing.
Currently, lapping liquid can be divided into diamond grinding liquid, Silica abrasive liquid, cerium oxide abrasive liquid according to the difference of abrasive material
Deng containing there are many tiny minerals powder in diamond grinding liquid, these minerals powder can remain in made of metal during the grinding process
The surface of part forms very tiny nanometer grade powder, if these tiny nanometer grade powders are not cleared up in time, made of metal
During use, the surface of metallic article will receive abrasion to part, may then influence the performance of product, therefore preparation is directed to
The cleaning agent of nanometer grade powder residue seems very necessary.
Summary of the invention
The technical problem to be solved in the present invention is to provide the production methods and its system of a kind of diamond grinding liquid aqueous cleaning agent
Preparation Method, the aqueous cleaning agent include the first cleaning agent and the second cleaning agent, the component of the first cleaning agent include: potassium hydroxide,
Complexing agent, cholamine, dispersing agent, compound surfactant are compounded, surplus is water, and the component in the second cleaning agent includes: weak acid, delays
Agent, surfactant, nanometer defoaming agent, water-soluble nano silica are lost, surplus is water.Using two kinds of detergents, cleaning effect
Fruit is more preferably thorough, high to the clearance rate of tiny nanometer grade powder, and workpiece device is not caused to corrode and be polluted, cleaning effect
It is good.
In order to solve the above technical problems, the technical scheme is that
A kind of production method of diamond grinding liquid aqueous cleaning agent, the dedicated aqueous cleaning agent of diamond grinding liquid include
First cleaning agent and the second cleaning agent, the component of first cleaning agent, by weight percentage, comprising: potassium hydroxide 3-
10%, additive for chrome-plating 3-8%, cholamine 1-5%, dispersing agent 1-5%, compound surfactant 3-7%, surplus is water, described
Additive for chrome-plating is HEDP, and the cholamine is a cholamine, and the dispersing agent is poly salt, and the compound surfactant is
RD129B。
As a preferred embodiment of the above technical solution, the use of second cleaning agent is after the first cleaning agent.
As a preferred embodiment of the above technical solution, second cleaning agent includes weak acid, corrosion inhibiter, surfactant, nanometer
Defoaming agent and water-soluble nano silica, the component of second cleaning agent, by weight percentage, comprising: weak acid 2-
10%, corrosion inhibiter 0.5-2%, surfactant 5-10%, nanometer defoaming agent 0.5-3% and water-soluble nano silica 1-
5%, surplus is water, and the weak acid is sodium sulfite, corrosion inhibiter is cholamine, and the surfactant is alkyl base phenol polyethenoxy
Ether, the nanometer defoaming agent are nano-silicon ether defoaming agent.
The present invention also provides a kind of preparation methods of the production method of diamond grinding liquid aqueous cleaning agent, including following step
It is rapid:
(1) additive for chrome-plating of 3-8%, the potassium hydroxide and water of 3-10% is proportionally added, stirs 15-20min, allows
It is sufficiently reacted, and then sequentially adds the compound surfactant of the cholamine of 1-5%, the dispersing agent of 1-5%, 3-7%, stirring
10-15min obtains the first cleaning agent；
(2) weak acid and water of 2-10% is proportionally added, stirs 15-20min, stirs evenly, sequentially add 0.5-2%
Corrosion inhibiter, the surfactant of 5-10%, the nanometer defoaming agent of 0.5-3% and 1-5% water-soluble nano silica, stir
It mixes to being completely dissolved, obtains the second cleaning agent；
(3) the first cleaning agent of step (1) preparation and the second cleaning agent composition diamond grinding liquid of step (2) preparation are dedicated
Aqueous cleaning agent.
As a preferred embodiment of the above technical solution, in the step (1), the potassium hydroxide is sodium hydroxide or/and hydrogen-oxygen
Change potassium, the additive for chrome-plating is one of HEDP, ATMP, EDTMPA, PAPEMP, PBTCA or several, and the cholamine is
One of one cholamine, two cholamine, three cholamine are several, and the dispersing agent is poly, poly acrylic acid, poly- horse
Come one of hydrochlorate, poly acrylates or several, the compound surfactant is RD129B, RD127, fat
One of three ether of alcohol polyoxyethylene ether, nine ether of fatty alcohol polyoxyethylene ether are several.
As a preferred embodiment of the above technical solution, in the step (2), the weak acid is sodium sulfite, corrosion inhibiter is ethyl alcohol
Amine, the surfactant are alkyl base phenol polyethenoxy ether, and the nanometer defoaming agent is nano-silicon ether defoaming agent.
As a preferred embodiment of the above technical solution, the application method of the dedicated aqueous cleaning agent of the diamond grinding liquid are as follows:
(1) in the workpiece device for needing to clean by the injection of the first cleaning agent, at 30-55 DEG C, forward circulation wipes 1-
3min, then recycled back wipe 1-3min；
(2) the first cleaning agent that step (1) is poured into is excluded into the workpiece device for needing to clean, the second cleaning agent is added,
At 50-80 DEG C, forward circulation wipes 1-3min, then recycled back wipes 1-3min；
(3) the second cleaning agent that step (2) is poured into is excluded into the workpiece device for needing to clean, water is added, rinsed 2-3 times,
Workpiece device is dried up.
