CN107032811A - A kind of coke oven low iron low-aluminum mullite brick and preparation method - Google Patents
A kind of coke oven low iron low-aluminum mullite brick and preparation method Download PDFInfo
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- CN107032811A CN107032811A CN201710368659.6A CN201710368659A CN107032811A CN 107032811 A CN107032811 A CN 107032811A CN 201710368659 A CN201710368659 A CN 201710368659A CN 107032811 A CN107032811 A CN 107032811A
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- calcined kaolin
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- coke oven
- brick
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 239000011449 brick Substances 0.000 title claims abstract description 67
- 229910052863 mullite Inorganic materials 0.000 title claims abstract description 49
- 239000000571 coke Substances 0.000 title claims abstract description 48
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 34
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 82
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 59
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims abstract description 59
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 59
- 239000002994 raw material Substances 0.000 claims abstract description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 229910052570 clay Inorganic materials 0.000 claims abstract description 30
- 239000004927 clay Substances 0.000 claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 238000011068 load Methods 0.000 claims abstract description 13
- 230000001066 destructive Effects 0.000 claims abstract description 12
- 229920000609 methyl cellulose Polymers 0.000 claims abstract description 7
- 239000001923 methylcellulose Substances 0.000 claims abstract description 7
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2R,3R,4S,5R,6S)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2S,3R,4S,5R,6R)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2R,3R,4S,5R,6R)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims abstract description 3
- 238000001035 drying Methods 0.000 claims abstract description 3
- 238000001125 extrusion Methods 0.000 claims abstract description 3
- 229910052903 pyrophyllite Inorganic materials 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 10
- NOTVAPJNGZMVSD-UHFFFAOYSA-N Potassium oxide Chemical compound [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 claims description 9
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 9
- 238000010348 incorporation Methods 0.000 claims description 9
- 229920003063 hydroxymethyl cellulose Polymers 0.000 claims description 8
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 8
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 8
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 8
- 229910000460 iron oxide Inorganic materials 0.000 claims description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 7
- 229920001353 Dextrin Polymers 0.000 claims description 6
- 229940031574 HYDROXYMETHYL CELLULOSE Drugs 0.000 claims description 6
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 4
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 4
- CWSZBVAUYPTXTG-UHFFFAOYSA-N 5-[6-[[3,4-dihydroxy-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxymethyl]-3,4-dihydroxy-5-[4-hydroxy-3-(2-hydroxyethoxy)-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxyoxan-2-yl]oxy-6-(hydroxymethyl)-2-methyloxane-3,4-diol Chemical compound O1C(CO)C(OC)C(O)C(O)C1OCC1C(OC2C(C(O)C(OC)C(CO)O2)OCCO)C(O)C(O)C(OC2C(OC(C)C(O)C2O)CO)O1 CWSZBVAUYPTXTG-UHFFFAOYSA-N 0.000 claims description 2
- 230000036536 Cave Effects 0.000 claims description 2
- FYGDTMLNYKFZSV-MRCIVHHJSA-N Dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 claims description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 2
- 239000011236 particulate material Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 12
- 235000019628 coolness Nutrition 0.000 abstract description 10
- 239000000428 dust Substances 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 238000005187 foaming Methods 0.000 abstract description 3
- 238000001764 infiltration Methods 0.000 abstract description 3
- 230000002159 abnormal effect Effects 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 239000011812 mixed powder Substances 0.000 abstract 1
- 238000001354 calcination Methods 0.000 description 12
- 238000007792 addition Methods 0.000 description 11
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 11
- 229910052622 kaolinite Inorganic materials 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- 239000000377 silicon dioxide Substances 0.000 description 8
- 230000002194 synthesizing Effects 0.000 description 7
- 239000011819 refractory material Substances 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 229910052849 andalusite Inorganic materials 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 238000004939 coking Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229910010271 silicon carbide Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000003723 Smelting Methods 0.000 description 2
- 230000003078 antioxidant Effects 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000007767 bonding agent Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 239000010431 corundum Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 229910052851 sillimanite Inorganic materials 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N Silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N Zirconium(IV) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- INJRKJPEYSAMPD-UHFFFAOYSA-N aluminum;silicic acid;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O INJRKJPEYSAMPD-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 230000001112 coagulant Effects 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001351 cycling Effects 0.000 description 1
