CN109653719A - A method of fine and close viscous crude fracturing effect is improved using microorganism in situ - Google Patents

A method of fine and close viscous crude fracturing effect is improved using microorganism in situ Download PDF

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Publication number
CN109653719A
CN109653719A CN201811541088.2A CN201811541088A CN109653719A CN 109653719 A CN109653719 A CN 109653719A CN 201811541088 A CN201811541088 A CN 201811541088A CN 109653719 A CN109653719 A CN 109653719A
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microorganism
crude
situ
fracturing
fluid
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CN109653719B (en
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周福建
左洁
姚二冬
梁星原
梁天博
李奔
曲鸿雁
李福远
刘雄飞
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China Petrochemical Engineering Research Center Ltd By Share Ltd
China University of Petroleum Beijing
Petrochina Co Ltd
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China Petrochemical Engineering Research Center Ltd By Share Ltd
China University of Petroleum Beijing
Petrochina Co Ltd
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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/25Methods for stimulating production
    • E21B43/26Methods for stimulating production by forming crevices or fractures
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/58Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
    • C09K8/582Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of bacteria

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mining & Mineral Resources (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Fluid Mechanics (AREA)
  • Physics & Mathematics (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Environmental & Geological Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Measuring Or Testing Involving Enzymes Or Micro-Organisms (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

The present invention provides a kind of methods for improving fine and close viscous crude fracturing effect using microorganism in situ.This method comprises the following steps: selecting oil reservoir experiment block, the type of sample detection original position microorganism and picks out the microorganism in situ that can reduce viscosity of crude and interfacial tension from the production fluid of Lin Jing;Configure the fracturing fluid that microorganism in situ can be made to grow and breed under ground environment;It waits for being pumped into fracturing fluid in fractured well to fine and close heavy crude reservoir and carries out pressing crack construction and bored well;Drain and production fluid and Optimum Fracturing liquid are returned in the row's of returning production, monitoring.The present invention reduces oil water interfacial tension and viscosity of crude using microorganism in situ, improve viscous crude mobility, in its fracturing fluid ingredient prepared nutrient solution is cheap, source is wide, environment is not injured, easy to operate using method of the invention, experiment effect is good, it is with strong points, it can be improved crude output, recovery ratio averagely improves 14% or more, can be widely applied in fine and close heavy crude reservoir fracturing reform.

