CN109776072A - Fire-resistant slurry powder - Google Patents

Fire-resistant slurry powder Download PDF

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Publication number
CN109776072A
CN109776072A CN201711125605.3A CN201711125605A CN109776072A CN 109776072 A CN109776072 A CN 109776072A CN 201711125605 A CN201711125605 A CN 201711125605A CN 109776072 A CN109776072 A CN 109776072A
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CN
China
Prior art keywords
fire
brick
silica brick
mud
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711125605.3A
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Chinese (zh)
Inventor
李足年
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Yue Zhan Type Material Co Ltd
Original Assignee
Jiangsu Yue Zhan Type Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Jiangsu Yue Zhan Type Material Co Ltd filed Critical Jiangsu Yue Zhan Type Material Co Ltd
Priority to CN201711125605.3A priority Critical patent/CN109776072A/en
Publication of CN109776072A publication Critical patent/CN109776072A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Ceramic Products (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)

Abstract

A kind of fire-resistant slurry powder is made: SiO of the raw material of following weight percents2Content is not less than 96% silica 46-48%, SiO2Content is not less than 92% residual silica brick 46-48%, Al2O3The graphite of fire clay 3-8%, 0.05-0.09% of the content not less than 25%, the phenol-formaldehyde resin powder of 0.03-0.05%;The residual silica brick is consistent with the silica brick material that the fire-resistant slurry powder is built.The adhesion strength of refractory wass is made to be able to maintain higher temperature using phenol-formaldehyde resin powder, the medium and high temperature adhesion strength of mud is improved, and residual silica brick is utilized, realizes maximally utilizing for waste material, the service life for extending ladle and furnace body is used suitable for high-temperature furnace body and ladle.

