CN109688813A - Flying pest attractant - Google Patents
Flying pest attractant Download PDFInfo
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- CN109688813A CN109688813A CN201780054569.8A CN201780054569A CN109688813A CN 109688813 A CN109688813 A CN 109688813A CN 201780054569 A CN201780054569 A CN 201780054569A CN 109688813 A CN109688813 A CN 109688813A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/02—Stationary means for catching or killing insects with devices or substances, e.g. food, pheronones attracting the insects
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
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- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Insects & Arthropods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The issue of the present invention is to provide a kind of flying pest attractant, attractant effect is better than existing attractant, shows attractant effect to various flying pests.The above subject can be solved by following flying pest attractants, the flying pest attractant is characterized in that, it contains that carbon atom number is 2 or more 6 aliphatic alcohols (A) below and/or carbon atom number is 3 or more 8 aliphatic acid esters (E) below and specific carboxylic acid (H), which is that carbon atom number is 3 or more 5 ketone acids or carboxylic acid or acetic acid below.In addition, can be improved attractant effect by sharing the foods such as carbohydrate, fruit, fruit processed goods, dairy products, fish and shellfish processed goods, fish and shellfish extract, edible meat processed goods, edible meat extract, drinks, vinasse and cereal in flying pest attractant.
Description
Technical field
The present invention relates to flying pest attractants, in more detail, be related to it is a kind of greatly improve attracting pests effect
Flying pest attractant.
Background technique
The flying pests such as fly, mosquito, small fly (hereinafter sometimes referred to simply as " pest ") appear in house etc., cause various danger
Evil: hygienic conditions are made to be deteriorated, stab the mankind or make one to feel hurt because appearance is bad.
As the method for control of the various harm caused by for preventing because of these flying pests, has developed and use various medicines
The method of agent.
As the method for control of flying pest, has and lure evil of circling in the air and volatilizing the chemical component that flying pest is liked
The method of control of worm.The flying pest being attracted is killed by being captured, being closed using adhesive etc. into enclosure space, with insecticidal constituent
The methods of drive away.
As for the above-mentioned flying pest attractant using in the method for control for luring progress, proposed in the past using each
The motion of kind chemical substance.
It describes in patent document 1 a kind of for using (R)-(-) isomery of the 1- alkene -3- alcohol such as 1-OCOL
Body is come the method for luring mosquito.
A kind of mosquito attractant is described in patent document 2, which is characterized in that it contains lysine, isovaleric acid, the third ammonia
It is one kind or two or more in acid, androstane enol, sebum.
A kind of mosquito attractant is described in patent document 3, contains the mixture of lactic acid and methyl lactate as effective
Ingredient.
But the attractant effect of these attractants sometimes may not be abundant.It is different in particular according to the type of pest, liked
Lure into branch's difference, different according to the type of flying pest, these attractants are displayed without effect sometimes.
Therefore, it is desirable to a kind of flying pest attractant that various flying pests are shown with sufficient attractant effect.
Existing technical literature
Patent document
Patent document 1: Japanese Unexamined Patent Publication 2006-232837 bulletin
Patent document 2: Japanese Unexamined Patent Publication 2002-241204 bulletin
Patent document 3: Japanese Unexamined Patent Publication 6-065005 bulletin
Summary of the invention
Problems to be solved by the invention
The present invention is completed in view of the aforementioned technical background, and project is to provide a kind of flying pest attractant,
Attractant effect is better than existing attractant, shows attractant effect to various flying pests.
Means for solving the problems
Further investigation has been repeated in the present inventor in order to solve above-mentioned problem, as a result, it has been found that, by the way that spy is applied in combination
The aliphatic alcohol and/or aliphatic acid ester and specific carboxylic acid for determining carbon atom number, can obtain attractant effect it is strong, to various pests
Show the attractant of sufficient attracting action, so as to complete the present invention.
That is, the present invention provides a kind of flying pest attractant, which is characterized in that it is 2 or more 6 or less that it, which contains carbon atom number,
Aliphatic alcohol (A) and/or carbon atom number be 3 or more 8 aliphatic acid esters (E) below and specific carboxylic acid (H), the specific carboxylic
Sour (H) is that carbon atom number is 3 or more 5 ketone acids or carboxylic acid or acetic acid below.
The present invention also provides a kind of expelling methods of flying pest, which is characterized in that it is drawn using above-mentioned flying pest
Lure.
Invention effect
In accordance with the invention it is possible to provide a kind of flying pest attractant, attractant effect is better than existing attractant, to each
Kind flying pest shows attractant effect.
Ingredient contained by flying pest attractant of the invention is ingredient safe to the human body, thus of the invention is circled in the air
Attracting pests agent is also able to use in general family etc..
In addition, using the mixture of compound of more than two kinds to draw as various in flying pest attractant of the invention
Lure ingredient (carbon atom number is 2 or more 6 aliphatic alcohols (A) below, carbon atom number be 3 or more 8 aliphatic acid esters (E) below,
Carbon atom number as specific carboxylic acid (H) is 3 or more 5 ketone acids or carboxylic acid or acetic acid below) when, it is easy to play to each
The attractant effect of kind pest.