Description

A method of fine and close viscous crude fracturing effect is improved using microorganism in situ
Technical field
It is the invention belongs to Microbial Enhanced Oil Recovery field, in particular to a kind of to improve fine and close viscous crude pressure using microorganism in situ Split the method for effect.
Background technique
Fine and close heavy crude reservoir recoverable reserves is abundant, but since fine and close heavy crude reservoir hole infiltration is lower, it usually needs hydraulic fracturing Technology forms fracture network, provides flow channel for crude oil, horizontal well fracturing has become the main of compact oil reservoir at present Recovery method.Fine and close heavy crude reservoir viscosity is larger, even if fracture network is formed by hydraulic fracturing, due to the original of viscosity resistance The fluid ability of cause, crude oil is also restrained, influences ultimate recovery.
Microbe oil production refers to the comprehensive function by microorganism itself and its metabolite and reservoir fluid, rock, drop Low oil water interfacial tension improves crude oil fluidity, to realize the purpose for improving crude output.Microbe oil production is in routine Huge effect is played in oil reservoir, is had a extensive future.But it not yet seeps in lower fine and close heavy crude reservoir and applies in hole.
Summary of the invention
Based on defect of the existing technology, densification is improved using microorganism in situ the purpose of the present invention is to provide a kind of The method of viscous crude fracturing effect, this method is easy to operate, with strong points, can effectively improve fine and close recovery factor of heavy oil reservoir.
The purpose of the present invention is achieved by the following technical programs:
On the one hand, the present invention provides a kind of method for improving fine and close viscous crude fracturing effect using microorganism in situ, including with Lower step:
Step 1 selects oil reservoir experiment block, and the type of sample detection original position microorganism is simultaneously from the production fluid of Lin Jing Pick out the microorganism in situ that can reduce viscosity of crude and interfacial tension;
Step 2 configures the fracturing fluid that microorganism in situ can be made to grow and breed under ground environment;
Step 3, Xiang Zhimi heavy crude reservoir wait for being pumped into fracturing fluid in fractured well and carry out pressing crack construction and bored well;
Drain and production fluid and Optimum Fracturing liquid are returned in step 4, the row's of returning production, monitoring.
In above-mentioned method, it is preferable that in step 1, the oil reservoir for selecting oil reservoir experiment block meets following condition:
It preserves and is covering pressure matrix permeability less than 0.1 × 10-3μm2Tight sand and/or dense carbonate reservoir In, the oil accumulation formed without extensive long-distance migration (nearly source aggregation), and the relative density of crude oil is in 20 DEG C of items It is greater than 0.92 under part, underground viscosity is greater than the oil reservoir of 50MPa.s.
In above-mentioned method, it is preferable that in step 1, the sample detection original position microorganism from the production fluid of Lin Jing Type simultaneously picks out the microorganism in situ that can reduce viscosity of crude and interfacial tension method particularly includes:
The Lin Jing flatly to fractured well is chosen, and the production layer position of the well is identical as target well, samples from production fluid, It is intact to prevent from polluting, using microbial rapid detection instrument, detect the type of the microorganism contained in fluid;
Reducing crude oil viscosity test and interfacial tension test are carried out to the various microorganisms in situ sampled in production fluid, choose energy Enough reduce the microorganism of viscosity of crude and interfacial tension, selection standard are as follows: it is required that viscosity of crude can be reduced to by microorganism 10MPas is hereinafter, oil water interfacial tension can reduce 0.1mN/m or less.
In above-mentioned method, it is preferable that selection can reduce viscosity of crude and the microorganism in situ of interfacial tension includes Aerobic microbiological, anaerobe and aerobic-anaerobic microbe.
In above-mentioned method, it is preferable that the original position microorganism includes clostridium, sulfate reducing bacteria, pole One of bacterium, enterobacteria, pseudomonas putida, green Agrobacterium, hare corynebacteria, mycobacteria and mycobacterium vaccae or It is a variety of.These microorganisms can be obtained by identifying species and screening and by culture breeding, can also pass through commercially available acquisition.
In above-mentioned method, it is preferable that the fracturing fluid is the vitamin for being added to 0.3%-0.5% in guanidine gum fracturing fluid With the fracturing fluid of the microelement of 0.08%-0.1%;
It further include the oxygen that 1mg/L is added into the fracturing fluid when containing aerobic microbiological in the microorganism in situ Gas.
