CN109652240A - A kind of livewire work detergent of low falling temperature gradient and its application - Google Patents

A kind of livewire work detergent of low falling temperature gradient and its application Download PDF

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Publication number
CN109652240A
CN109652240A CN201811531581.6A CN201811531581A CN109652240A CN 109652240 A CN109652240 A CN 109652240A CN 201811531581 A CN201811531581 A CN 201811531581A CN 109652240 A CN109652240 A CN 109652240A
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CN
China
Prior art keywords
parts
detergent
temperature gradient
falling temperature
livewire work
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Application number
CN201811531581.6A
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Chinese (zh)
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CN109652240B (en
Inventor
刘佶鑫
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Chongqing Qing Hui Energy-Saving Environmental Protection Technology Co Ltd
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Chongqing Qing Hui Energy-Saving Environmental Protection Technology Co Ltd
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Publication of CN109652240A publication Critical patent/CN109652240A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/02Compositions of detergents based essentially on soap on alkali or ammonium soaps
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/90Betaines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/18Hydrocarbons
    • C11D3/181Hydrocarbons linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/24Organic compounds containing halogen
    • C11D3/245Organic compounds containing halogen containing fluorine
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/007Soaps or soap mixtures with well defined chain length
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/24Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/26Organic compounds, e.g. vitamins containing oxygen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/28Organic compounds, e.g. vitamins containing halogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/20Industrial or commercial equipment, e.g. reactors, tubes or engines

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention belongs to detergent technical fields, and in particular to a kind of livewire work detergent of low falling temperature gradient and its application.The band point operation detergent includes following component by weight: 20-30 parts of methylene chloride, 5-10 parts of HFE7100,4-6 parts of tetrachloro-ethylene, C11~C17 5-7 parts of 1-2.5 parts of 20-25 parts of 10-13 parts of high boiling alkane, ODS substitute, stabilizer, surfactant.The livewire work detergent has the characteristics that low falling temperature gradient, avoid " condensate " and " ice crystal field-effect " occur because of high falling temperature gradient, to reduce short circuit, burn plate, corrosion phenomenon, there is high insulation, do not burn and the characteristic of environmental protection, deep clean can be carried out to electric system.

