CN1096842C - 香波组合物和其制备方法 - Google Patents
香波组合物和其制备方法 Download PDFInfo
- Publication number
- CN1096842C CN1096842C CN97198233A CN97198233A CN1096842C CN 1096842 C CN1096842 C CN 1096842C CN 97198233 A CN97198233 A CN 97198233A CN 97198233 A CN97198233 A CN 97198233A CN 1096842 C CN1096842 C CN 1096842C
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- CN
- China
- Prior art keywords
- siloxanes
- cationic
- lauryl
- surfactant
- sulfate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000002360 preparation method Methods 0.000 title claims description 10
- 125000002091 cationic group Chemical group 0.000 claims abstract description 31
- 239000000839 emulsion Substances 0.000 claims abstract description 31
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 9
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 5
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- -1 siloxanes Chemical class 0.000 claims description 99
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- 238000000034 method Methods 0.000 claims description 24
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 12
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 11
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 claims description 9
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 claims description 6
- 229940063953 ammonium lauryl sulfate Drugs 0.000 claims description 6
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- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
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- TVACALAUIQMRDF-UHFFFAOYSA-N dodecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCOP(O)(O)=O TVACALAUIQMRDF-UHFFFAOYSA-N 0.000 claims description 2
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- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 claims description 2
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Abstract
本发明公开了一种含水香波组合物，该组合物除包含水外，还包含：i)至少一种表面活性剂，其选自阴离子表面活性剂、非离子表面活性剂、两性离子表面活性剂、两性表面活性剂或其混合物；ii)不溶性不挥发硅氧烷的乳化颗粒；iii)一种阳离子头发调理聚合物，其阳离子电荷密度为约+3.0meq/g或更小，其中，将不溶性不挥发硅氧烷的乳化颗粒以预成形含水乳液掺入香波组合物中，在乳液和香波组合物中硅氧烷的平均粒度为2～30微米。
Description
发明领域
本发明涉及香波组合物，更具体地说，本发明涉及包含硅氧烷的乳化颗粒的香波组合物，该组合物可以调理头发，使其更为柔顺且易于整理。
发明背景
硅氧烷作为调理剂在化妆品制剂中使用已是众所周知的事情，在专利文献中多有报导。通常，硅氧烷油的分散液滴悬浮于组合物中，在将组合物涂敷于头发上时，硅氧烷会沉积于头发上。
WO92/10162公开了一种生产硅氧烷香波的常规方法。在该文献中，硅氧烷物质是通过就地加热法将其直接乳化进入香波中的，其中，掺入硅氧烷的整个香波混合物在升高的温度下充分混合，经高剪切碾磨机泵送，然后冷却。硅氧烷可在第一步中借助阴离子表面活性剂及脂肪醇进行分散，形成一种预混物。然后，将这种预混物再与香波的其它成分混合，经高剪切碾磨机泵送，冷却，得到最终的组合物。
WO92/10162所述就地加热法的缺点是，就整个香波的生产操作过程来说，粘稠硅氧烷油的工艺处理是较为困难的。
所述过程的其它缺陷还在于，常常需要特殊设备来控制生产过程中的硅氧烷粒度。GB2,170,216A公开了一种类似的方法，其中，向香波组合物中掺入不溶性不挥发硅氧烷是用高剪切混合机进行剪切完成的，需剪切至硅氧烷粒度平均小于2微米。据认为其粒度分布是约2～55微米。
为了解决上述硅氧烷就地加热法相关的问题，提出了另一种配成含水乳液掺入硅氧烷的方法。该方法可使得掺入的硅氧烷具有预定的可控制的粒度分布。硅氧烷是不溶性的，在全配方香波组合物中保持乳化状态，因而，就无需在全配方香波组合物中采用硅氧烷的高剪切加工步骤。这也使组合物的生产过程更为便利。
USP5,085,087公开了一种将不溶性不挥发硅氧烷掺入调理香波中的典型方法，该方法中，硅氧烷是以平均粒度小于2微米的预成形含水乳液掺入香波组合物中的。所有的成分在简单加热或冷却过程中进行混合，其中，硅氧烷在乳液中的平均粒度与其在最终香波组合物中的平均粒度相同。该粒度优选为0.01～1微米，如0.4微米。
EP 0 529 883 A1公开了一种采用类似方法制备的洗发香波组合物，该组合物包含微乳化的硅氧烷颗粒，其粒度为0.15微米或小于0.15微米，如0.036微米。以这种方式进一步减少粒度据认为可改善稳定性、光学性能及调理性能。
USP5,085,087与EP 0 529 883 A1所公开的香波均需要阳离子聚合物，以使硅氧烷可有效地沉积于头发上。但是，与这些较小粒度硅氧烷/阳离子聚合物配方相关的问题是，它们可能会造成不希望出现的感觉，通常表现为感觉到“滑腻”和/或干燥后的头发有沉重感。
现发现，如果在基于表面活性剂的香波组合物中采用大粒度含水预成形乳液形式的不溶性不挥发硅氧烷，那么，在赋予头发以调理作用的同时，将可以消除与上述现有技术组合物相关的干发不良感觉。
令人惊奇且有利地发现，本发明的组合物中，阳离子聚合物的存在可选择性地增强香波的湿发性能，如润湿感及易于湿梳理，同时可减少干发的易梳通性。与之相对照，在现有技术中掺有阳离子聚合物的配方中，阳离子聚合物的存在及较小粒度的预成形硅氧烷乳液，将不能选择性地增加湿发的易梳理性。至少在某种程度上干发的易梳通性也有增长。
本发明组合物所能观察到的湿性能的选择性增强，如易于进行湿梳理对于消费者而言是有益的。这是因为消费者需要在湿发状态下梳通头发，但当头发处于干燥状态时，如果头发太易于滑过梳子，其头发将难于进行定型。
发明概述
本发明提供了一种含水香波组合物，该组合物除包含水外，还包括：
i)至少一种表面活性剂，其选自阴离子表面活性剂、非离子表面活性剂、两性离子表面活性剂、两性表面活性剂或其混合物；
