CN1124837C - 香波组合物 - Google Patents
香波组合物 Download PDFInfo
- Publication number
- CN1124837C CN1124837C CN97199881A CN97199881A CN1124837C CN 1124837 C CN1124837 C CN 1124837C CN 97199881 A CN97199881 A CN 97199881A CN 97199881 A CN97199881 A CN 97199881A CN 1124837 C CN1124837 C CN 1124837C
- Authority
- CN
- China
- Prior art keywords
- surfactant
- compositions
- polymer
- siloxanes
- cationic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000000203 mixture Substances 0.000 title claims abstract description 39
- 239000002453 shampoo Substances 0.000 title claims abstract description 19
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 26
- 229920000642 polymer Polymers 0.000 claims abstract description 21
- 230000008021 deposition Effects 0.000 claims abstract description 18
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- 239000002245 particle Substances 0.000 claims abstract description 7
- -1 siloxanes Chemical class 0.000 claims description 72
- 125000002091 cationic group Chemical group 0.000 claims description 27
- 239000000178 monomer Substances 0.000 claims description 14
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 12
- 239000002131 composite material Substances 0.000 claims description 11
- 229920013750 conditioning polymer Polymers 0.000 claims description 10
- 239000000839 emulsion Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000003945 anionic surfactant Substances 0.000 claims description 9
- 239000003995 emulsifying agent Substances 0.000 claims description 9
- 239000003093 cationic surfactant Substances 0.000 claims description 4
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 4
- 244000007835 Cyamopsis tetragonoloba Species 0.000 claims 1
- 230000003750 conditioning effect Effects 0.000 abstract description 4
- 229920001296 polysiloxane Polymers 0.000 abstract description 3
- 125000000217 alkyl group Chemical group 0.000 description 12
- 241000282372 Panthera onca Species 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 7
- 239000002537 cosmetic Substances 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 229920002554 vinyl polymer Polymers 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 5
- 239000000375 suspending agent Substances 0.000 description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 4
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 230000001662 opsonic effect Effects 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- 125000001453 quaternary ammonium group Chemical group 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 102220549062 Low molecular weight phosphotyrosine protein phosphatase_C13S_mutation Human genes 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 3