- NTGONJLAOZZDJO-UHFFFAOYSA-M disodium;hydroxide Chemical compound [OH-].[Na+].[Na+] NTGONJLAOZZDJO-UHFFFAOYSA-M 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910052850 kyanite Inorganic materials 0.000 description 1
- 239000010443 kyanite Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000000051 modifying Effects 0.000 description 1
- 229910003465 moissanite Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000003638 reducing agent Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229910001929 titanium oxide Inorganic materials 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- 229910052846 zircon Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/66—Monolithic refractories or refractory mortars, including those whether or not containing clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/54—Particle size related information
- C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
- C04B2235/5427—Particle size related information expressed by the size of the particles or aggregates thereof millimeter or submillimeter sized, i.e. larger than 0,1 mm
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/54—Particle size related information
- C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
- C04B2235/5436—Particle size related information expressed by the size of the particles or aggregates thereof micrometer sized, i.e. from 1 to 100 micron
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/72—Products characterised by the absence or the low content of specific components, e.g. alkali metal free alumina ceramics
Abstract
A kind of coke oven is with low iron low-aluminum mullite brick, and its raw material included composition and wt% are：Granularity is more than 1 to≤5mm calcined kaolin clinker：40‑60%；Granularity is more than 0.1mm to≤1mm calcined kaolin clinker：8 ~ 15%, granularity≤0.088mm calcined kaolin clinker fine powder：15~35%；Granularity≤0.088mm clay powders：5~15%；Methylcellulose：0.1‑3%；And added water by the 1 3.5% of above-mentioned raw materials gross weight.Preparation process：By each raw material mixed powder；Add water and be well mixed；Extrusion forming, drying are fired.The present invention can reduce the absorption of dust in coke oven regenerator, infiltration, reaction, it is to avoid deformation, foaming in use, and heat resistanceheat resistant destructive characteristics can be made to recycle number of times under 1000 DEG C of water coolings be not less than 20 times, and refractoriness under load is not less than 1400 DEG C.Through on probation in 7.63 meters of coke ovens, do not occurred over-emitting black exhaust, the abnormal phenomenon of furnace temperature so far.
Description
Technical field
The present invention relates to a kind of metallurgical furnace kiln refractory and preparation method, particularly belong to a kind of for coking industry
Coke oven regenerator refractory material and other regenerator lattice brick refractory materials and preparation method.
Background technology
The usage cycles of coke oven are all longer, even up to upper ten year having.In existing coke oven, coke oven regenerator work
Layer typically uses clay brick, semi-silica brick, silica brick, and it belongs to ripe refractory products.Therefore, people often ignore
Performance and application study to refractory material used in coke oven.In recent years, due to factors such as strengthening smeltings, during the coking of some coke ovens
Between shortened to more than 20 hours.Its coking time is short, it is meant that cold cycling time increase, thus cause destruction to furnace lining also with
Aggravation.Such as 7.63 meters of coke oven of Wuhan Iron and Steel Plant, in the maintenance carried out to it（In production）It was found that refractory material goes wrong, i.e.,
There is deformation, blocked checkerwork cell, adhesion, the phenomenon of softening in checker brick, cause regenerator to exchange heat not enough, coke-pushing process occurs emitting black
Cigarette, the coke phenomenon such as wilfully.Through analyzing reason, the change of raw material, use environment with refractory material selection has compared with substantial connection.
Such as clay brick, semi-silica brick, when being prepared using the raw clay in Henan, because its sodium containing potassium is high, also in the clay pit in Shanxi
Containing higher titanium oxide, the impurity in this clay is also higher, and fine powder amount is on the high side, to prepared clay brick, semi-silica brick
High-temperature behavior has an impact.
How the refractory product for adapting to coke oven production is prepared from suitable raw material, be that those skilled in the art are closed
Note, it is of concern more in the refractory material used in blast furnace through retrieval, and constantly carry out innovation.As through retrieval：
Document number is CN201310651732.2 Chinese patent, and it discloses one kind《Blast furnace impermeabilisation low-aluminum mullite brick
And preparation method thereof》, play raw material composition：Granularity is 5-3mm 10-15 parts of mullite synthesizing, and granularity is not come for 3-1mm synthesis
25-30 parts of stone, granularity is≤1mm 20-30 part of mullite synthesizing, and granularity is 0.074mm 15-30 parts of andalusite, clay
0.074mm5-10 parts, promote to burn 3-5 parts of agent, 3-4 parts of bonding agent.Though the document has low-porosity, low impurity, high intensity, high temperature
Performance is good, and intensity is high, and corrosion resistance is strong, can holding structure stably, can improve height under high-temperature load for a long time on blast furnace
The service life of stove.But because the document uses mullite synthesizing raw material, and use excessive andalusite, and andalusite
Alumina content it is high, be such as used for coke oven, then due to coke oven can be reducing atmosphere and be not suitable for for high S flue gases environment, moreover
Cost is also high.