Description

Fire-resistant slurry powder
Technical field
The present invention relates to technical field of refractory materials, specially a kind of ladle, coke oven, glass furnace etc. of being suitable for needs fire resisting Field uses.
Background technique
Refractory wass (refractory mortar) is used as the unshape refractory of refractory masonry seam, also known as connects Sewing.Refractory wass can be divided into the hydraulicity, thermohardening, air hardening refractory mud according to its bonding agent condensation hardening feature;The hydraulicity Refractory wass is can be used under room temperature or may be with water or steam often in contact with place using cement as bonding agent.Thermohardening is resistance to Chamotte is starched the common thermohardenings bonding agent such as phosphoric acid or phosphate and is made.It is higher except having at various temperatures after such mud hardening Other than intensity, contraction is small, and seam is tight, and erosion resisting is strong;Air hardening refractory mud is often matched with the air-settings bonding agent such as sodium metasilicate System, this mud can make the seam of masonry tight.Different according to the material of refractory powder used, common refractory wass can divide Are as follows: clayey, High-Alumina, it is siliceous, magnesia, contain carbonaceous, heat-insulated matter, etc..Clay fire-resistant slurry uses hard paste clinker As base-material, combined with mild-clay or chemical bond.Be mainly used in blast furnace, hot-blast stove, coke oven, soaking pit, heat exchanger, The furnace body seam and repairing of the clay brick masonry such as boiler.High alumina fire-resistant slurry material of main part selects high alumina, bonding agent With mild-clay or chemical bond.Al2O3 content is determined according to the brick body ingredient and requirement at built position.It can be extensive Various Industrial Stoves for high alumina brick masonry.For building furnace roof, regenerative chamber, combustion chamber etc. on hot-blast stove, it to be used for blast furnace The parts such as furnace bottom, cupola well, bosh, furnace bosh, it may also be used for repair the positions such as industrial kiln top, furnace wall.Silica fire resistant mud is adopted Main material is done with Cab-O-sil or addition part silicon powder.Bonding agent can use mild-clay or chemical bond.Silica fire resistant mud master It is used to build and repair coke oven, glass melter, acid smelting furnace etc. and other Industrial Stoves built with silica brick.Magnesia fireproof Mud uses various magnesia as raw material, is combined with clay, bentonite or chemical bond, or is directly modulated with brine (MgCl2) Mud.Open hearth, electric furnace, oxygen coverter, smelting non-ferrous metal kiln etc. is mainly used in be built with magnesia brick, magnesite-chrome brick, magnesia-alumina brick etc. The part built.Carbon containing refractory wass is made by various light-weight refractory powders and bonding agent.Its main feature is that bulk density is small, thermal conductivity Rate is low, can be used for building and repairing on the various Industrial Stoves built with heat-barrier material.Other refractory wass are except above several resistance to Chamotte slurry is outer, and there are also silicon carbide based fire clay slurries, porzite flame-proof mud, corundum fireproof mud, zirconium fire-resistant slurry, chromium Fire-resistant slurry.Its different properties is respectively used to the masonry and repairing of same material refractory brick.Additionally some specific uses Mud, such as anhydrous (non-aqueous) mud, expansion mud.Make refractory wass powder can be selected the sufficient clinker of sintering and The various refractory raw materials of other volume stabilities.For the granularity of powder-material depending on requirement, Limit Grain Size is generally less than 1mm, Some is less than 0.5mm or thinner.Reasonable particle group guarantees that the workability of mud has a significant impact in pairs, bonding agent and additional Agent is also the same.The bonding agent that common refractory wass uses is bonding clay.With the requirements at the higher level of user, chemical bond is obtained More and more extensive use is arrived.Various additives are added in refractory wass can improve the workability of refractory wass, such as add Enter to protect water-proofing agent to extend losing time, guarantees construction quality;Plasticizer is added, mud can be increased in the lesser situation of additional amount The plasticity of slurry;Dispersing agent is added to improve the mobility etc. of mud.Refractory wass is refractory brick or brick to be connected into a heavily fortified point Real entirety is essential a kind of unshape refractory during most stoves are built.It will not only bear high temperature work With, while it will undertake the outer dimension tolerance of adjustment brick, balance the swelling stress between brick.Therefore only using the resistance to of top grade Chamotte slurry, can just obtain the kiln of high-efficiency long-life.
Siliceous mud powder is the binding material of refractory brick, and builds the binding material of the high-temperature furnace bodies such as coke oven, it Performance directly affects the masonry quality and service life of refractory brick and furnace body.Currently, people use always native mud, it is such as certain Then manufacturer mixes with the residual silica brick of a small amount of each production silica brick producer using tripoli as primary raw material and natural mud is made Starch since the primary raw material of native mud is tripoli, exists in actual use with silica brick used in the furnace bodies such as coke oven is built It is had differences in material, although also containing a small amount of residual silica brick in ingredient, due to the otherness in area, so that preparing mud There is also differences in material for silica brick used in the furnace bodies such as the residual silica brick and masonry coke oven of starch, therefore go out in the construction process Native mud at low ambient temperatures and silica brick bonding and under high temperature environment inadherent phenomenon are showed, to high temperature furnaces such as coke ovens Production from now on brings great hidden danger.
Summary of the invention
The present invention provides one to solve the problems, such as that existing siliceous mud powder is mutually inadherent during practical applied at elevated temperature Kind fire-resistant slurry powder.
The present invention is achieved by the following technical scheme: fire-resistant slurry powder is made of the raw material of following weight percents: Silica 46-48%, SiO2 content of the SiO2 content not less than 96% is not less than 92% residual silica brick 46-48%, and Al2O3 content is not The graphite of fire clay 3-8%, 0.05-0.09% lower than 25%, the phenol-formaldehyde resin powder of 0.03-0.05%;The residual silicon Brick is consistent with the silica brick material that the fire-resistant slurry powder is built.
The heat cured phenol-formaldehyde resin powder of heat-resistant fireproof makes the adhesion strength of refractory wass be able to maintain higher temperature, Improve the medium and high temperature adhesion strength of mud.
The residual silica brick refers to truncation, unfilled corner in finished product silica brick, has the shapes such as crackle, in appearance defective substandard products, The substandard products not reached requirement without referring to its physical and chemical index, so that guarantee is prepared used in residual silica brick and the masonry of mud powder Silica brick is consistent in material.
The invention has the advantages that using phenol-formaldehyde resin powder make refractory wass adhesion strength be able to maintain it is higher Temperature, improves the medium and high temperature adhesion strength of mud, and residual silica brick is utilized, and realizes maximally utilizing for waste material, extends The service life of ladle and furnace body, uses suitable for high-temperature furnace body and ladle.
Specific embodiment
Embodiment 1:
Fire-resistant slurry powder is made of the raw material of following weight percents: SiO2 content is not less than 96% silica 46%, and SiO2 contains Residual silica brick 46% of the amount not less than 92%, fire clay 7.92% of the Al2O3 content not less than 25%, 0.05% graphite, 0.03% phenol-formaldehyde resin powder;The residual silica brick is consistent with the silica brick material that the fire-resistant slurry powder is built.
Embodiment 2:
Fire-resistant slurry powder is made of the raw material of following weight percents: SiO2 content is not less than 96% silica 48%, and SiO2 contains Residual silica brick 48% of the amount not less than 92%, fire clay 3.96% of the Al2O3 content not less than 25%, 0.09% graphite, 0.05% phenol-formaldehyde resin powder;The residual silica brick is consistent with the silica brick material that the fire-resistant slurry powder is built.

Claims (1)

1. a kind of fire-resistant slurry powder, it is characterized in that: it is made of the raw material of following weight percents: SiO2Content is not less than 96% Silica 46-48%, SiO2Content is not less than 92% residual silica brick 46-48%, Al2O3Content is not less than 25% fire clay The graphite of 3-8%, 0.05-0.09%, the phenol-formaldehyde resin powder of 0.03-0.05%;The residual silica brick and the fire-resistant slurry powder institute The silica brick material of masonry is consistent.
CN201711125605.3A 2017-11-15 2017-11-15 Fire-resistant slurry powder Pending CN109776072A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711125605.3A CN109776072A (en) 2017-11-15 2017-11-15 Fire-resistant slurry powder

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711125605.3A CN109776072A (en) 2017-11-15 2017-11-15 Fire-resistant slurry powder

Publications (1)

Publication Number Publication Date
CN109776072A true CN109776072A (en) 2019-05-21

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711125605.3A Pending CN109776072A (en) 2017-11-15 2017-11-15 Fire-resistant slurry powder

Country Status (1)

Country Link
CN (1) CN109776072A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111689781A (en) * 2020-06-09 2020-09-22 中冶武汉冶金建筑研究院有限公司 Siliceous buffering slurry for hot-blast stove buffering seam

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111689781A (en) * 2020-06-09 2020-09-22 中冶武汉冶金建筑研究院有限公司 Siliceous buffering slurry for hot-blast stove buffering seam
CN111689781B (en) * 2020-06-09 2022-08-26 中冶武汉冶金建筑研究院有限公司 Siliceous buffering slurry for hot-blast stove buffering seam

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Application publication date: 20190521