- 125000002877 alkyl aryl group Chemical group 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 125000003710 aryl alkyl group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 150000003512 tertiary amines Chemical class 0.000 description 3
- BJAARRARQJZURR-UHFFFAOYSA-N trimethylazanium;hydroxide Chemical compound O.CN(C)C BJAARRARQJZURR-UHFFFAOYSA-N 0.000 description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- DHHFDKNIEVKVKS-MVUYWVKGSA-N Betanin Natural products O=C(O)[C@@H]1NC(C(=O)O)=C/C(=C\C=[N+]/2\[C@@H](C(=O)[O-])Cc3c\2cc(O)c(O[C@H]2[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O2)c3)/C1 DHHFDKNIEVKVKS-MVUYWVKGSA-N 0.000 description 2
- 244000241257 Cucumis melo Species 0.000 description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
- 244000303965 Cyamopsis psoralioides Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 2
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 235000012677 beetroot red Nutrition 0.000 description 2
- 239000001654 beetroot red Substances 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 235000002185 betanin Nutrition 0.000 description 2
- 229920003086 cellulose ether Polymers 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 2
- YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical group CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 description 2
- 125000005702 oxyalkylene group Chemical group 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- WLWHLUQQCLCFNE-UHFFFAOYSA-N 1-ethenyl-3-methyl-2h-imidazole Chemical class CN1CN(C=C)C=C1 WLWHLUQQCLCFNE-UHFFFAOYSA-N 0.000 description 1
- JECYNCQXXKQDJN-UHFFFAOYSA-N 2-(2-methylhexan-2-yloxymethyl)oxirane Chemical compound CCCCC(C)(C)OCC1CO1 JECYNCQXXKQDJN-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- MXXTVDSLIANCNG-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate;dimethyl sulfate;1-ethenylpyrrolidin-2-one Chemical compound COS(=O)(=O)OC.C=CN1CCCC1=O.CN(C)CCOC(=O)C(C)=C MXXTVDSLIANCNG-UHFFFAOYSA-N 0.000 description 1
- KSLINXQJWRKPET-UHFFFAOYSA-N 3-ethenyloxepan-2-one Chemical compound C=CC1CCCCOC1=O KSLINXQJWRKPET-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 description 1
- DHHFDKNIEVKVKS-FMOSSLLZSA-N Betanin Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC(C(=C1)O)=CC(C[C@H]2C([O-])=O)=C1[N+]2=C\C=C\1C=C(C(O)=O)N[C@H](C(O)=O)C/1 DHHFDKNIEVKVKS-FMOSSLLZSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 238000007696 Kjeldahl method Methods 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000688 Poly[(2-ethyldimethylammonioethyl methacrylate ethyl sulfate)-co-(1-vinylpyrrolidone)] Polymers 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 125000004171 alkoxy aryl group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- 150000001408 amides Chemical group 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- CESHKJCQQFFQQQ-UHFFFAOYSA-N azane 2-dodecyl-2-sulfobutanedioic acid Chemical compound N.CCCCCCCCCCCCC(S(O)(=O)=O)(C(O)=O)CC(O)=O CESHKJCQQFFQQQ-UHFFFAOYSA-N 0.000 description 1
