CN109762329A - 一种抗静电、耐高温黄变阻燃尼龙复合材料及其制备方法 - Google Patents
一种抗静电、耐高温黄变阻燃尼龙复合材料及其制备方法 Download PDFInfo
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- CN109762329A CN109762329A CN201811530031.2A CN201811530031A CN109762329A CN 109762329 A CN109762329 A CN 109762329A CN 201811530031 A CN201811530031 A CN 201811530031A CN 109762329 A CN109762329 A CN 109762329A
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- 239000004677 Nylon Substances 0.000 title claims abstract description 35
- 229920001778 nylon Polymers 0.000 title claims abstract description 35
- 238000004383 yellowing Methods 0.000 title claims abstract description 33
- 239000002131 composite material Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000004952 Polyamide Substances 0.000 claims abstract description 31
- 229920002647 polyamide Polymers 0.000 claims abstract description 31
- -1 phosphate compound Chemical class 0.000 claims abstract description 28
- 150000001875 compounds Chemical class 0.000 claims abstract description 16
- 239000004615 ingredient Substances 0.000 claims abstract description 15
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 10
- 150000001879 copper Chemical class 0.000 claims abstract description 10
- 150000002989 phenols Chemical class 0.000 claims abstract description 10
- 239000010452 phosphate Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 5
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- 125000002843 carboxylic acid group Chemical group 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 35
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 6
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 claims description 6
- 230000001737 promoting effect Effects 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 229910000403 monosodium phosphate Inorganic materials 0.000 claims description 3
- 235000019799 monosodium phosphate Nutrition 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 3
- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical class OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 claims description 2
- PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 claims description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 2
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 150000004985 diamines Chemical class 0.000 claims description 2
- 235000019700 dicalcium phosphate Nutrition 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 claims 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims 1
- 150000003016 phosphoric acids Chemical class 0.000 claims 1
- 150000004671 saturated fatty acids Chemical class 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 235000003441 saturated fatty acids Nutrition 0.000 abstract description 2
- 239000002216 antistatic agent Substances 0.000 description 14
- 230000000694 effects Effects 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000003381 stabilizer Substances 0.000 description 6
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- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
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- 229920001223 polyethylene glycol Polymers 0.000 description 2
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- 238000012360 testing method Methods 0.000 description 2
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 description 1
- DGZQEAKNZXNTNL-UHFFFAOYSA-N 1-bromo-4-butan-2-ylbenzene Chemical class CCC(C)C1=CC=C(Br)C=C1 DGZQEAKNZXNTNL-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