Document number is CN201310655250.4 Chinese patent, discloses one kind《Anti-erosion mullite brick for blast furnace and
Its preparation method》, its mullite brick is prepared from the following raw materials in parts by weight：Granularity is 3-1mm 15-30 parts of electro-corundum,
Granularity is 3-1mm 12-28 parts of mullite synthesizing, and 20-28 parts of granularity ＜ 1mm electro-corundum, granularity is 0.074mm electric smelting
10-20 parts of corundum, granularity is 0.21-0.12mm 3-6 parts of crystobalite, and granularity is≤5 μm of 8-10 parts of Alpha-alumina, and granularity is
4-6 parts of 0.074mm clay, 3-5 parts of bonding agent.Though the product of the document has low-porosity, low impurity, high intensity, high temperature
The characteristics of performance is good, and the features such as good anti-erosion, strong ability to resist penetration, but due to it using substantial amounts of corundum, Mo Lai
Stone raw material, is such as used for coke oven, and not only cost is high, and more importantly its heat resistanceheat resistant destructive characteristics is poor, therefore is not suitable for the work of coke oven
Make environment.
Document number is CN201210266706.3 Chinese patent, discloses one kind《High-strength high thermal shock low aluminum-containing mullite
Brick》, the component composition of its mullite brick：Fused mullite 15~50%, electrofused mullite 5~15%, superfine flint clay 10~
40%, sillimanite 10~30%, andalusite 10~30%, activated alumina 2~10%, zircon 2~15%, silica 2~12% and knot
Close clay 3~10%.Document product, though with higher refractoriness under load（≥1550℃）, heated volume stability, compared with
High thermal shock resistance（Water cooling 1100 DEG C >=50）, relatively low creep rate（20~50h≤0.15）, and excellent compressive resistance（≥
70Mpa）, and the advantages of good under high temperature volume stability and low impurity, but it still uses mullite synthesizing raw material,
And added with two kinds of electric smelting and sintering, its not only cost it is high, more importantly it use sillimanite, andalusite, both are former
The aluminum oxide of material is high；Due also to having used zirconium oxide, it can cause to exchange heat in the reducing atmosphere of coke oven, repeatedly coke pushing and regenerator
Damage is frequently easily caused in handoff procedure.
Document number is CN201210542032.5 Chinese patent, is disclosed《A kind of mullite lightweight thermal insulation brick and its system
Preparation Method》, its elder generation is with 30 ~ 40wt% flint clays clinker, 20 ~ 30wt% grogs, 20 ~ 32wt% kyanites micro mists, 2 ~ 8wt%
The light-burned calcium oxide of ρ-alumina powder, 1 ~ 6wt% and 0.5 ~ 2wt% fine silica powders are raw material, additional 10 ~ 20wt% of raw material water
With 0.5 ~ 2wt% water reducers, hybrid modulation is into slurry.The foam that additional 0.1 ~ 0.5wt% of raw material foaming agents are made again, stirring, so
Additional 0.5 ~ 2wt% of raw material gels, 0.1 ~ 1wt% thermosettings water-soluble high-molecular compound and 0.5 ~ 2.5wt% coagulant afterwards,
Stirring, moulding by casting.It is last to be stripped in 30 ~ 50 DEG C of dry 4 ~ 9h, 10 ~ 20h are toasted at 60 ~ 120 DEG C, in 1350 ~ 1500 DEG C of guarantors
3 ~ 12h of temperature, is made mullite lightweight thermal insulation brick.The features such as though technology demoulding is fast, arid cycle is short and environment-friendly, due to
Added with more kyanite micro mist, described product dilation can be caused big, it is impossible to be used in do the regenerator grid of coke oven
Brick.
Document number is CN201310171229.7 Chinese patent, is disclosed《A kind of Novel mullite brick and its preparation side
Method》, its raw material composition：10~15 parts of the fused mullite of 45~60 parts of aggregate, wherein 0~1mm of granularity, 1~3mm's of granularity
15~20 parts of fused mullite, 20~25 parts of 3~5mm of granularity fused mullite, the chemical composition quality hundred of fused mullite
Point ratio is：Mullite phase 80~90%, Fe2O3 ＜ 0.8%, K2O+Na2O ＜ 0.3%；37~45 parts of powder, granularity ＜ 0.074mm
30~35 parts of fused mullite, 7~10 parts of granularity ＜ 0.074mm carborundum, the chemical composition mass percent of carborundum
For：SiC ＞ 97%；3~5 parts of antioxidant, antioxidant is that metallic aluminium powder is more equal than mixing by 1~2: 1 weight with metallic silicon power
It is even, its particle mean size ＜ 0.05mm；4~5 parts of new junction agent.The product is as being used in coke oven atmosphere, due to its addition
Plus silicon carbide, it is difficult to ensure that coke oven requirement dust is adsorbed less, expansion and shrinkage deformation is small under conditions of rapid heat cycle, and regenerator has
When string wind tempering and cause the high condition of temperature.