ii)不溶性不挥发硅氧烷的乳化颗粒；
iii)一种阳离子头发调理聚合物，其阳离子电荷密度为约+3.0meq/g或更小，
其中，将不溶性不挥发硅氧烷的乳化颗粒以预成形含水乳液状态掺入香波组合物中，该乳液和香波组合物中硅氧烷的平均粒度为2～30微米。
另一方面，本发明提供了一种所述香波组合物的制备方法，该方法包括使水、表面活性剂、阳离子调理聚合物与硅氧烷的预成形乳液混合，其中，在乳液和香波组合物中硅氧烷的平均粒度为2～30微米。
发明详述i)表面活性剂
本发明的组合物包含表面活性剂，其选自阴离子表面活性剂、非离子表面活性剂、两性离子表面活性剂、两性表面活性剂或其混合物。
适宜的阴离子表面活性剂包括烷基硫酸盐、烷基醚硫酸盐、烷芳基磺酸盐、烷酰基羟乙基磺酸盐、烷基琥珀酸盐、烷基磺基琥珀酸盐、N-烷酰基(alkoyl)肌氨酸盐、烷基磷酸盐、烷基醚磷酸盐、烷基醚羧酸盐和α-烯烃磺酸盐，特别是其钠盐、镁盐、铵盐和单、二和三乙醇胺盐。烷基和酰基基团通常包含8～18个碳原子，并可为不饱和基团。每一分子烷基醚硫酸盐、烷基醚磺酸盐和烷基醚羧酸盐可包含1～10个氧化乙烯或氧化丙烯单元，优选包含2～3个氧化乙烯单元。
适宜的阴离子表面活性剂的实例包括：油基琥珀酸钠、月桂基磺基琥珀酸铵、月桂基硫酸铵、十二烷基苯磺酸钠、三乙醇胺十二烷基苯磺酸盐、椰油基羟乙基磺酸钠、月桂酰基羟乙基磺酸钠和N-月桂基肌氨酸钠。最优选的阴离子表面活性剂是月桂基硫酸铵、三乙醇胺月桂基硫酸盐、三乙醇胺单月桂基磷酸盐、月桂基醚1EO、2EO和3EO硫酸钠，月桂基硫酸铵以及月桂基醚1EO、2EO和3EO硫酸铵。
适用于本发明组合物的非离子表面活性剂可包括脂族(C8～C18)直链或支链伯或仲醇或酚与氧化烯的缩合产物，所述氧化烯通常为环氧乙烷，所述缩合产物通常具有6～30个氧化乙烯基团。其它适宜的非离子表面活性剂包括单或二烷基链烷醇酰胺。其实例包括椰油单或二乙醇酰胺和椰油单异丙醇酰胺。
适用于本发明组合物的两性与两性离子表面活性剂可包括烷基胺氧化物、烷基甜菜碱、烷基酰氨基丙基甜菜碱、烷基磺基甜菜碱、烷基甘氨酸盐、烷基羧基甘氨酸盐、烷基两性丙酸盐、烷基两性甘氨酸盐、烷基酰氨基丙基羟基甜菜碱、酰基牛磺酸盐和酰基谷氨酸盐，其中，烷基和酰基具有8～19个碳原子。其实例包括月桂基氧化胺、椰油基二甲基磺基丙基甜菜碱，优选月桂基甜菜碱、椰油酰氨基丙基甜菜碱和椰油两性丙酸钠。
本发明的香波组合物中，表面活性剂的含量为0.1～50wt％，优选0.5～30wt％。
通常，本发明的香波组合物中，表面活性剂的含量为0.1～50wt％，优选5～30wt％，更优选10～25wt％。ii)硅氧烷
本发明的香波组合物包含一种不溶性不挥发硅氧烷，其可以是一种或多种聚烷基硅氧烷、一种或多种聚烷芳基硅氧烷或其混合物。这种硅氧烷不溶于组合物的含水基质，因而是以乳化形式存在，硅氧烷作为被分散的颗粒。
适宜的聚烷基硅氧烷包括聚二甲基硅氧烷，由CAFTAN命名为聚二甲基硅氧烷(dimethicone)，25℃时的粘度为5～100,000厘沲。这些硅氧烷可从General Electric公司以Viscasil系列商购，或从DowCorning公司以DC200系列商购。硅氧烷的粘度可采用玻璃毛细管粘度计测量，所用方法为Doe Corning Corporate测量法CTM 004(1970.7.20)所介绍。
还可采用的聚烷基硅氧烷是聚二乙基硅氧烷。
可用于本发明组合物的聚烷芳基硅氧烷包括聚甲基苯基硅氧烷，其25℃时的粘度为15～65厘沲。这些硅氧烷可从General Elictric公司以SF1075甲基苯基流体商购，或从Dow Corning公司以556化妆品级流体商购。
还可采用硅氧烷胶，如USP4,152,416(Spitzer)所述的那些，以及General Electric的硅橡胶产品资料表SE30、SE33、SE54和SE76所列产品。“硅氧烷胶”是指分子量为200,000～1,000,000的聚二有机硅氧烷，其具体实例包括：聚二甲基硅氧烷聚合物、聚二甲基硅氧烷/二苯基/甲基乙烯基硅氧烷共聚物、聚二甲基硅氧烷/甲基乙烯基硅氧烷共聚物，及其混合物。
本发明的组合物中还可采用具有氨基官能团的硅氧烷，其CTFA命名为amodimethicone，具有羟基端基的聚二甲基硅氧烷(CTFA命名为dimethiconol)也可采用。
