CN109666548A - A kind of clean hair soap comprising seaweed essence extract - Google Patents

A kind of clean hair soap comprising seaweed essence extract Download PDF

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Publication number
CN109666548A
CN109666548A CN201811285076.8A CN201811285076A CN109666548A CN 109666548 A CN109666548 A CN 109666548A CN 201811285076 A CN201811285076 A CN 201811285076A CN 109666548 A CN109666548 A CN 109666548A
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siloxanes
hair
soap
clean
present
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CN109666548B (en
Inventor
孙新红
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Guangdong Touyuan Biotechnology Co Ltd
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Guangdong Touyuan Biotechnology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/38Products in which the composition is not well defined
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/26Organic compounds, e.g. vitamins containing oxygen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/30Organic compounds, e.g. vitamins containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/36Organic compounds, e.g. vitamins containing silicon

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

The object of the present invention is to provide a kind of clean hair soaps suitable for most of crowds.The clean hair soap includes the components such as seaweed essence, can effectively remove the grease of hair or scalp surface secretion, scurf, dust etc., and can effectively improve the smoothness of hair, and have good conditioning functions, it is often more important that be suitable for the special populations such as pregnant woman.The clean hair soap of the present invention, comprising: A, account for the natural soap base of clean hair soap weight percent 50% to 70% of the invention;B, clean 10% to 15% siloxanes of hair soap weight percent of the present invention is accounted for;C, the hair conditioner of the clean hair soap weight percent 1% to 3% of the present invention, the seaweed essence extract of D, 5-10%, the deionized water of surplus are accounted for.The present invention contains the siloxanes of constant weight percentage, it is preferred that being added by two kinds of siloxanes with the ratio of weight ratio 3:2, and synergistic effect can be played in the clean hair soap of the present invention, the wet combing power and dry combing power of hair can be effectively reduced, the smooth performance of hair is improved.Component involved in the present invention can substantially be obtained from natural surroundings, safety and environmental protection, friendly and nontoxic to human body.

