CN109678925A - A kind of method that soybean wastewater recycles - Google Patents

A kind of method that soybean wastewater recycles Download PDF

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Publication number
CN109678925A
CN109678925A CN201811567504.6A CN201811567504A CN109678925A CN 109678925 A CN109678925 A CN 109678925A CN 201811567504 A CN201811567504 A CN 201811567504A CN 109678925 A CN109678925 A CN 109678925A
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soybean
recycles
isoflavones
waste water
emulsifier
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CN201811567504.6A
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袁凯
王华川
李子廷
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Wuxi Xinhe Chuang Gong Food Technology Co Ltd
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Wuxi Xinhe Chuang Gong Food Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D311/00Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/04Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
    • C07D311/22Benzo[b]pyrans, not hydrogenated in the carbocyclic ring with oxygen or sulfur atoms directly attached in position 4
    • C07D311/26Benzo[b]pyrans, not hydrogenated in the carbocyclic ring with oxygen or sulfur atoms directly attached in position 4 with aromatic rings attached in position 2 or 3
    • C07D311/34Benzo[b]pyrans, not hydrogenated in the carbocyclic ring with oxygen or sulfur atoms directly attached in position 4 with aromatic rings attached in position 2 or 3 with aromatic rings attached in position 3 only
    • C07D311/36Benzo[b]pyrans, not hydrogenated in the carbocyclic ring with oxygen or sulfur atoms directly attached in position 4 with aromatic rings attached in position 2 or 3 with aromatic rings attached in position 3 only not hydrogenated in the hetero ring, e.g. isoflavones
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D311/00Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/04Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
    • C07D311/22Benzo[b]pyrans, not hydrogenated in the carbocyclic ring with oxygen or sulfur atoms directly attached in position 4
    • C07D311/26Benzo[b]pyrans, not hydrogenated in the carbocyclic ring with oxygen or sulfur atoms directly attached in position 4 with aromatic rings attached in position 2 or 3
    • C07D311/40Separation, e.g. from natural material; Purification
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07KPEPTIDES
    • C07K1/00General methods for the preparation of peptides, i.e. processes for the organic chemical preparation of peptides or proteins of any length
    • C07K1/14Extraction; Separation; Purification
    • C07K1/145Extraction; Separation; Purification by extraction or solubilisation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07KPEPTIDES
    • C07K1/00General methods for the preparation of peptides, i.e. processes for the organic chemical preparation of peptides or proteins of any length
    • C07K1/14Extraction; Separation; Purification
    • C07K1/34Extraction; Separation; Purification by filtration, ultrafiltration or reverse osmosis

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Biochemistry (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biophysics (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Medicinal Chemistry (AREA)
  • Molecular Biology (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention discloses a kind of method that soybean wastewater recycles, the step of this method, is as follows: 1) pre-processing;2) it emulsifies;3) air bearing;4) film filters.The present invention realizes soybean protein and isoflavones from the separation and Extraction in waste water by pneumatically supported one step of mode, soybean protein is recycled using hyperfiltration technique compared to the prior art, method equipment cost with resin adsorption or solvent method recycling isoflavones is low, and operating cost is low, the operation cycle is short, high-efficient;The present invention embeds isoflavones using beta-cyclodextrin, and finally obtained product can overcome the shortcomings that isoflavones is with bitter taste, and with the combination dryings such as soybean protein, chitosan, overcome isoflavones drying to be not easy the shortcomings that shaping.

Description

A kind of method that soybean wastewater recycles
Technical field
The present invention relates to technical field of wastewater recovery, a kind of method recycled more particularly to soybean wastewater.