如上所述的硅氧烷物质可以预成形含水乳液加入本发明的香波组合物中。在乳液和香波组合物中硅氧烷物质的平均粒度为2～30微米，优选2～20微米，更优选3～10微米。采用激光散射技术测量粒度，具体可使用来自malvern Instruments的2600D粒度测量仪进行测量。
预成形乳液可这样制备：使硅氧烷与水进行高剪切机械混合，或将不溶性不挥发硅氧烷与水及乳化剂乳化，例如，使硅氧烷混合进入加热的乳化剂溶液中，或同时采用机械与化学乳化法。另一种适宜用于制备乳液的技术是乳液聚合。US 2,891,820(Hyde)、3,294,725(Findlay)和US3,360,491(Axon)描述了乳液聚合的硅氧烷。
在制备预成形硅氧烷乳液时，任何表面活性剂物质可单独用作乳化剂，或加以组合用作乳化剂。适宜的乳化剂包括阴离子乳化剂、阳离子乳化剂和非离子乳化剂。阴离子乳化剂的实例为烷基芳基磺酸盐，如十二烷基苯磺酸钠；烷基硫酸盐，如月桂基硫酸钠；烷基醚硫酸盐，如月桂基醚nEO硫酸钠，其中n为1～20；烷基酚醚硫酸盐，如辛基酚醚nEO硫酸盐，其中n为1～20；磺基琥珀酸盐，如二辛基磺基琥珀酸钠。
非离子乳化剂的实例为烷基酚乙氧基化物，如壬基酚nEO乙氧基化物，其中n为1～50；醇乙氧基化物，如月桂基nEO醇，其中n为1～50；酯乙氧基化物，如聚氧乙烯单硬脂酸酯，其中，氧亚乙基单元的数目为1～30。
通常，预成形乳液包含约50％的硅氧烷。预成形乳液可从硅油供应商处购得，如下述公司：DoW Corning、General Electric、UnionCarbide、Wacker Chemie、Shin Etsu、Toshiba、Toyo Beauty Co和Toray Silicone Co。具体实例为由Dow Corning出售的DC-1310以及由Shin-Etsu出售的X-52-1086、X-52-2127和X-52-2112。
本发明的组合物通常包含0.01～20wt％，优选0.1～10wt％，更优选0.25～3wt％的不溶性不挥发硅氧烷。如果所述硅氧烷的含量小于0.01wt％，则几乎观察不到调理效果，如果该值大于20wt％，则头发会显得较为油腻。
在香波组合物中含水预成形乳液的含量为0.02～40wt％，优选0.2～20wt％。
当然，乳液的实际用量将取决于乳液的浓度，应对其进行适当选择使之在最终组合物中得到所需之量的不溶性不挥发硅氧烷。iii)阳离子调理聚合物
本发明的头发处理组合物的另一种成分是阳离子调理聚合物。
聚合物可以是均聚物，或由两种或多种不同类型的单体形成的聚合物。聚合物的分子量通常为5000～10,000,000，一般至少为10,000，优选范围为100,000～约2,000,000。所述聚合物应具有阳离子含氮基团，如季铵或质子化氨基基团，或其组合。
阳离子电荷密度以至少为0.1meq/g为宜，优选在0.8以上或更高。但阳离子电荷密度不应超过3meq/g，优选小于2meq/g。电荷密度用kjeldahl法测量，在所采用的pH值条件下应在上述限度之内，所述pH值通常为约3～9，优选4～8。
阳离子含氮基团通常是在阳离子调理聚合物的总单体单元一部分中以取代基存在。因而，当聚合物不是均聚物时，其应包含间隔基非阳离子单体单元。这种聚合物在下述文献中有述：CTFA Cosmetic IngredientDirectory(第3版)。
例如，适宜的阳离子调理聚合物包括：具有阳离子胺或季铵官能团的乙烯基单体与水溶性间隔基单体的共聚物，所述水溶性间隔基单体例如为(甲基)丙烯酰胺、烷基和二烷基(甲基)丙烯酰胺、(甲基)丙烯酸烷基酯、乙烯基己内酯和乙烯基吡咯烷。烷基和二烷基取代基的单体优选具有C1～C7烷基，更优选C1～C3烷基。其它适宜的间隔基包括乙烯基酯、乙烯基醇、马来酸酐、丙二醇及乙二醇。
阳离子胺可以是伯胺、仲胺或叔胺，这取决于组合物的具体类别及pH值。通常，优选采用仲胺和叔胺，更优选叔胺。
胺取代的乙烯基单体和胺可以以胺形式被聚合，然后通过季铵化转化成铵。