Description

A kind of clean hair soap comprising seaweed essence extract
Technical field
The invention belongs to daily chemicals fields, and in particular to a kind of clean hair soap of seaweed essence extract.
Background technique
Soap is just used to clean the personal hygienes such as body, skin field for a long time by the mankind, and many is also had ever done to this Improvement to significantly more efficient cleaning body and skin, but initial soap product be all with the saponification of animal and plant grease and Come.Clean hair soap is the extension of soap product.
Seaweed is rich in 60 kinds or more of microelement, the nutritional ingredients such as 12 kinds or more minerals, amino acid.Reach in the daytime Lasting to nourish, night strengthens intensive penetration, allows healthy hair while night metabolism and maintenance, and quickly go directly cell interior, depth Damaged hair is repaired, is reappeared perfect newborn.Seaweed can adsorb the grease in hair follicle, and sebum is thoroughly cleaned from hair follicle depths.Sea Alginic acid in algae, which is received, has certain protective effect to damage caused by ultraviolet light irradiation, and the methionine, cystine in seaweed contain Amount is abundant, can prevent dry scalp, can also make dry scalp rich in gloss, oiliness scalp can improve fat secretion.Institute in seaweed It is abundant containing vitamin, it can safeguard epithelial tissue healthy growth, be capable of the fat secretion of anti-inflammation and sterilization and adjusting skin, it is dark to treating Sore has extraordinary curative effect, and seaweed has effects that potent moisturizing, required moisture can be replenished in time for the scalp of water shortage, allow Dry scalp slowly become neutral scalp.To nursing because of hair damage excellent caused by having hair dyed, drying.
Over time, people in the continuous technology for improving hair washing for example, using non-saponified active material or Person mediates into surface active process such as, anionic surfactant, cationic surfactant, nonionic surfactant, and two Property surfactant etc. so that 21 amending shampoo technical formulas of conjunction of the invention later eighties develop always and are in use to the present It.However above-mentioned blocky soaps cleaning supplies are used for always the cleaning of the personal cleanliness such as skin and body of people, it is rarely found Cleaning to block-like fat soap for hair or scalp does not have the function of hair conditioning hair washing having yet.In addition, existing It is just more rare in the clean hair soap for being suitable for hair impaired, so that the problem of it becomes urgent need to resolve.
Summary of the invention
The object of the present invention is to provide a kind of clean hair soaps suitable for most of crowds.The clean hair soap includes the groups such as seaweed essence Point, the grease of hair or scalp surface secretion, scurf, dust etc. can be effectively removed, and the smoothness of hair can be effectively improved, And there are good conditioning functions, it is often more important that be suitable for hair and be damaged equal special populations.
Component involved in the present invention can substantially be obtained from natural surroundings, safety and environmental protection, and nothing friendly to human body Poison is harmless.
The technical scheme of the present invention is realized as follows: a kind of clean hair soap comprising seaweed essence extract, contains:
A, the natural soap base of clean hair soap weight percent 50% to 70% of the invention is accounted for;
B, 5% to 25% siloxanes, by (a) siloxanes A and (b), siloxanes (B) forms the siloxanes, siloxanes A and silicon Oxygen alkane B is shown in lower formula (I), and siloxanes A is different with siloxanes B;
Wherein, R1For methyl, R2For hydroxyl, R3For-(CH2)3N+(CH3) Cl-Or-(CH2)12COOCH3, the sum of m and n are 5000- 50000, and m/n > 500, m and n are not 0;
C, 1% to 3% hair conditioner, the conditioner is by (c) cocoyl sarcosine sodium and (d) ricinoleic acid cetyl Ester composition;
D, the seaweed essence extract of 5-10%;
E, the deionized water of surplus.
In the clean hair soap of the present invention, the R of siloxanes (A) in the siloxanes3For-(CH2)3N+(CH3) Cl-, siloxanes (B) R3For-(CH2)12COOCH3, the weight ratio of siloxanes (A) and siloxanes (B) are 3:2.
In the clean hair soap of the present invention, (c) cocoyl sarcosine sodium and (d) weight ratio of ricinoleic acid cetyl ester For 3:2.
In the clean hair soap of the present invention, B is preferably 15% silicone components;C is preferably the hair conditioner component of 1.5-2%.
The clean hair soap of the present invention, is grouped as by following groups:
A, 60% to 70% natural soap base;
B, 15% siloxanes, by (a) siloxanes A and (b), siloxanes (B) forms the siloxanes, siloxanes A and siloxanes B It is shown in lower formula (I), siloxanes A is different with siloxanes B,
Wherein, R1For methyl, R2For hydroxyl, R3For-(CH2)3N+(CH3) Cl-Or-(CH2)12COOCH3, the sum of m and n are 5000- 50000, and m/n > 500, m and n are not 0;The R of siloxanes (A)3For-(CH2)3N+(CH3) Cl-, the R of siloxanes (B)3For- (CH2)12COOCH3, the weight ratio of siloxanes (A) and siloxanes (B) are 3:2
C, 2% to 3% hair conditioner, the conditioner is by (c) cocoyl sarcosine sodium and (d) ricinoleic acid cetyl Ester composition, (c) cocoyl sarcosine sodium and (d) weight ratio of ricinoleic acid cetyl ester be 1:2;