- UHWHEIKTDHONME-UHFFFAOYSA-M benzyl-decyl-dimethylazanium;hydroxide Chemical compound [OH-].CCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 UHWHEIKTDHONME-UHFFFAOYSA-M 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- QCCKPZOPTXCJPL-UHFFFAOYSA-N dodecyl(dimethyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCCCCCC[NH+](C)C QCCKPZOPTXCJPL-UHFFFAOYSA-N 0.000 description 1
- JVQOASIPRRGMOS-UHFFFAOYSA-M dodecyl(trimethyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCCCCCC[N+](C)(C)C JVQOASIPRRGMOS-UHFFFAOYSA-M 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical group CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 235000008216 herbs Nutrition 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- WJLUBOLDZCQZEV-UHFFFAOYSA-M hexadecyl(trimethyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCCCCCCCCCC[N+](C)(C)C WJLUBOLDZCQZEV-UHFFFAOYSA-M 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229940071826 hydroxyethyl cellulose Drugs 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N isopropyl alcohol Natural products CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 229940094506 lauryl betaine Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000000593 microemulsion method Methods 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 230000003571 opsonizing effect Effects 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 229940079862 sodium lauryl sarcosinate Drugs 0.000 description 1
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 1
- 229960003212 sodium propionate Drugs 0.000 description 1
- 235000010334 sodium propionate Nutrition 0.000 description 1
- 239000004324 sodium propionate Substances 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/068—Microemulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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Abstract
本发明公开了一种用于头发和/或皮肤的调理香波组合物，其包含一种高粘度的稳定微乳液，粒度小于0.15微米的轻度交联的硅氧烷，以及一种沉积聚合物和表面活性剂。
Description
发明领域
本发明涉及一种香波组合物，特别是涉及一种包含硅氧烷的乳化颗粒的香波组合物，该组合物具有机械稳定性，并对头发具有优良的调理作用。
发明背景
众所周知，硅氧烷可用于头发护理组合物中，在很多专利文献中对此均有详细描述。一般说来，硅氧烷的分散液滴悬浮于组合物中，将组合物涂敷于头发后，所述物质可沉积在头发的发杆上。
迄今为止，还需要采取一些措施以防止硅油的乳化液滴在贮藏期间产生附聚现象以及组合物乳液分出乳油。这些措施例如包括添加作为悬浮剂的聚合物，如丙烯酸聚合物(Carbopol)或某些胶质，和/或结晶物质；但是采用这类物质将会使形成的组合物混浊或不透明。因而，当希望配制看起来澄清的组合物时，上述情形就成了人们需要面对的问题。
此外，由于这类悬浮剂会导致头发的光泽度下降，以及使其它调理剂的作用减弱，结果使打硅氧烷调理油沉积之外，悬浮剂也沉积于头发上时，构成头发护理组合物由此类悬浮剂所产生的缺陷。
在本技术领域中，人们还知道通过微乳化方法将油性化妆用试剂，如硅氧烷掺入化妆品中，从而硅氧烷可以以稳定乳化的液滴存在，该液滴的粒度约为0.15微米或更小。
例如，US 4 733 677公开了了含有阳离子有机聚合物及聚二有机硅氧烷微乳液不洗除的头发固定剂。EP A 268 982表明，聚二甲基硅氧烷微乳液可用于各种化妆品中，微乳化的聚二甲基硅氧烷通过乳液聚合制备，其粒度为0.15微米或更小。
