CN109667030A - A kind of method of milk protein fiber or its long filament or its blended fabric weaving and dyeing - Google Patents
A kind of method of milk protein fiber or its long filament or its blended fabric weaving and dyeing Download PDFInfo
- Publication number
- CN109667030A CN109667030A CN201710955477.9A CN201710955477A CN109667030A CN 109667030 A CN109667030 A CN 109667030A CN 201710955477 A CN201710955477 A CN 201710955477A CN 109667030 A CN109667030 A CN 109667030A
- Authority
- CN
- China
- Prior art keywords
- milk protein
- dyeing
- fabric
- protein fiber
- long filament
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/13—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen using inorganic agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/008—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/20—Protein-derived artificial fibres
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
The present invention relates to a kind of methods of milk protein fiber or its long filament or its blended fabric weaving and dyeing, which is characterized in that in weaving, needing relaxed fabric tightness is 10%-45%；In dyeing course, homemade milk protein fiber dyeing special assistant is added, it realizes polyacrylonitrile or polyvinyl alcohol is the dyeing of milk protein fiber with reactive dyestuff technology of carrier, it solves the technical problems such as dyeing defect, color difference, the low, poor color fastness of color saturation generated during textile dyeing, solves the problems, such as the dyeing of the milk protein fiber of high blending ratio or pure spinning and its long filament and its blended fabric.Using common reactive dyeing, using the heating at a slow speed at 48 DEG C of milk protein fiber glass transition temperature, step deflation, gradually upper dye, the technique of control heating rate, in the case where not increasing any new chemical pollutant, milk protein fiber and its blended fabric that moderate shrinking percentage, even dyeing, color fastness reach pure cotton fabric standard are obtained.
Description
Technical field
The present invention relates to a kind of methods of milk protein fiber or its long filament or its blended fabric weaving and dyeing, especially relate to
And a kind of milk protein fiber and its long filament and its simultaneously, twist, lining, cored or with the weaving of its short fiber blending fabric and dyeing
Method belongs to the technical field of weaving and the textile dyeing of new textile material.
Background technique
Milk protein fiber and its long filament are high-grade new fiber materials.The protein fibre and chemistry that it collects natural are fine
, with pro-skin, foster skin, moisture absorption is ventilative, soft, gloss is bright, appearance is luxurious, physical mechanical property for the advantage of dimension
The features such as excellent；With it is good can textile；With the compatibility of other fibers；Fungus-proof antisepsis；It is not afraid of and damages by worms；It is antibacterial, antibacterial；
The characteristics of performances such as health care are integrated.But milk protein fiber and textile dyeing technology is immature, restrict always and
It is affected in the application and popularization of textile industry.
Currently, there are two types of different methods for the production of milk protein fiber, it is all by amino acid in milk protein
The casein depolymerization of line style become straight chain macromolecular after, one is using acrylonitrile as carrier graft copolymerization, the second is with acetic acid
Vinyl alcohol is after carrier is grafted polycondensation, spinning solution is made, and small molecule exchange solidifies between carrying out solvent using wet spinning technology
At fibre, using drawing-off, drying, winding and become the long filament of milk protein fiber.By drawing-off, drying, curling, cut off
For milk protein staple fiber.
Since the spinning solution of milk protein fiber is different, the difference of the carrier of polymerization, catalyst and production technology, institute
With the performance of fiber and the methods of dyeing are also not quite similar.When milk protein fiber dedicated dye not yet, lead to
Normal polyacrylonitrile is the milk protein fiber of carrier, using the dye of positive ion, reactive dye, acid dyeing；Polyvinyl alcohol
Reactive dye, acid dyeing are generally used for the milk protein fiber of carrier.But either which kind of dyeing, all
It is very easy to occur that dyeing defect, color difference, color unsaturation, poor color fastness, dye utilization rate is low, fibre shrinkage is unstable etc. many asks
Topic.The method of most milk fibres and scribbled and blended fabric dyeing just under study for action is:
1, using loose stock dyeing: for dyeing defect, color difference, poor color fastness, color is unsaturated, shrinking percentage is unstable the problems such as,
Due to being to become colored yarns with other fiber blends again after using loose stock dyeing, do not seen after dyeing defect is blended yet
Come.The fiber of loose stock dyeing is heat shrinkable in a free state, the colored yarns and fabric produced after spinning, one
As will not generate significant shrinkage again.