Background technique
Bean product are deep by a kind of favorite vegetable protein food of our people, and protein content is high, amino acid forms Rationally and nutritive value height, taste and flavor are good.Based on bean curd, herein on derive dried bean curd, fermented bean curd, skin of beancurd etc. Various bean products enrich the diet of people.However, a large amount of waste water can be generated in bean product production process, wherein being mainly The yellow serofluid generated in waste water caused by bubble beans waste water, cleaning equipment used in bubble beans and expressing process.It is every to produce bean product Bubble beans waste water, the yellow plasm of soybean of 4~5t and the cleaning waste water of 10t or so of 1t or so can be about generated using 1t soybean. These wastewater biological oxygen demand (BOD), chemical oxygen consumption (COC) (COD) value are higher, and total nitrogen and ammonia nitrogen are also higher, and belonging to high concentration can give birth to The property the changed high waste water of degree, especially yellow serofluid, COD are up to 10000~20000mg/L.With the increasing of bean product processing capacity Greatly, it also urgently needs to solve the problem of wastewater treatment.Contain the biologies such as protein, oligosaccharide, isoflavones in soybean wastewater Active material.
Soluble solid content (mg/g) in 1 soybean wastewater of table
The protein majority contained in soybean wastewater is soybean whey protein, and main component is 2S ingredient and β-starch Enzyme, relative molecular mass are mainly distributed between 10000~30000, have good dissolubility and foaming characteristic.Wherein 2S ingredient In trypsin inhibitor be traditionally considered as anti-nutritional factors, but the trypsin inhibitor of low concentration has centainly Inhibit cancer to occur, reduce the effect of cholesterolemia.
Isoflavones is to be present in one of soybean bioactive ingredients, have pre- anti-cancer, adjust female hormone, The different physiological roles such as anti-oxidant, pre- preventing bone rarefaction, physical property is not soluble easily in water, but has in the hot water certain Dissolubility, so in the forming step of bean product with waste water flow out a part, account for about soybean total isoflavone content 50% or so.
Soyabean oligosaccharides are the general names of soluble oligosaccharide in soybean, and main component is raffinose, stachyose and sucrose.Its Middle raffinose and stachyose, which can not be digested enzyme in human body and decompose, to be absorbed, but can be by the Bifidobacterium in human body intestinal canal It utilizes, causes the proliferation of Bifidobacterium, and soyabean oligosaccharides are very small for the proliferation function of harmful bacteria.Bifidobacterium is in intestines Soyabean oligosaccharides are resolved into lactic acid and acetic acid in road, reduce intestinal pH, inhibit harmful bacterial growth, to reach improvement enteron aisle The purpose of environment.During making bean product, bean or pea, which wear into slurry and boil, makes most albumen using the process of solidification Matter all forms solid, and the water solubility of soyabean oligosaccharides is very good, thus most soyabean oligosaccharides be all present in therewith it is useless Among water.
Because there is the presence of above functions substance, if only soybean wastewater is entered at sewage disposal system It is discharged after reason, not only wastes good resource, but also the difficulty and cost that sewage treatment will be greatly increased significantly.Integrated treatment Soybean wastewater is to recycle effective component therein, and COD, the solubility of waste water can be significantly reduced after recycling Solid content and other indexs do so not only effectively to be located in and have managed waste water, but also make the investment to return flow There is return, is the thing killed two birds with one stone.
At present for the main method of soybean wastewater comprehensive utilization as disclosed in 103265614 A of patent CN: will give up After water pretreatment, protein concentrated solution and ultrafiltration membrane permeate are obtained through ultrafiltration membrane;Soyabean protein powder, ultrafiltration membrane is made in concentrate egg white liquor Permeate is after resin adsorption, and with ethanol elution resin, washing lotion is used for isoflavones processed;Resin efflux is obtained by nanofiltration membrane To oligosaccharide concentrate and nanofiltration membrane permeate, oligosaccharide concentrate is for making oligomeric Icing Sugar, and nanofiltration membrane permeate is using anti- Permeable membrane can obtain pure water.
Current technology is mainly the method recycling albumen for passing through UF membrane, different with resin adsorption or solvent method recycling soybean Flavones.But since the solid content of soybean wastewater is very low, only 1% or so, using the above method handle equipment at This is very big, and other organic matters such as grease are very big to the interference effect of film and resin, equipment cleaning, regeneration or the week replaced Phase is short, and the efficiency of operation is very low.For disadvantage mentioned above, the present invention proposes what a kind of soybean wastewater high efficiente callback utilized Method.
