CN109706004A - A kind of anti-mite washing powder - Google Patents

A kind of anti-mite washing powder Download PDF

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Publication number
CN109706004A
CN109706004A CN201711005895.8A CN201711005895A CN109706004A CN 109706004 A CN109706004 A CN 109706004A CN 201711005895 A CN201711005895 A CN 201711005895A CN 109706004 A CN109706004 A CN 109706004A
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CN
China
Prior art keywords
mite
washing powder
agent
activator
hydrogen peroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711005895.8A
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Chinese (zh)
Inventor
任九庆
王泽云
芦红
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NANFENG CHEMICAL GROUP CO Ltd
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NANFENG CHEMICAL GROUP CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NANFENG CHEMICAL GROUP CO Ltd filed Critical NANFENG CHEMICAL GROUP CO Ltd
Priority to CN201711005895.8A priority Critical patent/CN109706004A/en
Publication of CN109706004A publication Critical patent/CN109706004A/en
Pending legal-status Critical Current

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Abstract

The present invention relates to the formulas and production method of a kind of anti-mite washing powder, be composed of the following raw materials in parts by weight: washing powder 80-90%(is by anionic surfactant, nonionic surfactant, soda ash, sodium silicate, acrylate copolymer, 4A zeolite, brightening agent, essence, anhydrous sodium sulphate etc. at being grouped as), anti-mite agent 10-20%(Solid hydrogen peroxide 80-90%, activator 10-20%).Anti-mite washing powder prepared by the present invention, strong detergency, dissolubility be good, easy rinsing, meanwhile, fast decoupled coloured soils efficiently remove the acarid on fabric, washing powder are made to have multiple functions, fill up this domestic and international product blank.