2 or scribbled when weaving, low ratio is added and is usually no more than 20% milk protein fiber and natural fine
The problems such as dimension, regenerated celulose fibre, synthetic fibers etc. are blended or interweave, do not consider the dyeing of milk protein fiber；Or ox
Milk proem fiber, which is left white, not to be dyed.The shortcomings that this production technology and production method, is: can not produce high blending ratio and pure
Milk protein fiber product can not fully demonstrate the excellent performance of milk protein fiber；And the fiber due to contaminating other components
And generate staining, seriously affect every color fastness index of product and the vividness of color, the saturation degree of dyeing, color it is equal
Even property and homochromatism；Feel cannot be fully played, and flexibility, drapability, the elasticity of fabric are all very poor.
3, since milk protein fiber is wet spinning, fibrous inside contains many polar groups, fiber longitudinal surface
There are many grooves, and there is irregular polygon micropore in section, and plays the role of moisture absorbing and sweat releasing.Fiber is small when being solidified into fibre
Molecule exchanges many holes left, while providing Dye Adsorption, infiltration, dye seat, also causes fiber, yarn, fabric tool
There are the unstability of extremely strong heat-shrinkable and size, the uncertainty of fabric weight, breadth.Using traditional production method,
Fiber, yarn, fabric by heat are also easy to produce that impermeable dye, the irregular, dyeing defect of dye, color are uneven, and dyeing post-shrinkage ratio is big, and feel is poor, fabric
The problems such as cloth cover hardening, poor reproducibility.The milk protein fiber of usual polyacrylonitrile carrier generally use the dye of positive ion,
Reactive dye, acid dyeing；The milk protein fiber of PVA Carrier generally uses reactive dye, acid dyes dye
Color.But no matter which kind of dyeing is used, even if selecting reasonable production technology, milk protein fiber is also difficult to realize contaminate
The uniformity of color reaches good color fastness.Therefore, the density and tightness when fabric knitting how are controlled, sufficient receipts are provided
Contracting space；How to solve the colouring problem of fabric is the key problem in technology that can milk protein fiber obtain popularizing in an all-round way application.
Summary of the invention
The object of the present invention is to provide a kind of milk protein fiber or its long filaments or its blended fabric weaving and dyeing with after
It arranges, stability is good, favorable reproducibility, even dyeing, color fastness is high, elasticity is good for feel, gloss is bright, loss and waste is small, technique
It is simple and convenient to operate, is consistent, it is blended to improve milk protein fiber height for the variation and deep processing of product variety easy to accomplish
The method of the milk protein fiber or its long filament or its blended fabric weaving and dyeing and final finishing of ratio and pure spinning.
In order to realize the above object, the technical solution of the present invention is to provide a kind of milk protein fiber or its long filament or its
The method of blended fabric weaving and dyeing, method are as follows:
Step 1: the weaving of milk protein fiber or its long filament or its blended fabric
A. the weaving of yarn machine fabric: base yarn --- warping --- sizing --- woven fabric rack on beam of a loom --- weaving ---
--- cylinder is matched in mending --- perching --- for the inspection of semifinished product；
B. the weaving of yarn knitted fabric: base yarn --- rewinding --- waxing --- be above knitted rack --- weaving --- partly at
Product examine is tested, and --- cylinder is matched in mending --- perching ---；
It is characterized in that, needing relaxed fabric tightness is 10%-45% in weaving；
Step 2: the dyeing of milk protein fiber or its long filament or its blended fabric
A. milk protein fiber or its long filament or its blended fabric are put into liquid stream dye vat, according to 1: 6-1: 15 bath
Than adding water to submerge fabric, then be added bleaching stibilizer 0.5g/L-4g/L, hydrogen peroxide 1%-12%, soda ash 0.5g/L-3g/L,
Bleeding agent 0.5g/L-2g/L, operating are warming up to 40 DEG C -60 DEG C after ten minutes, with the speed that 1 DEG C/min-3 DEG C/min is heated, and protect
It is 5-15 minutes warm, then 75 DEG C -90 DEG C are warming up to the speed that 1 DEG C/min-3 DEG C/min is heated, heat preservation is floated for 30-50 minutes
It is white, after deoxygenating pre-treatment with deoxyenzyme, prepare dyeing.For in, the dark fabric for not needing bleaching, by the stabilizer of oxygen bleaching and
Hydrogen peroxide changes the yarn agent 1g/L-2.5g/L that deoils into, equally carries out above-mentioned boiling-off pre-treatment, and does not need at the deoxidation of deoxyenzyme
Reason；
B. step a is cooled down into 70 DEG C of heel row except residual into the milk protein fiber of cylinder or its long filament or its blended fabric
Liquid adds water to submerge milk protein fiber in cylinder or its long filament or its blended fabric according still further to bath raio, then, milk protein is added
The special assistant 1g/L-5g/L of stock-dye, operating add bleeding agent, dyestuff and promote dye salt operating 8-10 after 4-10 minutes
Minute prepares dyeing: wherein the special assistant of milk protein fiber dyeing is the reaction produced by Shanghai Ao Su Chemical Co., Ltd.