适宜的阳离子氨基和季铵单体的实例包括被下述化合物取代的乙烯基化合物：二烷基氨基烷基丙烯酸酯、二烷基氨基烷基甲基丙烯酸酯、单烷基氨基烷基丙烯酸酯、单烷基氨基烷基甲基丙烯酸酯、三烷基甲基丙烯酰氧基烷基铵盐、三烷基丙烯酰氧烷基铵盐、二烯丙基季铵盐，以及具有环状阳离子含氮环的乙烯基季铵单体，如吡啶鎓、咪唑鎓及季铵化吡咯烷，如烷基乙烯基咪唑鎓、烷基乙烯基吡啶鎓、烷基乙烯基吡咯烷盐。这些单体的烷基部分优选低级烷基，如C1～C3烷基，更优选C1烷基和C2烷基。
适宜的胺取代乙烯基单体包括：二烷基氨基烷基丙烯酸酯、二烷基氨基烷基甲基丙烯酸酯、二烷基氨基烷基丙烯酰胺和二烷基氨基烷基甲基丙烯酰胺，其中，烷基优选C1～C7烃基，更优选C1～C3烷基。
阳离子调理聚合物可包含由胺和/或季铵取代的单体和/或相容的间隔基单体衍生的单体单元的混合物。
适宜的阳离子调理聚合物的实例包括：1-乙烯基-2-吡咯烷与1-乙烯基-3-甲基-1-咪唑鎓盐(如氯化物盐)的共聚物(在工业上被化妆品、盥洗用品和香料协会“CTFA”命名为Polyquaternium-16)，如由BASFWyandotte Corp.(Parsippany，NJ.USA)以LUVIQUAT商品名出售的产品(如LUVIQUATFC 370)；1-乙烯基-2-吡咯烷与二甲基氨基乙基甲基丙烯酸酯的共聚物(在工业上被CTFA命名为Polyquaternium-11)，如由Gar Corporation(Wayne，NJ.USA)以GAFQUAT商品名出售的产品(如GAFQUAT 755N)；含阳离子二烯丙基季铵的聚合物，例如包括二甲基二烯丙基氯化铵均聚合物，及丙烯酰胺与二甲基二烯丙基氯化铵的共聚物，在工业上被CTFA分别命名为Polyquaternium-6和Polyquaternium-7；具有3～5个碳原子的不饱和羧酸均聚物和共聚物的氨基烷基酯的无机酸盐，如USP 4,009,256所述的那些；和阳离子聚丙烯酰胺，如本申请人共同未决UK专利申请号9403156.4(WO 95/22311)所述的那些。
其它可使用的阳离子调理聚合物包括多糖聚合物，如阳离子纤维素衍生物和阳离子淀粉衍生物。
适用于本发明组合物中的阳离子多糖聚合物包括下式的那些：
R1A-O(R-N+-R3X-)
R2其中，A为葡糖酐残基，如淀粉或纤维素葡糖酐残基，R为亚烷基氧亚烷基、聚氧化烯基团或羟基亚烷基基团或其组合，R1、R2和R3独立地为烷基、芳基、烷芳基、芳烷基、烷氧基烷基或烷氧基芳基，每个基团至多包含约18个碳原子，对于每个阳离子部分而言，碳原子的总数(即R1、R2和R3的碳原子总数)优选为约20或小于20，X为阴离子抗衡离子，如前所述。
阳离子纤维素可从Amerchol Corp.(Edison，NJ，USA)以其聚合物系列Polymer JR(商标)和LR(商标)商购，为羟乙基纤维素与环氧化物取代的三甲基铵反应的盐，其在工业上被CTFA称之为Polyquaternium 10。另一类阳离子纤维素包括羟乙基纤维素与环氧化物取代的月桂基二甲基铵反应的聚合季铵盐，其在工业上被CTFA称之为Polyquaternium 24。这些物质均可从Amerchol Corp.(Edison，NJ，USA)以商品名Polymer LM-200商购。
其它可采用的阳离子调理聚合物包括阳离子瓜尔胶衍生物，如瓜尔胶羟丙基氯化三铵(trimonium chloride)(可从Celanese Corp.以Jaguar商标系列商购)。其它物质包括含季氮的纤维素醚(如USP 3,962,418所述)，以及醚化纤维素与淀粉的共聚物(如USP3,958,581所述)。
阳离子调理聚合物优选选自：阳离子聚丙烯酰胺、羟基烷基纤维素醚和阳离子瓜尔胶衍生物。特别优选电荷密度为0.8meq/g的JaguarC13S。Jaguar C13S为瓜尔胶羟丙基氯化三铵。其它特别适宜的物质包括Jaguar C15、Jaguar C17和Jaguar C16和Jaguar C162。优选的纤维素醚为Polymer JR400。
如上所述，令人惊奇地发现，在本发明的组合物中，加入阳离子聚合物可增强香波的润湿性，而不会造成以后干发的负面效果，如会导致定型困难的滑溜感。
有利的是，本发明组合物中的阳离子调理聚合物用量，并不受这些物质应当作为硅氧烷成分的沉积助剂所需量的控制。在本发明组合物中，其具体含量主要取决于具体采用的表面活性剂体系。通常，其含量可为0.01～3wt％。
