CN109797013A - A kind of energy conservation and environmental protection BF fuel oil - Google Patents

A kind of energy conservation and environmental protection BF fuel oil Download PDF

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Publication number
CN109797013A
CN109797013A CN201811087064.4A CN201811087064A CN109797013A CN 109797013 A CN109797013 A CN 109797013A CN 201811087064 A CN201811087064 A CN 201811087064A CN 109797013 A CN109797013 A CN 109797013A
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CN
China
Prior art keywords
fuel oil
boron
fluorine
environmental protection
energy conservation
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Pending
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CN201811087064.4A
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Chinese (zh)
Inventor
刘宇祥
刘卫东
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Xiangtan Zhengyu Energy-Saving Science & Technology Co Ltd
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Xiangtan Zhengyu Energy-Saving Science & Technology Co Ltd
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Priority to CN201811087064.4A priority Critical patent/CN109797013A/en
Publication of CN109797013A publication Critical patent/CN109797013A/en
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Abstract

A kind of energy conservation and environmental protection BF fuel oil, it mainly solves fuel oil energy automated cleaning and maintains engine fuel oil system, inhibits carbon deposit formation and removal carbon deposit, and fogging degree is good, the technical problems such as efficiency of combustion height.Its key points of the technical solution are that: it includes boron-containing compound component and fluorine-containing surfactant component by adding in fuel oil component, and the fluorine-containing surfactant is that degradable short chain fluorinated surfactant polymer includes