Type dye levelling agent, 85-92 parts, ethylene glycol amine, crosslinking agent made of 3-10 parts, hexamethylene diamine and epoxychloropropane condensation, 5-10
Part, according to parts by weight than prepare after, by high-speed stirred, emulsification, uniformly mixing, with reach preservation it is not stratified until；
C. it will dye into the milk protein fiber of cylinder or its long filament or its blended fabric with the heating of 1 DEG C/min-3 DEG C/min
Speed is warming up to 40 DEG C -60 DEG C, keeps the temperature 5-15 minutes, then is warming up to 55 DEG C -85 with the speed that 1 DEG C/min-2 DEG C/min is heated
DEG C, 8-12 minutes are kept the temperature, soda ash is added and keeps the temperature the 30-60 minutes fixation carried out between dyestuff and fiber, later according to another fibre
The performance of dimension carries out resisdye；
D. by dyeing and the good fabric of fixation, 50 DEG C are cooled to hereinafter, being washed again.
E. the fabric in, dark, carrying out the method that loose colour is removed out in washing is: by the fabric in cylinder according to bath raio
Add water, soaping agent 0.5g/L-3g/L is added, is warming up to 70 DEG C -90 DEG C, 10-20 points of heat preservation with 1 DEG C/min-3 DEG C/min speed
Then clock is cooled to 50 DEG C hereinafter, drain is washed again；
F. by the fabric after soaping or washing, acetic acid is added and adjusts pH value to 5-6.5, softening agent 1g/L-5g/ is added
L continues to be heated up to 40 DEG C -60 DEG C, keeps the temperature progress soft finish in 10-30 minutes；
G. soft good milk protein fiber or its long filament or its blended fabric are cooled to room temperature, the cloth outputting out of cylinder, into
Row dehydration, drying；
H. the fabric after drying is padded into softening agent 2g/L-10g/L again, control shapes in 120 DEG C or less tenterings, then
Carry out the quality inspection of finished product, finished product perching, clot and packaging after product is qualified.
The milk protein fiber or its long filament or its blended fabric are as follows: 100% milk protein long filament and milk egg
The yarn and fabric of white staple fiber；Milk protein long filament and natural cotton, fiber crops, the viscose glue of silk or regenerated celulose fibre, tencel,
Long filaments or the staple fibers such as bamboo fibre, Modal, beautiful match and twist, combine, cored, cladding spinning, liner silk yarn and fabric,
Or the fabric of all yarns that its reactive dye can dye；Milk protein fiber long filament or its staple fiber and filament of synthetic fibre
Or the yarn and fabric of its staple fiber；And the yarn and fabric of the loose stock dyeing of milk protein fiber.
The bleaching stibilizer are as follows: hydrogen peroxide stabilizer CAN, sodium metasilicate or common hydrogen peroxide bleaching stabilizer.
The bleeding agent are as follows: common bleeding agent is JET, JFC.
The reaction type dye levelling agent of the Shanghai Ao Su Chemical Co., Ltd. production are as follows: R-42；The hexamethylene diamine
It is EH-1 with crosslinking agent made of epoxychloropropane condensation.
The softening agent are as follows: amido silicon oil and hydroxy silicon oil are formulated according to 7: 3 mass ratio.
The dyestuff is the reactive dye of conventional medium temperature or high temperature modification.
The present invention during milk protein fiber or its long filament or its blended fabric weaving, take low-tension, low-density,
The method and measure of low tightness, it is homemade by being added in process of production the characteristics of contraction in conjunction with milk protein fiber heat
Milk protein fiber dyes special assistant, realizes Dyeing Technology of Reactive Dyes, solves the color generated during textile dyeing
The technical problems such as the low, poor color fastness of flower, color difference, color saturation, solve high blending ratio or pure spinning milk protein fiber and its
The problem of dyeing of long filament and its blended fabric.Using common reactive dyeing, using in milk protein fiber vitrifying
Heating at a slow speed, step deflation at 48 DEG C of temperature, gradually upper dye, the technique of control heating rate, are not increasing any new change
In the case where learning pollutant, the milk protein fiber that moderate shrinking percentage, even dyeing, color fastness reach pure cotton fabric standard is obtained
Or its long filament or its blended fabric.Small, simple process, easy to operate, consistent, reproducibility using this technology loss and waste
It is good.The deep processing of product easy to accomplish and the variation of kind after dyeing obtain the milk protein fiber or its length of any blending ratio
The product of silk or its blended fabric.