Summary of the invention
In view of the above shortcomings, the purpose of the present invention is to provide the systems that a kind of Guilin rice-flour noodle is burnt with non-fried crackling pot Make method, does not use frying technological process, and the unique oral sensations for keeping crackling pot to burn of energy long period are with regard to flavor.
Technical solution of the present invention is summarized as follows:
A kind of method that soybean wastewater recycles, wherein the step of this method is as follows:
1) it pre-processes
Waste water filtering or filters pressing are removed into the solid contents such as bean dregs, impurity, obtain filtrate;
2) it emulsifies
Emulsifier is added into the filtrate that step 1) obtains, is stirred evenly, ultrasonic wave co-emulsifier is for a period of time, then quiet It sets;
3) air bearing
The waste water bottom obtained to step 2) is passed through forced air, countless fine bubbles is formed in water, using scraper plate Scraping wastewater surface bubble is simultaneously collected, and leachate is obtained, and the waste water for scraping off blibbing is spare as clear liquid retention;The leachate Dehydration, dry, crushing obtain mixture;
4) film filters
The clear liquid that step 3) is obtained obtains nanofiltration membrane concentrate and nanofiltration membrane permeate through nanofiltration membrane, collects dense Contracting liquid, permeate obtain pure water through reverse osmosis membrane filtration.
Preferably, the method that the soybean wastewater recycles, wherein the emulsifier includes beta-cyclodextrin, The additional amount of the cyclodextrin is 0.5~1g/L.
Preferably, the method that the soybean wastewater recycles, wherein the emulsifier further includes chitosan, The additional amount of the chitosan is 0.03~0.08g/L.
Preferably, the method that the soybean wastewater recycles, wherein the ultrasonic wave co-emulsifier power is 800~1000w, time are 30~90min.
Preferably, the method that the soybean wastewater recycles, wherein the step 2) stands 30~60min.
Preferably, the method that the soybean wastewater recycles, wherein the step 3) mixture includes soybean Albumen and isoflavones.
Preferably, the method that the soybean wastewater recycles, wherein the step 3) dehydration is using disk point It disembarks;It is described dry using vacuum belt drier.
The beneficial effects of the present invention are:
(1) present invention realizes soybean protein and isoflavones from the separation and Extraction in waste water by pneumatically supported one step of mode, Soybean protein is recycled using hyperfiltration technique compared to the prior art, is set with the method for resin adsorption or solvent method recycling isoflavones Standby at low cost, operating cost is low, the operation cycle is short, high-efficient.
(2) present invention embeds isoflavones using beta-cyclodextrin, and finally obtained product can overcome isoflavones with bitter taste The shortcomings that, and with the combination dryings such as soybean protein, chitosan, overcome isoflavones drying to be not easy the shortcomings that shaping.
Specific embodiment
The present invention will be further described in detail below with reference to the embodiments, to enable those skilled in the art referring to specification Text can be implemented accordingly.
The invention discloses a kind of method that soybean wastewater recycles, the step of this method, is as follows:
1) it pre-processes
Waste water filtering or filters pressing are removed into the solid contents such as bean dregs, impurity, obtain filtrate;
2) it emulsifies
Emulsifier is added into the filtrate that step 1) obtains, is stirred evenly, ultrasonic wave co-emulsifier for a period of time, makes different Huang Ketone can be emulsified and is embedded in the hydrophobic structure of beta-cyclodextrin, be then allowed to stand;
3) air bearing
The waste water bottom obtained to step 2) is passed through forced air, forms countless fine bubbles in water, has certain The impurity of surface-active and foaming characteristic can scrape wastewater surface bubble using scraper plate and receive with bubble floating to liquid surface Collection obtains leachate, realizes the separation with liquid such as albumen, isoflavones, and protein, isoflavones and the beta-cyclodextrin of collection can pass through Further centrifugal dehydration, drying, obtain the mix products of soybean protein and isoflavones, scrape off the waste water of blibbing as clear liquid It retains spare;
4) film filters
The clear liquid that step 3) is obtained obtains nanofiltration membrane concentrate and nanofiltration membrane permeate through nanofiltration membrane, collects dense Contracting liquid, concentrate can be used for preparing oligosaccharide, and permeate obtains pure water through reverse osmosis membrane filtration.
