CN109652240B - Low-cooling-gradient cleaning agent for live working and application thereof - Google Patents

Low-cooling-gradient cleaning agent for live working and application thereof Download PDF

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CN109652240B
CN109652240B CN201811531581.6A CN201811531581A CN109652240B CN 109652240 B CN109652240 B CN 109652240B CN 201811531581 A CN201811531581 A CN 201811531581A CN 109652240 B CN109652240 B CN 109652240B
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parts
cleaning agent
low
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CN109652240A (en
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刘佶鑫
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Chongqing Qinghui Energy Saving And Environmental Protection Technology Co ltd
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Chongqing Qinghui Energy Saving And Environmental Protection Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/02Compositions of detergents based essentially on soap on alkali or ammonium soaps
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/90Betaines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/18Hydrocarbons
    • C11D3/181Hydrocarbons linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/24Organic compounds containing halogen
    • C11D3/245Organic compounds containing halogen containing fluorine
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/007Soaps or soap mixtures with well defined chain length
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/24Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/26Organic compounds, e.g. vitamins containing oxygen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/28Organic compounds, e.g. vitamins containing halogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/20Industrial or commercial equipment, e.g. reactors, tubes or engines

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention belongs to the technical field of cleaning agents, and particularly relates to a live working cleaning agent with low cooling gradient and application thereof. The cleaning agent for operation with points comprises the following components in parts by weight: 20-30 parts of dichloromethane, 10-005 parts of HFE 71005, 4-6 parts of tetrachloroethylene, 10-13 parts of C11-C17 high-boiling alkane, 20-25 parts of ODS substitute, 1-2.5 parts of stabilizer and 5-7 parts of surfactant. The hot-line work cleaning agent has the characteristic of low cooling gradient, avoids 'condensed water' and 'ice crystal field effect' caused by high cooling gradient, reduces the phenomena of short circuit, board burning and corrosion of a circuit, has the characteristics of high insulation, non-burning and environmental protection, and can deeply clean an electric power system.

