CN1096920A - The preparation of bensulfuron-methyl and butachlor - Google Patents

The preparation of bensulfuron-methyl and butachlor Download PDF

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Publication number
CN1096920A
CN1096920A CN 93112042 CN93112042A CN1096920A CN 1096920 A CN1096920 A CN 1096920A CN 93112042 CN93112042 CN 93112042 CN 93112042 A CN93112042 A CN 93112042A CN 1096920 A CN1096920 A CN 1096920A
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China
Prior art keywords
preparation
weed
bensulfuron
butachlor
methyl
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Pending
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CN 93112042
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Chinese (zh)
Inventor
郭武棣
张瑞亭
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Shenyang Research Institute of Chemical Industry Co Ltd
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Shenyang Research Institute of Chemical Industry Co Ltd
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Priority to CN 93112042 priority Critical patent/CN1096920A/en
Publication of CN1096920A publication Critical patent/CN1096920A/en
Pending legal-status Critical Current

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Abstract

Bensulfuron-methyl and butachlor are mixed with mix preparation, are used to prevent and kill off broad leaved weed, sedge weed, the grassy weed in paddy field, and to rice safety.

Description

The preparation of bensulfuron-methyl and butachlor
The preparation of bensulfuron-methyl and butachlor and the application in the paddy field thereof belong to the preparation of farm weeding.
Bensulfuron-methyl is a highy potent herbicide
Figure 93112042X_IMG1
This weed killer herbicide uses separately to be prevented and kill off annual or perennial broadleaf weed and the active height of sedge weed, but to preventing and kill off the active low of barnyard grass grass.
The herbicide butachlor structural formula is:
Figure 93112042X_IMG2
Butachlor is the selectivity preemergence herbicide, is mainly used in paddy field and prevents and kill off annual gramineous weed, and as to barnyard grass grass preventive effect height, but low to preventive effects such as broadleaved herb and nutgrass flatsedges.Above-mentioned two kinds of weed killer herbicides can not be prevented and kill off paddy land weed fully as using separately all.
For overcoming above-mentioned deficiency, the present invention proposes above-mentioned two kinds of weed killer herbicides are made into mixture, can prevent and kill off broad leaved weed, sedge weed, grassy weed in the paddy field fully through using proof, and to rice safety.Said preparation is not seen domestic and international report.
The herbicidal formulations effective ingredient that the present invention proposes is bensulfuron-methyl and butachlor, and the two mixed proportion (weight ratio) is 1: 15-50, formulation has granule, pulvis, wetting powder.Granule effective ingredient total content is 3-10%, and pulvis, wetting powder effective component content are 10-40%.
Granule can be used coating method, kneading method or infusion process manufacturing, and filler is sand, clay, potter's clay, diatomite, bentonite etc., adhesive available polyethylene alcohol, starch, paraffin, gum Arabic etc.
Wetting powder, dust diluent is clay, potter's clay, diatomite, white carbon, bentonite, attapulgite, talcum powder etc., auxiliary agent can be with sodium lignin sulfonate or calcium lignosulfonate, carboxymethyl cellulose, NNO, draw back powder, dodecyl sodium sulfate etc., and auxiliary dosage is the 5-20% of preparation.
Butachlor and bensulfuron-methyl mix and can cause that bensulfuron-methyl slowly decomposes, and add B in the preparation aSO 4Or C aSO 4With phosphatic mixture as stabilizing agent, effect is fine.Used phosphate has dipotassium hydrogen phosphate or sodium, ammonium salt, potassium dihydrogen phosphate, sodium or ammonium salt etc., and the two gross weight of barium sulfate that is added and phosphate is the 5-20% of preparation.
For bensulfuron-methyl is uniformly dispersed, is processed into female powder earlier, and then is processed into granule of the present invention, pulvis or wetting powder with usual method and herbicide butachlor.
Embodiment 1
Butachlor 3%, bensulfuron-methyl 0.20%, B aSO 45%, phosphate 3%, polyvinyl alcohol 2%, diatomite 7%, all the other are sand, make granule with coating method.Herbicidal effect sees Table 1.
Embodiment 2
Butachlor 10%, bensulfuron-methyl 0.40%, B aSO 410%, N aH 2PO 410%, carboxymethyl cellulose 5%, adopts the kneading legal system to get granule.
Embodiment 3
Butachlor 3%, bensulfuron-methyl 0.15%, B aSO 45%, potter's clay 5%, and all the other are zeolite, adopts absorption method to make granule.
Embodiment 4
Butachlor 12%, bensulfuron-methyl 0.5%, white carbon 15%, KH 2PO 410%, B aSO 45%, all the other add bentonite, mix to pulverize to make pulvis.
Embodiment 5
Butachlor 10%, bensulfuron-methyl 0.5%, B aSO 410%, phosphate 5%, and all the other add potter's clay mixing pulverizing and make pulvis.
Embodiment 6
Butachlor 10%, bensulfuron-methyl 0.5%, sodium lignin sulfonate 5%, NNO5%, white carbon 10%, B aSO 410%, potassium dihydrogen phosphate 5%, and all the other add diatomite and make pulvis.Herbicidal effect sees Table 2.
Table 1 granule is to the production-increasing function of paddy rice
Handle Preparation consumption (gram/mu) Per unit area yield (kilogram/mu) Volume increase (kilogram/mu)
But example 1 granule bensulfuron-methyl 10% wet-milling butachlor 60% missible oil CK 1250 1875 2500 15 100 467.6 520.9 534.9 441.6 382.9 218.8 113.7 138.1 144.5 101.8 75.0
The herbicidal effect of table 2 wetting powder and volume increase situation
Handle Preparation consumption (gram/mu) Herbicidal effect (%) Per unit area yield (kilogram/mu) Volume increase (%)
But 2 CK of example 6 pulvis 60% butachlor ec, 10% bensulfuron-methyl wet-milling artificial weedings 250 200 15 91.5 72.7 70.8 42.5 622.3 544.5 513.4 468.9 410 51.8 32.8 25.2 14.4