EP A 0 529 883公开了一种香波，其包含硅氧烷微乳液及阳离子沉积聚合物。由于悬浮体系不需要对硅氧烷的微乳化颗粒进行稳定化处理，这种香波具有优异的机械稳定性和很高的透明性或半透明性。
EP A 0 529 883中所采用的硅氧烷微乳液的粒度为0.036微米，粘度为15,000厘沲。EP A 0 674 898指明如何在这样一种体系中使用高粘度微乳液以改善调理性能。此处所使用的微乳液的粘度为60,000厘沲。
问题是，即使如EP A 0 674 898中所述的高粘度微乳液也不能为多数使用者提供足够的调理作用。
业已发现，如果采用的硅氧烷微乳液其中硅氧烷是极少量交联的乳液，便可以获得具有优异机械稳定性和调理能力的香波组合物。EP A529 883和EPA 0 674 898均未提及采用交联的硅氧烷微乳液。
发明概述
本发明提供了一种香波组合物，其包含：
a)2-35％的至少一种表面活性剂；
b)0.01-10％高粘度轻度交联的硅氧烷调理聚合物颗粒微乳液，
其颗粒度小于0.15微米，所述乳液包含水、乳化剂和硅氧烷颗粒；
c)0.01-10％的阳离子沉积助剂。发明详述
本文中，术语“高粘度”是指粘度大于100,000厘沲。粘度范围优选800,000-1,500,000厘沲。粘度最好为约1,000,000厘沲。被测量的粘度值是硅氧烷自身的粘度，并非乳液或最终的香波组合物的粘度。该粘度值是采用旋转式粘度计以常规方式测得的。
本文中，术语“轻度交联”是指在硅氧烷调理聚合物中，支链单体单元的百分比小于约0.05％，优选为约0.001-0.04％
在这种低交联度下，可观察到硅氧烷微乳液的优异调理作用。采用0.02交联的硅氧烷微乳液可获得优异的整体性能。
以组合物总重量计，交联的硅氧烷调理聚合物微乳液在本发明组合物中的用量为约0.01-10wt％，优选0.3-5wt％。其下限值是由能达到调理作用所需的最小值确定的，而上限值则由避免使头发产生令人难以接受的油腻感的最大值确定。
优选用于本发明中的硅氧烷调理聚合物为聚二有机硅氧烷，优选由R3SiO0.5单元和R2SiO单元的适宜组合得到的那些，其中，R独立地代表烷基、链烯基(如乙烯基)、烷芳基、芳烷基或芳基(如苯基)。R首选甲基。
本发明优选的硅氧烷调理聚合物为轻度交联的聚二甲基硅氧烷，其任选具有羟基之类的端基。采用轻度交联的聚二甲基硅氧烷可得到良好的结果。
本发明中，可采用各种制备硅氧烷颗粒微乳液的方法，这些方法也是本领域公知的，并在文献中多有描述。
EP A 228 575公开了一种特别优选的制备硅氧烷微乳液的技术。
在这些文献中，描述了制备高分子量硅氧烷聚合物与水的稳定微乳液的方法，该方法是在搅拌下，按序加入有效比例的含聚二有机硅氧烷前体、表面活性剂和水的标准乳液于聚合催化剂介质中，形成一种澄清而稳定的聚二有机硅氧烷含水微乳液。
EP A 0 138 192公开了另一种用于本发明的适宜微乳液的制备方法。
硅氧烷调理聚合物的交联通常是在聚合物的乳液聚合过程中同时进行的，交联过程包含需要量的三官能和四官能硅烷单体单元，例如式RSi(OH)3单体，其中，R代表烷基、链烯基(如乙烯基)、烷芳基、芳烷基或芳基(如苯基)，优选甲基。
适宜的微乳化的、轻度交联的硅氧烷调理聚合物可商购，或易于按照本领域技术人员公知的常规技术制备。
优选硅氧烷调理聚合物的微乳液中硅氧烷物质的平均粒度小于约0.05微米，优选约0.045微米。这样一种粒度可确保硅氧烷在香波基质中呈明显的自悬浮液，从而避免对附加悬浮体系的需求。
采用激光散射技术，使用2600D粒度测定仪(来自MalvernInstruments)测量粒度。
硅氧烷的微乳液通过适宜用量的一种或多种乳化剂进行稳定化处理，所述乳化剂优选选自阴离子表面活性剂、阳离子表面活性剂、非离子表面活性剂、两性表面活性剂和两性离子表面活性剂，及其混合物。
乳化剂的用量通常以乳化剂与硅氧烷的重量比为1∶1-1∶7之量使用，当然也可以采用较大量的乳化剂，例如，其与硅氧烷的重量比为5∶1或更大。
适宜的阴离子表面活性剂为烷基硫酸盐、烷基醚硫酸盐、烷芳基磺酸盐、烷基琥珀酸盐、烷基磺基琥珀酸盐、酰基牛磺酸盐、酰基谷氨酸盐、N-烷氧基肌氨酸盐、烷基磷酸盐、烷基醚磷酸盐、烷基醚羧酸盐和α-烯烃磺酸盐，特别是其钠盐、钾盐、镁盐、铵盐和单、二和三乙醇胺盐。烷基和酰基通常包含8-18个碳原子，可以是不饱和基团。烷基醚硫酸盐、烷基醚磷酸盐和烷基醚羧酸盐每分子可包含1-10个氧化乙烯或氧化丙烯单元，优选每分子包含2-3个氧化乙烯单元。
适宜的阴离子表面活性剂的实例包括油基琥珀酸钠、月桂基磺基琥珀酸铵、月桂基硫酸铵、十二烷基苯磺酸钠、十二烷基苯磺酸的三乙醇胺和钠盐及N-月桂基肌氨酸钠。最优选的阴离子表面活性剂是月桂基醚1EO、2EO和3EO硫酸钠、月桂基硫酸铵、月桂基醚1EO、2EO和3EO硫酸铵和十二烷基苯磺酸的三乙醇胺和钠盐。由于月桂基醚3EO硫酸钠与高粘度微乳液一起使用时可得到特别澄清且稳定的香波，因而其为优选的阴离子表面活性剂。
适宜的阳离子表面活性剂可包括季铵氢氧化物，如四甲基氢氧化铵、辛基三甲基氢氧化铵、十二烷基三甲基氢氧化铵、十六烷基三甲基氢氧化铵、辛基二甲基苄基氢氧化铵、癸基二甲基苄基氢氧化铵、双十二烷基二甲基氢氧化铵、双十八烷基二甲基氢氧化铵、牛油基三甲基氢氧化铵、椰子基三甲基氢氧化铵，和其相应的盐。
适宜的非离子表面活性剂可包括脂族(C8-C18)伯或仲直链或支链醇或酚与氧化烯的缩合产物，所述氧化烯通常为环氧乙烷，优选其具有6-30个环氧乙烷基团。
其它适宜的非离子表面活性剂包括烷基多糖苷和单或二烷基链烷醇酰胺。所述链烷醇酰胺的实例包括椰子基单或二乙醇酰胺和椰子基单异丙醇酰胺。
适宜的两性表面活性剂和两性离子表面活性剂可包括烷基胺氧化物、烷基甜菜碱、烷基酰氨基丙基甜菜碱、烷基磺基甜菜碱、烷基甘氨酸盐、烷基羧基甘氨酸盐、烷基两性丙酸盐、烷基两性甘氨酸盐、烷基酰氨基丙基和羟基甜菜碱，其中，烷基和酰基包含8-19个碳原子。其实例包括月桂基氧化胺、椰子基二甲基磺基丙基甜菜碱，优选月桂基甜菜碱、椰油酰氨丙基甜菜碱和椰子基两性丙酸钠。
按照本发明优选的化妆品组合物为一种香波组合物，该香波组合物除含硅氧烷微乳液外还包含表面活性剂以提供洗涤效果。组合物优选包含的表面活性剂总量为约2-35wt％。洗涤用表面活性剂选自阴离子表面活性剂、阳离子表面活性剂、非离子表面活性剂和两性与两性离子表面活性剂，及其混合物，其实例如前所述。洗涤用表面活性剂可以是与乳化剂相同的表面活性剂。
本发明的香波组合物的另一个组分是阳离子沉积助剂，优选阳离子沉积聚合物。