Description

Low-cooling-gradient cleaning agent for live working and application thereof
Technical Field
The invention belongs to the technical field of cleaning agents, and particularly relates to a live working cleaning agent with low cooling gradient and application thereof.
Background
In the long-term continuous operation process of the electric power equipment, due to various comprehensive pollutants such as dust, salt, oil and the like floating in the atmosphere and water films with electrolytes such as salt and the like dissolved in the water films formed by condensation, the serious pollution of the electric power equipment is caused by the adsorption action of machinery, the adsorption action of intermolecular force and the adsorption action of electrostatic force, so that the heat dissipation capacity of the precise electronic equipment is reduced, and the operation quality and the reliability of the precise electronic equipment are influenced. These contaminants also contribute to the "microcircuit effect" and "corrosion inhibition" of the circuitry within the device. The fault rates of the electrical equipment, such as the error rate, the obstacle rate, the failure rate and the like, are increased to different degrees. Therefore, it is necessary to regularly perform cleaning and maintenance on the electric power equipment which is continuously operated for a long period of time.
The cleaning agent for live working is initiated in 90 s of 20 th century in China, is mainly applied to online maintenance of communication equipment such as a program controlled switch and the like, and is gradually popularized and applied in the field of electric power in 2000 years. The cleaning agent is high-insulation, non-combustible, volatile and environment-friendly, and special tools and instruments such as a high-voltage-resistant insulation cleaning spray gun are used.
Because the cleaning agent can take away a large amount of heat when volatilizing, the 'condensed water' and the 'ice crystal field effect' are easily generated, the 'condensed water' and the 'ice crystal field effect' are different states of water deposited on a circuit, and the water is combined with salt, alkali and acid in 'harmful substances' deposited on the circuit and soluble acidic and alkaline oxides to form a 'strong and weak electrolyte solution' conductor, thereby easily causing short circuit, breakdown (board burning) and strong corrosion action of the circuit. The cooling gradient, the boiling point and the latent heat of evaporation affect the cooling gradient together, and when the cooling gradient is too large, the electronic element with a smaller expansion coefficient is broken, the strength and the electrical property of the material of the electronic element are changed, and an unknown communication fault or a major accident is caused.
Therefore, in summary, the present invention provides a cleaning agent for hot-line work, which can reduce the temperature gradient.
Disclosure of Invention
Accordingly, one objective of the present invention is to provide a low-temperature gradient cleaner for hot-line work, which has a low temperature gradient and prevents the occurrence of "condensed water" and "ice crystal field effect".
In order to achieve the purpose, the invention adopts the following scheme:
a low-cooling-gradient cleaner for live working comprises the following components in parts by weight: 20-30 parts of dichloromethane, 5-10 parts of HFE7100 (methoxy nonafluorobutane), 4-6 parts of tetrachloroethylene, 10-13 parts of C11-C17 high-boiling alkane, 20-25 parts of ODS substitute, 1-2.5 parts of stabilizer and 5-7 parts of surfactant.
Preferably, the cleaning agent comprises the following components in parts by weight: 25 parts of dichloromethane, 71007 parts of HFE, 4 parts of tetrachloroethylene, 10 parts of C11-C17 high-boiling alkane, 20 parts of ODS substitute, 1.5 parts of stabilizer and 5 parts of surfactant.
Further, the ODS substitute is one or more of propane, perfluoropropane, HFC-365 mfc.
The ODS substance is actually the eliminated ozone-depleting substance specified in the Montreal protocol, and contains five kinds of chlorofluorocarbons such as CFC-11, CFC-12, CFC-113, CFC-114 and CFC-115, and the affected industries comprise electron optical cleaning agents, air conditioners, foaming agents, spraying agents, fire extinguishers, etc. Among 94 ODS substances, there are 10 that are currently mainly produced and used in our country: CFC-11, CFC-12, CFC-113, Halon-1301, carbon tetrachloride, 1,1, 1-trichloroethylene, HCFC-22, HCFC-141b, HFCC-142b and methyl bromide. Among them, trichloroethylene is widely used in the industry of industrial cleaning agents, and many cleaning agents for cleaning metal parts contain trichloroethylene, and moreover, the long-term use of the trichloroethylene can also produce paralysis on the central nervous system. Can be used for treating liver, kidney, heart, and trigeminal nerve injury.
The cleaning agent used as an environment-friendly dotted cleaning agent does not contain ODS (ozone depleting substance), does not contain a phosphate auxiliary agent, and is easy to degrade.
Preferably, the stabilizer is a foam stabilizer.
Preferably, the surfactant is an artificially synthesized surfactant.
The cleaning agent with low surface tension can penetrate into the tiny gaps of the cleaned object, and the effects of deep cleaning and thorough cleaning are achieved. Meanwhile, the surface tension is high or low, and the drainage of the cleaning agent is not good.
Further, the artificial synthetic surfactant is one or more of sodium stearate, sodium octadecyl sulfate and alkyl dimethyl betaine.
The invention also aims to provide an application of the cleaning agent, in particular an application of the cleaning agent for the hot-line work with low cooling gradient in the process of reducing the cooling gradient.
The invention also aims to provide another application of the cleaning agent, in particular to an application of the cleaning agent for the hot-line work with low cooling gradient in the hot-line cleaning work.
In addition, some charged detergents can meet the requirement of cleaning, but contain CFC-113, which is an ozone-depleting substance that is banned by environmental program administration of United nations, and can destroy the ecological environment and bring serious harm to human beings and other living beings in the world.
The invention has the beneficial effects that:
1) the hot-line work cleaning agent with low cooling gradient provided by the invention has the characteristic of low cooling gradient, and avoids 'condensed water' and 'ice crystal field effect' caused by high cooling gradient, thereby reducing the phenomena of short circuit, plate burning and corrosion of a circuit;
2) the hot-line work cleaning agent has the characteristics of high insulation, no combustion and environmental protection;
3) the hot-line work cleaning agent belongs to a low surface tension cleaning agent, can deeply clean an electric power system and electric power facility equipment, and has good drainage property.
Detailed Description
The examples are given for the purpose of better illustration of the invention, but the invention is not limited to the examples. Therefore, those skilled in the art should make insubstantial modifications and adaptations to the embodiments of the present invention in light of the above teachings and remain within the scope of the invention.
Example 1
Hot-line work cleaning agent with low cooling gradient
A low-cooling-gradient cleaner for live working comprises the following components in parts by weight: 30 parts of dichloromethane, 6 parts of HFE 710010 parts of tetrachloroethylene, 13 parts of C11-C17 high-boiling alkane, 2.5 parts of propane-HCF-2225 parts of foam stabilizer and 7 parts of sodium stearate.
Example 2
Hot-line work cleaning agent with low cooling gradient
A low-cooling-gradient cleaner for live working comprises the following components in parts by weight: 25 parts of dichloromethane, 71007 parts of HFE, 4 parts of tetrachloroethylene, 10 parts of C11-C17 high-boiling-point alkane, 20 parts of HFC-365mfc, 1.5 parts of foam stabilizer and 5 parts of sodium octadecyl sulfate.
Example 3
Hot-line work cleaning agent with low cooling gradient
A low-cooling-gradient cleaner for live working comprises the following components in parts by weight: 20 parts of dichloromethane, 71005 parts of HFE, 4 parts of tetrachloroethylene, 10 parts of C11-C17 high-boiling alkane, 0 part of perfluoropropane-HCF-2220 part, 1 part of foam stabilizer and 5 parts of alkyl dimethyl betaine.
Example 4
Performance research of hot-line work cleaning agent with low cooling gradient
The performance indexes of the low cooling gradient hot-line work cleaning agent in the embodiments 1 to 3 are shown in table one, which indicates that the hot-line work cleaning agent has good insulation property, low surface tension, proper boiling point, low latent heat increase, environmental friendliness, no corrosion to relevant elements of an electric power system, and high relative density, and ensures that the cleaning agent can be well discharged.
TABLE 1 Performance study of a Low temperature gradient Hot-line Cleaner
Figure BDA0001905772570000051
Example 5
Low-cooling-gradient live-line work cleaning agent practical application research
The charged cleaning agents of examples 1-3 were used for high voltage charging cleaning, and the cleaning effect, and related performance, were recorded.
As a result: through 3 times of cleaning, no combustion phenomenon exists in the cleaning, the insulation performance is good, no corrosion trace exists, no condensed water and ice crystal field effect exists, finally, the dirt is basically removed, and the cleaning is as new after the cleaning.
Finally, the above embodiments are only for illustrating the technical solutions of the present invention and not for limiting, although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made to the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, and all of them should be covered in the claims of the present invention.