Found from above-mentioned literature search result, clay brick that current similar 7.63 meters of coke ovens are used, semi-silica brick are due to height
Pure raw material limited source, the aggregate pressure brick of vast scale causes the profile of brick to control difficulty, and mullite brick cost is high, mullite synthesizing
Many process procedures are needed, therefore the present invention is using high-quality coal measures height iron, the low aluminum-containing mullite of low alkali metal content
Brick, this formula and the product price constituted are low, and better performances can meet the use needs of coke oven regenerator clay brick, by
In its excellent physicochemical property so that it also disclosure satisfy that in the case where regenerator furnace wall Local Cracking produces a small amount of string fire
The demand of coking production.
The content of the invention
It is an object of the invention to overcome deficiency present in above-mentioned document to be reduced there is provided one kind in coke oven regenerator
Absorption, infiltration, the reaction of dust, it is to avoid deformation, foaming in use, and prepared brick heat resistanceheat resistant destructive characteristics can be made 1000
Under DEG C water cooling, recycle number of times and be not less than 20 times, refractoriness under load is not less than 1400 DEG C, and 7 meter of 63 coke oven can be met will
The low iron low-aluminum mullite brick and preparation method asked.
Realize the measure of above-mentioned purpose：
A kind of coke oven is with low iron low-aluminum mullite brick, and its raw material included composition and weight percent content are：Granularity be more than 1 to
≤ 5mm calcined kaolin clinker：40-60%；Granularity is more than 0.1mm to≤1mm calcined kaolin clinker：8 ~ 15%, granularity
≤ 0.088mm calcined kaolin clinker fine powder：15~35%；Granularity≤0.088mm clay powders：5~15%；Bonding agent-methyl is fine
Dimension element：0.1-3%；And add water according to the 1-3.5 % of above-mentioned raw materials total amount；And control in total raw material：Potassium oxide and sodium oxide molybdena are total
Total amount≤1.2% of amount≤0.8%, metallic iron and iron oxide；The performance of the mullite brick：Heat resistanceheat resistant destructive characteristics are in 1000 DEG C of water
SAPMAC method number of times is no less than 20 times, and its refractoriness under load is not less than 1400 DEG C.
Preferably：Pyrophyllite powder added with granularity ＜ 0.088mm is no more than 15wt%.
It is：The methylcellulose is hydroxymethyl cellulose or hydroxyethyl cellulose or dextrine powder.
Preferably：In the calcined kaolin clinker fine powder of the granularity≤0.088mm, granularity ＜ 0.01mm calcining is high
Ridge soil clinker fine powder accounts for its percentage by weight:3~8%.
Prepare a kind of method of coke oven with low iron low-aluminum mullite brick, its step：
1）First by particulate material, i.e.,：Granularity is more than 1 to≤5mm calcined kaolin clinker：40-60%；Granularity is more than 0.1mm extremely
≤ 1mm calcined kaolin clinker：8 ~ 15%, granularity≤0.088mm calcined kaolin clinker fine powder：15~35%；Granularity≤
0.088mm clay powders：5 ~ 15%, bonding agent-methylcellulose：0.1-3% is stirred mixing, including adds granularity ＜
0.088mm pyrophyllite powder is no more than 15wt%；Incorporation time is controlled in 5 ~ 20min；
2）1-3.5% according to above-mentioned raw materials total amount adds water and is uniformly mixed；
3）Extrusion forming, brick blank drying, then burn till in tunnel cave or other high temperature kilns on brick machine.
The mechanism and effect of each raw material and main technique in the present invention
Granularity is more than 1 to≤5mm calcined kaolin clinker：In the present invention, its addition why is limited in 40-60%,
It is due to that, such as less than 40%, the main aggregate of brick is easily deformed, softening is collapsed in use very little；Such as it is higher than 60%, then due to particle too
It is many, cause difficult forming, especially in the corner of checkerwork cell, the hardly possible shaping of circular arc shape.
