CN109777538A - A kind of energy conservation and environmental protection BF heavy oil - Google Patents

A kind of energy conservation and environmental protection BF heavy oil Download PDF

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Publication number
CN109777538A
CN109777538A CN201811088009.7A CN201811088009A CN109777538A CN 109777538 A CN109777538 A CN 109777538A CN 201811088009 A CN201811088009 A CN 201811088009A CN 109777538 A CN109777538 A CN 109777538A
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CN
China
Prior art keywords
heavy oil
boron
environmental protection
energy conservation
fluorine
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Pending
Application number
CN201811088009.7A
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Chinese (zh)
Inventor
刘宇祥
刘卫东
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Xiangtan Zhengyu Energy-Saving Science & Technology Co Ltd
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Xiangtan Zhengyu Energy-Saving Science & Technology Co Ltd
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Priority to CN201811088009.7A priority Critical patent/CN109777538A/en
Publication of CN109777538A publication Critical patent/CN109777538A/en
Pending legal-status Critical Current

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Abstract

A kind of energy conservation and environmental protection BF heavy oil, it mainly solves heavy oil energy automated cleaning and maintains engine Heavy Oil System, inhibits carbon deposit formation and removal carbon deposit, and fogging degree is good, the technical problems such as efficiency of combustion height.Its key points of the technical solution are that: it is it by adding in heavy oil component including boron-containing compound component and fluorine-containing surfactant component, the weight ratio (part) of heavy oil, boron-containing compound and fluorine-containing surfactant are as follows: heavy oil 600-1000, boron-containing compound 2-13, fluorine-containing surfactant 2-16.The fluorine-containing surfactant is that degradable short chain fluorinated surfactant polymer includes