Specific embodiment
The present invention will be described below, but the present invention is not limited to the following embodiments and the accompanying drawings, can be come with random variation real
It applies.
It is that 2 or more 6 aliphatic alcohols (A) below and/or carbon are former that flying pest attractant of the invention, which contains carbon atom number,
Subnumber is 3 or more 8 aliphatic acid esters (E) below and specific carboxylic acid (H), which is that carbon atom number is 3 or more
5 ketone acids or carboxylic acid or acetic acid below.
In flying pest attractant of the invention, neccessary composition is used as containing specific carboxylic acid (H).Specific carboxylic acid (H) is carbon
Atomicity is 3 or more 5 ketone acids or carboxylic acid or acetic acid below.
Play the role of in known carboxylic acid it is several have lure pest etc., but according to the type of carbon atom number or substituent group and
The type of pest also walks quickly and keeps away pest etc. sometimes.
In the case that specific carboxylic acid (H) is ketone acid (carboxylic acid with ketone group), carbon atom number can for 3, can be 4,
It can be 5.
The ketone group of ketone acid can be located at α, can be located at β or positioned at γ.
The carbochain of ketone acid can have branch, can also not have branch.In addition, ketone acid can have between carbon atom not
Saturated bond, can also not have carbon atom between unsaturated bond.
It is the concrete example of 3 or more 5 ketone acids below as such carbon atom number, Acetylformic acid, 2- oxygen can be enumerated
For butyric acid, 3- ketobutyric acid, 2- oxopentanoic acid, 3- oxopentanoic acid, 4-oxopentanoic acid, 2- oxo -3 Methylbutanoic acid etc., these ketone
Acid can be used alone, can also be mixed with two or more.
In the case that specific carboxylic acid (H) is carboxylic acid (carboxylic acid with hydroxyl), carbon atom number can for 3, can be 4,
It may be 5.
The hydroxyl of carboxylic acid can be located at α, can be located at β, can be located at γ or positioned at δ.
The carbochain of carboxylic acid can have branch, can also not have branch.In addition, carboxylic acid can have between carbon atom
Unsaturated bond, can also not have carbon atom between unsaturated bond.
It is the concrete example of 3 or more 5 carboxylic acids below as such carbon atom number, 2 hydroxy propanoic acid, 3- can be enumerated
Hydracrylic acid, 2- hydroxybutyric acid, 3-hydroxybutyrate, 4 hydroxybutyric acid, 2- hydroxy-2-methyl propionic acid, 3- hydroxy-2-methyl third
Acid, 2- hydroxypentanoic acid, 3- hydroxypentanoic acid, 4- hydroxypentanoic acid, 2- hydroxy-2-methyl butyric acid, 3- hydroxy-2-methyl butyric acid, 2- hydroxyl
Base -3 Methylbutanoic acid, 3-Hydroxy-3-methylbutyric acid, 3- hydroxyl -2,2-Dimethylpropionic acid etc., these carboxylic acids can individually make
With a kind, can also be mixed with two or more.
It is particularly preferred to lure ingredient different according to the difference of pest.In addition, also having even if being identical compound
Hobby property is high under a certain concentration (being easy to be lured), there is a situation where walk quickly and keep away if concentration increases.Therefore, two kinds are used in mixed way
When above compound is as specific carboxylic acid (H), it is easy to be adjusted to the high concentration of hobby property, is easy to play effect to various pests
Fruit.
It is 2 or more 6 aliphatic alcohols (A) below and carbon atom number that flying pest attractant of the invention, which contains carbon atom number,
For in 3 or more 8 aliphatic acid esters (E) below at least any one as neccessary composition.
In aliphatic alcohol (A), aliphatic acid ester (E), has as ingredient known to fragrance component, have as pest etc.
The ingredient that the ingredient of attractant uses.But these ingredients lead to the effect enhancing for walking quickly and keeping away pest etc. due to carbon atom number etc..
In flying pest attractant of the invention, by by specific carboxylic acid (H) and aliphatic alcohol (A) or aliphatic acid ester
(E) it shares, makes the collaboration enhancing of attracting pests effect.
Especially in the case where containing aliphatic alcohol (A), aliphatic acid ester (E), this 3 kinds of ingredients of specific carboxylic acid (H), association
It is extremely strong with attractant effect, thus particularly preferably.
In the present invention, " aliphatic alcohol (A) " refers to the alcohol with aliphatic alkyl.
The carbon atom number of aliphatic alcohol (A) is more preferably 3 or more 5 or less, particularly preferably 4.
The aliphatic alkyl of aliphatic alcohol (A) can be saturation or unsaturated.Furthermore it is possible to be straight-chain
Also it can have branch.