Description

A kind of anti-mite washing powder
Technical field
The invention belongs to field of daily chemicals, and in particular to a kind of anti-mite washing powder.
Background technique
Acarid is the extremely harmful biology of a kind of pair of human health, its energy transmitted virus, bacterium, and the heat that can cause bleeding, A variety of diseases such as dermatitis, epifolliculitis, scabies.It is monitored according to relevant department, the mite class survived in the home environment of China city is shared As many as 16 kinds, acarid is distributed at most in carpet, is secondly cotton-wadded quilt, mattress, pillow, sofa etc..Flour mite and dust mite, which are used as, deposits It is most important two big mite class in family room, many kinds of, incredible amount is even more to endanger seriously to human health.
In room in the environment of mild and moist, occupying indoor acarid is one of primary pathogenic event of allergic patients.These Visually see less than tiny insect, people life place it is ubiquitous.The epidermis that they rely on human skin to fall off It makes a living.Meanwhile excreta enters human respiratory tract eventually as dust into air and by breathing, many people arrange acarid Letting out object has allergic reaction, such as strong sneezing and unsmooth breath.
Common anti-mite agent currently on the market mostly contains chlorbenside bacterium insecticide and the dedicated anti-mite agent of agricultural, smell compare thorn Swash, it is bad with washing powder compatibility, there is unsafe factor in use, such as three chlorbenside spirits, fenpyroximate, the third bromine Lian Deng;Japanese uyeki anti-mite antibacterial spray is organic, safer, but it is that anti-mite agent is sprayed directly on to fabric surface, is removed Mite agent remains on the fabric, makes one directly to contact, is also easy to produce sense of discomfort.
Therefore, it develops and a kind of is applied to that washing powder, stability is good, compatibility is good, has no irritating odor, is not damaged to fabric , anti-mite agent easy-to-use, safe to the human body be the industry there is an urgent need to.
Solid hydrogen peroxide be added washing powder in, function be bleaching, increase it is gorgeous, can be to the coloured soils (tomato on fabric Juice, watermelon juice, coffee sweat etc.) it is bleached, the chromophoric group in molecule is destroyed, becomes the molecule being invisible to the naked eye, reaching makes Pure white, the bright-coloured purpose of fabric.Detergent containing peroxide can hydrolyze generation hydrogen peroxide, hydrogen peroxide when being dissolved in water Then dissociate active oxygen and generate blanching effect.Meanwhile hydrogen peroxide is a kind of strong oxidant, can kill enteropathic Bacterium, pyococcus, pathogenic yeast bacterium have certain disinfection, bactericidal effect.Peroxide is applied in washing powder, this Technology is very universal in washing industry.
Peroxide is applied in washing powder, has certain biocidal property, but bacteriostasis rate is lower, it is pre- that consumer is often not achieved The target call of phase.
Cold activator is a kind of acylating agent, when being used in compounding with peroxide, can reduce peroxidating with peroxide activator The oxygen release temperature of object improves oxygen release speed.Cold activator, which is compounded with peroxide by optimal proportion, becomes composition, application In washing powder, stronger, the better peroxide second of fungistatic effect that during laundering of textile fabrics, under room temperature can release oxidisability Acid, thus the effect of reaching antibacterial anti-mite.
Peracetic acid is strong oxidizer, meet organic matter release nascent oxygen and rise oxidation, for it is efficient, quick-acting, less toxic, Wide-spectrum bactericide.In addition, Peracetic acid has stronger volatility in air.The present invention is using its this characteristic to fabric On acarid carry out repellent, reach suppression mite and mite removal effect.
Summary of the invention
There are many anti-mite agent for being applied to family, agricultural, hospital etc., such as three chlorbenside spirits, fenpyroximate, the third bromine in the market Lian etc.;Its composition is mostly to contain chlorbenside bacterium insecticide and the dedicated anti-mite agent of agricultural, smell comparison stimulus, due to very strong oxidation Property, there are certain insecurity factors in family's application process, such as: it, can skin ambustion if directly contacting skin;If straight Spraying is connect in fabric surface, then fabric surface can be made to change colour or damage.Moreover, this kind of anti-mite agent and washing powder compatibility are bad, It is applied in washing powder if being directly added into, can greatly weaken the washability of washing powder or the washability of washing powder is directly Zero.Japanese uyeki anti-mite antibacterial spray is organic, safer, but it is that anti-mite agent is sprayed directly on to fabric surface, is removed Mite agent remains on the fabric, makes one directly to contact, is also easy to produce sense of discomfort.A kind of anti-mite washing powder is developed, in cleaning fabric process In, that is, it ensure that the cleanliness of fabric, while reaching mite removal effect again, anti-mite agent will not be made directly to remain in fabric surface, two The secondary discomfort for causing skin.For a kind of safe, convenient and fast, environmental protection anti-mite washing powder.Shanghai light industry research institute and Du Pont A kind of anti-mite agent R301 of company's cooperative research and development, it is more effective in liquid detergent for a kind of anti-mite agent organically, safe, but It is unobvious for effect in washing powder.
The present invention utilizes Solid hydrogen peroxide, by being compounded with the optimization of cold activator into except acaricidal composition, will match after it Mode be added in washing powder, formed the detergent containing peroxide.After detergent is dissolved in water, peroxide and low temperature cold are living Agent reaction releases Peracetic acid.Peracetic acid is strong oxidizer, has stronger volatility in air, for efficient, speed Effect, low toxicity, wide-spectrum bactericide, have the function of repellent to the acarid on fabric.Anti-mite washing powder of the invention is pre- through Chinese disease Anti- control centre's prevention of parasitic diseases control is detected, and to acarid scattering ratio >=90%, complies fully with standard GB/T/T Requirement in 24253-2009 " evaluations of the anti-mite performance of textile " to acarid scattering ratio.
In the market there are many anti-mite agent cannot be directly added into washing powder and be applied due to its particularity.Mesh of the invention Be to provide a kind of novel washing powder special efficient that can be applied in washing powder except acaricidal composition, with peroxide and low temperature Cold activator is compounded according to certain formula, is then applied in different washing powder systems, is reached and is driven mite, anti-mite effect.
Production technology and application method of the invention includes the following steps:
1. production method
The preparation of anti-mite agent: by Solid hydrogen peroxide (80 % ~ 90%), and low-temperature activation agent (10% ~ 20%), in polygonal displacement taper Mixer vertical response kettle is sufficiently mixed uniformly.
2. application method in washing powder
It is raw uniformly mixed composition to be added in the way of matching technique after the recipe requirements of detergent synthetic detergent powder It produces in formula.
Specific embodiment: tetraacetyl ethylene diamine, pelargonyl group phenyl ester sulfonate, capryl phenyl ester sulfonate.
Embodiment 1
Washing powder 80%
Anti-mite agent 20%
(anti-mite agent: 90 % of sodium peroxydisulfate, 10 % of tetraacetyl ethylene diamine)
Above-mentioned raw materials manufacturing technique method according to the invention carry out it is uniformly mixed, product composition with after 10% dosage with addition of Enter in washing powder, according to GB/T 24253-2009 defined detection method detect respectively be not added except acaricidal composition washing powder with The anti-mite effect for removing acaricidal composition is added.The acarid scattering ratio of commercially available regular powder is 35%, is done washing with money plus except acaricidal composition The acarid scattering ratio of powder is 94%.
Embodiment 2
Washing powder 85%
Anti-mite agent 15%
Anti-mite agent (90 % of sodium peroxydisulfate, 10 % of pelargonyl group phenyl ester sulfonate)
Above-mentioned raw materials manufacturing technique method according to the invention carry out it is uniformly mixed, product composition with after 15% dosage with addition of Enter in washing powder, is detected respectively according to GB/T 24253-2009 and be not added except acaricidal composition washing powder and be added except acaricidal composition Anti-mite effect;The acarid scattering ratio of commercially available regular powder is 350%, with money plus except the acarid repellent of acaricidal composition washing powder Rate is 91%.
Embodiment 3
Washing powder 90%
Anti-mite agent 10%
Anti-mite agent (90 % of sodium peroxydisulfate, 10 % of capryl phenyl ester sulfonate)
Above-mentioned raw materials manufacturing technique method according to the invention carry out it is uniformly mixed, product composition with after 10% dosage with addition of Enter in washing powder, test performance is as follows:
It is commercially available common according to the anti-mite effect of GB/T 24253-2009 " evaluation of the anti-mite performance of textile " detection detergent The acarid scattering ratio of washing powder is 42%, with money plus except the acarid scattering ratio of acaricidal composition washing powder is 93%.
From above three experimental data as can be seen that comparison regular powder, using be added anti-mite agent washing powder, The anti-effect of anti-mite is clearly.