Description

A kind of energy conservation and environmental protection BF heavy oil
Technical field
The present invention relates to a kind of novel energy-saving environment-friendly BF heavy oil, especially a kind of substitution is various using heavy fuel burning engine as power Various heavy oil it is mechanical.The invention further relates to the preparation methods of the heavy oil.
Background technique
Currently, heavy fuel burning engine is in the process of running, since the pollution of oil circuit, carbon deposit increase, especially power is big, temperature Degree height causes effective engine power to decline, and oil consumption is increased, and exhaust pollutant increases sharply, and therefore, improves the self-cleaning function of heavy oil, goes The formation of carbon deposit is removed and inhibited, guarantees one good burning situation of engine, while improving the fogging degree of heavy oil, improves combustion Efficiency is burnt, the pollutant emission for reducing tail gas is energy-saving and environment-friendly important means, and heavy oil is mainly used in industrial heavy oil power generation The equipment such as unit and heavy oil burner.
Summary of the invention
The object of the present invention is to provide a kind of automatic maintenance engine Heavy Oil Systems can greatly improve burning oil firing effect again Rate can substantially save heavy oil again compared with the heavy oil with category, reduce the energy conservation and environmental protection BF heavy oil of discharge.
The technical solution adopted by the present invention to solve the technical problems is: being that it includes by adding in heavy oil component Boron-containing compound component and fluorine-containing surfactant component.The weight ratio of heavy oil, boron-containing compound and fluorine-containing surfactant (part) are as follows: heavy oil 600-1000, boron-containing compound 2-13, fluorine-containing surfactant 2-16.
The weight ratio (part) of each component in heavy oil of the present invention are as follows: heavy oil 600-1000, boron-containing compound 2-13, fluorine-containing Surfactant 2-16, decarbonizer 4-9, deicer 2-9, oxygenation agent 25-110, combustion adjuvant 4-9, cosolvent 250-600,16 Alkane value modifier 20-30.
The preferred weight ratio (part) of each component in heavy oil of the present invention are as follows: heavy oil 600-1000, boron-containing compound 3-12, fluorine-containing Surfactant 4-14, decarbonizer 3-7, deicer 2-8, oxygenation agent 30-100, combustion adjuvant 5-8, cosolvent 300-500,16 Alkane value modifier 20-25.
Fluorine-containing surfactant of the present invention is that degradable short chain fluorinated surfactant polymer includesN < 5, the boron-containing compound are that organic boride includes boron hydrogen ion Compound, sodium borohydride.
Decarbonizer of the invention includes organic amine, imidazoles, amide, fatty acid succimide, polyetheramine, polyisobutene fourth Imidodicarbonic diamide.
Combustion adjuvant of the invention is that oil-soluble organic metal salt includes naphthenate.
Oxygenation agent of the invention is oxygen-containing alcohols abundant and dimethyl carbonate.
Cosolvent of the invention is alcohols, ethers, ketone and kerosene, such as acetone, dimethylformamide, ethyl ester, butyl ether.
Cetane number improver of the invention be nitrate compound, organic peroxide, ethers, derivative of fatty acid, Such as amyl nitrate, isooctyl ester nitrate.
With colloid chemistry principle, select heavy oil 600-1000, boron-containing compound 3-12, fluorine-containing surfactant 4-14, Decarbonizer 3-7, deicer 2-8, oxygenation agent 30-100, combustion adjuvant 5-8, cosolvent 300-500, cetane number improver 20-25, Innovation chelating technology is formulated, static 24 hours, and qualified factory is examined in filtering.
The ingredient of original weight oil increases two special elements of boron (B) and fluorine (F) in new formula compared with newly formula heavy oil.
The beneficial effects of the present invention are: energy conservation and environmental protection BF heavy oil can not generate various influence engine combustions in the process of running The clean-burning carbon distribution in room is burnt, and efficiency of combustion can be greatly improved, ensure that the maintenance oil-saving discharging-reducing of engine.It is mainly answered It is various with the engines such as heavy oil, including ship and various heavy oil machinery for being suitable for.
Specific embodiment
The present invention is described in further details below with reference to embodiment.
Embodiment 1, the present invention include following component, heavy oil 600-1000, boron-containing compound 2-13, fluorine-containing surfactant 2-16, decarbonizer 4-9, deicer 2-9, oxygenation agent 25-110, combustion adjuvant 4-9, cosolvent 250-600, cetane number improver 20-30, the fluorine-containing surfactant are that degradable short chain fluorinated surfactant polymer includes(n < 5), the boron-containing compound be organic boride include boron hydrogen from Sub- compound, sodium borohydride etc.., by operation, the burning in Heavy Oil System, automated cleaning oil circuit removes carbon remover, makes heavy oil Fogging degree is more preferable, burns more abundant, improves efficiency of combustion, achievees the purpose that maintenance, fuel-economizing, emission reduction.
Embodiment 2, heavy oil 600-1000 of the invention, boron-containing compound 3-12, fluorine-containing surfactant 4-14, decarbonizer 3-7, deicer 2-8, oxygenation agent 30-100, combustion adjuvant 5-8, cosolvent 300-500, cetane number improver 20-25.Remaining is same The combination of other any embodiments of the invention or 2 above embodiments.
Embodiment 3, decarbonizer of the invention include organic amine, imidazoles, amide, fatty acid succimide, polyetheramine, gather Isobutene succimide.Remaining combination with other any embodiments of the invention or 2 above embodiments.
Embodiment 4, combustion adjuvant of the invention are that oil-soluble organic metal salt includes naphthenate.Remaining is the same as of the invention its The combination of its any embodiment or 2 above embodiments.
Embodiment 5, oxygenation agent of the invention are oxygen-containing alcohols abundant and dimethyl carbonate.Remaining is the same as of the invention other The combination of any embodiment or 2 above embodiments.
Embodiment 6, cosolvent of the invention are alcohols, ethers, ketone and kerosene, such as acetone, dimethylformamide, second Ester, butyl ether.Remaining combination with other any embodiments of the invention or 2 above embodiments.
Embodiment 7, cetane number improver of the invention are nitrate compound, organic peroxide, ethers, fatty acid Derivative, such as amyl nitrate, isooctyl ester nitrate.Remaining is the same as other any embodiments of the invention or 2 above embodiments Combination.
Embodiment 8, the present invention respectively removes the component of heavy oil group especially ratio in formula and role is as follows:
Remaining combination with other any embodiments of the invention or 2 above embodiments.
Embodiment 9, performance test of the invention are as follows:
(1) present invention 2 are formulated by weight:
(2) decontamination is except carbon test, the comparative test with existing product, and data source is technical supervision department test center.
In insulating box at a temperature of -10 DEG C and 30 DEG C, takes and be attached with jelly, 5 pieces of the sheet metal of grease and deposition product 3 pieces of the sheet metal (burning charcoal) of carbon fouling, immerse respectively plus the different types of heavy oil of same volume in immerses two hours after, take out golden Belong to piece and claim its weight, calculates the grease weight being cleaned out;Again in addition sheet metal is washed into grease, obtains the weight of sheet metal Amount, calculates the total weight of the grease, carbon distribution that wash, show that heavy oil adds with energy conservation and environmental protection BF heavy oil of the invention identical Cleaning speed in dosage.
The test data of energy conservation and environmental protection BF heavy oil is as follows:
The test data of stability in heavy oil is as follows:

Claims (10)