As a preferred embodiment of the above technical solution, the step (1) and step (2) form a cycle, and the period can be followed
Ring 2-3 times.
As a preferred embodiment of the above technical solution, the method for the drying is air or is dried with nitrogen.
Compared with prior art, the invention has the following advantages:
(1) the dedicated aqueous cleaning agent of diamond grinding liquid prepared by the present invention includes the first cleaning agent and the second cleaning agent,
Contain potassium hydroxide, additive for chrome-plating, cholamine, dispersing agent and compound surfactant in first cleaning agent, potassium hydroxide can be with
It is high to the solvability of lapping liquid, it is easy to rinse, additive for chrome-plating can be complexed with tiny metallic particles, increase metallic particles
Dissolubility, improve cleaning efficiency, cholamine can prevent workpiece to be corroded, and dispersing agent and compound surfactant are conducive to improve clear
The dispersibility and stability of lotion, the first cleaning agent can make the dissolution of soluble and insoluble compound remnant parts and pine
It is dynamic, weak acid, corrosion inhibiter, surfactant, nanometer defoaming agent, water-soluble nano silica, weak acid are contained in the second cleaning agent
Dissolution can be carried out with loosely to residue again, corrosion inhibiter can protect workpiece to be corroded, and nanometer defoaming agent can eliminate bubble, guarantee
Cleaning agent is in the stability of cleaning process, and water-soluble nano silica also can prevent the residual of cleaning agent, prevents
Major structure is at secondary pollution.
(2) the dedicated aqueous cleaning agent of diamond grinding liquid prepared by the present invention using the second cleaning agent again to residue into
Row dissolution and loosening, are conducive to the dissolution and peeling of residue, alkaline matter are contained in the first cleaning agent, is contained in the second cleaning agent
There are acidic materials, the two combination maximum magnitude cleans the lapping liquid residue of workpiece surface, and cleaning effect is good, nontoxic
It is without side-effects, and cost is relatively low, and further includes water flushing and gas drying in use process, carries out again to workpiece surface clear
It washes, further increases cleaning rate.
(3) the dedicated aqueous cleaning agent preparation method of diamond grinding liquid prepared by the present invention is simple, and cost is relatively low, user
Just, cleaning effect is excellent, especially good to the cleaning effect to the remaining tiny nanometer powder of diamond grinding liquid, nontoxic to make without pair
With cleaning is simple, and noresidue not will cause secondary pollution, and almost corrosion-free to workpiece, and the rust-proofing time is long.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be described in detail, herein illustrative examples and explanation of the invention
For explaining the present invention, but it is not as a limitation of the invention.
Embodiment 1:
A kind of production method of diamond grinding liquid aqueous cleaning agent includes the first cleaning agent and the second cleaning agent.First cleaning
The component of agent, by weight percentage, comprising: the additive for chrome-plating 3% of sodium hydroxide 3%, HEDP and ATMP, a cholamine 1%,
The compound surfactant 3% of poly dispersing agent 1%, RD129B and RD127, surplus are water.The component of second cleaning agent,
By weight percentage, comprising: sodium sulfite 2%, cholamine corrosion inhibiter 0.5%, alkyl base phenol polyethenoxy ether surface active agent
5%, nano-silicon ether defoaming agent 0.5% and water-soluble nano silica 1 %, surplus are water.
The preparation method comprises the following steps: additive for chrome-plating, potassium hydroxide and water is proportionally added in (1), 15min is stirred, makes it abundant
Then reaction sequentially adds cholamine, dispersing agent, compound surfactant, stir 10min, obtain the first cleaning agent.
(2) weak acid and water is proportionally added, stirs 15min, stirs evenly, sequentially add corrosion inhibiter, surfactant,
Nanometer defoaming agent and water-soluble nano silica stir to being completely dissolved, obtain the second cleaning agent.
(3) first cleaning agents and the second cleaning agent form the dedicated aqueous cleaning agent of diamond grinding liquid.
Application method are as follows: (1) in the workpiece device that by first cleaning agent injection needs clean, at 30 DEG C, forward circulation
1min is wiped, then recycled back wipes 1min.
(2) the first cleaning agent is excluded into the workpiece device for needing to clean, the second cleaning agent is added, it is positive at 50-80 DEG C
Circulation wiping 1min, then recycled back wipe 1min.
(3) the second cleaning agent is excluded into the workpiece device for needing to clean, step (1) and step (2) is formed into a cycle,
Loop cycle 2 times, the second cleaning agent is excluded to the workpiece device for needing to clean, water is added, rinses 2 times, is set workpiece with air
Standby drying.