D, the seaweed essence extract of 5-10%;
E, the deionized water of surplus.
Beneficial effects of the present invention:
1, the siloxanes of the invention containing constant weight percentage is preferably added by two kinds of siloxanes with the ratio of weight ratio 3:2, And synergistic effect can be played in the clean hair soap of the present invention, the wet combing power and dry combing power of hair can be effectively reduced, is improved The smooth performance of hair.
2, the present invention contains (c) cocoyl sarcosine sodium and (d) two kinds of hair conditioners of ricinoleic acid cetyl ester The hair for enhancing the clean hair soap of the present invention to a certain extent is dry, wet cardability.
3, the clean hair soap of the present invention not only may be used as cleaning hair and scalp but also can be used to daily skin and clean body, with The shampoo etc. of liquid is compared, and the clean hair soap of solid-like uses stronger to the control ability of amount, it is not easy to it is excessive to generate dosage Generate waste.
Specific embodiment
Below with reference to embodiment, the present invention is described in further detail.
A kind of clean hair soap comprising seaweed essence extract of the present invention can be used to clean hair and scalp, skin and body Body.Natural soap base is that the mixture of fatty acid salt such as utilizes animal and plant grease to be saponified acquisition by base, and base can adopt With sodium hydroxide or potassium hydroxide or alkanolamine such as ethanol amine etc., the natural soap base of the present invention uses the coconut oil of saponification for original Material.
The present invention synthesizes soap base and can be used in compounding with natural soap base, and the suitable soap base that synthesizes is usually a kind of anionic Or a kind of non-ionic synthesis of detergent surfactant.The synthesis soap base being adapted to natural soap base of the invention can be anion Type such as, alkylbenzene sulfonate, alkyl sulfate, alkylbenzene polyoxyethylene sulfonic acid salt, cocounut oil monoglyceride sulfuric acid, fatty alcohol Ether sulfate, alkyl acid esters disodium, cocoyl glucoside sulfosuccinate disodium, isethionate etc., the present invention Synthesis of detergent soap base may be nonionic surface active agent such as polyoxyethylene sorbitan fatty acid ester (tween) etc..
The present composition can only include genuine soap base, may include natural soap base and synthetic surfactant (synthesis soap Base), natural soap base has the 50-70% of Zhan Jiefa soap altogether with synthesis soap base, preferred to the formed solid for improving the clean hair soap of the present invention Performance, synthesis soap base account for the clean hair soap weight percent of the present invention and are less than or equal to 30%.
Other than natural soap base, the present invention also includes siloxanes, such as accounts for weight percent 10% to 15%, is advanced optimized It is 15%
(a) siloxanes A and (b) siloxanes (B) forms, siloxanes A and siloxanes B be shown in lower formula (I), siloxanes A and Siloxanes B is different,
Wherein, R1For methyl, R2For hydroxyl, R3For-(CH2)3N+(CH3) Cl-Or-(CH2)12COOCH3, the sum of m and n are 5000- 50000, and m/n > 500, m and n are not 0;The R of siloxanes (A)3For-(CH2)3N+(CH3) Cl-, the R of siloxanes (B)3For- (CH2)12COOCH3, the weight ratio of siloxanes (A) and siloxanes (B) are 3:2.
Above-mentioned (a) component and (b) component weight ratio are 3:2, can play synergy, moreover it is possible to play and help bubble and conditioning skin With the effect of hair, the cardability of hair is improved.
Natural soap base: the natural soap base of the present invention derives from the product of coconut oil saponification, preferably natural coconut oil soap base.It Right soap base content is not less than natural soap base and the 50% of synthesis soap base total amount.
Synthesis of detergent soap base (synthetic surfactant): synthesis of detergent soap base of the present invention is anionic synthetic surface activity Agent such as, laruyl alcohol sulfosuccinate disodium or laureth sulfosuccinate disodium.The present invention synthesizes soap base Nonionic surfactant such as coconut monoethanol amide, coconut monoethanol amide play thickening and foam stabilizing and reduction in the present invention The effect of soap base stimulation.
Hair conditioner: the clean hair soap composition of the present invention also includes a kind of hair conditioner, the hair being suitble in the present invention Conditioner cannot have an adverse effect to the demoulding of clean hair soap, can not use and generate accumulation effect to hair and scalp. The hair conditioner of the invention ricinoleic acid cetyl ester for (c) cocoyl sarcosine sodium and (d), when its ratio be 1:2 When the effect that obtains it is more excellent.
The clean hair soap production method of solid-state of the present invention:
1, natural soap base is heated with warm fire, and is separately added into suitable water, siloxanes (A) and siloxanes (B) stir evenly;
2, by (c) cocoyl sarcosine sodium and (d) ricinoleic acid cetyl ester and seaweed essence extract and suitable Water is added in 1, continues stirring until dispersing and dissolving;
3, above 2 are rolled through equipment, press strip, cooling, demoulding is packed until finished product.