Granularity is more than 0.1mm to≤1mm calcined kaolin clinker：In the present invention, its addition why is limited 8
~ 15%, it is due to that, such as less than 8%, the fine aggregate of brick is inadequate, it is difficult to reach consistency；Such as it is higher than 15%, then due to more than middle particle
It is unfavorable for the formation of consistency structure.
Granularity≤0.088mm calcined kaolin clinker fine powder：In the present invention, why limit its addition 15 ~
35%, and require that granularity ＜ 0.01mm calcined kaolin clinker fine powder accounts for its percentage by weight:3 ~ 8%, be due to such as less than
15%, the fine powder of brick very little, is unfavorable for matrix sintering；Such as it is higher than 35%, fine powder is too many, and checker brick are easily deformed contraction；Wherein grain
＜ 0.01mm superfine powder is spent as being less than 3%, is not had agglomeration, is such as higher than 8%, cost is higher.
Granularity≤0.088mm clay powders：In the present invention, why limit its addition 5 ~ 15%, be due to such as less than
5%, the plasticity of brick is poor, and processability is bad；Such as it is higher than 15%, the easy contraction distortion of checker brick green compact.
Bonding agent-methylcellulose：In the present invention, why limit its addition in 0.1-3%, be due to such as less than
0.1%, the bond strength of brick is low；Such as it is higher than 3%, checker brick stomata can be made many.
Why granularity ＜ 0.088mm pyrophyllite powder, in the present invention, limit its addition no more than 15wt%, be
Because the pyrophillite mineral reserve of pyrophillite resource-constrained, especially high-quality are seldom, while can have an impact to cost；For another example it is higher than
15%, impurity can be caused high and be difficult to control, therefore excessive pyrophillite should not be used.
The incorporation time why present invention requires added raw material, at 5-20 minutes, is due to that batch mixing was not less than 5 minutes
Uniformly, excessive batch mixing, i.e., more than 20 minutes, easily cause particle second-time breakage, make Task-size Controlling bad again.
The present invention compared with prior art, its absorption that can reduce dust in coke oven regenerator, infiltration, react, it is to avoid
Deformation, foaming in use, and prepared brick heat resistanceheat resistant destructive characteristics can be made under 1000 DEG C of water coolings, recycle number of times not low
In 20 times, refractoriness under load is not less than 1400 DEG C, and can meet 7. 63 meters of coke oven requirements.The product of development is in 7.63 meters of Jiao
Stove has been changed how empty regenerator and used, and does not occur over-emitting black exhaust, the abnormal phenomenon of furnace temperature, the use longevity of regenerator lattice brick so far
Common brick, semi-silica brick of the life at least than using in the past improve more than 1 year life-span.
Embodiment
The present invention is described in detail below：
Embodiment 1：
A kind of coke oven is with low iron low-aluminum mullite brick, and its raw material included composition and weight percent content are：Granularity be more than 1 to
≤ 5mm calcined kaolin clinker：40%；Granularity is more than 0.1mm to≤1mm calcined kaolin clinker：15%, granularity≤
0.088mm calcined kaolin clinker fine powder：35%, wherein, granularity ＜ 0.01mm calcined kaolin clinker fine powder accounts for 8%；Grain
Degree≤0.088mm clay powders：9.5%；Bonding agent-first hydroxymethyl cellulose 0.5%；And according to 2% outer addition of above-mentioned raw materials total amount
Water；In total raw material：Potassium oxide and sodium oxide molybdena total amount are 0.7%, the total amount position 1.0% of metallic iron and iron oxide；
Preparation process：
1）Granularity is first more than to 1 to≤5mm calcined kaolin clinker：40%；Granularity is more than 0.1mm to≤1mm calcining kaolinite
Native clinker：15%, granularity≤0.088mm calcined kaolin clinker fine powder：35%, wherein, granularity ＜ 0.01mm calcining kaolinite
Native clinker fine powder accounts for 8%；Granularity≤0.088mm clay powders：9.5%；Bonding agent-first hydroxymethyl cellulose 0.5% is stirred mixed
Close, incorporation time is in 20min；
2）2% according to above-mentioned raw materials total amount adds water and is uniformly mixed outside；
3）It is conventional to be press-formed, dry and fire on forming machine.
After testing, prepared coke oven is with low iron low-aluminum mullite brick, and its heat resistanceheat resistant destructive characteristics is in 1000 DEG C of water cooling conditions
Under, cycle-index is 30 times, and refractoriness under load is at 1430 DEG C.