It is an advantage of the invention that fabric surface is smooth, soft, uniform color, no color differnece, without dyeing defect, the color of yarn and fabric
Standard of the fastness close to cotton fabric, the favorable reproducibility of dyeing, loss and waste is few, does not generate new chemical pollutant.
Specific embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
Milk protein fiber long filament and its simultaneously, twist, composite yarn and its staple fiber and cotton blended fabric are weaved and are dyed
Processing method, method are as follows:
Step 1: weaving
A. weaved using large circle machine or circular knitting machine trolley: --- rewinding --- waxing --- is above knitted rack-and knits base yarn
Make --- the inspection of semifinished product --- mending --- perching
B. using has shuttle and shuttle-free loom weaving: base yarn --- --- knit warping by sizing --- loom on beam of a loom ---
Make --- inspection of semifinished product --- mending --- perching --- match cylinder
Wherein: in weaving, it is 25% that relaxed fabric tightness is needed compared with conventional products；
Step 2: dyeing
A. the blended fabric of milk protein fiber or its long filament or itself and cotton is put into liquid stream dye vat, according to 1: 8 bath
Than water saturates fabric is added, hydrogen peroxide bleaching stabilizer CAN 1.0g/L, hydrogen peroxide 6%, soda ash 2g/L, bleeding agent 0.7g/ is then added
L, after operating 10 minutes, 50 DEG C are warming up to the speed that 1.5 DEG C/min is heated, heat preservation is added again with 1.5 DEG C/min after ten minutes
The speed of temperature is warming up to 90 DEG C, keeps the temperature 30 minutes progresss bleachings, after the whiteness that needs are reached by deoxyenzyme deoxidation, standard
The stabilizer of oxygen bleaching and hydrogen peroxide are changed into the yarn agent WS1.5g/ that deoils in, the dark fabric for not needing bleaching by standby dyeing
L equally carries out above-mentioned boiling-off pre-treatment, and does not need the deoxidation processing of deoxyenzyme；
B. the blended fabric of step a into the milk protein fiber of cylinder or its long filament or itself and cotton is cooled down into 70 DEG C of heel row
Residul liquid-removing adds water to submerge the blended fabric of the milk protein fiber or its long filament or itself and cotton in cylinder according still further to bath raio, then plus
Enter the special assistant 1g/L-2g/L of milk protein fiber dyeing, operating adds bleeding agent, dyestuff and promotees dye salt after 5 minutes
Operating is dyed for 10 minutes；
The bleeding agent are as follows: JET, the milk protein fiber dyeing special assistant is by the limited public affairs of Shanghai Australia element chemistry
It takes charge of R-42:90 parts of chemically-reactive dyes levelling agent, the ethylene glycol amine of production: being handed over made of 5 parts, hexamethylene diamine and epoxychloropropane condensation
After joining agent EH-1:5 parts, preparing according to parts by weight, by high-speed stirred, emulsification, uniformly mixing, to reach, preservation is not stratified to be
Only；
C. it will dye into the milk protein fiber of cylinder or its long filament or its blended fabric with cotton with the heating of 1.5 DEG C/min
Speed is warming up to 45 DEG C, and heat preservation after ten minutes, then with the speed that 1.0 DEG C/min is heated is warming up to 60 DEG C, if living using high temperature
Property dyestuff when be warming up to 80 DEG C, after heat preservation 10 minutes, soda ash is added in fast method after first slow, heat preservation is reacted for 50 minutes
Fixation；
D. the good fabric of fixation is cooled to 50 DEG C hereinafter, excluding waste liquid, progress pickling is washed；
E. in, deep-colour fabric, soaping agent 1g/L is added, 80 DEG C are warming up to the speed that 2 DEG C/min is heated, using height
It is warming up to 90 DEG C when warm reactive dye, keeps the temperature 15 minutes, is cooled to 50 DEG C of drains, washing；
F. by the fabric after soaping or washing, acetic acid is added and adjusts pH value to 5.5, softening agent 1.5g/L is added, continues
Be heated up to 55 DEG C, keep the temperature 20 minutes soft treatments for carrying out fabric, softening agent be amido silicon oil and hydroxy silicon oil according to 7: 3 weight
Amount ratio is formulated；
G. the blended fabric of soft good milk protein fiber or its long filament or itself and cotton is cooled to room temperature, is gone out out of cylinder
Cloth is dehydrated, is dried.