Description

A kind of livewire work detergent of low falling temperature gradient and its application
Technical field
The invention belongs to detergent technical fields, and in particular to a kind of livewire work detergent of low falling temperature gradient and its answer With.
Background technique
Electric apparatus equipment is during long-term continuous operation, because of various dust and dirt, salinity, the greasy dirt etc. floated in atmosphere Comprehensive pollution object, and because condensation forms the moisture film dissolved with electrolyte such as salinities, pass through mechanical suction-operated, molecular separating force Suction-operated and electrostatic force suction-operated and cause the serious pollution of electric apparatus equipment, make dissipating for sophisticated electronics Thermal energy power decline, influences its running quality and reliability.These pollutants also form additional " micro- electricity to the circuit inside equipment Road effect " and " slow corrosion " effect.The failures such as the different degrees of bit error rate for causing electric apparatus equipment, obstacle rate and crash rate The raising of rate.Therefore, it is necessary to which the electric apparatus equipment to long-term continuous operation periodically carries out cleaning.
Livewire work detergent is originated in the 1990s in China, starts to be mainly used in the communication such as programme-controlled exchange The on-line maintenance of equipment has gradually been widely applied in power domain since 2000.It is using high insulation, does not burn, easily Volatilization, environment-friendly cleaning agent, using the professional tools such as high pressure resistant insulation cleaning spray gun and instrument, it is to be insulated using height, is non-ignitable It burns, volatile, environment-friendly cleaning agent, uses the professional tools such as high pressure resistant insulation cleaning spray gun and instrument, high and low voltage switchgear, control Cabinet processed, video monitoring system, computer automatic protection system, generating set, motor carry out depth cleaning.
Due to detergent volatilization when can take away a large amount of heat, easily appearance " condensate " and " ice crystal field-effect " is " solidifying Water " and " ice crystal field-effect " are all the different conditions that water is deposited on circuit, and water is with being deposited on circuit in " harmful substance " Salt, alkali, acid and soluble acid, basic anhydride combine and just form " strong, weak electricity electrolyte solution " conductor, to easily cause Short circuit, breakdown (burning plate) and strong corrosiveness.And falling temperature gradient and boiling point, evaporation latent heat joint effect cooling ladder Degree, will cause the lesser electronic component of the coefficient of expansion and ruptures, and cause electronic component material when falling temperature gradient is excessive Intensity and electrical property change, and unknown communication failure or major accident is caused to occur.
Therefore, to sum up reason, the invention proposes the detergents that one kind can reduce the livewire work of falling temperature gradient.
Summary of the invention
In view of this, one of the objects of the present invention is to provide a kind of livewire work detergent of low falling temperature gradient, it should Detergent has lower falling temperature gradient, prevents " condensate " and " ice crystal field-effect ".
To achieve the above object, the present invention uses following scheme:
A kind of livewire work detergent of low falling temperature gradient includes following component: methylene chloride 20-30 by weight Part, 5-10 parts of HFE7100 (MSX 4518), 4-6 parts of tetrachloro-ethylene, C11~C17 10-13 parts of high boiling alkane, 20-25 parts of ODS substitute, 1-2.5 parts of stabilizer, 5-7 parts of surfactant.
Preferably, the detergent includes following component by weight: 25 parts of methylene chloride, 7 parts of HFE7100, tetrachloro 5 parts of 1.5 parts of 20 parts of 10 parts of high boiling alkane, ODS substitute, stabilizer, the surfactant of 4 parts of ethylene, C11~C17.
Further, the ODS substitute be propane, perfluoropropane, HFC-365mfc, one of or it is a variety of.
So-called ODS substance refers to the ozone layer depletion object to be eliminated of " Montreal Protocol book " defined in fact Matter, wherein containing five chlorofluorocarbons such as CFC-11, CFC-12, CFC-113, CFC-114, CFC-115, the row influenced Industry includes electron-optical cleaning agent, air conditioner, foaming agent, spray, fire extinguisher ... etc..In 94 kinds of ODS substances, I What state mainly produced and used at present has 10 kinds, they are: CFC-11, CFC-12, CFC-113, Ha Long -1301, carbon tetrachloride, 1,1,1- trichloro ethylene, HCFC-22, HCFC-141b, HFCC-142b and methyl bromide.Wherein trichloro ethylene is largely applied to Among industrial cleaning agent industry, many all contains trichloro ethylene in the cleaning agent for cleaning metal parts, furthermore makes for a long time It can also the generation paralysis effect of Central nervous system with trichloro ethylene.Liver, kidney, heart, trigeminal neuralgia can be damaged.
Band point detergent as environmental protection does not contain ODS centainly, does not contain phosphate builder, and should be easy to degrade, this The detergent of invention is just environment-friendly type detergent, environmentally friendly while protecting that detergent operating personnel's is healthy and safe.
Preferably, the stabilizer is foam stabiliser.
Preferably, the surfactant is artificially synthesised surfactant.
The low cleaning agent of surface tension can be just deep into the tiny gap of cleaned object, obtained depth and cleaned, is thorough The clean effect in bottom.Surface tension height is also concerning the drainage good or not of cleaning agent simultaneously.
Further, the artificially synthesised surfactant is odium stearate, sodium stearyl sulfate and alkyl dimethyl sweet tea One of dish alkali is a variety of.
The second object of the present invention is to provide a kind of application of detergent, a kind of specially described sinking temperature ladder Application of the livewire work detergent of degree during reducing cleaning in falling temperature gradient.
The third object of the present invention is that the another kind for providing a kind of detergent is applied, and the specially described one kind is low Application of the livewire work detergent of falling temperature gradient in electrification cleaning operation.
In addition, also some electrification detergents are able to satisfy clean requirement, but wherein contain CFC-113, such substance is The substance of ozone layer depletion, is disabled by United Nations Environment Programme, and this substance can destroy ecological environment, to the mankind and its Other biological in the world brings serious harm.
The beneficial effects of the present invention are:
1) a kind of livewire work detergent of low falling temperature gradient provided by the invention has the characteristics that low falling temperature gradient, avoids Because " condensate " and " ice crystal field-effect " occurs in high falling temperature gradient, to reduce short circuit, burn plate, corrosion phenomenon;
2) livewire work detergent of the invention has high insulation, does not burn and the characteristic of environmental protection;
3) livewire work detergent of the invention belongs to low surface tension detergent, can set to electric system, electric power facility The standby cleaning for carrying out depth, and drainage is good.
Specific embodiment
Illustrated embodiment is in order to which preferably the present invention will be described, but is not that the contents of the present invention are limited only to institute For embodiment.So those skilled in the art according to foregoing invention content to embodiment carry out it is nonessential improvement and Adjustment, still falls within protection scope of the present invention.
Embodiment 1
A kind of livewire work detergent of low falling temperature gradient
A kind of livewire work detergent of low falling temperature gradient includes following component by weight: 30 parts of methylene chloride, 10 parts of HFE7100,6 parts of tetrachloro-ethylene, C11~C17 25 parts of 13 parts of high boiling alkane, propane-HCF-22, foam stabiliser 2.5 parts, 7 parts of odium stearate.
Embodiment 2
A kind of livewire work detergent of low falling temperature gradient
A kind of livewire work detergent of low falling temperature gradient includes following component by weight: 25 parts of methylene chloride, 7 parts of HFE7100,4 parts of tetrachloro-ethylene, C11~C17 20 parts of 10 parts of high boiling alkane, HFC-365mfc, foam stabiliser 1.5 parts, 5 parts of sodium stearyl sulfate.
Embodiment 3
A kind of livewire work detergent of low falling temperature gradient
A kind of livewire work detergent of low falling temperature gradient includes following component by weight: 20 parts of methylene chloride, 5 parts of HFE7100,4 parts of tetrachloro-ethylene, 20 parts of 10 parts of high boiling alkane, perfluoropropane-HCF-22, the foam of C11~C17 are steady Determine 1 part of agent, 5 parts of alkyl dimethyl betaine.
Embodiment 4
A kind of performance study of the livewire work detergent of low falling temperature gradient
The performance indicator of the livewire work detergent of low falling temperature gradient described in embodiment 1-3 is as shown in Table 1, illustrates institute The insulating properties for stating livewire work detergent is good, and surface tension is lower, boiling point be suitable for, additional issue latent heat it is lower, it is environmentally friendly and Do not corrode electric system related elements, relative density also with higher ensure that detergent can be very good to be discharged, to sum up, A kind of livewire work detergent of low falling temperature gradient is a kind of good band point operation detergent, can be very good to apply Into the cleaning to electric power facility equipment.
A kind of performance study of the livewire work detergent of low falling temperature gradient of table 1.
Embodiment 5
A kind of livewire work detergent real application research of low falling temperature gradient
The electrification detergent in embodiment 1-3 is used for electrification in high voltage cleaning, records cleaning effect and correlation Energy.
As a result: by 3 cleanings, without combustion phenomena, good insulating, corrosion-free trace, no condensate and ice crystal in cleaning Field-effect, and last dirt is removed substantially, it is clean as new after cleaning.
Finally, it is stated that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although referring to compared with Good embodiment describes the invention in detail, those skilled in the art should understand that, it can be to skill of the invention Art scheme is modified or replaced equivalently, and without departing from the objective and range of technical solution of the present invention, should all be covered at this In the scope of the claims of invention.