Embodiment 2：
A kind of coke oven is with low iron low-aluminum mullite brick, and its raw material included composition and weight percent content are：Granularity be more than 1 to
≤ 5mm calcined kaolin clinker：60%；Granularity is more than 0.1mm to≤1mm calcined kaolin clinker：8%, granularity≤
0.088mm calcined kaolin clinker fine powder：21.9%, wherein, granularity ＜ 0.01mm calcined kaolin clinker fine powder accounts for 5%；
Granularity≤0.088mm clay powders 5%；Bonding agent-first hydroxymethyl cellulose 0.1%, granularity ＜ 0.088mm pyrophyllite powder 5%；And
According to 3% outer addition water of above-mentioned raw materials total amount；In total raw material：Potassium oxide and sodium oxide molybdena total amount are 0.59%, metallic iron and oxidation
The total amount position 0.8% of iron；
Preparation process：
1）Granularity is first more than to 1 to≤5mm calcined kaolin clinker：60%；Granularity is more than 0.1mm to≤1mm calcining kaolinite
Native clinker：8%, granularity≤0.088mm calcined kaolin clinker fine powder：21.9%, wherein, granularity ＜ 0.01mm calcining kaolinite
Native clinker fine powder accounts for 5%；Granularity≤0.088mm clay powders 5%；Bonding agent-first hydroxymethyl cellulose 0.1%, granularity ＜ 0.088mm
Pyrophyllite powder 5% be stirred mixing, incorporation time is in 18min；
2）3% according to above-mentioned raw materials total amount adds water and is uniformly mixed outside；
3）It is conventional to be press-formed, dry and fire on forming machine.
After testing, prepared coke oven is with low iron low-aluminum mullite brick, and its heat resistanceheat resistant destructive characteristics is in 1000 DEG C of water cooling conditions
Under, cycle-index is 25 times, and refractoriness under load is at 1460 DEG C.
Embodiment 3：
A kind of coke oven is with low iron low-aluminum mullite brick, and its raw material included composition and weight percent content are：Granularity be more than 1 to
≤ 5mm calcined kaolin clinker：48%；Granularity is more than 0.1mm to≤1mm calcined kaolin clinker：12%, granularity≤
0.088mm calcined kaolin clinker fine powder：15%, wherein, granularity ＜ 0.01mm calcined kaolin clinker fine powder accounts for 3%；Grain
Degree≤0.088mm clay powders 7%；Bonding agent-dextrine powder 3%, granularity ＜ 0.088mm pyrophyllite powder 15%；And according to above-mentioned raw materials
The 1% of total amount is outer to add water；In total raw material：Potassium oxide and sodium oxide molybdena total amount are 0.5%, the total amount position of metallic iron and iron oxide
0.88%；
Preparation process：
1）Granularity is first more than to 1 to≤5mm calcined kaolin clinker：48%；Granularity is more than 0.1mm to≤1mm calcining kaolinite
Native clinker：12%, granularity≤0.088mm calcined kaolin clinker fine powder：15%, wherein, granularity ＜ 0.01mm calcining kaolinite
Native clinker fine powder accounts for 3%；Granularity≤0.088mm clay powders 7%；Bonding agent-dextrine powder 3%, granularity ＜ 0.088mm pyrophyllite powder
15% is stirred mixing, and incorporation time is in 19min；
2）1% according to above-mentioned raw materials total amount adds water and is uniformly mixed outside；
3）It is conventional to be press-formed, dry and fire on forming machine.
After testing, prepared coke oven is with low iron low-aluminum mullite brick, and its heat resistanceheat resistant destructive characteristics is in 1000 DEG C of water cooling conditions
Under, cycle-index is 28 times, and refractoriness under load is at 1435 DEG C.