本发明还涉及不溶性不挥发硅氧烷的含水预成形乳液在包含大量表面活性剂的香波组合物中的用途，所述硅氧烷在乳液及香波组合物中的平均粒度为2～30微米，这种乳液可用于改善香波组合物对头发的调理性能。
本发明的香波组合物还可包含0.1～5wt％的硅氧烷悬浮剂。其实例为聚丙烯酸、丙烯酸的交联聚合物、丙烯酸与疏水性单体的共聚物、含羧酸单体与丙烯酸酯的共聚物、丙烯酸与丙烯酸酯的交联共聚物、杂多糖胶和结晶型长链酰基衍生物。长链酰基衍生物优选选自：乙二醇硬脂酸酯、具有16～22个碳原子的脂肪酸的链烷醇酰胺和其混合物。乙二醇二硬脂酸酯和聚乙二醇3二硬脂酸酯是优选的长链酰基衍生物。聚丙烯酸可以Carbopol420、Carbopol488或Carbopol493商品名商购。也可以使用用多官能试剂交联的丙烯酸的聚合物，它们可以Carbopol910、Carbopol934、Carbopol940、Carbopol941和Carbopo1980商品名商购。包含一种单体与丙烯酸酯的羧酸共聚物的适宜实例为Carbopol1342。所有这些Carbopol物质均可从Goodrich商购，Carbopol为其商标。
适宜的丙烯酸与丙烯酸酯的交联聚合物为Pemulen TR1或PemulenTR2。适宜的杂多糖胶为黄原胶，例如可以Kelzan mu商购。
根据所采用的组合物的类型，本发明的组合物中还可加入一种或多种常规加至头发调理组合物中的成分。这种附加成分包括：定型剂，如树脂与定发聚合物、香料、染料、缓冲剂或pH值调节剂、粘度改性剂、遮光剂、珠光剂、防腐剂、杀菌剂、去头屑剂、泡沫促进剂、蛋白质、增湿剂、草本植物或其它植物提取物以及其它天然成分。
通过下述非限定性实例对本发明进行进一步说明。
实施例
将下述成分按照所述用量进行混合以制备香波组合物：实施例1
wt％
月桂基硫酸铵 14.0
椰油酰氨基丙基甜菜碱 2.0
硅油(1) 2.0
Carbopol 980(2) 0.4
Jaguar C13S(3) 0.2
防腐剂、香料、粘度调节剂 适量
加水至 100.0
(1)硅油是由Dow Corning公司出售的DC-1310，为聚二甲基硅氧烷(dimethicone 60,000cs)在非离子表面活性剂中的乳液。
(2)Carbopol 980为从B F Goodrich商购的交联聚丙烯酸酯。
(3)Jaguar C13S为由Celanese公司商购的瓜尔胶羟丙基氯化三铵。实施例2
Wt％
月桂基硫酸铵 14.0
椰油酰氨基丙基甜菜碱 2.0
硅油(1) 2.0
Carbopol 980 0.4
乙二醇单硬脂酸酯 1.5
Jaguar C13S 0.2
防腐剂、香料、粘度调节剂 适量
加水至 100.0
(1)如实施例1。实施例3
Wt％
月桂基醚2EO硫酸钠 12.0
椰油酰氨基丙基甜菜碱 4.0
硅油(1) 0.5
Carbopol 980 0.4
Jaguar C13S 0.03
乙二醇单硬脂酸酯 1.5
防腐剂、香料、粘度调节剂 适量
加水至 100.0
(1)如实施例1。
所有实施例1～3的香波均采用简单冷制法制备，其中，所有的成分采用桨式搅拌器进行混合。
乳液中的硅氧烷颗粒的平均粒度为7.7微米，在香波组合物中也保持该粒度。实施例4和比较例A
对在采用或不采用阳离子聚合物的情况下，掺入不同粒度的预乳化硅氧烷的香波配方的湿/干调理性能进行评价。实验用香波
所要制备的香波组合物包含如下表所示成分。实施例4为本发明的配方。比较例A的配方中，实施例4的预乳化大粒度硅氧烷被等量的现有技术所述的预乳化较小粒度硅氧烷替换。对照例1为实施例4的配方除去阳离子聚合物(Jaguar C-13-S)后的配方。对照例2为比较例A除去了阳离子聚合物(Jaguar C-13-S)后的配方。
| 成分 | 实施例4 | 对照例1 | 比较例A | 对照例2 |
| SLES(100％) | 14 | 14 | 14 | 14 |
| CAPB(100％) | 2 | 2 | 2 | 2 |
| Jaguar C-13-S | 0.2 | - | 0.2 | - |
| DC-1310(60％) | 3.3 | 3.3 | - | - |
| BY22-026(50％)(1) | - | - | 4 | 4 |