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- 150000001412 amines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000011231 conductive filler Substances 0.000 description 1
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- 235000014113 dietary fatty acids Nutrition 0.000 description 1
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- 239000012467 final product Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
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- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- HHJJPFYGIRKQOM-UHFFFAOYSA-N sodium;oxido-oxo-phenylphosphanium Chemical group [Na+].[O-][P+](=O)C1=CC=CC=C1 HHJJPFYGIRKQOM-UHFFFAOYSA-N 0.000 description 1
- 230000001550 time effect Effects 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
性能 | 实施例1 | 实施例2 | 实施例3 | 对比例1 | 对比例2 |
表面电阻<sup>1#</sup> | 10<sup>7~8</sup> | 10<sup>7~8</sup> | 10<sup>7~8</sup> | 10<sup>10~11</sup> | 10<sup>9~10</sup> |
表面电阻<sup>2#</sup> | 10<sup>7~8</sup> | 10<sup>7~8</sup> | 10<sup>7~8</sup> | 10<sup>9~10</sup> | 10<sup>8~9</sup> |
高温黄变<sup>3#</sup> | 1.8 | 1.2 | 1.4 | 16.7 | 2.1 |
灼热丝阻燃(960℃,1.0mm) | ≤20s | ≤20s | ≤20s | ≤20s | ≤20s |
Claims (10)
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CN201811530031.2A CN109762329B (zh) | 2018-12-14 | 2018-12-14 | 一种抗静电、耐高温黄变阻燃尼龙复合材料及其制备方法 |
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Citations (9)
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DE102004054390A1 (de) * | 2004-11-11 | 2006-05-18 | Rehau Ag + Co | Kupplungsleitung |
CN101298517A (zh) * | 2007-05-03 | 2008-11-05 | Ems专利股份公司 | 半芳族聚酰胺模塑组合物及其用途 |
CN102449028A (zh) * | 2009-05-28 | 2012-05-09 | 三菱瓦斯化学株式会社 | 聚酰胺树脂 |
CN102459444A (zh) * | 2009-06-05 | 2012-05-16 | Ems专利股份公司 | 阻燃半芳族聚酰胺模塑组合物 |
CN102964674A (zh) * | 2011-09-01 | 2013-03-13 | 合肥杰事杰新材料股份有限公司 | 一种超高韧性阻燃聚丙烯复合材料及其制备方法 |
CN103183957A (zh) * | 2011-12-29 | 2013-07-03 | 第一毛织株式会社 | 具有包括薄壁成型性的改进物理性能的聚酰胺树脂组合物 |
CN103354825A (zh) * | 2010-12-21 | 2013-10-16 | 巴斯夫欧洲公司 | 热塑性模塑组合物 |
CN106117813A (zh) * | 2016-09-05 | 2016-11-16 | 李锦明 | 一种用于电池密封圈的改性尼龙 |
CN108165002A (zh) * | 2017-12-25 | 2018-06-15 | 江苏金发科技新材料有限公司 | Mca阻燃尼龙66复合材料及其制备方法 |
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- 2018-12-14 CN CN201811530031.2A patent/CN109762329B/zh active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004054390A1 (de) * | 2004-11-11 | 2006-05-18 | Rehau Ag + Co | Kupplungsleitung |
CN101298517A (zh) * | 2007-05-03 | 2008-11-05 | Ems专利股份公司 | 半芳族聚酰胺模塑组合物及其用途 |
CN102449028A (zh) * | 2009-05-28 | 2012-05-09 | 三菱瓦斯化学株式会社 | 聚酰胺树脂 |
CN102459444A (zh) * | 2009-06-05 | 2012-05-16 | Ems专利股份公司 | 阻燃半芳族聚酰胺模塑组合物 |
CN103354825A (zh) * | 2010-12-21 | 2013-10-16 | 巴斯夫欧洲公司 | 热塑性模塑组合物 |
CN102964674A (zh) * | 2011-09-01 | 2013-03-13 | 合肥杰事杰新材料股份有限公司 | 一种超高韧性阻燃聚丙烯复合材料及其制备方法 |
CN103183957A (zh) * | 2011-12-29 | 2013-07-03 | 第一毛织株式会社 | 具有包括薄壁成型性的改进物理性能的聚酰胺树脂组合物 |
CN106117813A (zh) * | 2016-09-05 | 2016-11-16 | 李锦明 | 一种用于电池密封圈的改性尼龙 |
CN108165002A (zh) * | 2017-12-25 | 2018-06-15 | 江苏金发科技新材料有限公司 | Mca阻燃尼龙66复合材料及其制备方法 |
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Address after: No. 380 Kangyuan Road, Zhujiajiao Town, Qingpu District, Shanghai, 201706 Patentee after: CGN JUNER (SHANGHAI) NEW MATERIALS Co.,Ltd. Country or region after: China Patentee after: CGN JUNER NEW MATERIALS Co.,Ltd. Address before: No.60, Gaoyi Road, Puzhou street, Longwan District, Wenzhou City, Zhejiang Province, 325011 Patentee before: CGN JUNER NEW MATERIALS Co.,Ltd. Country or region before: China Patentee before: CGN JUNER (SHANGHAI) NEW MATERIALS Co.,Ltd. |