The synthesis soap base wherein used is laruyl alcohol sulfosuccinate disodium, if necessary to which synthesis soap base is added, with day Right soap base is added in step 1 simultaneously.
1 embodiment 1-7 dosage of each component of table
Component (unit: weight %) Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7
Natural soap base 70 70 70 70 70 70 70
Synthesize soap base 0 0 0 0 0 0 0
Siloxanes (A) 12 15 0 7.5 9 6 3
Siloxanes (B) 3 0 15 7.5 6 9 12
Cocoyl sarcosine sodium 1 1 1 1 1 1 1
Ricinoleic acid cetyl ester 2 2 2 2 2 2 2
Seaweed essence extract 10 10 10 10 10 10 10
Water 2 2 2 2 2 2 2
2 embodiment 8-14 dosage of each component of table
Component (unit: weight %) Embodiment 8 Embodiment 9 Embodiment 10 Embodiment 11 Embodiment 12 Embodiment 13 Embodiment 14
Natural soap base 70 70 70 70 60 40 30
Synthesize soap base 0 0 0 0 10 30 40
Siloxanes (A) 6 9 9 9 9 9 9
Siloxanes (B) 4 6 6 6 6 6 6
Cocoyl sarcosine sodium 1 2 3 0 1 1 1
Ricinoleic acid cetyl ester 2 1 0 3 2 2 2
Seaweed essence extract 10 10 10 10 10 10 10
Water 7 2 2 2 2 2 2
Experiment shows under above embodiments 1-13 room temperature to be solid forms, but 14 mouldability of embodiment is bad.
The application method of the clean hair soap of the present invention:
1, first drench hair with clear water, then hold clean hair soap, water is added to crumple out foam;
2, the scalp and hair or body after being drenched with both hands massage are until there is abundant foam;
3, the movement that can repeat above 1 and 2 if necessary, is finally cleaned with clear water.
Efficacy assessments:
Instrument test
As liquid shampoo, the cardability test includes dry cardability, the test of wet cardability, the wet cardability test It is: first soaks hair, is rubbed with about 2g embodiment 1-14 (the pure coconut oil soap base of blank sample) and washed 2-3min, then used Flowing water is rinsed well, is combed with comb once to remove extra moisture, is surveyed on 2343 miniature spring tester of Instron Fixed wet cardability, rate of extension 300mm/min;It repeats the above steps, every a sample measures 6 times, each embodiment the 6th time punching Measurement result after washing is listed in table 1.
The dry cardability test is: hair sample is placed on air drying after the completion of wet cardability test, it is dry to it Its dry cardability is measured after dry.
The numerical value of dry and wet combing power is smaller to show that product is more preferable to the smoothness of hair.
Sensory evaluation
Referring to the application method of the clean hair soap of the present invention, 100 testers are selected, wherein using the test sample period 1 time, test Person according to oneself feel score, the feeling that is related to of scoring includes hair washing effect and cleaning effect, and standards of grading use 10 Divide system, 1 point worst, and 10 points best.Mathematic(al) mean is carried out to the marking of tester and obtains whole scoring.
The test result of each embodiment is listed in table 3.
The clean hair soap test result of 3 embodiment 1-14 of table
Evaluation index Wet combing power (J) Dry combing power (J) Average Sensory's evaluation
Blank 0.698 0.059 2.64
Embodiment 1 0.332 0.036 4.68
Embodiment 2 0.465 0.045 3.57
Embodiment 3 0.465 0.046 3.78
Embodiment 4 0.223 0.025 7.09
Embodiment 5 0.158 0.017 8.63
Embodiment 6 0.256 0.029 6.76
Embodiment 7 0.312 0.032 4.86
Embodiment 8 0.224 0.024 7.26
Embodiment 9 0.189 0.020 7.66
Embodiment 10 0.264 0.026 6.55
Embodiment 11 0.278 0.027 6.39
Embodiment 12 0.178 0.018 8.32
Embodiment 13 0.175 0.018 8.38
Embodiment 14 0.202 0.021 7.98
The above test result table 1 is it can be seen that by comparing embodiment 2-3 and 1,4-7, only wherein comprising siloxanes (A) or (B) One of embodiment 2,3 combing powers and sensory evaluation effect be not so good as above-described embodiment 1,4-7, illustrate that siloxanes (A) and (B) are combined It is more preferable relative to single siloxanes (A) or (B) effect, it include the clean hair soap product of siloxanes (A) and (B), embodiment 1,4-7 All show relatively good dry and wet combing power test result and Analyses Methods for Sensory Evaluation Results, wet combing power no more than 0.332J, For dry combing power no more than 0.036J, sensory evaluation is 4 points or more, by selecting siloxanes (A) and (B) ratio, Embodiment 1,4-7 implement siloxanes (A)/siloxanes (B)=4/1 respectively, and 1/1,3/2,2/3,1/4, by comparing, in silicon oxygen The effect obtained when alkane (A)/siloxanes (B)=3/2 is best, including wet combing power 0.158J, dry combing power 0.017J, and sense organ is commented Divide 8.63, hence it is evident that better than the effect of other ratios, illustrate that the synergy of two kinds of siloxanes under the ratio is more excellent.Determining silicon oxygen After alkane (A)/siloxanes (B)=3/2, the influence of siloxanes total amount and hair conditioner and soap base type to effect has been investigated, Embodiment 8 illustrates that the smoothness of hair can be improved in siloxanes total amount between 10-15%, and hair conditioner selects (c) cocounut oil acyl Two kinds of combined effects of sodium sarcosinate and (d) ricinoleic acid cetyl ester are more preferable, are preferably in a proportion of 1:2;In addition, if natural 50% of soap base content lower than natural soap base and synthesis soap base total amount may cause mouldability variation, and effect is best still only to adopt With natural soap base.