In above-mentioned method, it is preferable that the formula of the guanidine gum fracturing fluid includes guanidine glue, the 0.1%- of 0.4%-0.5% 0.15% drag reducer, the demulsifier of 0.4%-0.5%, the gel breaker of 0.2%-0.3%, 0.2% row drive agent and surplus Water.In the formula of the guanidine gum fracturing fluid, drag reducer, demulsifier, gel breaker, row's drive agent etc. are this field conventional additives, This formula guanidine gum fracturing fluid can be used equally for by commercially available acquisition.Drag reducer rubs for reducing fracturing fluid and pit shaft and stratum Resistance;Demulsifier is emulsified for preventing fracturing fluid from entering reservoir with crude oil;Gel breaker accelerates fracturing liquid rubber-breaking;Row drives agent and helps Go out stratum in fracturing fluid recovery (backflow).
In above-mentioned method, it is preferable that the vitamin may include in vitamin B2, vitamin B12 and vitamin beta etc. One or more combinations.
In above-mentioned method, it is preferable that the microelement may include one of sulphur, nitrogen, phosphorus and potassium etc. or a variety of Combination.
In above-mentioned method, the fracturing fluid configured not only has the function of conventional fracturing fluid, including prop-carrying capacity is strong, rubs Hinder low, stability is good and compatibility is good etc., and microorganism in situ can also be promoted to grow and breeding, meet environmental requirement.
In above-mentioned method, it is preferable that the pressing crack construction includes first fracturing reform and refracturing transformation.
In above-mentioned method, it is preferable that the bored well period is 1 day to 4 months.
In above-mentioned method, it is preferable that the specific steps of the step 4 are as follows:
The row's of returning production is carried out after bored well, collects the sample of production fluid, records target well yield increasing degree, prison Microorganism growth and breeding situation in drain are returned in survey, are further accumulated experience for Optimum Fracturing formula of liquid.
In above-mentioned method, it is preferable that influence of the monitoring fracturing fluid to the growth and breeding of microorganism is needed in strata pressure It is carried out at a temperature of.
Beneficial effects of the present invention:
The present invention reduces oil water interfacial tension and viscosity of crude using microorganism in situ, improves viscous crude mobility, prepares Fracturing fluid ingredient in nutrient solution is cheap, source is wide, do not injure environment, it is easy to operate using method of the invention, it is real It is good to test effect, it is with strong points, it can be improved crude output, oil recovery factor averagely improves 14% or more, can be widely applied to cause In close heavy crude reservoir fracturing reform, to improve fine and close heavy crude reservoir yield.
Specific embodiment
In order to which technical characteristic of the invention, purpose and beneficial effect are more clearly understood, now to skill of the invention Art scheme carries out described further below, but should not be understood as that limiting the scope of the invention.
Embodiment 1
The present embodiment provides a kind of methods for improving fine and close viscous crude fracturing effect using microorganism in situ, including following step It is rapid:
Step 1 selects oil reservoir experiment block, and the oil reservoir experiment block selected is certain domestic fine and close heavy crude reservoir, reservoir Depth 2300m-3200m, strata pressure 28MPa, 86 DEG C of formation temperature, porosity 11%, in-place permeability 0.1mD, crude oil is viscous 60mpa.s is spent, carries out simulated experiment after block Lin Jing obtains underground rock core and production fluid;
It is sampled from the production fluid of Lin Jing and the type of microorganism in situ is detected by microbial rapid detection instrument and is chosen Select the microorganism in situ that can reduce viscosity of crude and interfacial tension;It is required that microorganism can be by viscosity of crude from 60MPa.s It is reduced to 10MPa.s or less, it is desirable that oil water interfacial tension can be reduced to 0.1mN/m or less from 24mN/m.The present embodiment detection To microbe species include following several: clostruidium, sulfate reducing bacteria, arthrobacterium, enterobacteria.
Step 2 configures the fracturing fluid that microorganism in situ can be made to grow and breed under ground environment;The present embodiment is matched The fracturing fluid set is different from conventional guanidine gum fracturing fluid, in addition to conventional guanidine gum fracturing fluid need 0.4% guanidine glue to be added, 0.1% subtract Resist, 0.5% demulsifier, 0.2% gel breaker, 0.2% row drive agent, are furthermore also added into 0.5% vitamin solution (vitamin B2, vitamin B12, vitamin beta are added by 1:1:1) and 0.1% trace element solution (including the required nitrogen of microorganism growth, Phosphorus, potassium element are added by 2:1:1) it is used to that microorganism in situ is helped to grow.