1. a kind of energy conservation and environmental protection BF heavy oil, it is characterised in that it by heavy oil component add include boron-containing compound component and Fluorine-containing surfactant component.
2. energy conservation and environmental protection BF heavy oil according to claim 1, it is characterised in that the fluorine-containing surfactant is degradable Short chain fluorinated surfactant polymer includesThe boracic chemical combination Object is that organic boride includes boron hydrogen ion compound.
3. energy conservation and environmental protection BF heavy oil according to claim 1, it is characterised in that heavy oil, boron-containing compound and fluorine-containing surfactants The weight ratio (part) of agent are as follows: heavy oil 600-1000, boron-containing compound 2-13, fluorine-containing surfactant 2-16.
4. energy conservation and environmental protection BF heavy oil according to claim 1, it is characterised in that the weight ratio (part) of each component in heavy oil are as follows: weight Oily 600-1000, boron-containing compound 2-13, fluorine-containing surfactant 2-16, decarbonizer 4-9, deicer 2-9, oxygenation agent 25- 110, combustion adjuvant 4-9, cosolvent 250-600, cetane number improver 20-30.
5. a kind of energy conservation and environmental protection BF heavy oil according to claim 1, it is characterised in that the weight ratio of each component in heavy oil (part) are as follows: heavy oil 600-1000, boron-containing compound 3-12, fluorine-containing surfactant 4-14, decarbonizer 3-7, deicer 2-8, increase Oxygen agent 30-100, combustion adjuvant 5-8, cosolvent 300-500, cetane number improver 20-25.
6. energy conservation and environmental protection BF heavy oil according to claim 4 or 5, it is characterized in that: the decarbonizer include organic amine, imidazoles, Amide, fatty acid succimide, polyetheramine, polyisobutene succinimide.
7. energy conservation and environmental protection BF heavy oil according to claim 4 or 5, it is characterized in that: the combustion adjuvant is oil-soluble organic metal Salt includes naphthenate.
8. energy conservation and environmental protection BF heavy oil according to claim 4 or 5, it is characterized in that: the oxygenation agent is oxygen-containing alcohols abundant And dimethyl carbonate.
9. energy conservation and environmental protection BF heavy oil according to claim 4 or 5, it is characterized in that: the cosolvent is alcohols, ethers, ketone And kerosene.
10. energy conservation and environmental protection BF heavy oil according to claim 4 or 5, it is characterized in that: the cetane number improver is nitrate Compound, organic peroxide, ethers, derivative of fatty acid include amyl nitrate, the different good fortune ester of nitric acid.
CN201811088009.7A 2018-09-18 2018-09-18 A kind of energy conservation and environmental protection BF heavy oil Pending CN109777538A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811088009.7A CN109777538A (en) 2018-09-18 2018-09-18 A kind of energy conservation and environmental protection BF heavy oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811088009.7A CN109777538A (en) 2018-09-18 2018-09-18 A kind of energy conservation and environmental protection BF heavy oil

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Publication Number Publication Date
CN109777538A true CN109777538A (en) 2019-05-21

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1213694A (en) * 1998-08-18 1999-04-14 张云 Formulation and prodn. method of gas light oil
CN1219574A (en) * 1997-08-01 1999-06-16 乙基公司 Phosphorylated and/or boronated dispersants as thermal stability additives for distillate fuels
CN1401745A (en) * 2002-09-26 2003-03-12 武汉理工大学 Multifunctional heavy oil and fuel oil additive, preparation and use thereof in preparing emulsified oil
CN101146895A (en) * 2005-03-22 2008-03-19 摩尔能源有限公司 Fuel composition for fuel cells
CN101705123A (en) * 2009-11-26 2010-05-12 济南开发区星火科学技术研究院 Environment friendly and energy-saving heavy oil additive
CN102300804A (en) * 2009-01-27 2011-12-28 H2燃料系统有限公司 Method, device and fuel for hydrogen generation
CN102559335A (en) * 2011-12-21 2012-07-11 刘卫东 Detachment-exempting efficient detergent of fuel system of fuel oil engine
CN106753604A (en) * 2016-12-20 2017-05-31 墨宝股份有限公司 A kind of novel energy-saving environment-friendly is without benzene low-carbon (LC) machinery alcohol-based fuel

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1219574A (en) * 1997-08-01 1999-06-16 乙基公司 Phosphorylated and/or boronated dispersants as thermal stability additives for distillate fuels
CN1213694A (en) * 1998-08-18 1999-04-14 张云 Formulation and prodn. method of gas light oil
CN1401745A (en) * 2002-09-26 2003-03-12 武汉理工大学 Multifunctional heavy oil and fuel oil additive, preparation and use thereof in preparing emulsified oil
CN101146895A (en) * 2005-03-22 2008-03-19 摩尔能源有限公司 Fuel composition for fuel cells
CN102300804A (en) * 2009-01-27 2011-12-28 H2燃料系统有限公司 Method, device and fuel for hydrogen generation
CN101705123A (en) * 2009-11-26 2010-05-12 济南开发区星火科学技术研究院 Environment friendly and energy-saving heavy oil additive
CN102559335A (en) * 2011-12-21 2012-07-11 刘卫东 Detachment-exempting efficient detergent of fuel system of fuel oil engine
CN106753604A (en) * 2016-12-20 2017-05-31 墨宝股份有限公司 A kind of novel energy-saving environment-friendly is without benzene low-carbon (LC) machinery alcohol-based fuel

Non-Patent Citations (2)

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Title
邢航等: "氟表面活性剂和氟聚合物(Ⅳ)-PFOS问题的应对策略", 《日用化学工业》 *
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