As the concrete example of the aliphatic alcohol (A) contained by flying pest attractant of the invention, ethyl alcohol, 1- can be enumerated
Propyl alcohol, 2- propyl alcohol, 2- propylene-1- alcohol, n-butyl alcohol, 2- methyl-1-propyl alcohol, 2- butanol, 2- methyl-2-propanol, 1- amylalcohol, 2- penta
Alcohol, 2-methyl-1-butene alcohol, 3- methyl-1-butanol, 2- methyl -2- butanol, 2-M3BOL, 3- methyl -2- fourth
Alkene -1- alcohol, 1- hexanol, 3- methyl-1-pentene alcohol, 4- methyl -2- amylalcohol, 2,2- dimethyl-1-butanol etc., they can individually make
With a kind, can also be mixed with two or more.
It is particularly preferred to lure ingredient different according to the difference of pest.In addition, also having even if being identical compound
Hobby property is high under a certain concentration (being easy to be lured), there is a situation where walk quickly and keep away if concentration increases.Therefore, two kinds are used in mixed way
When above compound is as aliphatic alcohol (A), it is easy to be adjusted to the high concentration of hobby property, is easy to play effect to various pests
Fruit.
In the present invention, " aliphatic acid ester (E) " refers to aliphatic acid (E1) and alcohol (E2) through structure made of dehydrating condensation
Ester, but be not limited to the ester produced by the dehydrating condensation of aliphatic acid (E1) and alcohol (E2).
" aliphatic acid (E1) " refers to a part of hydrogen atom substitutedization of fatty acid (1 yuan of carboxylic acid of hydrocarbon) or fatty acid
Close object.
Aliphatic acid (E1) in the present invention can be saturation or unsaturated.Furthermore it is possible to be straight-chain
Also it can have branch.
In addition, in " aliphatic acid (E1) of the substituted compound of the hydrogen atom of a part as fatty acid ", as
The type for replacing the substituent group of a part of hydrogen atom, can enumerate hydroxyl, oxo base etc..
The carbon atom number of aliphatic acid (E1) is preferably 2 or more 6 or less, more preferably 3 or more 5 or less.
As the concrete example of aliphatic acid (E1), acetic acid, propionic acid, 2 hydroxy propanoic acid, Acetylformic acid, fourth can be enumerated
Acid, 2 Methylpropionic acid, 2- hydroxybutyric acid, 3-hydroxybutyrate, 2- butenoic acid, valeric acid, 2,2- neopentanoic acid, 2-Methyl Butyric Acid,
3 Methylbutanoic acid, (Z) -2- methyl but-2-ene acid, (E) -2- methyl but-2-ene acid, 4-oxopentanoic acid, caproic acid, 2- ethyl fourth
Acid, 2- hexenoic acid etc..
Alcohol (E2) can be saturation or unsaturated.Furthermore it is possible to also can have branch for straight-chain.
The carbon atom number of alcohol (E2) is preferably 2 or more 6 or less, more preferably 3 or more 5 or less.
As the concrete example of alcohol (E2), methanol, ethyl alcohol, 1- propyl alcohol, 2- propyl alcohol, 2- propylene -1- alcohol, 1- fourth can be enumerated
Alcohol, 2- methyl-1-propyl alcohol, 2- butanol, 2- methyl-2-propanol, 1- amylalcohol, 2- amylalcohol, 2-methyl-1-butene alcohol, 3- methyl-1-fourth
Alcohol, 2- methyl -2- butanol, 2-M3BOL, 3-M2BOL, 1- hexanol, 3- methyl-1-pentene alcohol,
4- methyl -2- amylalcohol, 2,2- dimethyl-1-butanol etc..
Aliphatic acid ester (E) of the invention is aliphatic acid (E1) and the ester of alcohol (E2) through structure made of dehydrating condensation,
As the combination of aliphatic acid (E1) and alcohol (E2), can enumerate aliphatic acid that carbon atom number is 2 and carbon atom number is 1 or more
The aliphatic acid and carbon atom number that the combination of 6 alcohol below, carbon atom number are 3 are the combination of 1 or more 5 alcohol below, carbon atom
The aliphatic acid that number is 4 and carbon atom number is the combination of 1 or more 4 alcohol below, carbon atom number is 5 aliphatic acid and carbon atom
The aliphatic acid that number is the combination of 1 or more 3 alcohol below, carbon atom number is 6 and the group that carbon atom number is 1 or more 2 alcohol below
It closes.
As the concrete example of aliphatic acid ester (E), acetic acid 1- propyl alcohol ester, acetic acid 1- amylalcohol ester, propionic acid 2- third can be enumerated
Alkene -1- alcohol ester, propionic acid n-butyl alcohol ester, 2 hydroxy propanoic acid n-butyl alcohol ester, Acetylformic acid ethyl alcohol ester, butyric acid 1- propyl alcohol ester, butyric acid
2- propyl alcohol ester, butyric acid ethyl alcohol ester, 2 Methylpropionic acid 2- propyl alcohol ester, 2- hydroxybutyric acid ethyl alcohol ester, 3-hydroxybutyrate ethyl alcohol ester, 2- fourth
Olefin(e) acid 2- methylpropane -1- alcohol ester, valeric acid methanol ester, 2,2- neopentanoic acid methanol ester, 2-Methyl Butyric Acid ethyl alcohol ester, 3- methyl
Butyric acid ethyl alcohol ester, 3 Methylbutanoic acid methanol ester, (E) -2- methyl but-2-ene acid ethyl alcohol ester, 4-oxopentanoic acid methanol ester, 2- ethyl
Butyric acid methanol ester, 2 Ethylbutanoic acid ethyl alcohol ester, 2- hexenoic acid ethyl alcohol ester etc., they can be used alone, and can also mix makes
Use two or more.