Claims (3)

1. The low-cooling-gradient cleaning agent for live working is characterized by comprising the following components in parts by weight: 20-30 parts of dichloromethane, 4-6 parts of HFE 71005, 4-6 parts of tetrachloroethylene, 10-13 parts of C11-C17 high boiling point alkane, 20-25 parts of ODS substitute, 1-2.5 parts of foam stabilizer and 5-7 parts of synthetic surfactant;
the artificial synthetic surfactant is one or more of sodium stearate, sodium octadecyl sulfate and alkyl dimethyl betaine, and the ODS substitute is one or more of propane, perfluoropropane, HFC-365mfc and HCF-22.
2. The cleaning agent according to claim 1, wherein the cleaning agent comprises the following components in parts by weight: 25 parts of dichloromethane, 71007 parts of HFE, 4 parts of tetrachloroethylene, 10 parts of C11-C17 high-boiling-point alkane, 20 parts of ODS substitute, 1.5 parts of foam stabilizer and 5 parts of synthetic surfactant.
3. Use of the cleaning agent according to claims 1-2 in an electrified cleaning operation.
CN201811531581.6A 2018-12-14 2018-12-14 Low-cooling-gradient cleaning agent for live working and application thereof Active CN109652240B (en)

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Publication number Priority date Publication date Assignee Title
CN110628524B (en) * 2019-10-10 2021-03-23 江苏电卫能源科技有限公司 Composite cleaning agent for electrified insulating equipment

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1417315A (en) * 2001-10-31 2003-05-14 广州南沙经济技术开发区高奇环保技术有限公司 Live cleaning agent for high-voltage electric power equipment
CN101538511A (en) * 2009-03-11 2009-09-23 上海九盛实业有限公司 Decarburization cleaner

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1417315A (en) * 2001-10-31 2003-05-14 广州南沙经济技术开发区高奇环保技术有限公司 Live cleaning agent for high-voltage electric power equipment
CN101538511A (en) * 2009-03-11 2009-09-23 上海九盛实业有限公司 Decarburization cleaner

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
《ODS清洗替代技术为清洗行业带来的机遇和挑战》;唐艳冬等;《清洗世界》;20070930;第23卷(第9期);32-37 *

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