Embodiment 2:
A kind of production method of diamond grinding liquid aqueous cleaning agent includes the first cleaning agent and the second cleaning agent.First cleaning
The component of agent, by weight percentage, comprising: sodium hydroxide and potassium hydroxide 10%, HEDP, ATMP, EDTMPA, PAPEMP and
The additive for chrome-plating 8% of PBTCA, a cholamine, two cholamine and three cholamine 5%, poly, poly acrylic acid, poly- Malaysia
The dispersing agent 5% of hydrochlorate and poly acrylates, RD129B, RD127, three ether of fatty alcohol polyoxyethylene ether and poly alkyl alcohol
The compound surfactant 7% of nine ether of ethylene oxide ether, surplus are water.The component of second cleaning agent, by weight percentage, packet
It includes: sodium sulfite 10%, cholamine corrosion inhibiter 2%, alkyl base phenol polyethenoxy ether surface active agent 10%, nano-silicon ether defoaming agent
3% and water-soluble nano silica 5%, surplus be water.
The preparation method comprises the following steps: additive for chrome-plating, potassium hydroxide and water is proportionally added in (1), 20min is stirred, makes it abundant
Then reaction sequentially adds cholamine, dispersing agent, compound surfactant, stir 15min, obtain the first cleaning agent.
(2) weak acid and water is proportionally added, stirs 20min, stirs evenly, sequentially add corrosion inhibiter, surfactant,
Nanometer defoaming agent and water-soluble nano silica stir to being completely dissolved, obtain the second cleaning agent.
(3) first cleaning agents and the second cleaning agent form the dedicated aqueous cleaning agent of diamond grinding liquid.
Application method are as follows: (1) in the workpiece device that by first cleaning agent injection needs clean, at 55 DEG C, forward circulation
3min is wiped, then recycled back wipes 3min.
(2) the first cleaning agent is excluded into the workpiece device for needing to clean, the second cleaning agent is added, at 80 DEG C, forward direction is followed
Ring wipes 3min, then recycled back wipes 3min.
(3) the second cleaning agent is excluded into the workpiece device for needing to clean, step (1) and step (2) is formed into a cycle,
Loop cycle 3 times, the second cleaning agent is excluded to the workpiece device for needing to clean, water is added, rinses 3 times, is set workpiece with nitrogen
Standby drying.
The above-described embodiments merely illustrate the principles and effects of the present invention, and is not intended to limit the present invention.It is any ripe
The personage for knowing this technology all without departing from the spirit and scope of the present invention, carries out modifications and changes to above-described embodiment.Cause
This, institute is complete without departing from the spirit and technical ideas disclosed in the present invention by those of ordinary skill in the art such as
At all equivalent modifications or change, should be covered by the claims of the present invention.
Claims (3)
1. a kind of production method of diamond grinding liquid aqueous cleaning agent, it is characterised in that: the diamond grinding liquid is dedicated water base
Cleaning agent include the first cleaning agent and the second cleaning agent, the component of first cleaning agent, by weight percentage, comprising: hydrogen
Potassium oxide 3-10%, additive for chrome-plating 3-8%, cholamine 1-5%, dispersing agent 1-5%, compound surfactant 3-7%, surplus are
Water, the additive for chrome-plating are HEDP, and the cholamine is a cholamine, and the dispersing agent is poly salt, the compounding surface
Activating agent is RD129B.
2. a kind of production method of diamond grinding liquid aqueous cleaning agent according to claim 1, it is characterised in that: described
The use of two cleaning agents is after the first cleaning agent.
3. a kind of production method of diamond grinding liquid aqueous cleaning agent according to claim 1, it is characterised in that: described
Two cleaning agents include weak acid, corrosion inhibiter, surfactant, nanometer defoaming agent and water-soluble nano silica, and described second is clear
The component of lotion, by weight percentage, comprising: weak acid 2-10%, corrosion inhibiter 0.5-2%, surfactant 5-10%, nanometer
Defoaming agent 0.5-3% and water-soluble nano silica 1-5%, surplus are water, and the weak acid is sodium sulfite, corrosion inhibiter is second
Hydramine, the surfactant are alkyl base phenol polyethenoxy ether, and the nanometer defoaming agent is nano-silicon ether defoaming agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711117501.8A CN109777641A (en) | 2017-11-13 | 2017-11-13 | A kind of production method of diamond grinding liquid aqueous cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711117501.8A CN109777641A (en) | 2017-11-13 | 2017-11-13 | A kind of production method of diamond grinding liquid aqueous cleaning agent |
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| Publication Number | Publication Date |
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| CN109777641A true CN109777641A (en) | 2019-05-21 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201711117501.8A Pending CN109777641A (en) | 2017-11-13 | 2017-11-13 | A kind of production method of diamond grinding liquid aqueous cleaning agent |
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- 2017-11-13 CN CN201711117501.8A patent/CN109777641A/en active Pending
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Application publication date: 20190521 |
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