H. the fabric after drying is padded into softening agent 3g/L again, controls in 120 DEG C or less stentering formings, then carries out into
The quality inspection of product carries out the cloth-inspecting rolling and packaging of finished product after product is qualified.
Embodiment 2
Milk protein fiber long filament and its milk protein fiber yarn and natural or regenerated celulose fibre is blended or plying
Yarn, when yarn of the long filaments such as coating spandex, nylon, XLA, PTT or weaving is embedded in the fabric weaving and dyeing of these long filaments
Method are as follows:
Step 1: weaving
Weaved using warp knitting machine: base yarn --- warping --- be knitted on beam of a loom rack --- weaving --- semi-finished product inspection
Test --- mending --- perching --- match cylinder
--- rewinding --- waxing --- upper tubular knitting rack --- weaving --- is weaved: base yarn using weft-knitting machine
--- cylinder is matched in mending --- perching --- for the inspection of semifinished product
Wherein, in weaving, needing relaxed fabric tightness is 30%；
Step 2: dyeing
Reactive dyeing is carried out using milk protein fiber dyeing special assistant is added, one-bath method can make milk protein
Fiber and native cellulose fibre or regenerated celulose fibre are painted simultaneously, and nylon and PTT filament dyeing then use it is traditional
Acid dyes, disperse dyeing, it is noted that dyeing temperature should control at 100 DEG C hereinafter, traditional carrier is added, adopt
It is not dyed and is left white with dyeable PTT fiber or ptt fiber on disperse dyes, to guarantee that milk protein fiber is not destroyed, reach excellent
Good pliability and gloss, hydrogen peroxide stabilizer are CAN or sodium metasilicate, bleeding agent JET, the milk protein fiber dye
R-42:85 parts of reaction type dye levelling agent that color special assistant is produced by Shanghai Ao Su Chemical Co., Ltd., ethylene glycol amine: 7 parts,
Hexamethylene diamine and epoxychloropropane condensation made of crosslinking agent: 8 parts, after being prepared according to weight part ratio, by high-speed stirred, emulsification,
Uniformly mixing, with reach save it is not stratified until.The fastness index of the other the same as in Example 1, dyeing reach or better than pure cotton finger
Mark.
Embodiment 3
The animal/vegetable proteins such as wool, the rabbit hair, cashmere, silk, milk protein fiber, soybean fiber fiber and its blended
The fabric weaving and dyeing of these long filaments are embedded in when yarn coating spandex, polyamide fibre, the yarn of XLA, PTT long filament or weaving:
Step 1: weaving
Weaving process is as example 1.
Wherein: in weaving, needing relaxed fabric tightness is 25%；
Step 2: dyeing
Dyeing in the same manner as in Example 1, however, it is desirable to contaminate natural protein fibre using traditional acid dyes, is gone
Except loose colour and then with reactive dye resisdye milk protein fiber, to guarantee the uniform of the fastness of dyeing, vividness and color
Property, hydrogen peroxide stabilizer CAN.
Embodiment 4
The yarn or its cladding that flax, ramie, hemp, sweat are numb, regenerated hemp fibre and milk protein fiber are blended, combine
Spandex filament, chinlon filament, XLA long filament or PTT long filament fabric or weaving when insertion fabric fabric weaving and dyeing:
Step 1: weaving
Weaving process is in the same manner as in Example 1；
Wherein: in weaving, needing relaxed fabric tightness is 15%；
Step 2: dyeing
Before oxygen bleaching in processing, when natural primary colors flaxen fiber ratio is greater than 40%, hydrogen peroxide bleaching stabilizer CAN1.2g/ is added
L, hydrogen peroxide 10%, soda ash 4g/L, bleeding agent 1.5g/L, other techniques are in the same manner as in Example 2.