It is particularly preferred to lure ingredient different according to the difference of pest.In addition, also having even if being identical compound
Hobby property is high under a certain concentration (being easy to be lured), there is a situation where walk quickly and keep away if concentration increases.Therefore, two kinds are used in mixed way
When above compound is as aliphatic acid ester (E), it is easy to be adjusted to the high concentration of hobby property, is easy to play various pests
Effect.
Flying pest attractant of the invention contain simultaneously " carbon atom number be 2 or more 6 aliphatic alcohols (A) below and/or
Carbon atom number is 3 or more 8 aliphatic acid esters (E) below " and " (it is that carbon atom number is 3 or more 5 below to specific carboxylic acid (H)
Ketone acid or carboxylic acid or acetic acid) " it is used as effective component, the aliphatic alcohol (A), the aliphatic acid ester (E), the specific carboxylic acid
(H) content ratio (quality criteria) be preferably 0.1≤(H)/[(A)+(E)+]≤0.9 (H), more preferably 0.2≤(H)/
[(A)+(E)+]≤0.8 (H), particularly preferably 0.3≤(H)/[(A)+(E)+]≤0.7 (H).
When the content ratio is in above range, it is easy to play sufficient attractant effect to various pests.
The aliphatic alcohol (A) as effective component, aliphatic acid ester (E) and spy in flying pest attractant of the invention
The content ratio of carboxylic acid (H) is determined relative to whole preferably 0.1 matter in terms of the sum of (A), (E) and (H) of flying pest attractant
Measure % or more 20 mass % or less, more preferably 0.5 mass % or more, 10 mass % or less, particularly preferably 1 mass % or more 5
Quality % or less.
When the content ratio is above-mentioned lower limit or more, sufficient attractant effect can be played.In addition, the content ratio is
When below the above-mentioned upper limit, it can be achieved that appropriateness be vaporized speed, the duration of effect becomes long enough.
As described above, flying pest attractant of the invention contains aliphatic alcohol (A), aliphatic acid ester (E), specific carboxylic acid
(H) when this 3 kinds of ingredients, collaboration attractant effect is extremely strong, in this case, aliphatic alcohol (A) and aliphatic acid ester (E) containing than
Example (quality criteria) be preferably 0.05≤(A)/[]≤0.95 (A)+(E), more preferably 0.10≤(A)/[(A)+(E)]≤
0.90, it is particularly preferably 0.20≤(A)/[]≤0.80 (A)+(E).
Flying pest attractant of the invention is in addition to containing aliphatic alcohol (A), the aliphatic acid ester as effective component
(E), other than specific carboxylic acid (H), solvent can also be contained in the range of not interfering effect of the invention；Fragrance, essential oil etc. its
He lures ingredient；For killing the insecticidal constituent of lured pest；The addition such as emulsifier, dispersing agent, preservative, preservative
Agent；Etc..
As solvent, water can be enumerated；The monohydric alcohols such as methanol, ethyl alcohol, propyl alcohol, isopropanol, butanol；Ethylene glycol, propylene glycol
Equal polyalcohols；The ketone such as acetone, methyl ethyl ketone；The ethers such as tetrahydrofuran, dioxane, diethyl ether；Hexane, kerosene, alkane etc.
Aliphatic hydrocarbon；The aromatic hydrocarbons such as benzene, toluene；The halogenated hydrocarbons such as chloroform, dichloroethanes；The esters such as ethyl acetate, butyl acetate；Etc.,
These substances can be used alone, and can also be mixed with two or more.
Flying pest attractant of the invention is also able to use in general family etc., due to solvent requirement safety,
Thus preferably water, monohydric alcohol, polyalcohol or their combination.Particularly preferred water, ethyl alcohol, propylene glycol or their combination.
The optium concentration of effective component (specific carboxylic acid (H), aliphatic alcohol (A), aliphatic acid ester (E)) is sometimes according to pest
Type and it is different, can be to various pests by suitably diluting flying pest attractant of the invention with above-mentioned solvent
Play attractant effect.
Form as flying pest attractant of the invention is not particularly limited, for example, can with liquid, gel,
The forms such as granular, powdered use, and in addition can also be made and use by spraying.
The invention further relates to a kind of expelling methods of flying pest, which is characterized in that it is lured using above-mentioned flying pest
Agent.
Expelling method is not particularly limited, insecticidal constituent can be added into flying pest attractant, pass through desinsection
Lured pest is killed in the effect of ingredient, shown in embodiment that can also be as be described hereinafter, by using having used adhesive etc.
Trapper captures lured pest to be driven away.