Embodiment 4：
A kind of coke oven is with low iron low-aluminum mullite brick, and its raw material included composition and weight percent content are：Granularity be more than 1 to
≤ 5mm calcined kaolin clinker：55%；Granularity is more than 0.1mm to≤1mm calcined kaolin clinker：10%, granularity≤
0.088mm calcined kaolin clinker fine powder：20%, wherein, granularity ＜ 0.01mm calcined kaolin clinker fine powder accounts for 8%；Grain
Degree≤0.088mm clay powders 6%；Bonding agent-hydroxyethyl cellulose 1%, granularity ＜ 0.088mm pyrophyllite powder 8%；And according to upper
State 3.5% outer addition water of raw material total amount；In total raw material：Potassium oxide and sodium oxide molybdena total amount are 0.52%, metallic iron and iron oxide
Total amount position 0.8%；
Preparation process：
1）Granularity is first more than to 1 to≤5mm calcined kaolin clinker：55%；Granularity is more than 0.1mm to≤1mm calcining kaolinite
Native clinker：10%, granularity≤0.088mm calcined kaolin clinker fine powder：20%, wherein, granularity ＜ 0.01mm calcining kaolinite
Native clinker fine powder accounts for 8%；Granularity≤0.088mm clay powders 6%；Bonding agent-hydroxyethyl cellulose 1%, granularity ＜ 0.088mm leaf
Cured stone powder 8% is stirred mixing, and incorporation time is in 12min；
2）3.5% according to above-mentioned raw materials total amount adds water and is uniformly mixed outside；
3）It is conventional to be press-formed, dry and fire on forming machine.
After testing, prepared coke oven is with low iron low-aluminum mullite brick, and its heat resistanceheat resistant destructive characteristics is in 1000 DEG C of water cooling conditions
Under, cycle-index is 37 times, and refractoriness under load is at 1450 DEG C.
Embodiment 5：
A kind of coke oven is with low iron low-aluminum mullite brick, and its raw material included composition and weight percent content are：Granularity be more than 1 to
≤ 5mm calcined kaolin clinker：52%；Granularity is more than 0.1mm to≤1mm calcined kaolin clinker：9%, granularity≤
0.088mm calcined kaolin clinker fine powder：25%, wherein, granularity ＜ 0.01mm calcined kaolin clinker fine powder accounts for 5%；Grain
Degree≤0.088mm clay powders 7.5%；Bonding agent-hydroxymethyl cellulose 1.5%, granularity ＜ 0.088mm pyrophyllite powder 5%；And press
According to 2.5% outer addition water of above-mentioned raw materials total amount；In total raw material：Potassium oxide and sodium oxide molybdena total amount are 0.7%, metallic iron and iron oxide
Total amount position 1.1%；
Preparation process：
1）Granularity is first more than to 1 to≤5mm calcined kaolin clinker：52%；Granularity is more than 0.1mm to≤1mm calcining kaolinite
Native clinker：9%, granularity≤0.088mm calcined kaolin clinker fine powder：25%, wherein, granularity ＜ 0.01mm calcined kaolin
Clinker fine powder accounts for 5%；Granularity≤0.088mm clay powders 7.5%；Bonding agent-hydroxymethyl cellulose 1.5%, granularity ＜ 0.088mm's
Pyrophyllite powder 5% is stirred mixing, and incorporation time is in 9min；
2）2.5% according to above-mentioned raw materials total amount adds water and is uniformly mixed outside；
3）It is conventional to be press-formed, dry and fire on forming machine.
After testing, prepared coke oven is with low iron low-aluminum mullite brick, and its heat resistanceheat resistant destructive characteristics is in 1000 DEG C of water cooling conditions
Under, cycle-index is 28 times, and refractoriness under load is at 1455 DEG C.
Embodiment 6：
A kind of coke oven is with low iron low-aluminum mullite brick, and its raw material included composition and weight percent content are：Granularity be more than 1 to
≤ 5mm calcined kaolin clinker：45%；Granularity is more than 0.1mm to≤1mm calcined kaolin clinker：13%, granularity≤
0.088mm calcined kaolin clinker fine powder：26%, wherein, granularity ＜ 0.01mm calcined kaolin clinker fine powder accounts for 7%；Grain
Degree≤0.088mm clay powders 11%；Bonding agent-dextrine powder 1%, granularity ＜ 0.088mm pyrophyllite powder 4%；And according to above-mentioned raw materials
The 2.2% of total amount is outer to add water；In total raw material：Potassium oxide and sodium oxide molybdena total amount are 0.6%, the total amount position of metallic iron and iron oxide
0.75%；
Preparation process：
1）Granularity is first more than to 1 to≤5mm calcined kaolin clinker：45%；Granularity is more than 0.1mm to≤1mm calcining kaolinite
Native clinker：13%, granularity≤0.088mm calcined kaolin clinker fine powder：26%, wherein, granularity ＜ 0.01mm calcining kaolinite
Native clinker fine powder accounts for 7%；Granularity≤0.088mm clay powders 11%；Bonding agent-dextrine powder 1%, granularity ＜ 0.088mm pyrophyllite powder
4% is stirred mixing, and incorporation time is in 14min；
2）2.2% according to above-mentioned raw materials total amount adds water and is uniformly mixed outside；
3）It is conventional to be press-formed, dry and fire on forming machine.