As the another embodiment of this case, emulsifier includes beta-cyclodextrin, and the additional amount of cyclodextrin is 0.5~1g/L.β-ring Dextrin is 7 D (+)-glucopyranose composition cyclic oligomer, and molecule is in wide at the top and narrow at the bottom, both ends open, hollow cylinder Shape object, intracavitary portion are in relative hydrophobicity, and all hydroxyls are then outside molecule, since the outer rim of cyclodextrin is hydrophilic and inner cavity is dredged Water, thus it can provide a hydrophobic binding site as enzyme, it is such as organic as the various objects appropriate of main body envelope Molecule, inorganic ions and gas molecule etc., inner cavity is hydrophobic and the characteristic of external hydrophilic makes it can be according to Van der Waals force, hydrophobic Intermolecular matching effect of interaction force, Subjective and Objective etc. forms inclusion compound and molecular assembly with many organic and inorganic molecule System.The present invention utilizes the property of beta-cyclodextrin " internal drainage, external hydrophilicity " and the surface-active and isoflavones of soybean whey protein Hydrophobicity so that soybean whey protein, beta-cyclodextrin and isoflavones is formed condensate under ultrasonication.
As the another embodiment of this case, emulsifier further includes chitosan, and the additional amount of the chitosan is 0.03~ 0.08g/L.Chitosan have good flocculation, clarification, by be added chitosan make soybean whey protein, beta-cyclodextrin and The condensate that isoflavones is formed flocculates rapidly, natural sedimentation, improves the yield of soybean protein and isoflavones.
As the another embodiment of this case, ultrasonic wave co-emulsifier power is 800~1000w, and the time is 30~90min.It is super Sound wave co-emulsifier power and time have an impact to emulsifying power, therefore power and time should be limited.
As the another embodiment of this case, step 2) stands 30~60min.
As the another embodiment of this case, step 3) mixture includes soybean protein and isoflavones.
As the another embodiment of this case, step 3) dehydration uses disc separator;It is described dry using vacuum belt type drying Machine.
The present invention utilizes the property of beta-cyclodextrin " internal drainage, external hydrophilicity ", using the surface-active of soybean whey protein, with And the hydrophobicity of isoflavones makes soybean whey protein, beta-cyclodextrin and isoflavones form condensate under ultrasonication, uses Pneumatically supported method makes polymer form bubble, and separates in liquid level with liquid, thus in a step realization bean product soybean protein and The separation and Extraction of isoflavones, remaining clear liquid pass through membrane separation technique again and recycle oligosaccharide.
Specific embodiment and comparative example is listed below:
Embodiment 1:
A kind of method that soybean wastewater recycles,
The step of this method, is as follows:
1) it pre-processes
Waste water filtering or filters pressing are removed into the solid contents such as bean dregs, impurity, obtain filtrate;
2) it emulsifies
The cyclodextrin and 0.03g/L chitosan that 0.5g/L is added into the filtrate that step 1) obtains, stir evenly, ultrasonic wave Co-emulsifier, power 800w, time 30min are then allowed to stand 50min;
3) air bearing
The waste water bottom obtained to step 2) is passed through forced air, countless fine bubbles is formed in water, using scraper plate Scraping wastewater surface bubble is simultaneously collected, and leachate is obtained, and the waste water for scraping off blibbing is spare as clear liquid retention;Leachate uses Disc separator dehydration, vacuum belt drier drying, crushing obtain mixture soybean protein and isoflavones;
4) film filters
The clear liquid that step 3) is obtained obtains nanofiltration membrane concentrate and nanofiltration membrane permeate through nanofiltration membrane, collects dense Contracting liquid, permeate obtain pure water through reverse osmosis membrane filtration.