Embodiment 5
The native cellulose fibres such as cotton, fiber crops, the tencel fiber of the long filament of regenerated cellulose or its staple fiber, Modal are fine
Dimension, bamboo fibre, richcel fiber and milk protein short fiber blending or the weaving of plying and the fabric blank of intertexture and dyeing.Using adding
Enter the special assistant of milk protein fiber dyeing, reactive dyeing can complete the process of dyeing with bath.When the ratio of primary colors fiber crops
When example is more than 40%, the dosage of oxygenic bleaching aids is the same as example 4；The alkali fixation time is added to extend to 60 minutes, soaping agent dosage is 2g/L,
Time 20 minutes；Other techniques are as example 1.
Embodiment 6
The artificial beef plants such as soybean fiber, zein fiber (acid fiber by polylactic) and milk protein short fiber blending and plying
Yarn weaving and openpore fabric dyeing.When dyeing, soybean fiber and milk protein fiber are using addition milk protein
The method of the special assistant of stock-dye carries out reactive dyeing, and Zein fibers then use the low temperature of disperse dyes to contaminate
Color occurs dodging the effect of color since tinctorial yield is low.Other techniques are in the same manner as in Example 1.
Embodiment 7
Wool, the rabbit hair, cashmere, Sheep Cashmere, camel's hair etc. be natural or regenerated animal protein fiber and milk protein staple fiber
Plurality of raw materials is blended or combines the weaving of fabric and the dyeing of openpore fabric.
The tightness of Density and fabric loosens 20%, using dedicated the helping that milk protein fiber dyeing is added when dyeing
Agent contaminates natural protein fibre using traditional acid dyes technique, and dye is not usually fine using milk protein is added again
Dimension dyeing special assistant carries out the set dyeing technique of reactive dye dye milk protein fiber, and other techniques are in the same manner as in Example 1.
Embodiment 8
The fabric knitting of the synthetic staples such as terylene, polyamide fibre, acrylic fibers, PTT and milk protein short fiber blending or plying with
The dyeing of openpore fabric.For containing the component other than milk protein fiber, needing to carry out tradition according to the performance of synthetic fibers
Disperse dyes, acid dyes, the dye of positive ion resisdye.Pay attention to taking into account thermo-labile, the not alkaline-resisting property of milk protein fiber
The dyeing of synthetic fibers can be formulated.Damp and hot drying, setting temperature are at 120 DEG C or less.When washing shrinkage is big, using xeothermic fixed
Type, temperature are controlled at 150 DEG C or less.When washing shrinkage is still unqualified, super soft 100 DEG C using rotating cage type pine formula, 15 minutes
It arranges.
Embodiment 9
Two kinds or more natural fibers, regenerated celulose fibre, synthetic fibers and milk protein fiber it is blended or plying it is white
Base textile dyeing.The dyeing of milk protein fiber is the same with 1 technique of embodiment.And other components other than milk protein fiber
Fiber needs the part according to its performance disperse dyes or acid dyes or the dye of positive ion set dyed synthetic fiber.Fiber group
It is point more, there is shot effects and be more obvious, homochromatism is poorer.However, it is possible to embody the effect of another dim color.
Dyeing explanation: the above master to illustrate that milk protein fiber colouring method, for containing native cellulose fibre
The yarn and fabric of dimension, regenerated celulose fibre class, being capable of simultaneously dyeing according to the method for the above reactive dyeing.For containing
There are the yarn and fabric of silk, hairs native protein, additionally needs acid dyes resisdye.For the yarn containing acrylic fibers and knit
Object needs dye of positive ion resisdye.For yarn and fabric containing polyesters, disperse dyes resisdye is needed.Total principle is,
Pay attention to dyeing temperature cannot it is too high, alkaline cannot the too strong, time cannot be too long.