After testing, prepared coke oven is with low iron low-aluminum mullite brick, and its heat resistanceheat resistant destructive characteristics is in 1000 DEG C of water cooling conditions
Under, cycle-index is 30 times, and refractoriness under load is at 1455 DEG C.
Above-described embodiment use of 17 months, it is still intact, still it is being continuing with.
Above-described embodiment is only most preferably to enumerate, and is not the restriction to embodiments of the present invention.
Claims (5)
1. a kind of coke oven is with low iron low-aluminum mullite brick, its raw material included composition and weight percent content：Granularity is more than 1
Extremely≤5mm calcined kaolin clinker：40-60%；Granularity is more than 0.1mm to≤1mm calcined kaolin clinker：8 ~ 15%, grain
Degree≤0.088mm calcined kaolin clinker fine powder：15~35%；Granularity≤0.088mm clay powders：5~15%；Bonding agent-methyl
Cellulose：0.1-3%；And add water according to the 1-3.5 % of above-mentioned raw materials total amount；And control in total raw material：Potassium oxide and sodium oxide molybdena
Total amount≤1.2% of total amount≤0.8%, metallic iron and iron oxide；The performance of the mullite brick：Heat resistanceheat resistant destructive characteristics are at 1000 DEG C
Water-cooling circulating number of times is no less than 20 times, and its refractoriness under load is not less than 1400 DEG C.
2. a kind of coke oven as claimed in claim 1 is with low iron low-aluminum mullite brick, it is characterised in that：Added with granularity ＜
0.088mm pyrophyllite powder is no more than 15wt%.
3. a kind of coke oven as claimed in claim 1 is with low iron low-aluminum mullite brick, it is characterised in that：The methylcellulose is
Hydroxymethyl cellulose or hydroxyethyl cellulose or dextrine powder.
4. a kind of coke oven as claimed in claim 1 is with low iron low-aluminum mullite brick, it is characterised in that：The granularity≤
In 0.088mm calcined kaolin clinker fine powder, granularity ＜ 0.01mm calcined kaolin clinker fine powder accounts for its percentage by weight
's:3~8%.
5. prepare a kind of coke oven method of low iron low-aluminum mullite brick as claimed in claim 1, its step：
First by particulate material, i.e.,：Granularity is more than 1 to≤5mm calcined kaolin clinker：40-60%；Granularity be more than 0.1mm to≤
1mm calcined kaolin clinker：8 ~ 15%, granularity≤0.088mm calcined kaolin clinker fine powder：15~35%；Granularity≤
0.088mm clay powders：5 ~ 15%, bonding agent-methylcellulose：0.1-3% is stirred mixing, including adds granularity ＜
0.088mm pyrophyllite powder is no more than 15wt%；Incorporation time is controlled in 5 ~ 20min；
1-3.5% according to above-mentioned raw materials total amount adds water and is uniformly mixed；
3）Extrusion forming, brick blank drying, then burn till in tunnel cave or other high temperature kilns on brick machine.
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| CN108753316A (en) * | 2018-05-18 | 2018-11-06 | 武汉钢铁有限公司 | A kind of compound masonry construction of coke oven regenerator checker brick |
| CN111574191A (en) * | 2020-05-25 | 2020-08-25 | 郑州宏瑞耐火材料有限公司 | Semi-silica brick for multi-electrode magnesium electrolytic cell and preparation process thereof |
| CN112341177A (en) * | 2020-09-28 | 2021-02-09 | 山东耐材集团鲁耐窑业有限公司 | Corrosion-resistant compact lattice brick for upper part of coke oven regenerator and preparation method thereof |
| CN115286404A (en) * | 2022-08-23 | 2022-11-04 | 宜兴瑞泰耐火材料有限公司 | Low-aluminum mullite castable for molybdenum-containing waste liquid incinerator and preparation method thereof |
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| CN111574191A (en) * | 2020-05-25 | 2020-08-25 | 郑州宏瑞耐火材料有限公司 | Semi-silica brick for multi-electrode magnesium electrolytic cell and preparation process thereof |
| CN112341177A (en) * | 2020-09-28 | 2021-02-09 | 山东耐材集团鲁耐窑业有限公司 | Corrosion-resistant compact lattice brick for upper part of coke oven regenerator and preparation method thereof |
| CN115286404A (en) * | 2022-08-23 | 2022-11-04 | 宜兴瑞泰耐火材料有限公司 | Low-aluminum mullite castable for molybdenum-containing waste liquid incinerator and preparation method thereof |
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