There is pest hobby honey, carbohydrate, fruit, fruit processed goods, dairy products, fish and shellfish processed goods, fish and shellfish to extract
The tendency of the foods such as object, edible meat processed goods, edible meat extract, drinks, vinasse, cereal, thus sometimes can be by sharing
These foods improve attractant effect.
Above-mentioned food can be used alone, and can also be mixed with two or more.
Particularly preferably flying pest attractant is made to contain the honey that most pests tend to like.
Above-mentioned food ingredients can containing in flying pest attractant of the invention, can also be additionally provided on coating,
It is arranged near the place of flying pest attractant of the invention etc..
Flying pest attractant of the invention is especially played the flying pests such as fly class, mosquito class, small flies and is lured
Effect, thus it is preferred for these pests.
In particular, it is preferred that for flies classes such as housefly, latrine flies；The mosquitos class such as Culex pipiens pallens, aedes albopictus；Drosophila, eye fly,
The small flies such as mushroom fly, fungus gnat, moth fly.
Embodiment
Enumerate below embodiment to the present invention carry out more specific description, but as long as without departing from its main points, then the present invention simultaneously
It is not limited to these embodiments and comparative example.
Hereinafter, when being abbreviated as " % ", refer to " quality % ".
Aliphatic alcohol used in embodiment etc. (A), aliphatic acid ester (E) and specific carboxylic acid (H) are shown in table 1~3.
[table 1]
| No. | Aliphatic alcohol (A) |
| (1) | Ethyl alcohol |
| (2) | 1- propyl alcohol |
| (3) | 2- propyl alcohol |
| (4) | 2- propylene -1- alcohol |
| (5) | N-butyl alcohol |
| (6) | 2- methyl-1-propyl alcohol |
| (7) | 2- butanol |
| (8) | 2- methyl-2-propanol |
| (9) | 1- amylalcohol |
| (10) | 2- amylalcohol |
| (11) | 2-methyl-1-butene alcohol |
| (12) | 3- methyl-1-butanol |
| (13) | 2- methyl -2- butanol |
| (14) | 2-M3BOL |
| (15) | 3-M2BOL |
| (16) | 1- hexanol |
| (17) | 3- methyl-1-pentene alcohol |
| (18) | 4- methyl -2- amylalcohol |
[table 2]
[table 3]
| No. | Specific carboxylic acid (H) |
| (21) | Acetic acid |
| (23) | 2 hydroxy propanoic acid |
| (24) | Acetylformic acid |
| (27) | 2- hydroxybutyric acid |
| (28) | 3-hydroxybutyrate |
| (36) | 4-oxopentanoic acid |
| (41) | 3- hydracrylic acid |
| (42) | 2- hydroxy-2-methyl propionic acid |
| (43) | 3- hydroxy-2-methyl propionic acid |
| (44) | 2- hydroxypentanoic acid |
| (45) | 2- hydroxy-2-methyl butyric acid |
| (46) | 3-Hydroxy-3-methylbutyric acid |
| (47) | 3- hydroxyl -2,2- neopentanoic acid |
Test example 1 (trapping experiment of drosophila)
By substances A shown in table 4 (aliphatic alcohol (A)), substances E (aliphatic acid ester (E)), substances H
(specific carboxylic acid (H)), substances A+H (mixture of aliphatic alcohol (A) and specific carboxylic acid (H)), substances E+H (fat
The mixture of race's acid esters (E) and specific carboxylic acid (H)), substances A+E+H (aliphatic alcohol (A), aliphatic acid ester (E) and specific
The mixture of carboxylic acid (H)) it is added in hydromel (40%) according to 2.0% respectively, prepare each experimental liquid.
[table 4]
In table 4, the case where for using individual substances (substances A, substances E, substances H) and
Using individual substances mixture (substances A+H, substances E+H, substances A+E+H) the case where implement
Trapping experiment.
Below mainly to use substances A and substances H as individual substances, use substances A+H
The operation in embodiment is illustrated for the case where mixture as individual substances (No.61 and No.62), but
Same operation is also implemented in other cases.
Infiltrate prepared each experimental liquid respectively in 14mm (length) × 24mm (width) × 2mm (thickness) pulp respectively
The pulp for being impregnated with each experimental liquid is air-dried about 1 hour, produces made of each substances penetrate into pulp and lure by 1.0g
Agent.
Use 582mm (length) × 900mm (width) × 600mm (height) (0.31m3) glued board container as chamber.
2 faces of container side cover wire mesh, and for ease of observation, transparent plastic plate is arranged in top.
Prepare the bonding sheet of 4 100mm × 80mm as trapper, is provided with and is infiltrated in the central portion of wherein 2 pieces
The attractant of substances A (or substances H).It is provided in the central portion of other 2 pieces and is infiltrated with drawing for substances A+H
Lure.
4 are provided with the piece (trapper) of attractant to be arranged in chamber with 200mm space crossings.That is, from upper
In the case where side's observation chamber, the piece (trapper) for being infiltrated with the attractant of substances A (or substances H) will be provided with
Setting will be provided with the piece (trapping for being infiltrated with the attractant of substances A+H in upper left (position<1>) and bottom right (position<4>)
Device) it is arranged in upper right (position<2>) and lower-left (position<3>).