阳离子沉积助剂的用量通常为0.001-5wt％，优选约0.01-1wt％，更优选约0.02-0.5wt％。聚合物可为均聚物或由两种或多种类型的单体形成的聚合物。聚合物的分子量通常为5,000-10,000,000，优选至少为10,000，更优选100,000-2,000,000。聚合物应具有阳离子含氮基团，如季铵基团或质子化氨基基团，或其混合物。
所需的阳离子的电荷密度至少为0.1meq/g，，优选高于0.8meq/g。阳离子的电荷密度应不超过4meq/g，优选小于3meq/g，更优选小于2meq/g。电荷密度可采用Kjeldahl法测量，应在使用时所需的pH值条件的上限范围内，所述pH值通常为约3-9，优选4-8。
阳离子含氮基团通常作为阳离子沉积聚合物的总单体单元部分上的取代基存在。
因此，当聚合物不是均聚物时，其可包含间隔基非阳离子单体单元。这种聚合物在下述文献中有述：CTFA Cosmetic IngredientDirectory，第三版。
适宜的阳离子沉积助剂的实例包括具有阳离子胺或季铵官能团的乙烯基单体与水溶性间隔基单体的共聚物，所述水溶性间隔基单体例如为(甲基)丙烯酰胺、烷基和二烷基(甲基)丙烯酰胺、烷基(甲基)丙烯酸酯、乙烯基己内酯和乙烯基吡咯烷酮。烷基和二烷基取代的单体优选具有C1-C7烷基，更优选C1-C3烷基。其它适宜的间隔基包括乙烯基酯、乙烯醇、马来酸酐、丙二醇和乙二醇。
阳离子胺可为伯胺、仲胺或叔胺，这取决于具体的物种及组合物的pH值。通常，优选仲胺和叔胺，更优选叔胺。
胺取代的乙烯基单体和胺可以胺形式聚合，然后通过季铵化反应转化成铵。
适宜的阳离子氨基和季铵单体的实例包括被下述基团取代的乙烯基化合物：二烷基氨基烷基丙烯酸酯、二烷基氨基烷基甲基丙烯酸酯、单烷基氨基烷基丙烯酸酯、单烷基氨基烷基甲基丙烯酸酯、三烷基甲基丙烯酰氧基烷基铵盐、三烷基丙烯酰氧基烷基铵盐，二烯丙基李铵盐和乙烯基季铵单体其具有环状阳离子含氮环，如吡啶鎓、咪唑鎓，和季铵化吡咯烷，如烷基乙烯基咪唑鎓，烷基乙烯基吡啶鎓、烷基乙烯基吡咯烷盐。这些单体的烷基部分优选为低级烷基，如C1-C3烷基，更优选甲基和乙基。
适宜的用于本发明的胺取代乙烯基单体包括二烷基氨基烷基丙烯酸酯、二烷基氨基烷基甲基丙烯酸酯、二烷基氨基烷基丙烯酰胺、二烷基氨基烷基甲基丙烯酰胺，其中，烷基优选C1-C7烃基，更优选C1-C3烷基。
阳离子沉积助剂可包含由胺和/或季铵取代的单体得到的单体单元和/或相容性间隔基单体的混合物。
适宜的阳离子沉积助剂的实例包括：1-乙烯基-2-吡咯烷酮与1-乙烯基-3-甲基-咪唑鎓盐(如氯化物盐)的共聚物(被化妆品、盥洗用品和香料协会“CFTA”称之为Polyquaternium-16)，如从BASFWyandotte Corp.(Parsippany，NJ，USA)以商品名LUVIQUAT(例如，LUVIQUAT FC 370)商购的产品；1-乙烯基-2-吡咯烷与二甲基氨基乙基甲基丙烯酸酯的共聚物(在工业上被CTFA称之为Polyquaternium-11)，如从Gar Corporation(Wayne，NJ，USA)以商品名GAFQUAT(如，GAFQUAT 755N)商购的产品；含阳离子二烯丙基季铵的聚合物，例如，包括二甲基二烯丙基氯化铵均聚物和丙烯酰胺与二甲基二烯丙基氯化铵的共聚物，它们分别被CTFA称之为Polyquaternium6和7；具有3-5个碳原子的不饱和羧酸的均聚物和共聚物的氨基烷基酯的无机酸盐，如US 4,009,256所述；以及阳离子聚丙烯酰胺，如共同未决UK申请9403156.4(WO95/22311)所述。
其它可用于本发明的阳离子沉积助剂包括多糖聚合物，如阳离子纤维素衍生物和阳离子淀粉衍生物。
适用于本发明组合物的阳离子多糖聚合物物质包括下式的化合物：其中A为葡糖酐残基，如淀粉或纤维素葡糖酐残基，R为亚烷基氧亚烷基、聚氧亚烷基或羟基亚烷基，或其混合物，R1、R2和R3独立地为烷基、芳基、烷芳基、芳烷基、烷氧基烷基或烷氧基芳基，各基团可包含至多约18个碳原子，每一个阳离子部分的碳原子总数(即，R1、R2和R3的碳原子总数)优选为约20或小于20，X为阴离子抗衡离子，如前所述。
阳离子纤维素可从Amerchol Corp.(Edison，NJ，USA)以其Polymer JR(商标)和LR(商标)系列聚合物商购，如羟乙基纤维素与三甲基铵取代的环氧乙烷反应的盐，被CTFA称之为Polyquaternium10。另一种类型的阳离子纤维素包括羟乙基纤维与月桂基二甲基铵取代的环氧乙烷反应的高分子季铵盐，被CTFA称之为Polyquaternium24。这些物质均可从Amerchol Corp.(Edison，NJ，USA)以商品名Polymer LM-200商购。
其它可使用的阳离子沉积助剂包括阳离子瓜尔胶衍生物，如瓜尔羟丙基氯化三铵(商购自Celanese Corp.的Jaguar商标系列).其它物质包括含季氮的纤维素醚(如US 3,962,418所述，该文献引入本文作为参考)、醚化纤维素与淀粉的共聚物(如US 3,958,581所述，该文献引入本文作为参考)。
优选沉积助剂选自阳离子聚丙烯酰胺、羟烷基纤维素醚和阳离子瓜尔胶衍生物。特别优选的沉积助剂为阳离子电荷密度0.8meq/g的Jaguar C13S。Jaguar C13S为瓜尔羟丙基氯化三铵。其它特别适宜的物质包括Jaguar C15、Jaguar C17、Jaguar C16和Jaguar C162，优选的纤维素醚是Polymer JR400。
本发明的化妆品组合物优选为水基组合物，水构成微乳液连续相的基础。以组合物总重量计，组合物优选包含的水量为约20-99wt％。
本发明的组合物优选为漂洗清除型组合物，即，适宜涂敷于头发上，在头发上停留一段适当时间后，用水漂洗去。
本发明的组合物在视觉上是澄清的。
根据所采用的香波或硅氧烷的类型不同，常规掺入香波配方中的一种或多种其它配料也可包含在本发明的组合物中。这些附加配料包括：杀菌剂、去头屑剂、增泡剂、香料、着色剂、防腐剂、粘度调节剂、遮光剂、珠光剂、蛋白质、聚合物、缓冲剂或pH值调节剂、保湿剂、草药或其它植物提取物以及其它天然配料。
通过下述非限定性实施例对发明进行进一步描述。实施例1
将下列组分以所列出的用量混合，制备香波组合物。
组分
wt％
月桂基醚2EO硫酸钠 14.0
椰油酰氨基丙基甜菜碱 2.0
Jaguar C13S 0.05
硅氧烷(1) 2.4
防腐剂、着色剂、香料 适量
水 至100％
(1)微乳化硅油，交联度0.02％，25％含水乳液，来自Dow Corning。