| Carbopol 980 | 0.4 | 0.4 | 0.4 | 0.4 |
| 甲醛液 | 0.1 | 0.1 | 0.1 | 0.1 |
| 加水至 | 100 | 100 | 100 | 100 |
(1)BY22-026为粒度 0.5微米的60,000cs聚二甲基硅氧烷的乳液，来自ToraySilicone公司。调理性能
上述实验用各香波的调理性能评价如下：
将一簇7g的头发用0.7g实验用产品进行处理，涂沫起泡30秒，用水漂洗。所述过程重复一次。每种产品准备三簇头发用于评估，由12个训练有素的专家来进行调理性能的评估，其方式是评定每对比较试验和以95％以上确信度来评出其明显差别。结果
其结果列于下表中，其各排包括的项目是将总分记为100时两种被加以比较的香波的相对分配值，分值较高的表明每对中所优选的一个。
两个由专家组评定的特性是(a)容易湿梳理，(b)容易干梳理，其结果如下：
| 容易湿梳理 | 容易干梳理 | |
| 实施例4比对照1 | 70 | 26 |
| 比较例A比对照2 | 72 | 80 |
该结果表明：就湿梳理容易性来看，实施例4明显大于对照例1，而就干梳理容易性来看，则对照例1明显大于实施例4，比较例A比对照例2千和湿梳理容易性均明显较大。结论
本发明的实施例4表明，加入阳离子聚合物可增加由配方赋予的湿发易梳理性，而降低干发的易梳理性。
比较例A表明，如果本发明的预乳化硅氧烷的大粒度被现有技术的预乳化硅氧烷的小粒度替换，那么，不能观察到湿梳理性的选择性提高。与本发明的实施例相对照，比较例A表明，加入阳离子聚合物可提高由配方赋予的湿发易梳理性，但在很大程度上也会增加干发的易梳理性(正如由专家组所评定的)。
Claims (9)
1.一种含水香波组合物的制备方法，该方法包括使水与下述成分混合：
i)至少一种表面活性剂，其选自阴离子表面活性剂、非离子表面活性剂、两性离子表面活性剂、两性表面活性剂或其混合物：
ii)不溶性不挥发硅氧烷的乳化颗粒；
iii)可溶性阳离子头发调理聚合物，其阳离子电荷密度为约+3.0meq/g或更小，
其特征在于，将不溶性不挥发硅氧烷的乳化颗粒以预成形含水乳液形式掺入香波组合物中，在乳液和香波组合物中硅氧烷的平均粒度为2～30微米。
2.根据权利要求1的方法，其中，以组合物重量计，所述至少一种表面活性剂的含量为0.1～50wt％。
3.根据权利要求1的方法，其中，阴离子表面活性剂选自：月桂基硫酸钠、三乙醇胺月桂基硫酸盐、三乙醇胺单月桂基磷酸盐、月桂基醚2EO硫酸钠、月桂基醚3EO硫酸钠、月桂基硫酸铵、月桂基醚1EO硫酸钠、月桂基醚2EO硫酸铵和月桂基醚3EO硫酸铵和其混合物。
4.根据权利要求1的方法，其中，两性表面活性剂选自椰油酰氨基丙基甜菜碱、月桂基甜菜碱和椰油两性丙酸钠。
5.根据权利要求1的方法，其中，以组合物重量计，不溶性不挥发硅氧烷的含量为0.01～20wt％。
6.根据权利要求1的方法，其中，不溶性不挥发硅氧烷选自聚二甲基硅氧烷和具有羟基端基的聚二甲基硅氧烷。
7.根据权利要求1的方法，其中，以组合物重量计，阳离子头发调理聚合物的含量为0.01～3wt％。
8.根据权利要求1的方法，其中，阳离子头发调理聚合物选自瓜尔胶阳离子衍生物、阳离子纤维素醚衍生物和阳离子聚丙烯酰胺。
9.一种由权利要求1～8任一项的方法制备的香波组合物。
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| US20020012646A1 (en) * | 1997-05-06 | 2002-01-31 | Royce Douglas Allan | Shampoo compositions with cationic polymers |
| US6177390B1 (en) * | 1998-02-03 | 2001-01-23 | The Procter & Gamble Company | Styling shampoo compositions which deliver improved hair curl retention and hair feel |