About 100 Drosophila melanogasters are put in a suitable place to breed in chamber.After putting in a suitable place to breed after about 24 hours investigation captured by bonding sheet it is grey
Fly number (insect-catching number).
In addition, making influence brought by the acquisition easiness difference of pest because the position in chamber is different to eliminate
(detailed reason is still not clear, it is believed that is due to caused by radiation modality of light etc.), make be provided be infiltrated with substances A
The piece (trapper) of the attractant of (or substances H) is infiltrated with the piece (trapping of the attractant of substances A+H with being provided with
Device) positional relationship be subjected to the same test on the contrary, investigate the fly number that is captured by bonding sheet.
In the test implemented, add up each (trapper) setting position in 2 kinds of the positional relationship for making piece (trapper)
Insect-catching number, calculate enhancing rate, the enhancing rate be using substances A+H when insect-catching number divided by substances A is used when
Insect-catching number obtained from be worth.
The test result in the case where the combination of the substances of the No.61 using table 4 is shown in table 5 and table 6.
[table 5]
Enhancing rate=73/51=1.43
[table 6]
Enhancing rate=80/61=1.31
Confirmed by table 5 and table 6, with ethyl alcohol is used alone or the case where 3-hydroxybutyrate compared with, by ethyl alcohol and 3-
In the case that hydroxybutyric acid mixes, there is collaboration attractant effect to drosophila.
In addition, the test result in the case where the combination using other substances shown in table 4 has been shown in table 7.
[table 7]
It is confirmed by table 7, compared with the case where aliphatic alcohol (A) or specific carboxylic acid (H) is used alone, is using these
Mixture in the case where, to drosophila have collaboration attractant effect.
In addition, aliphatic acid ester (E) and specific carboxylic acid (H) are similarly confirmed, compared with the case where being used alone,
There is collaboration attractant effect using these mixture.
In turn it is found that when by aliphatic alcohol (A), aliphatic acid ester (E), this 3 groups of mixing of specific carboxylic acid (H), enhancing rate
Very high, the tendency that collaboration attractant effect improves further enhances.
Then, making at least one of " substances A or substances E " and substances H is two or more chemical combination
The mixture of object carries out the trapping experiment of drosophila.
The test result in the case where the combination using substances shown in table 8 is shown in table 9.
[table 8]
[table 9]
According to table 9, the case where mixture of two or more compounds is as substances A or substances E is being used
Under also confirm, compared with the case where using individually aliphatic alcohol group or aliphatic acid ester group, by carbon atom number be 2
The above 6 aliphatic alcohol group below is to have in the case that 3 or more 8 aliphatic acid ester groups below mix to drosophila with carbon atom number
There is collaboration attractant effect.
According to table 9, use the mixture of two or more compounds as substances A, substances E, trier
It is also confirmed in the case where matter H, compared with the case where aliphatic alcohol (A) or specific carboxylic acid (H) is used alone, is using these
Mixture in the case where to drosophila have collaboration attractant effect.
In addition, also confirming same tendency for aliphatic acid ester (E) and specific carboxylic acid (H).
In turn, when by aliphatic alcohol (A), aliphatic acid ester (E), this 3 groups of mixing of specific carboxylic acid (H), similarly increase
Strong rate is very high, multiplication attractant effect further increases.
Test example 2 (trapping experiment of moth fly)
Use 582mm (length) × 900mm (width) × 600mm (height) (0.31m3) glued board container, made using moth fly
For test worm, to carry out similarly testing with test example 1.
The feelings for using a kind of compound as substances A, substances E and substances H respectively are shown in table 11
Condition (using substances shown in table 10 combination the case where) under test result.
[table 10]
[table 11]
According to table 11, in the case where moth fly also with the drosophila the case where in the same manner as confirm, by aliphatic alcohol (A) and/
Or in the case that aliphatic acid ester (E) and specific carboxylic acid (H) are used in mixed way, there is collaboration attractant effect.In addition, by aliphatic alcohol
(A), when aliphatic acid ester (E), this 3 groups of mixing of specific carboxylic acid (H), enhancing rate is very high.
Then, making at least one of " substances A or substances E " and substances H is two or more chemical combination
The mixture of object carries out the trapping experiment of moth fly.
The test result in the case where the combination using substances shown in table 12 is shown in table 13.
[table 12]
[table 13]
According to table 13, use the mixture of two or more compounds as substances A, substances E, trier
In the case where matter H, also there is same tendency with the case where individual substance is as these substances are used.
Test example 3 (trapping experiment of Culex pipiens pallens)
By substances A shown in table 14 (aliphatic alcohol (A)), substances E (aliphatic acid ester (E)), substances H
(specific carboxylic acid (H)), substances A+H (mixture of aliphatic alcohol (A) and specific carboxylic acid (H)), substances E+H (fat
The mixture of race's acid esters (E) and specific carboxylic acid (H)), substances A+E+H (aliphatic alcohol (A), aliphatic acid ester (E) and specific
The mixture of carboxylic acid (H)) it is mixed respectively according to 2.0% with the black honey of sugarcane, prepare liquid attractant.