Step 3 simulates pressing crack construction, is pumped into the fracturing fluid of above-mentioned configuration, and bored well;
After the filtering of fracturing liquid rubber-breaking liquid, it is packed into intermediate receptacle, intact underground rock core is saturated crude oil, on stratum Test original permeability is just being driven using crude oil under the conditions of temperature, is then using termination of pumping after the fracturing fluid reverse displacement 0.3PV of configuration, Simulate pressure break and bored well 7 days.
Drain and production fluid and Optimum Fracturing liquid are returned in step 4, the row's of returning production, monitoring;
It after bored well, is just being driven using crude oil, is simulating the row's of returning production, stopping experiment after rate to be infiltrated is constant, using same batch Secondary rock core compares experiment using conventional fracturing fluid, comparing result shows permeability wound under same experimental conditions and step Evil value reduces 10.5%, improves recovery ratio 16%.
Embodiment 2
The present embodiment provides a kind of methods for improving fine and close viscous crude fracturing effect using microorganism in situ, including following step It is rapid:
Step 1 selects oil reservoir experiment block, and it is fine and close thick that the oil reservoir experiment block selected, which is certain domestic oil field B block, Oil reservoir, depth of reservoirs 3200m~4500m, strata pressure 35MPa, 90 DEG C of formation temperature, porosity 10%, in-place permeability 0.05mD, viscosity of crude 55mpa.s carry out simulated experiment after block Lin Jing obtains underground rock core and production fluid;
The Lin Jing flatly to fractured well is chosen, and the production layer position of the well is identical as target well, well spacing 500m, is flowed from production It is sampled in body, it is intact to prevent pollution-free, to contain in microbial rapid detection instrument detection fluid microbe species.It will production The various microorganisms in situ of fluid carry out reducing crude oil viscosities test and interfacial tension test, it is desirable that microorganism can by viscosity of crude from 55mpa.s is reduced to 8mpa.s or less, it is desirable that oil water interfacial tension can be reduced to 0.1mN/m from 24mN/m hereinafter, obtaining energy The microorganism of viscosity of crude and interfacial tension is enough reduced, the microbe species that the present embodiment detects include following several: stench Pseudomonad, green Agrobacterium, hare corynebacteria, mycobacteria, mycobacterium vaccae.
Step 2 configures the fracturing fluid that microorganism in situ can be made to grow and breed under ground environment;The present embodiment is matched The fracturing fluid set is different from conventional guanidine gum fracturing fluid, in addition to conventional guanidine gum fracturing fluid need 0.5% guanidine glue to be added, 0.15% subtract Resist, 0.4% demulsifier, 0.3% gel breaker, 0.2% row drive agent, are furthermore also added into 0.3% vitamin solution (vitamin B2, vitamin B12, vitamin beta are added by 2:1:1) and 0.08% trace element solution it is (required including microorganism growth Sulphur, nitrogen, phosphorus, potassium element are added by 1:1:1:1) it is used to that microorganism in situ is helped to grow, due to having detected part aerobic bacteria, Therefore the oxygen of 1mg/L need to be added.
Step 3, pressing crack construction are pumped into the fracturing fluid of above-mentioned configuration, and bored well;
Fracturing reform construction, and bored well 20 days are carried out containing nutritious fracturing fluid using above-mentioned preparation, to promote Microorganism can growth and breeding, reduce interfacial tension, improve crude oil fluidity.
Drain and production fluid and Optimum Fracturing liquid are returned in step 4, the row's of returning production, monitoring;
The row's of returning production is carried out after bored well, collects the sample for returning drain and producing liquid, carries out yield data with Lin Jing Comparison, daily output amplification 14%.
In conclusion the present invention reduces oil water interfacial tension and viscosity of crude using microorganism in situ, viscous crude flowing is improved Property, the nutrient solution in fracturing fluid ingredient prepared is cheap, source is wide, does not injure environment, is grasped using method of the invention To make simply, experiment effect is good, and it is with strong points, it can be improved crude output, oil recovery factor averagely improves 15%, can be widely applied In fine and close heavy crude reservoir fracturing reform, to improve fine and close heavy crude reservoir yield.
Embodiment described above is merely to illustrate technical idea and feature of the invention, in the art its object is to make Technical staff it will be appreciated that the contents of the present invention and implement accordingly, patent of the invention only cannot be limited with the present embodiment It encloses, i.e., same changes or modifications made by all disclosed spirit are still fallen in the scope of the patents of the invention.