| GB9804720D0 (en) | 1998-03-05 | 1998-04-29 | Unilever Plc | Shampoo compositions |
| GB9804725D0 (en) * | 1998-03-05 | 1998-04-29 | Unilever Plc | Shampoo compositions |
| GB9808310D0 (en) * | 1998-04-20 | 1998-06-17 | Unilever Plc | Shampoo compositions |
| AU8760598A (en) * | 1998-07-30 | 2000-02-21 | Procter & Gamble Company, The | Hair care compositions |
| FR2785799B1 (fr) * | 1998-11-12 | 2002-11-29 | Oreal | Composition cosmetique conditionnante et detergente comprenant un tensioactif carboxylique, une silicone et un polymere cationique, utilisation et procede. |
| GB9827614D0 (en) * | 1998-12-15 | 1999-02-10 | Unilever Plc | Detergent composition |
| US6974569B2 (en) * | 1999-05-03 | 2005-12-13 | The Procter & Gamble Company | Shampoos providing a superior combination anti-dandruff efficacy and condition |
| US6451300B1 (en) | 1999-05-03 | 2002-09-17 | The Procter & Gamble Company | Anti-dandruff and conditioning shampoos containing polyalkylene glycols and cationic polymers |
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- 1997-07-09 JP JP10507509A patent/JP2000505805A/ja active Pending
- 1997-07-09 AU AU37670/97A patent/AU3767097A/en not_active Abandoned
- 1997-08-01 AR ARP970103491A patent/AR008142A1/es active IP Right Grant
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Also Published As
| Publication number | Publication date |
|---|---|
| AR008142A1 (es) | 1999-12-09 |
| GB9616411D0 (en) | 1996-09-25 |
| WO1998005296A1 (en) | 1998-02-12 |
| CA2261755A1 (en) | 1998-02-12 |
| JP2000505805A (ja) | 2000-05-16 |
| CA2261755C (en) | 2003-01-28 |
| US5977038A (en) | 1999-11-02 |
| CN1231594A (zh) | 1999-10-13 |
| BR9711020A (pt) | 1999-08-17 |
| AU3767097A (en) | 1998-02-25 |
| US6355234B1 (en) | 2002-03-12 |
| EP0917454A1 (en) | 1999-05-26 |
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