Claims (7)

1. a kind of clean hair soap comprising seaweed essence extract, comprising:
A, 50% to 70% natural soap base and/or synthesis soap base;
B, 10% to 15% siloxanes, by (a) siloxanes A and (b), siloxanes (B) forms the siloxanes, siloxanes A and silicon Oxygen alkane B is shown in lower formula (I), and siloxanes A is different with siloxanes B,
Wherein, R1For methyl, R2For hydroxyl, R3For-(CH2)3N+(CH3) Cl-Or-(CH2)12COOCH3, the sum of m and n are 5000- 50000, and m/n > 500, m and n are not 0;
C, 1% to 3% hair conditioner, the conditioner is by (c) cocoyl sarcosine sodium and (d) ricinoleic acid cetyl Ester composition;
D, the seaweed essence extract of 5-10%;
E, the deionized water of surplus.
2. clean hair soap according to claim 1, the R of siloxanes (A) in the siloxanes3For-(CH2)3N+(CH3) Cl-, silicon The R of oxygen alkane (B)3For-(CH2)12COOCH3, the weight ratio of siloxanes (A) and siloxanes (B) are 3:2.
3. clean hair soap according to claim 1, wherein (c) cocoyl sarcosine sodium and (d) ricinoleic acid cetyl The weight ratio of ester is 1:2.
4. clean hair soap according to claim 1, B are preferably 15% silicone components.
5. clean hair soap according to claim 1, C is preferably the hair conditioner component of 2-3%.
6. clean hair soap according to claim 1, natural soap base content is not less than natural soap base and synthesizes soap base total amount 50%。
7. clean hair soap described in -6 according to claim 1, is grouped as by following groups:
A, 60% to 70% natural soap base and/or synthesis soap base;
B, 15% or so siloxanes, by (a) siloxanes A and (b), siloxanes (B) forms the siloxanes, siloxanes A and silicon oxygen Alkane B is shown in lower formula (I), and siloxanes A is different with siloxanes B,
Wherein, R1For methyl, R2For hydroxyl, R3For-(CH2)3N+(CH3) Cl-Or-(CH2)12COOCH3, the sum of m and n are 5000- 50000, and m/n > 500, m and n are not 0;The R of siloxanes (A)3For-(CH2)3N+(CH3) Cl-, the R of siloxanes (B)3For- (CH2)12COOCH3, the weight ratio of siloxanes (A) and siloxanes (B) are 3:2
C, 2% to 3% hair conditioner, the conditioner is by (c) cocoyl sarcosine sodium and (d) ricinoleic acid cetyl Ester composition, (c) cocoyl sarcosine sodium and (d) weight ratio of ricinoleic acid cetyl ester be 1:2;
D, the seaweed essence extract of 5-10%;
E, the deionized water of surplus.
CN201811285076.8A 2018-10-31 2018-10-31 Hair soap containing seaweed essence extract Active CN109666548B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1116234A (en) * 1995-05-30 1996-02-07 成进学 Shampoo of hair washing and conditioning containing snake fat, tissue or its extract
CN107603789A (en) * 2017-09-01 2018-01-19 拉芳家化股份有限公司 A kind of conditioning-type solid-state hair soap
CN108096173A (en) * 2017-12-28 2018-06-01 广州蜜妆生物科技有限公司 Mild amino acid shampoo of a kind of green and preparation method thereof
CN108294998A (en) * 2018-04-12 2018-07-20 广东医科大学 Anticreep shampoo and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1116234A (en) * 1995-05-30 1996-02-07 成进学 Shampoo of hair washing and conditioning containing snake fat, tissue or its extract
CN107603789A (en) * 2017-09-01 2018-01-19 拉芳家化股份有限公司 A kind of conditioning-type solid-state hair soap
CN108096173A (en) * 2017-12-28 2018-06-01 广州蜜妆生物科技有限公司 Mild amino acid shampoo of a kind of green and preparation method thereof
CN108294998A (en) * 2018-04-12 2018-07-20 广东医科大学 Anticreep shampoo and preparation method thereof

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