Claims (10)

1. a kind of method for improving fine and close viscous crude fracturing effect using microorganism in situ, which comprises the following steps:
Step 1 is selected oil reservoir experiment block, the type of sample detection original position microorganism and is selected from the production fluid of Lin Jing It can reduce the microorganism in situ of viscosity of crude and interfacial tension out;
Step 2 configures the fracturing fluid that microorganism in situ can be made to grow and breed under ground environment;
Step 3, Xiang Zhimi heavy crude reservoir wait for being pumped into fracturing fluid in fractured well and carry out pressing crack construction and bored well;
Drain and production fluid and Optimum Fracturing liquid are returned in step 4, the row's of returning production, monitoring.
2. the method according to claim 1, wherein the oil reservoir for selecting oil reservoir experiment block is full in step 1 The following condition of foot:
It preserves and is covering pressure matrix permeability less than 0.1 × 10-3μm2Tight sand and/or dense carbonate reservoir in, not The oil accumulation formed by extensive long-distance migration, and the relative density of crude oil is greater than 0.92 at 20 °C, ground Lower viscosity is greater than the oil reservoir of 50MPa.s.
3. the method according to claim 1, wherein sampling inspection from the production fluid of Lin Jing in step 1 It surveys the type of microorganism in situ and picks out the microorganism in situ that can reduce viscosity of crude and interfacial tension method particularly includes:
The Lin Jing flatly to fractured well is chosen, and the production layer position of the well is identical as target well, samples from production fluid, saved It is intact to prevent from polluting, using microbial rapid detection instrument, detect the type of the microorganism contained in fluid;
Reducing crude oil viscosity test and interfacial tension test are carried out to the various microorganisms in situ sampled in production fluid, selection can drop The microorganism of low viscosity of crude and interfacial tension, selection standard are as follows: it is required that viscosity of crude can be reduced to 10MPa by microorganism S is hereinafter, oil water interfacial tension can reduce 0.1mN/m or less.
4. according to the method described in claim 3, it is characterized by: the original that can reduce viscosity of crude and interfacial tension chosen Microorganism includes aerobic microbiological, anaerobe and aerobic-anaerobic microbe for position;
Preferably, the microorganism in situ includes clostridium, sulfate reducing bacteria, arthrobacterium, enterobacteria, the false list of stench One of born of the same parents bacterium, green Agrobacterium, hare corynebacteria, mycobacteria and mycobacterium vaccae are a variety of.
5. according to the method described in claim 1, it is characterized by: the fracturing fluid is to be added to 0.3%- in guanidine gum fracturing fluid The fracturing fluid of the microelement of 0.5% vitamin and 0.08%-0.1%;
It further include the oxygen that 1mg/L is added into the fracturing fluid when containing aerobic microbiological in the microorganism in situ.
6. according to the method described in claim 5, it is characterized by: the formula of the guanidine gum fracturing fluid includes 0.4%-0.5% Guanidine glue, the drag reducer of 0.1%-0.15%, the demulsifier of 0.4%-0.5%, the gel breaker of 0.2%-0.3%, 0.2% row Drive the water of agent and surplus.
7. according to the method described in claim 5, it is characterized by: the vitamin includes vitamin B2, vitamin B12 and dimension One of raw element β or a variety of combinations.
8. according to the method described in claim 5, it is characterized by: the microelement includes one of sulphur, nitrogen, phosphorus and potassium Or a variety of combination.
9. according to the method described in claim 1, it is characterized by: the pressing crack construction includes first fracturing reform and repeats to press Split transformation;
Preferably, the bored well period is 1 day to 4 months.
10. the method according to claim 1, wherein the specific steps of the step 4 are as follows:
The row's of returning production is carried out after bored well, collects the sample of production fluid, records target well yield increasing degree, and monitoring is returned Microorganism growth and breeding situation, further accumulate experience for Optimum Fracturing formula of liquid in drain;
Preferably, influence of the monitoring fracturing fluid to the growth and breeding of microorganism need strata pressure and at a temperature of carry out.
CN201811541088.2A 2018-12-17 2018-12-17 Method for improving fracturing effect of dense thick oil by using in-situ microorganisms Active CN109653719B (en)

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