Description

A kind of energy conservation and environmental protection BF fuel oil
Technical field
The present invention relates to a kind of novel energy-saving environment-friendly BF fuel oil, especially a kind of substitution is various using fuel engines as power Gasoline, diesel oil, heavy oil and kerosene, the engine fuel including automobile ship aircraft and various fuel oils machinery.The present invention also relates to And the preparation method of the fuel oil.
Background technique
Currently, fuel engines is in the process of running, since the pollution of oil circuit, carbon deposit increase, cause engine effective Power decline, oil consumption are increased, and exhaust pollutant increases sharply, and therefore, improve the self-cleaning function of fuel oil, removal and the shape for inhibiting product rock At, guarantee one good burning situation of engine, while improving the fogging degree of fuel oil, raising efficiency of combustion, reduction tail gas Pollutant emission be energy-saving and environment-friendly important means.
Summary of the invention
The object of the present invention is to provide a kind of automatic maintenance engine fuel oil systems can greatly improve burning oil firing effect again Rate can substantially save fuel oil again compared with the fuel oil with category, reduce the energy conservation and environmental protection BF fuel oil of discharge.
The technical solution adopted by the present invention to solve the technical problems is: it includes boracic by adding in fuel oil component Compound component and fluorine-containing surfactant component, the fluorine-containing surfactant are degradable short chain fluorinated surfactant Polymer includesThe boron-containing compound is organic boride Including boron hydrogen ion compound, sodium borohydride, the weight ratio (part) of the fuel oil, boron-containing compound and fluorine-containing surfactant Are as follows: fuel oil 600-1000, boron-containing compound 1-13, fluorine-containing surfactant 1-16.
The weight ratio (part) of each component in fuel oil of the invention are as follows: gasoline 700-900, boron-containing compound 1-8, fluorochemical surface Activating agent 1-10, decarbonizer 2-5, deicer 1-5, oxygenation agent 20-100, combustion adjuvant 2-5, cosolvent 200-500, octane number change Into agent 2-10.
The weight ratio (part) of each component in fuel oil of the invention are as follows: diesel oil 700-1000, boron-containing compound 1.5-12, fluorine-containing Surfactant 1.5-15, decarbonizer 3-8, deicer 1.5-8, oxygenation agent 20-100, combustion adjuvant 3-8, cosolvent 200-500, Cetane number improver 15-25.
The weight ratio (part) of each component in fuel oil of the invention are as follows: heavy oil 600-1000, boron-containing compound 2-13, fluorine-containing table Face activating agent 2-16, decarbonizer 4-9, deicer 2-9, oxygenation agent 25-110, combustion adjuvant 4-9, cosolvent 250-600, hexadecane It is worth modifier 20-30.
Decarbonizer of the invention includes organic amine, imidazoles, amide, fatty acid succimide, polyetheramine, polyisobutene fourth Imidodicarbonic diamide.
Combustion adjuvant of the invention is that oil-soluble organic metal salt includes naphthenate.
Oxygenation agent of the invention is oxygen-containing alcohols abundant and dimethyl carbonate.
Cosolvent of the invention is alcohols, ethers, ketone and kerosene, such as acetone, dimethylformamide, ethyl ester, butyl ether.
Octane number transformation agent of the invention is methyl tertiary butyl ether(MTBE).
Cetane number improver of the invention be nitrate compound, organic peroxide, ethers, derivative of fatty acid, Such as amyl nitrate, isooctyl ester nitrate.
With colloid chemistry principle, fuel oil 700-1000, boron-containing compound 1.5-12, fluorine-containing surfactant 1.5- are selected 15, decarbonizer 3-8, deicer 1.5-8, oxygenation agent 20-100, combustion adjuvant 3-8, cosolvent 200-500, cetane number improver 15-25 or octane enhancing additive 2-10, innovation chelating technology are formulated, and static 24 hours, qualified factory is examined in filtering.
The ingredient of former fuel oil increases two special elements of fluorine and boron in new formula compared with newly formula fuel oil.
The beneficial effects of the present invention are: energy conservation and environmental protection BF fuel oil can not generate various influence engine combustions in the process of running The clean-burning carbon distribution in room is burnt, and efficiency of combustion can be greatly improved, ensure that the maintenance oil-saving discharging-reducing of engine.It is mainly It is various mechanical with the engines such as gasoline, diesel oil, aviation kerosine, including automobile, ship and various fuel oils applied to being suitable for.
Specific embodiment
The present invention is described in further details below with reference to embodiment.
Embodiment 1, the present invention it by fuel oil component add include boron-containing compound component and fluorine-containing surfactants Agent component, the fluorine-containing surfactant are that degradable short chain fluorinated surfactant polymer includesThe boron-containing compound is that organic boride includes boron hydrogen ion Compound, sodium borohydride, the weight ratio (part) of the fuel oil, boron-containing compound and fluorine-containing surfactant are as follows: fuel oil 600- 1000, boron-containing compound 1-13, fluorine-containing surfactant 1-16 pass through operation, the burning in fuel system, automated cleaning Oil circuit removes carbon remover, keeps fuel-oil atmozation degree more preferable, burns more abundant, improves efficiency of combustion, reaches maintenance, fuel-economizing, emission reduction Purpose.
Embodiment 2, the weight ratio (part) of each component in fuel oil of the invention are as follows: gasoline 700-900, boron-containing compound 1-8, Fluorine-containing surfactant 1-10, decarbonizer 2-5, deicer 1-5, oxygenation agent 20-100, combustion adjuvant 2-5, cosolvent 200-500, Octane enhancing additive 2-10.Remaining combination with other any embodiments of the invention or 2 above embodiments.
Embodiment 3, the weight ratio (part) of each component in fuel oil of the invention are as follows: diesel oil 700-1000, boron-containing compound 1.5-12, it fluorine-containing surfactant 1.5-15, decarbonizer 3-8, deicer 1.5-8, oxygenation agent 20-100, combustion adjuvant 3-8, helps Solvent 200-500, cetane number improver 15-25.Remaining is the same as other any embodiments of the invention or 2 above embodiments Combination.
Embodiment 4, the weight ratio (part) of each component in fuel oil of the invention are as follows: heavy oil 600-1000, boron-containing compound 2- 13, fluorine-containing surfactant 2-16, decarbonizer 4-9, deicer 2-9, oxygenation agent 25-110, combustion adjuvant 4-9, cosolvent 250- 600, cetane number improver 20-30.Remaining combination with other any embodiments of the invention or 2 above embodiments.