Claims (8)
1. a kind of method of milk protein fiber or its long filament or its blended fabric weaving and dyeing, method are as follows:
Step 1: the weaving of milk protein fiber or its long filament or its blended fabric
A. the weaving of yarn machine fabric: base yarn --- warping --- sizing --- woven fabric rack on beam of a loom --- weaving --- half at
Product examine is tested, and --- cylinder is matched in mending --- perching ---；
B. --- --- waxing --- is above knitted the inspection of rack --- weaving --- semi-finished product to rewinding for the weaving of yarn knitted fabric: base yarn
Test --- mending --- perching --- match cylinder；
It is characterized in that, needing relaxed fabric tightness is 10%-45% in weaving；
Step 2: the dyeing of milk protein fiber or its long filament or its blended fabric
A. milk protein fiber or its long filament or its blended fabric are put into liquid stream dye vat, are added according to 1: 6-1: 15 bath raio
Then hydrogen peroxide bleaching stabilizer 0.5g/L-4g/L, hydrogen peroxide 1%-12%, soda ash 0.5g/L-3g/ is added in water immersion fabric
L, bleeding agent 0.5g/L-2g/L, operating after ten minutes, are warming up to 40 DEG C -60 DEG C with the speed that 1 DEG C/min-3 DEG C/min is heated,
Heat preservation 5-15 minutes, then 75 DEG C -90 DEG C are warming up to the speed that 1 DEG C/min-3 DEG C/min is heated, heat preservation is floated for 30-50 minutes
It is white, after deoxygenating pre-treatment with deoxyenzyme, prepare dyeing, in, the dark fabric for not needing bleaching, by the stabilizer of oxygen bleaching and
Hydrogen peroxide changes the yarn agent 1g/L-2.5g/L that deoils into, equally carries out above-mentioned boiling-off pre-treatment, and does not need at the deoxidation of deoxyenzyme
Reason；
B. step a is cooled down into 70 DEG C of heel row residul liquid-removings into the milk protein fiber of cylinder or its long filament or its blended fabric, then
Milk protein fiber in cylinder or its long filament or its blended fabric are added water to submerge according to bath raio, then, milk protein fiber is added
The special assistant 1g/L-5g/L of dyeing, operating add bleeding agent, dyestuff and promote dye salt and operate 8-10 minutes after 4-10 minutes
Prepare dyeing: wherein the special assistant of milk protein fiber dyeing is the response type dye by the production of Shanghai Ao Su Chemical Co., Ltd.
Expect that levelling agent, 85-92 parts, ethylene glycol amine, crosslinking agent made of 3-10 parts, hexamethylene diamine and epoxychloropropane condensation, are pressed by 5-10 parts
According to weight fraction ratio prepare after, by high-speed stirred, emulsification, uniformly mixing, with reach preservation it is not stratified until；
C. it will dye into the milk protein fiber of cylinder or its long filament or its blended fabric with the rate of warming of 1 DEG C/min-3 DEG C/min
40 DEG C -60 DEG C are raised to, keeps the temperature 5-15 minutes, 55 DEG C -85 DEG C is warming up to the speed that 1 DEG C/min-2 DEG C/min is heated, keeps the temperature 8-
12 minutes, then, soda ash is added and keeps the temperature the 30-60 minutes fixation carried out between dyestuff and fiber, further according to another component fibre
Performance carry out resisdye；
D. by after dyeing and the good fabric of fixation, 50 DEG C are cooled to hereinafter, being washed again；
E. it in, deep-colour fabric, needs to be washed with water, the method for place to go loose colour is: soaping agent 0.5g/L-3g/L is added, with 1
DEG C/speed of min-3 DEG C/min heating, it is warming up to 70 DEG C -90 DEG C, keeps the temperature 10-20 minute, be then cooled to 50 DEG C hereinafter, arranging
Liquid is washed again；
F. by the fabric after soaping or washing, acetic acid is added and adjusts pH value to 5-6.5, adds softening agent 1g/L-5g/L,
It is continuously heating to 40 DEG C of -60 DEG C of heat preservations progress soft finish in 10-30 minutes；
G. soft good milk protein fiber or its long filament or its blended fabric are cooled to room temperature, the cloth outputting out of cylinder is taken off
Water, drying；
H. the fabric after drying is padded into softening agent 2g/L-10g/L again, controls in 120 DEG C or less stentering formings, then carries out
The quality inspection of finished product, after product is qualified, finished product perching, clot and packaging.
2. the side of a kind of milk protein fiber according to claim 1 or its long filament or its blended fabric weaving and dyeing
Method, which is characterized in that the milk protein fiber or its long filament or its blended fabric are as follows: 100% milk protein long filament and ox
The yarn and fabric of milk proem staple fiber；Milk protein long filament and natural cotton, fiber crops, silk or regenerated celulose fibre viscose glue,
Long filaments or the staple fibers such as tencel, bamboo fibre, Modal, beautiful match and twist, combine, cored, cladding spinning, liner silk yarn with
All yarns and fabric that fabric or its reactive dye can dye；And the yarn of the loose stock dyeing of milk protein fiber
With fabric.
3. the side of a kind of milk protein fiber according to claim 1 or its long filament or its blended fabric weaving and dyeing
Method, which is characterized in that the hydrogen peroxide stabilizer is CAN, sodium metasilicate or common hydrogen peroxide bleaching stabilizer.