Prepared liquid attractant is respectively packed into 10.0g in the round container of 60mm (internal diameter) × 45mm (height).
[table 14]
Use 850mm (length) × 1500mm (width) × 820mm (height) (1.04m3) glued board container as chamber.
2 faces of container side cover wire mesh, and for ease of observation, transparent plastic plate is arranged in top.
2 therein settings are being added the bonding sheet (hole for being provided with 4 diameter 5mm) for preparing 4 100mm × 80mm
On the round container of liquid attractant added with substances A (or substances H), trapper is made.Other 2 are set
It sets on the round container that joined the liquid attractant added with substances A+H, makes trapper.
4 trappers are arranged in chamber with 300mm space crossings.That is, the chamber viewed from above the case where
Under, the liquid added with substances A (or substances H) has been set using in upper left (position<1>) and bottom right (position<4>)
The trapper of attractant has been set using the liquid added with substances A+H in upper right (position<2>) and lower-left (position<3>)
The trapper of state attractant.
About 100 Culex pipiens pallens are put in a suitable place to breed in chamber.After putting in a suitable place to breed after about 24 hours investigation captured by bonding sheet it is light
Color culex number.
In addition, having used the trapper of the liquid attractant added with substances A (or substances H) and having used
The positional relationship of the trapper of liquid attractant added with substances A+H is subjected to the same test on the contrary, and investigation is glued
Close the Culex pipiens pallens number of piece capture.
The test result in the case where the combination of the substances of the No.81 using table 14 is shown in table 15 and table 16.
[table 15]
Enhancing rate=83/64=1.30
[table 16]
Enhancing rate=85/62=1.37
Confirmed by table 15 and table 16, with n-butyl alcohol is used alone or the case where Acetylformic acid compared with, by 1- fourth
In the case that alcohol is mixed with Acetylformic acid, there is collaboration attractant effect to Culex pipiens pallens.
In addition, showing the test result in the case where combination using other substances shown in table 14 in table 17.
[table 17]
According to table 17, in the case where Culex pipiens pallens also with the drosophila the case where in the same manner as confirm, by aliphatic alcohol (A)
And/or in the case that aliphatic acid ester (E) and specific carboxylic acid (H) are used in mixed way, there is collaboration attractant effect.In addition, by fatty
When race's alcohol (A), aliphatic acid ester (E), this 3 groups of mixing of specific carboxylic acid (H), enhancing rate is very high.
Then, making at least one of " substances A or substances E " and substances H is two or more chemical combination
The mixture of object carries out the trapping experiment of moth fly.
The test result in the case where the combination using substances shown in table 18 is shown in table 19.
[table 18]
[table 19]
According to table 19, use the mixture of two or more compounds as substances A, substances E, trier
In the case where matter H, also there is same tendency with the case where individual substance is as these substances are used.
Industrial applicibility
Flying pest attractant of the invention shows attractant effect to various flying pests, thus is widely used as general
Home-use, industrial etc. attractant.
Claims (11)
1. a kind of flying pest attractant, which is characterized in that it is 2 or more 6 aliphatic alcohols (A) below that it, which contains carbon atom number,
And/or carbon atom number is 3 or more 8 aliphatic acid esters (E) below and specific carboxylic acid (H), which is carbon atom
Number is 3 or more 5 ketone acids or carboxylic acid or acetic acid below.
2. flying pest attractant as described in claim 1 contains the aliphatic alcohol (A), the aliphatic acid ester (E)
With the specific carboxylic acid (H).
3. flying pest attractant as claimed in claim 1 or 2, wherein the aliphatic alcohol (A), the aliphatic acid ester
(E) and the content ratio of the quality criteria of the specific carboxylic acid (H) is 0.1≤(H)/[(A)+(E)+]≤0.9 (H).
4. flying pest attractant as claimed any one in claims 1 to 3, wherein the specific carboxylic acid (H) be selected from by
2 hydroxy propanoic acid, Acetylformic acid, 2- hydroxybutyric acid, 3-hydroxybutyrate, 4-oxopentanoic acid, 3- hydracrylic acid, 2- hydroxyl -2- first
Base propionic acid, 3- hydroxy-2-methyl propionic acid, 2- hydroxypentanoic acid, 2- hydroxy-2-methyl butyric acid, 3-Hydroxy-3-methylbutyric acid, 3- hydroxyl
The carboxylic acid of one or more of the group of base -2,2- neopentanoic acid and acetic acid composition.
5. flying pest attractant according to any one of claims 1 to 4, wherein the aliphatic alcohol (A) be selected from by
Ethyl alcohol, 1- propyl alcohol, 2- propyl alcohol, 2- propylene-1- alcohol, n-butyl alcohol, 2- methyl-1-propyl alcohol, 2- butanol, 2- methyl-2-propanol, 1- penta
Alcohol, 2- amylalcohol, 2-methyl-1-butene alcohol, 3- methyl-1-butanol, 2- methyl -2- butanol, 2-M3BOL, 3- first
The group of base -2- butene-1-ol, 1- hexanol, 3- methyl-1-pentene alcohol, 4- methyl -2- amylalcohol and 2,2- dimethyl-1-butanol composition
One or more of aliphatic alcohol.