Embodiment 2:
A kind of the step of method that soybean wastewater recycles, this method, is as follows:
1) it pre-processes
Waste water filtering or filters pressing are removed into the solid contents such as bean dregs, impurity, obtain filtrate;
2) it emulsifies
0.8g/L cyclodextrin and 0.05g/L chitosan are added into the filtrate that step 1) obtains, and are stirred evenly, ultrasonic wave is auxiliary Help emulsification, power 900w, time 60min;It is then allowed to stand 30min;
3) air bearing
The waste water bottom obtained to step 2) is passed through forced air, countless fine bubbles is formed in water, using scraper plate Scraping wastewater surface bubble is simultaneously collected, and leachate is obtained, and the waste water for scraping off blibbing is spare as clear liquid retention;Leachate uses Disc separator dehydration, vacuum belt drier drying, crushing obtain mixture soybean protein and isoflavones;
4) film filters
The clear liquid that step 3) is obtained obtains nanofiltration membrane concentrate and nanofiltration membrane permeate through nanofiltration membrane, collects dense Contracting liquid, concentrate can be used for preparing oligosaccharide, and permeate obtains pure water through reverse osmosis membrane filtration.
Embodiment 3:
A kind of the step of method that soybean wastewater recycles, this method, is as follows:
1) it pre-processes
Waste water filtering or filters pressing are removed into the solid contents such as bean dregs, impurity, obtain filtrate;
2) it emulsifies
1g/L cyclodextrin and 0.08g/L chitosan are added into the filtrate that step 1) obtains, and are stirred evenly, ultrasonic wave auxiliary Emulsification, emulsification power are 1000w, and time 90min is then allowed to stand 40min;
3) air bearing
The waste water bottom obtained to step 2) is passed through forced air, countless fine bubbles is formed in water, using scraper plate Scraping wastewater surface bubble is simultaneously collected, and leachate is obtained, and the waste water for scraping off blibbing is spare as clear liquid retention;The leachate Mixture soybean protein and isoflavones are obtained using disc separator dehydration, vacuum belt drier drying, crushing;
4) film filters
The clear liquid that step 3) is obtained obtains nanofiltration membrane concentrate and nanofiltration membrane permeate through nanofiltration membrane, collects dense Contracting liquid, permeate obtain pure water through reverse osmosis membrane filtration.
Comparative example 1:
A kind of method that soybean wastewater recycles,
The step of this method, is as follows:
1) it pre-processes
Waste water filtering or filters pressing are removed into the solid contents such as bean dregs, impurity, obtain filtrate;
2) it emulsifies
0.03g/L chitosan is added into the filtrate that step 1) obtains, and is stirred evenly, ultrasonic wave co-emulsifier, power is 800w, time 30min, is then allowed to stand 50min;
3) air bearing
The waste water bottom obtained to step 2) is passed through forced air, countless fine bubbles is formed in water, using scraper plate Scraping wastewater surface bubble is simultaneously collected, and leachate is obtained, and the waste water for scraping off blibbing is spare as clear liquid retention;Leachate uses Disc separator dehydration, vacuum belt drier drying, crushing obtain mixture soybean protein and isoflavones;
4) film filters
The clear liquid that step 3) is obtained obtains nanofiltration membrane concentrate and nanofiltration membrane permeate through nanofiltration membrane, collects dense Contracting liquid, permeate obtain pure water through reverse osmosis membrane filtration.
Comparative example 2:
A kind of the step of method that soybean wastewater recycles, this method, is as follows:
1) it pre-processes
Waste water filtering or filters pressing are removed into the solid contents such as bean dregs, impurity, obtain filtrate;
2) it emulsifies
0.8g/L cyclodextrin is added into the filtrate that step 1) obtains, and is stirred evenly, ultrasonic wave co-emulsifier, power is 900w, time 60min;It is then allowed to stand 30min;
3) air bearing
The waste water bottom obtained to step 2) is passed through forced air, countless fine bubbles is formed in water, using scraper plate Scraping wastewater surface bubble is simultaneously collected, and leachate is obtained, and the waste water for scraping off blibbing is spare as clear liquid retention;Leachate uses Disc separator dehydration, vacuum belt drier drying, crushing obtain mixture soybean protein and isoflavones;
4) film filters
The clear liquid that step 3) is obtained obtains nanofiltration membrane concentrate and nanofiltration membrane permeate through nanofiltration membrane, collects dense Contracting liquid, concentrate can be used for preparing oligosaccharide, and permeate obtains pure water through reverse osmosis membrane filtration.