Embodiment 5, decarbonizer of the invention include organic amine, imidazoles, amide, fatty acid succimide, polyetheramine, gather Isobutene succimide.Remaining combination with other any embodiments of the invention or 2 above embodiments.
Embodiment 6, combustion adjuvant of the invention are that oil-soluble organic metal salt includes naphthenate.Remaining is the same as of the invention its The combination of its any embodiment or 2 above embodiments.
Embodiment 7, oxygenation agent of the invention are oxygen-containing alcohols abundant and dimethyl carbonate.Remaining is the same as of the invention other The combination of any embodiment or 2 above embodiments.
Embodiment 8, cosolvent of the invention are alcohols, ethers, ketone and kerosene, such as acetone, dimethylformamide, second Ester, butyl ether.Remaining combination with other any embodiments of the invention or 2 above embodiments.
Embodiment 9, octane number transformation agent of the invention is methyl tertiary butyl ether(MTBE).Remaining is the same as other any implementations of the invention The combination of example or 2 above embodiments.
Embodiment 10, cetane number improver of the invention are nitrate compound, organic peroxide, ethers, fat Acid derivative, such as amyl nitrate, isooctyl ester nitrate.Remaining is the same as other any embodiments of the invention or 2 above embodiments Combination.
Dimethyl carbonate embodiment 11, component of the invention ratio in formula and role are as follows:
Remaining combination with other any embodiments of the invention or 2 above embodiments.
Embodiment 12, performance test of the invention are as follows:
(1) present invention 2 are formulated by weight:
(2) decontamination is except carbon test, the comparative test with existing product, and data source is technical supervision department test center.
In insulating box at a temperature of -20 DEG C and 30 DEG C, takes and be attached with jelly, 3 pieces of the sheet metal of grease and deposition product 3 pieces of the sheet metal (burning charcoal) of carbon fouling, immerses No. 92 gasoline of same volume, the fuel oil of example 1 and the fuel oil of example 2 respectively, immerses two After hour, takes out sheet metal and claim its weight, calculate the grease weight being cleaned out;Again in addition sheet metal is washed into grease, The weight for obtaining sheet metal calculates the total weight of grease, carbon distribution, show that different fuel oils descends the effect of scale removal at the same time Fruit.
The test data of energy conservation and environmental protection BF fuel oil is as follows:
The test data of stability is as follows:
The present invention is as follows to engine energy-saving environmental protection BF gasoline maintenance oil-saving discharging-reducing service condition experimental data:
(1) joint city is taken the lead through letter committee and Environmental Protection Agency, under the whole supervision of media, to Hunan CA1590 by Xiang Tan high and new technology industrial development zone Kart actual effect tests fuel-economizing 11.2%, CO emission reduction 91.67%, HC emission reduction 84.62% when high speed.
(2) in Qinghai-Tibet military depot license plate numbers orchid J00091, it is 10.12% that 62201 army's jeeps, which test rate of economizing gasoline,.
Embodiment 13, component of the invention ratio in formula and role are as follows:
Remaining combination with other any embodiments of the invention or 2 above embodiments.
Embodiment 14, performance test of the invention are as follows:
(1) present invention 2 are formulated by weight:
(2) decontamination is except carbon test, the comparative test with existing product, and data source is technical supervision department test center.
In insulating box at a temperature of -10 DEG C and 30 DEG C, takes and be attached with jelly, 3 pieces of the sheet metal of grease and deposition product 3 pieces of the sheet metal (burning charcoal) of carbon fouling, immerse respectively plus the different types of fuel oil of same volume in immerses two hours after, taking-up Sheet metal claims its weight, calculates the grease weight being cleaned out;Again in addition sheet metal is washed into grease, obtains sheet metal Weight, calculate the total weight of the grease, carbon distribution that wash, show that -10# diesel oil exists from different energy conservation and environmental protection BF fuel oils Cleaning speed in identical additive amount.
The test data of energy conservation and environmental protection BF fuel oil is as follows:
The test data of the stability of fuel oil is as follows:
The present invention and conventional diesel oil-saving discharging-reducing service condition experimental data are as follows:
(1) Hunan Hunan steel flood storage flow device portion can be the same as carrying out before and after seven branch companies, nine water station, seven trolley pair for each 20 days Than the hundred ton kilometre oil consumption using conventional diesel are 6.13, the use of hundred ton kilometre oil consumption of the invention are 5.23, by hundred tons of public affairs In average computation rate of economizing gasoline be 14.7.
(2) the flat high speed shipping in Hunan Hunan compares test in Xiang Tan goods 0069, and 800 turns of same revolving speed uses traditional bavin The preceding oil consumption in 2 hours of oil is 16.32kg, the use of preceding oil consumption in 2 hours of the invention is 14.41kg, rate of economizing gasoline 11.7.
Embodiment 15, component of the invention ratio in formula and role are as follows:
Remaining combination with other any embodiments of the invention or 2 above embodiments.
Embodiment 16, performance test of the invention are as follows:
(1) present invention 2 are formulated by weight:
(2) decontamination is except carbon test, the comparative test with existing product, and data source is technical supervision department test center.
In insulating box at a temperature of -10 DEG C and 30 DEG C, takes and be attached with jelly, 5 pieces of the sheet metal of grease and deposition product 3 pieces of the sheet metal (burning charcoal) of carbon fouling, immerse respectively plus the different types of fuel oil of same volume in immerses two hours after, taking-up Sheet metal claims its weight, calculates the grease weight being cleaned out;Again in addition sheet metal is washed into grease, obtains sheet metal Weight, calculate the total weight of the grease, carbon distribution that wash, obtain heavy oil with energy conservation and environmental protection BF fuel oil of the invention in phase Cleaning speed in same additive amount.
The test data of energy conservation and environmental protection BF fuel oil is as follows:
The test data of stability in fuel oil is as follows:

Claims (10)

1. a kind of energy conservation and environmental protection BF fuel oil, it is characterized in that: it by added in fuel oil component include boron-containing compound component and Fluorine-containing surfactant component, the fluorine-containing surfactant are that degradable short chain fluorinated surfactant polymer includesThe boron-containing compound is that organic boride includes boron hydrogen ion Compound, the weight ratio (part) of the fuel oil, boron-containing compound and fluorine-containing surfactant are as follows: fuel oil 600-1000, contain boronation Close object 1-13, fluorine-containing surfactant 1-16.
2. energy conservation and environmental protection BF fuel oil according to claim 1, it is characterised in that the weight ratio (part) of each component in fuel oil are as follows: vapour Oily 700-900, boron-containing compound 1-8, fluorine-containing surfactant 1-10, decarbonizer 2-5, deicer 1-5, oxygenation agent 20-100, Combustion adjuvant 2-5, cosolvent 200-500, octane enhancing additive 2-10.
3. energy conservation and environmental protection BF fuel oil according to claim 1, it is characterised in that the weight ratio (part) of each component in fuel oil are as follows: bavin Oily 700-1000, boron-containing compound 1.5-12, fluorine-containing surfactant 1.5-15, decarbonizer 3-8, deicer 1.5-8, oxygenation agent 20-100, combustion adjuvant 3-8, cosolvent 200-500, cetane number improver 15-25.
4. energy conservation and environmental protection BF fuel oil according to claim 1, it is characterised in that the weight ratio (part) of each component in fuel oil are as follows: weight Oily 600-1000, boron-containing compound 2-13, fluorine-containing surfactant 2-16, decarbonizer 4-9, deicer 2-9, oxygenation agent 25- 110, combustion adjuvant 4-9, cosolvent 250-600, cetane number improver 20-30.
5. a kind of energy conservation and environmental protection BF fuel oil according to claim 2 to 4 any one, it is characterized in that: the decarbonizer packet Include organic amine, imidazoles, amide, fatty acid succimide, polyetheramine, polyisobutene succinimide.
6. a kind of energy conservation and environmental protection BF fuel oil according to claim 2 to 4 any one, it is characterized in that: the combustion adjuvant is Oil-soluble organic metal salt includes naphthenate.
7. a kind of energy conservation and environmental protection BF fuel oil according to claim 2 to 4 any one, it is characterized in that: the oxygenation agent is Oxygen-containing alcohols abundant and dimethyl carbonate.
8. a kind of energy conservation and environmental protection BF fuel oil according to claim 2 to 4 any one, it is characterized in that: the cosolvent is Alcohols, ethers, ketone and kerosene.
9. a kind of energy conservation and environmental protection BF fuel oil according to claim 2, it is characterized in that: the octane enhancing additive is methyl- tert Butyl ether.
10. a kind of energy conservation and environmental protection BF fuel oil according to claim 3 to 4 any one, it is characterized in that: the Cetane number Modifier is nitrate compound, organic peroxide, ethers, derivative of fatty acid.
CN201811087064.4A 2018-09-18 2018-09-18 A kind of energy conservation and environmental protection BF fuel oil Pending CN109797013A (en)

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Application Number Priority Date Filing Date Title
CN201811087064.4A CN109797013A (en) 2018-09-18 2018-09-18 A kind of energy conservation and environmental protection BF fuel oil

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Citations (7)

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Publication number Priority date Publication date Assignee Title
CN1213694A (en) * 1998-08-18 1999-04-14 张云 Formulation and prodn. method of gas light oil
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CN102300804A (en) * 2009-01-27 2011-12-28 H2燃料系统有限公司 Method, device and fuel for hydrogen generation
CN102559335A (en) * 2011-12-21 2012-07-11 刘卫东 Detachment-exempting efficient detergent of fuel system of fuel oil engine
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Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1219574A (en) * 1997-08-01 1999-06-16 乙基公司 Phosphorylated and/or boronated dispersants as thermal stability additives for distillate fuels
CN1213694A (en) * 1998-08-18 1999-04-14 张云 Formulation and prodn. method of gas light oil
CN1594513A (en) * 2004-06-25 2005-03-16 厦门维环洁油技术有限公司 Energy-saving fuel-oil cleaning agent and method for making same
CN101146895A (en) * 2005-03-22 2008-03-19 摩尔能源有限公司 Fuel composition for fuel cells
CN102300804A (en) * 2009-01-27 2011-12-28 H2燃料系统有限公司 Method, device and fuel for hydrogen generation
CN102559335A (en) * 2011-12-21 2012-07-11 刘卫东 Detachment-exempting efficient detergent of fuel system of fuel oil engine
CN106753604A (en) * 2016-12-20 2017-05-31 墨宝股份有限公司 A kind of novel energy-saving environment-friendly is without benzene low-carbon (LC) machinery alcohol-based fuel

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Application publication date: 20190524