4. the side of a kind of milk protein fiber according to claim 1 or its long filament or its blended fabric weaving and dyeing
Method, which is characterized in that the bleeding agent is JET, JFC.
5. the side of a kind of milk protein fiber according to claim 5 or its long filament or its blended fabric weaving and dyeing
Method, which is characterized in that the reaction type dye levelling agent of the Shanghai Ao Su Chemical Co., Ltd. production is R-42.
6. the side of a kind of milk protein fiber according to claim 1 or its long filament or its blended fabric weaving and dyeing
Method, which is characterized in that the softening agent is that amido silicon oil and hydroxy silicon oil are formulated according to 7: 3 weight ratio.
7. the side of a kind of milk protein fiber according to claim 5 or its long filament or its blended fabric weaving and dyeing
Method, which is characterized in that crosslinking agent made of the hexamethylene diamine and epoxychloropropane condensation is EH-1.
8. the side of a kind of milk protein fiber according to claim 1 or its long filament or its blended fabric weaving and dyeing
Method, which is characterized in that the dyestuff is the reactive dye of common medium temperature or high temperature modification.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710955477.9A CN109667030A (en) | 2017-10-14 | 2017-10-14 | A kind of method of milk protein fiber or its long filament or its blended fabric weaving and dyeing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710955477.9A CN109667030A (en) | 2017-10-14 | 2017-10-14 | A kind of method of milk protein fiber or its long filament or its blended fabric weaving and dyeing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109667030A true CN109667030A (en) | 2019-04-23 |
Family
ID=66139012
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710955477.9A Pending CN109667030A (en) | 2017-10-14 | 2017-10-14 | A kind of method of milk protein fiber or its long filament or its blended fabric weaving and dyeing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109667030A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113604930A (en) * | 2021-06-15 | 2021-11-05 | 苏州苏雪纺织科技有限公司 | Preparation process of regenerated cellulose blended real silk jacquard fabric for home textiles |
-
2017
- 2017-10-14 CN CN201710955477.9A patent/CN109667030A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113604930A (en) * | 2021-06-15 | 2021-11-05 | 苏州苏雪纺织科技有限公司 | Preparation process of regenerated cellulose blended real silk jacquard fabric for home textiles |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1865559B (en) | Milk protein fiber or its filament or its blended fabric weaving and dyeing method | |
| CN100507129C (en) | Milk protein fiber or its filament or its blended yarn dyeing method and coloured woven fabric producing method | |
| CN101182665B (en) | Tussah silk and bamboo fibre blended colored cloth and processing method thereof | |
| CN103437103A (en) | Dyeing and finishing processing technology of polyester filament high-imitation cotton fabric | |
| CN104480757B (en) | A kind of cellulose fibre diacetate fibre interwoven fabric dyeing and finishing processing method | |
| JP7433332B2 (en) | Yarn-dyed cotton polyester fabric, its manufacturing method, and use | |
| CN106368014A (en) | Dyeing process for modal/cotton blended fabric | |
| CN103361866A (en) | Jutecell and coffee carbon fiber knitted fabric and manufacturing method thereof | |
| CN101956268B (en) | Production process of Christmas tree yarns | |
| CN101603235A (en) | Soybean fiber knitted terry and production technology thereof | |
| CN104358054B (en) | A kind of manufacture method of the washable knitting leader of not crimping | |
| CN109137565A (en) | A kind of acid dyes continuous pad dyeing method of polyamide fibre ribbon | |
| CN108442146A (en) | A kind of Modal washs peach face fibrillation dyeing | |
| CN106368019A (en) | Black cellulosic fiber dyeing method | |
| CN107558267A (en) | The dyeing and finishing method and textile product of textile material | |
| CN113897797A (en) | Ancient silk weaving process | |
| CN103382667A (en) | Dyeing method for blended and interwoven fabric of cotton fiber, linen fiber and wool fiber | |
| KR100988978B1 (en) | Process Of Dyeing For Wool/Polylacticacid-fiber Ply-yarn | |
| CN112981646A (en) | Method for manufacturing yak wool loop yarn | |
| CN109667030A (en) | A kind of method of milk protein fiber or its long filament or its blended fabric weaving and dyeing | |
| Chu et al. | The dyeing and printing of silk fabrics | |
| CN102704092B (en) | A kind of iridescent yarn and production method thereof | |
| CN109371533A (en) | Hair washs elastic force valitin and preparation method thereof | |
| CN107447355A (en) | A kind of production technology of super soft short-floss fabric | |
| CN106337304A (en) | Jeans fabric and dying method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190423 |