Claims (7)

1, the preparation of bensulfuron-methyl and butachlor, it is characterized in that effective ingredient is bensulfuron-methyl and butachlor in the preparation, add carrier in addition, adhesive, stabilizing agent, auxiliary agent, or do not add stabilizing agent and be mixed with granule, pulvis or wetting powder, two kinds of shared ratios of effective ingredient are 1 in the preparation: 15-50, the consumption of auxiliary agent and stabilizing agent is the 5-20% of preparation, other is a carrier, effective component content is 3-10% in the granule, pulvis, the wetting powder effective component content is 10-40%, and preparation of the present invention is mainly used in the broad leaved weed in the control paddy field, sedge weed, grassy weed.
2, herbicidal formulations according to claim 1 is characterized in that used carrier is sand, clay, potter's clay, diatomite, bentonite, and adhesive is polyvinyl alcohol, polyvinyl acetate, starch, paraffin, gum Arabic, carboxymethyl cellulose.
3, herbicidal formulations according to claim 1 is characterized in that used stabilizing agent is sulphate and phosphate.
4,, it is characterized in that used sulphate stabilizing agent is B according to claim 1 and 3 described herbicidal formulations aSO 4, C aSO 4, phosphate stabilizer is dipotassium hydrogen phosphate, sodium, ammonium salt, potassium dihydrogen phosphate, sodium, ammonium salt, the potassium or the sodium salt of pyrophosphoric acid, tripolyphosphate, four polyphosphoric acids, metaphosphoric acid, single using or the mixing application.
5, herbicidal formulations according to claim 1 is characterized in that the filler in described pulvis or the wetting powder is clay, potter's clay, diatomite, white carbon, bentonite, attapulgite, talcum powder etc.
6, herbicidal formulations according to claim 1 is characterized in that used auxiliary agent is sodium lignin sulfonate or calcium, carboxymethyl cellulose, NNO, draws back powder, dodecyl sodium sulfate etc.
7, herbicidal formulations according to claim 1 is characterized in that preparation of the present invention is mainly used in broad leaved weed, sedge weed, the grassy weed in the control paddy field.
CN 93112042 1993-06-29 1993-06-29 The preparation of bensulfuron-methyl and butachlor Pending CN1096920A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 93112042 CN1096920A (en) 1993-06-29 1993-06-29 The preparation of bensulfuron-methyl and butachlor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 93112042 CN1096920A (en) 1993-06-29 1993-06-29 The preparation of bensulfuron-methyl and butachlor

Publications (1)

Publication Number Publication Date
CN1096920A true CN1096920A (en) 1995-01-04

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CN 93112042 Pending CN1096920A (en) 1993-06-29 1993-06-29 The preparation of bensulfuron-methyl and butachlor

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CN (1) CN1096920A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100356847C (en) * 2006-03-10 2007-12-26 廖克祥 Weeding pesticide-added fertilizer for paddy and method for preparing the same
CN102047895A (en) * 2010-12-20 2011-05-11 安徽美兰农化有限公司 Weeding wettable powder for paddy field
CN102845446A (en) * 2011-06-30 2013-01-02 浙江天丰化学有限公司 Herbicidal composition containing bensulfuron methyl and butachlorfor for paddy field
CN104068036A (en) * 2014-07-09 2014-10-01 江苏省苏科农化有限责任公司 Closed weeding method for machine transplanting rice field
CN104522018A (en) * 2004-12-17 2015-04-22 株式会社Lg生命科学 Synergistic herbicidal compositions

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104522018A (en) * 2004-12-17 2015-04-22 株式会社Lg生命科学 Synergistic herbicidal compositions
CN100356847C (en) * 2006-03-10 2007-12-26 廖克祥 Weeding pesticide-added fertilizer for paddy and method for preparing the same
CN102047895A (en) * 2010-12-20 2011-05-11 安徽美兰农化有限公司 Weeding wettable powder for paddy field
CN102845446A (en) * 2011-06-30 2013-01-02 浙江天丰化学有限公司 Herbicidal composition containing bensulfuron methyl and butachlorfor for paddy field
CN104068036A (en) * 2014-07-09 2014-10-01 江苏省苏科农化有限责任公司 Closed weeding method for machine transplanting rice field

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