硅氧烷的粘度为1,000,000厘沲，粒度为0.045微米。
该实施例中，硅氧烷的交联度％是指在硅氧烷中支链单体单元的％。
该配方中，硅氧烷在25℃、37℃和45℃下均稳定形成乳液。对此硅氧烷，无需再使用悬浮剂。
在干梳理评价小组试验中，等量硅氧烷沉积情况下，实施例1的配方与对照组配方相比，显示出优异的干调理效果，所述对照配方中，硅氧烷(1)被60,000厘沲、粒度小于0.04微米、未交联的硅氧烷微乳液代替。
Claims (8)
1、一种香波组合物，包含：
a)2-35％的表面活性剂；
b)0.01-10％高粘度轻度交联的硅氧烷调理聚合物颗粒的微乳液，该聚合物具有0.001-0.04％的支链单体单元并且颗粒度小于0.15微米，所述乳液包含水、乳化剂和该硅氧烷颗粒；
c)0.01-10％的阳离子沉积助剂。
2、根据权利要求1的组合物，其中，硅氧烷调理聚合物的颗粒度小于0.05微米。
3、根据权利要求1-2任一项的组合物，其中，微乳液(b)在组合物中的用量为0.3-5wt％。
4、根据权利要求1的组合物，其中，阳离子沉积助剂为选自阳离子瓜尔胶衍生物和阳离子聚丙烯酰胺的阳离子沉积聚合物。
5、根据权利要求1的组合物，其中，表面活性剂选自阴离子表面活性剂、阳离子表面活性剂、非离子表面活性剂、两性和两性离子表面活性剂，和其混合物。
6、根据权利要求1的组合物，其中，表面活性剂是阴离子表面活性剂。
7、根据权利要求6的组合物，其中，组分(b)中的乳化剂与用于组分(a)中的阴离子表面活性剂相同。
8、根据权利要求1的组合物，其中，硅氧烷自身的粘度为800,000-1,500,000厘沲。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9619761.1A GB9619761D0 (en) | 1996-09-23 | 1996-09-23 | Shampoo composition |
| GB9619761.1 | 1996-09-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1237893A CN1237893A (zh) | 1999-12-08 |
| CN1124837C true CN1124837C (zh) | 2003-10-22 |
Family
ID=10800329
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97199881A Expired - Lifetime CN1124837C (zh) | 1996-09-23 | 1997-09-16 | 香波组合物 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5990059A (zh) |
| EP (1) | EP0952810B1 (zh) |
| JP (1) | JP3560984B2 (zh) |
| CN (1) | CN1124837C (zh) |
| AR (1) | AR009091A1 (zh) |
| AU (1) | AU4623997A (zh) |
| BR (1) | BR9712101A (zh) |
| CA (1) | CA2265652A1 (zh) |
| DE (1) | DE69717494T2 (zh) |
| ES (1) | ES2187827T3 (zh) |
| GB (1) | GB9619761D0 (zh) |
| HU (1) | HU229191B1 (zh) |
| WO (1) | WO1998013011A1 (zh) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9726970D0 (en) * | 1997-12-19 | 1998-02-18 | Unilever Plc | Shampoo compositions |
| GB9804725D0 (en) * | 1998-03-05 | 1998-04-29 | Unilever Plc | Shampoo compositions |
| GB9822419D0 (en) * | 1998-10-14 | 1998-12-09 | Unilever Plc | Hair styling composition |
| EP0998906B1 (en) * | 1998-10-26 | 2005-05-25 | DSM IP Assets B.V. | Shampoo composition containing light screening agents |
| EP1064909B1 (en) * | 1999-06-21 | 2016-02-03 | Shiseido Company Limited | High internal aqueous phase water-in-oil type emulsion cosmetic composition |
| AU2351300A (en) * | 1999-12-02 | 2001-06-12 | Procter & Gamble Company, The | Conditioning shampoo compositions |
| US6808701B2 (en) | 2000-03-21 | 2004-10-26 | Johnson & Johnson Consumer Companies, Inc. | Conditioning compositions |
| US6514918B1 (en) | 2000-08-18 | 2003-02-04 | Johnson & Johnson Consumer Companies, Inc. | Viscous, mild, and effective cleansing compositions |
| CN1247699C (zh) * | 2001-03-13 | 2006-03-29 | 陶氏康宁东丽硅氧烷株式会社 | 聚有机硅氧烷乳液、其制备方法与化妆品原料 |
| US7300648B2 (en) * | 2001-04-27 | 2007-11-27 | Dowecorning Toray Silicone, Co., Ltd. | Polyorganosiloxane emulsion composition and a cosmetic material made therefrom |