The performance test results of embodiment and comparative example are listed below:
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited In specific details.

Claims (7)

1. a kind of method that soybean wastewater recycles, which is characterized in that the step of this method is as follows:
1) it pre-processes
Waste water filtering or filters pressing are removed into the solid contents such as bean dregs, impurity, obtain filtrate;
2) it emulsifies
Emulsifier is added into the filtrate that step 1) obtains, is stirred evenly, ultrasonic wave co-emulsifier for a period of time, is then allowed to stand;
3) air bearing
The waste water bottom obtained to step 2) is passed through forced air, forms countless fine bubbles in water, is scraped using scraper plate Wastewater surface bubble is simultaneously collected, and leachate is obtained, and the waste water for scraping off blibbing is spare as clear liquid retention;The leachate is de- Water, drying, crushing obtain mixture;
4) film filters
The clear liquid that step 3) is obtained obtains nanofiltration membrane concentrate and nanofiltration membrane permeate through nanofiltration membrane, collects concentrate, Permeate obtains pure water through reverse osmosis membrane filtration.
2. the method that soybean wastewater according to claim 1 recycles, which is characterized in that the emulsifier includes β- Cyclodextrin, the additional amount of the cyclodextrin are 0.5~1g/L.
3. the method that soybean wastewater according to claim 2 recycles, which is characterized in that the emulsifier further includes Chitosan, the additional amount of the chitosan are 0.03~0.08g/L.
4. the method that soybean wastewater according to claim 1 recycles, which is characterized in that the ultrasonic wave auxiliary cream Change power is 800~1000w, and the time is 30~90min.
5. the method that soybean wastewater according to claim 1 recycles, which is characterized in that the step 2) stands 30 ~60min.
6. the method that soybean wastewater according to claim 1 recycles, which is characterized in that the step 3) mixture Including soybean protein and isoflavones.
7. the method that soybean wastewater according to claim 1 recycles, which is characterized in that the step 3) dehydration is adopted Use disc separator;It is described dry using vacuum belt drier.
CN201811567504.6A 2018-12-21 2018-12-21 A kind of method that soybean wastewater recycles Withdrawn CN109678925A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110540532A (en) * 2019-06-17 2019-12-06 山东禹王生态食业有限公司 Method for extracting soybean isoflavone from soybean milk water first-stage scum
CN111903916A (en) * 2020-08-20 2020-11-10 福建顶旺食品有限公司 Preparation method of pea powder
CN111944010A (en) * 2020-08-20 2020-11-17 运城学院 Equipment and method for extracting soybean protein, isoflavone and oligosaccharide from bean product wastewater

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110540532A (en) * 2019-06-17 2019-12-06 山东禹王生态食业有限公司 Method for extracting soybean isoflavone from soybean milk water first-stage scum
CN110540532B (en) * 2019-06-17 2021-06-01 山东禹王生态食业有限公司 Method for extracting soybean isoflavone from soybean milk water first-stage scum
CN111903916A (en) * 2020-08-20 2020-11-10 福建顶旺食品有限公司 Preparation method of pea powder
CN111944010A (en) * 2020-08-20 2020-11-17 运城学院 Equipment and method for extracting soybean protein, isoflavone and oligosaccharide from bean product wastewater
CN111944010B (en) * 2020-08-20 2023-05-09 运城学院 Extraction equipment and method for soybean protein, isoflavone and oligosaccharide in bean product wastewater

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Application publication date: 20190426

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