6. the flying pest attractant as described in any one of claims 1 to 5, wherein the aliphatic acid ester (E) is fat
For race's acid (E1) and alcohol (E2) through structure made of dehydrating condensation, which is selected from by acetic acid, propionic acid, 2- hydroxyl third
Acid, Acetylformic acid, butyric acid, 2 Methylpropionic acid, 2- hydroxybutyric acid, 3-hydroxybutyrate, 2- butenoic acid, valeric acid, 2,2- dimethyl
Propionic acid, 2-Methyl Butyric Acid, 3 Methylbutanoic acid, (Z) -2- methyl but-2-ene acid, (E) -2- methyl but-2-ene acid, 4- oxo penta
The aliphatic acid of one or more of the group of acid, caproic acid, 2 Ethylbutanoic acid and 2- hexenoic acid composition, the alcohol (E2) are selected from by first
Alcohol, ethyl alcohol, 1- propyl alcohol, 2- propyl alcohol, 2- propylene-1- alcohol, n-butyl alcohol, 2- methyl-1-propyl alcohol, 2- butanol, 2- methyl-2-propanol,
1- amylalcohol, 2- amylalcohol, 2-methyl-1-butene alcohol, 3- methyl-1-butanol, 2- methyl -2- butanol, 2-M3BOL, 3-
What methyl-2-butene -1- alcohol, 1- hexanol, 3- methyl-1-pentene alcohol, 4- methyl -2- amylalcohol and 2,2- dimethyl-1-butanol formed
The alcohol of one or more of group.
7. such as flying pest attractant described in any one of claims 1 to 6, wherein make containing two or more compounds
For the specific carboxylic acid (H).
8. the flying pest attractant as described in any one of claims 1 to 7 is liquid, gel, graininess or powder
Shape.
9. such as flying pest attractant described in any item of the claim 1 to 8, wherein further containing selected from by honey, sugar
Class, fruit, fruit processed goods, dairy products, fish and shellfish processed goods, fish and shellfish extract, edible meat processed goods, edible meat extract
One or more of object, drinks, vinasse and group of cereal composition.
10. flying pest attractant as claimed in any one of claims 1-9 wherein, be used for selected from by Culex pipiens pallens, lineae ablicantes she
The flying pest of one or more of the group that mosquito, drosophila, eye fly, mushroom fly, fungus gnat and moth fly form.
11. a kind of expelling method of flying pest, which is characterized in that it uses winged described in any one of any one of claims 1 to 10 10
Xiang attracting pests agent.
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| PCT/JP2017/037804 WO2018083992A1 (en) | 2016-11-01 | 2017-10-19 | Harmful flying insect attractant |
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|---|---|---|---|---|
| CN101268786A (en) * | 2008-04-18 | 2008-09-24 | 浙江大学 | Winged insect attractant |
| CN102599193A (en) * | 2012-03-01 | 2012-07-25 | 西南大学 | Food attractant of Bactrocera minax |
| CN103155919A (en) * | 2013-03-26 | 2013-06-19 | 德清科中杰生物科技有限公司 | Culex attractant |
| CN104054749A (en) * | 2014-06-24 | 2014-09-24 | 泉州市青翠山农业科技有限公司 | Attractant and insect-catching device |
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| JP4680574B2 (en) * | 2004-11-17 | 2011-05-11 | 大日本除蟲菊株式会社 | Gel-like flying insect attractant composition |
| JP2012041326A (en) * | 2010-08-17 | 2012-03-01 | Yuutekku Business Kk | Pest control material |
| JP5829445B2 (en) * | 2011-07-08 | 2015-12-09 | フマキラー株式会社 | Insect attractant and insect attractant kit |
| JP6093164B2 (en) * | 2011-12-28 | 2017-03-08 | 大日本除蟲菊株式会社 | Flying pest attractant |
| CN103651580B (en) * | 2012-09-15 | 2015-11-18 | 长沙绿骑士生物科技有限公司 | One catches mosquito lure and preparation method thereof |
| CN103636680A (en) * | 2013-12-04 | 2014-03-19 | 范宇 | Compound for trapping and killing drosophila melanogaster |
| CN104381329A (en) * | 2014-11-19 | 2015-03-04 | 湖南师范大学 | Bactrocera minax adult attractant as well as preparation method and application of bactrocera minax adult attractant |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101268786A (en) * | 2008-04-18 | 2008-09-24 | 浙江大学 | Winged insect attractant |
| CN102599193A (en) * | 2012-03-01 | 2012-07-25 | 西南大学 | Food attractant of Bactrocera minax |
| CN103155919A (en) * | 2013-03-26 | 2013-06-19 | 德清科中杰生物科技有限公司 | Culex attractant |
| CN104054749A (en) * | 2014-06-24 | 2014-09-24 | 泉州市青翠山农业科技有限公司 | Attractant and insect-catching device |
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| WO2018083992A1 (en) | 2018-05-11 |
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