| JP2002348474A (ja) * | 2001-05-23 | 2002-12-04 | Dow Corning Toray Silicone Co Ltd | ポリオルガノシロキサンマイクロエマルジョン組成物および化粧料原料 |
| US20040115159A1 (en) * | 2002-03-29 | 2004-06-17 | Tadlock Charles C | Novel nanoemulsions |
| CN1646085A (zh) * | 2002-04-22 | 2005-07-27 | 宝洁公司 | 包含阳离子瓜耳胶衍生物的洗发剂 |
| EP1541633B1 (en) * | 2002-08-30 | 2013-01-16 | Dow Corning Toray Co., Ltd. | Aqueous suspension of crosslinked silicone particles, aqueous emulsion of oil containing crosslinked silicone particles, and cosmetic ingredients |
| DE60309741T2 (de) * | 2002-12-03 | 2007-03-29 | Unilever N.V. | Behandlungszusammensetzungen für wäsche |
| WO2005072687A1 (en) * | 2004-01-16 | 2005-08-11 | The Procter & Gamble Company | Conditioning shampoo compositions |
| MX2007008451A (es) | 2005-01-12 | 2008-03-13 | Amcol International Corp | Composiciones detergentes que contienen agentes de beneficio hidrofobico, pre-emulsificados usando particulas cationicas coloidales. |
| US7871972B2 (en) | 2005-01-12 | 2011-01-18 | Amcol International Corporation | Compositions containing benefit agents pre-emulsified using colloidal cationic particles |
| US7915214B2 (en) * | 2006-01-12 | 2011-03-29 | Amcol International Corporation | Compositions containing benefit agent composites pre-emulsified using colloidal cationic particles |
| US7977288B2 (en) | 2005-01-12 | 2011-07-12 | Amcol International Corporation | Compositions containing cationically surface-modified microparticulate carrier for benefit agents |
| WO2008143862A1 (en) | 2007-05-14 | 2008-11-27 | Amcol International Corporation | Compositions containing benefit agent composites pre-emulsified using colloidal cationic particles |
| US8188022B2 (en) | 2008-04-11 | 2012-05-29 | Amcol International Corporation | Multilayer fragrance encapsulation comprising kappa carrageenan |
| US20100202985A1 (en) * | 2009-02-11 | 2010-08-12 | Amcol International Corporation | Sunscreen compositions including particulate sunscreen actives that exhibit boosting of sun protection factor |
| JP2013529659A (ja) | 2010-07-08 | 2013-07-22 | ユニリーバー・ナームローゼ・ベンノートシヤープ | ヘアケア組成物 |
| MX2020012527A (es) | 2018-06-21 | 2021-01-20 | Unilever Ip Holdings B V | Composicion para la higiene personal. |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4620878A (en) * | 1983-10-17 | 1986-11-04 | Dow Corning Corporation | Method of preparing polyorganosiloxane emulsions having small particle size |
| US4902499A (en) * | 1986-04-04 | 1990-02-20 | The Procter & Gamble Company | Hair care compositions containing a rigid silicone polymer |
| US4733677A (en) * | 1986-11-04 | 1988-03-29 | Dow Corning Corporation | Hair fixative composition containing cationic organic polymer and polydiorganosiloxane microemulsions |