Claims (7)

1. a kind of livewire work detergent of low falling temperature gradient, which is characterized in that the detergent includes following by weight Component: 20-30 parts of methylene chloride, 5-10 parts of HFE7100,4-6 parts of tetrachloro-ethylene, C11~C17 high boiling alkane 10-13 Part, 20-25 parts of ODS substitute, 1-2.5 parts of stabilizer, 5-7 parts of surfactant.
2. detergent according to claim 1, which is characterized in that the detergent includes following component by weight: 25 parts of methylene chloride, 7 parts of HFE7100,4 parts of tetrachloro-ethylene, C11~C17 20 parts of 10 parts of high boiling alkane, ODS substitute, 1.5 parts of stabilizer, 5 parts of surfactant.
3. detergent according to claim 1, which is characterized in that the ODS substitute is propane, perfluoropropane, HFC- One of 365mfc, HCF-22 or a variety of.
4. detergent according to claim 1, which is characterized in that the stabilizer is foam stabiliser.
5. detergent according to claim 1, which is characterized in that the surfactant is artificial synthetic surface activity Agent.
6. detergent according to claim 5, which is characterized in that the artificially synthesised surfactant be odium stearate, One of sodium stearyl sulfate and alkyl dimethyl betaine are a variety of.
7. application of the detergent described in claim 1-6 in electrification cleaning operation.
CN201811531581.6A 2018-12-14 2018-12-14 Low-cooling-gradient cleaning agent for live working and application thereof Active CN109652240B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110628524A (en) * 2019-10-10 2019-12-31 江苏电卫能源科技有限公司 Composite cleaning agent for electrified insulating equipment

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1417315A (en) * 2001-10-31 2003-05-14 广州南沙经济技术开发区高奇环保技术有限公司 Live cleaning agent for high-voltage electric power equipment
CN101538511A (en) * 2009-03-11 2009-09-23 上海九盛实业有限公司 Decarburization cleaner

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1417315A (en) * 2001-10-31 2003-05-14 广州南沙经济技术开发区高奇环保技术有限公司 Live cleaning agent for high-voltage electric power equipment
CN101538511A (en) * 2009-03-11 2009-09-23 上海九盛实业有限公司 Decarburization cleaner

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
唐艳冬等: "《ODS清洗替代技术为清洗行业带来的机遇和挑战》", 《清洗世界》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110628524A (en) * 2019-10-10 2019-12-31 江苏电卫能源科技有限公司 Composite cleaning agent for electrified insulating equipment

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