Claims (3)

1. a kind of anti-mite washing powder, which is characterized in that be composed of the following raw materials in parts by weight: washing powder 80-90%(is by anion Surfactant, nonionic surfactant, soda ash, sodium silicate, 4A zeolite, acrylate copolymer, brightening agent, essence, member are bright The groups such as powder are grouped as), anti-mite agent (Solid hydrogen peroxide 80-90%, activator 10-20%).
2. a kind of anti-mite agent according to right 1, it is characterised in that: Solid hydrogen peroxide used is sodium sulphate-hydrogen peroxide- Sodium chloride adduct, dosage 80-90%.
3. a kind of anti-mite agent according to right 1, it is characterised in that: the activator is tetraacetyl ethylene diamine, pelargonyl group The one or more of phenyl ester sulfonate, capryl phenyl ester sulfonate, the preferred dosage of the activator are 10-20%.
CN201711005895.8A 2017-10-25 2017-10-25 A kind of anti-mite washing powder Pending CN109706004A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711005895.8A CN109706004A (en) 2017-10-25 2017-10-25 A kind of anti-mite washing powder

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711005895.8A CN109706004A (en) 2017-10-25 2017-10-25 A kind of anti-mite washing powder

Publications (1)

Publication Number Publication Date
CN109706004A true CN109706004A (en) 2019-05-03

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CN201711005895.8A Pending CN109706004A (en) 2017-10-25 2017-10-25 A kind of anti-mite washing powder

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111436458A (en) * 2020-05-15 2020-07-24 广州超威生物科技有限公司 Household anti-mite agent composition and preparation method thereof
CN111848481A (en) * 2020-04-08 2020-10-30 郭保来 Solid generating agent for preparing solid peroxyacetic acid and preparation method and application thereof
CN114480032A (en) * 2020-10-27 2022-05-13 山西焦煤运城盐化集团有限责任公司 Formula and production of antibacterial and acarus killing concentrated washing powder

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102899181A (en) * 2012-09-18 2013-01-30 启东乾朔电子有限公司 Mite-removal carpet washing agent
CN103351961A (en) * 2013-07-19 2013-10-16 常州工程职业技术学院 Solid hydrogen peroxide preparation technology
CN103468445A (en) * 2013-09-13 2013-12-25 广州立白企业集团有限公司 Washing powder composition and preparation method thereof
CN106590949A (en) * 2016-12-11 2017-04-26 深圳市美益洁生物科技有限公司 Clothes washing tank biological enzyme sterilization cleaning agent and preparing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102899181A (en) * 2012-09-18 2013-01-30 启东乾朔电子有限公司 Mite-removal carpet washing agent
CN103351961A (en) * 2013-07-19 2013-10-16 常州工程职业技术学院 Solid hydrogen peroxide preparation technology
CN103468445A (en) * 2013-09-13 2013-12-25 广州立白企业集团有限公司 Washing powder composition and preparation method thereof
CN106590949A (en) * 2016-12-11 2017-04-26 深圳市美益洁生物科技有限公司 Clothes washing tank biological enzyme sterilization cleaning agent and preparing method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
任九庆等: ""过氧化硫酸钠在洗衣粉中的应用"", 《中国洗涤用品工业》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111848481A (en) * 2020-04-08 2020-10-30 郭保来 Solid generating agent for preparing solid peroxyacetic acid and preparation method and application thereof
CN111436458A (en) * 2020-05-15 2020-07-24 广州超威生物科技有限公司 Household anti-mite agent composition and preparation method thereof
CN111436458B (en) * 2020-05-15 2022-11-18 广州超威生物科技有限公司 Household anti-mite agent composition and preparation method thereof
CN114480032A (en) * 2020-10-27 2022-05-13 山西焦煤运城盐化集团有限责任公司 Formula and production of antibacterial and acarus killing concentrated washing powder

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Application publication date: 20190503

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