| JPS63130512A (ja) * | 1986-11-18 | 1988-06-02 | Toray Silicone Co Ltd | 化粧料 |
| EP0432951B2 (en) * | 1989-12-04 | 2004-06-30 | Unilever Plc | Hair treatment composition |
| GB9016100D0 (en) * | 1990-07-23 | 1990-09-05 | Unilever Plc | Shampoo composition |
| GB9117740D0 (en) * | 1991-08-16 | 1991-10-02 | Unilever Plc | Cosmetic composition |
| GB9204509D0 (en) * | 1992-03-02 | 1992-04-15 | Unilever Plc | Hair care composition |
| AU7653294A (en) * | 1993-08-18 | 1995-03-14 | Unilever Plc | Shaving composition |
| GB9406555D0 (en) * | 1994-03-31 | 1994-05-25 | Unilever Plc | Shampoo composition |
| US5578298A (en) * | 1994-05-27 | 1996-11-26 | General Electric Company | Microemulsions for high viscosity amino silicone fluids and gums and their preparation |
| US5504149A (en) * | 1994-08-25 | 1996-04-02 | Dow Corning Corporation | Method of emulsion polymerization |
| GB9507130D0 (en) * | 1995-04-06 | 1995-05-31 | Unilever Plc | Hair treatment composition |
| US5705562A (en) * | 1995-11-20 | 1998-01-06 | Dow Corning Corporation | Spontaneously formed clear silicone microemulsions |
-
1996
- 1996-09-23 GB GBGB9619761.1A patent/GB9619761D0/en active Pending
-
1997
- 1997-09-16 BR BR9712101-0A patent/BR9712101A/pt not_active IP Right Cessation
- 1997-09-16 CA CA002265652A patent/CA2265652A1/en not_active Abandoned
- 1997-09-16 DE DE69717494T patent/DE69717494T2/de not_active Expired - Lifetime
- 1997-09-16 CN CN97199881A patent/CN1124837C/zh not_active Expired - Lifetime
- 1997-09-16 WO PCT/EP1997/005176 patent/WO1998013011A1/en active IP Right Grant
- 1997-09-16 ES ES97944890T patent/ES2187827T3/es not_active Expired - Lifetime
- 1997-09-16 EP EP97944890A patent/EP0952810B1/en not_active Expired - Lifetime
- 1997-09-16 JP JP51524598A patent/JP3560984B2/ja not_active Expired - Lifetime
- 1997-09-16 HU HU9904637A patent/HU229191B1/hu unknown
- 1997-09-16 AU AU46239/97A patent/AU4623997A/en not_active Abandoned
- 1997-09-23 AR ARP970104353A patent/AR009091A1/es active IP Right Grant
- 1997-09-23 US US08/936,102 patent/US5990059A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| WO1998013011A1 (en) | 1998-04-02 |
| AU4623997A (en) | 1998-04-17 |
| BR9712101A (pt) | 1999-08-31 |
| AR009091A1 (es) | 2000-03-08 |
| ES2187827T3 (es) | 2003-06-16 |
| HUP9904637A2 (hu) | 2000-05-28 |
| JP2000507606A (ja) | 2000-06-20 |
| GB9619761D0 (en) | 1996-11-06 |
| US5990059A (en) | 1999-11-23 |
| CA2265652A1 (en) | 1998-04-02 |
| DE69717494T2 (de) | 2003-04-24 |
| DE69717494D1 (en) | 2003-01-09 |
| EP0952810B1 (en) | 2002-11-27 |
| EP0952810A1 (en) | 1999-11-03 |
| JP3560984B2 (ja) | 2004-09-02 |
| HU229191B1 (en) | 2013-09-30 |
| HUP9904637A3 (en) | 2001-11-28 |
| CN1237893A (zh) | 1999-12-08 |
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